含铜类水滑石催化Glaser反应的性能研究
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- 英文论文题名：Study on the performance of layered double hydroxides in Glaser reaction
- 论文作者：王丽丽 ; 包永胜 ; 贾美林
- 英文论文作者：Lili Wang ; Yongsheng Bao ; Meilin Jia ; College of Chemistry and Environmental Science ; Inner Mongolia Key Laboratory of Green Catalysis ; Inner Mongolia Normal University
- 年：2016
- 作者机构：内蒙古师范大学化学与环境科学学院内蒙古自治区绿色催化重点实验室;
- 论文关键词：水滑石 ; 二炔类化合物
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十七分会：纳米催化
- 语种：中文
- 分类号：O643.36
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十七分会 ; 纳米催化
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：188k
- 原文格式：D
- 会议级别：全国
摘要
水滑石类阴离子黏土(Layered double hydroxides)是一种重要的层状无机材料。由于独特的结构特性,表面酸碱性和阴阳离子可调变等特性,使其在催化领域被广泛应用。我们研究了含铜类水滑石催化苯乙炔自身偶联反应生成二乙炔类聚合物。本研究利用水滑石类化合物的碱性以及催化性能,通过共沉淀方法制备铜镁铝类水滑石,并考察了其在苯乙炔自身偶联反应中的催化性能。研究发现,3Mg-Al-LDH类水滑石对催化Glaser反应没有活性,而Cu-2Mg-LDH表现出一定的催化活性,在该催化剂的催化下,苯乙炔的转化率可达51%,1,4-二苯基-1,3-丁二炔的选择性为100%。Cu-Mg-LDH类水滑石作为一种廉价的催化剂,在低温催化有机合成领域具有广泛的应用前景。
LDHs are a class of anion clays, which have attracted interest in the fields of catalysis owing to their unique structural properties like anionic exchange capacity, acid-base property. Symmetrical 1,3-diynes and their derivatives are useful motifs for the construction of complex molecules, which received great attention. In this research, co-precipitation method was utilized for the preparation of Cu-2Mg-Al-LDH catalysts. The activity of catalysts were carried out in Glaser reaction, and the results showed Cu-2Mg-Al-LDH performed excellent.
LDHs are a class of anion clays, which have attracted interest in the fields of catalysis owing to their unique structural properties like anionic exchange capacity, acid-base property. Symmetrical 1,3-diynes and their derivatives are useful motifs for the construction of complex molecules, which received great attention. In this research, co-precipitation method was utilized for the preparation of Cu-2Mg-Al-LDH catalysts. The activity of catalysts were carried out in Glaser reaction, and the results showed Cu-2Mg-Al-LDH performed excellent.
引文
[1]Guo,F.;Li,F.;Chem.Soc.Rev.2014,43:7040.
[2]Sindhu,K.S.;Gopinathan Anilkumar;RSC.Adv.2014,4:27867.
[2]Sindhu,K.S.;Gopinathan Anilkumar;RSC.Adv.2014,4:27867.