氧化还原、改变受体调节二茂铁类配合物的非线性光学性质
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- 英文论文题名：Redox-switchable second order nonlinear optics property of the ferrocene-based complexes: properties controlled by acceptors
- 论文作者：仇永清 ; 王文勇 ; 王丽 ; 方新燕 ; 朱长利
- 英文论文作者：Yong-Qing Qiu ; Wen-Yong Wang ; Li Wang ; Xin-Yan Fang ; Chang-Li Zhu ; Institute of Functional Material Chemistry ; Faculty of Chemistry ; Northeast Normal University
- 年：2016
- 作者机构：东北师范大学化学学院功能材料化学研究所;
- 论文关键词：夹心二茂铁 ; 层间电荷转移 ; 分子开关 ; 非线性光学
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第十八分会：电子结构理论方法的发展与应用
- 语种：中文
- 分类号：O641.4
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第十八分会 ; 电子结构理论方法的发展与应用
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：121k
- 原文格式：D
- 会议级别：全国
摘要
夹心型金属配合物在分子识别、催化、光学和生物传感器等领域有潜在应用。作为一种最重要的夹心型金属配合物,二茂铁因其独特的性质和热化学稳定性被广泛应用于非线性光学领域。我们研究了系列二茂铁衍生物受体基团的作用。结果表明,增加受体吸电子能力可导致第一超极化率值显著增强且分子开关效应明显。这主要由于二茂铁到受体基团的电荷转移混合着受体基团层与层之间的电荷转移。
Sandwich-type metal complexes have shown a potential application in the field of molecular recognition, catalysis, optics and biological sensors.As one of the most important sandwich-type metal complexes, ferrocene with its unique property and high thermal and chemical stability has been widely applied in the field of nonlinear optics(NLO).We investigated a series of ferrocene derivatives, which is composed of varied acceptors.Results show that increasing the ability of acceptor can cause a significant enhancement in first hyperpolarizability and result in the molecular switching with large NLO contrast.The increase of the first hyperpolarizabilities for these ferrocene derivatives are mainly of ferrocene to acceptor charge transfer and the mixture of intramolecular charge transfer within the respective acceptors coupled with interlayer charge transfer between two acceptors.
Sandwich-type metal complexes have shown a potential application in the field of molecular recognition, catalysis, optics and biological sensors.As one of the most important sandwich-type metal complexes, ferrocene with its unique property and high thermal and chemical stability has been widely applied in the field of nonlinear optics(NLO).We investigated a series of ferrocene derivatives, which is composed of varied acceptors.Results show that increasing the ability of acceptor can cause a significant enhancement in first hyperpolarizability and result in the molecular switching with large NLO contrast.The increase of the first hyperpolarizabilities for these ferrocene derivatives are mainly of ferrocene to acceptor charge transfer and the mixture of intramolecular charge transfer within the respective acceptors coupled with interlayer charge transfer between two acceptors.
引文
[1]Wang,W.Y.;Ma,N.N.;Sun,S.L.;Qiu,Y.Q.Phys.Chem.Chem.Phys.2014,16:4900.
[2]Kealy,T.J.;Pauson,P.L.Nature 1951,168:1039.
[2]Kealy,T.J.;Pauson,P.L.Nature 1951,168:1039.