氯化苄基喹啉衍生物的高效缓蚀性能研究
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- 英文论文题名：Research on N-Benzylquinolinium Chloride Derivatives and Its Effective Anti-Corrosion Performance
- 论文作者：杨震 ; 战风涛 ; 胡以朋 ; 陈彦飞 ; 肖长林 ; 张婷 ; 吕志凤
- 英文论文作者：YANG Zhen ; ZHAN Feng-tao ; HU Yi-peng ; CHEN Yan-fei ; XIAO Chang-lin ; ZHANG Ting ; LU Zhi-feng ; College of Science ; China University of Petroleum ; College of Chemical Engineering ; China University of Petroleum
- 年：2014
- 作者机构：中国石油大学(华东)理学院;中国石油大学(华东)化学工程学院;
- 论文关键词：酸化缓蚀剂 ; 氯化苄基喹啉 ; 静态失重法
- 英文论文关键词：acidification corrosion inhibitor ; N-Benzylquinolinium chloride ; static weight-loss measurement
- 会议召开时间：2014-07-28
- 会议录名称：第十八届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TG174.42
- 学会代码：ZGHA
- 会议名称：第十八届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国四川成都
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：5
- 文件大小：240k
- 原文格式：O
- 会议级别：全国
摘要
从氯化苄基喹啉合成过程中分离得到一种具有高效缓蚀性能的物质(BQD),用静态失重法研究了其对N80钢的缓蚀性能。结果表明,其加量为0.05%时,于90℃、质量分数为15%盐酸中的腐蚀速率便可降至3.0g·m~2·h~1以下,而纯的氯化苄基喹啉(BQC)在加剂量为1%时,N80钢的腐蚀速率为249.1 g·m~2·h~1。采用元素分析、红外以及液质联机技术对BQD可能的性质及结构进行了探究。
A new kind of substance(BQD) with effective anti-corrosion Performance was separated from the synthesis of N-Benzylquinolinium chloride(BQC) and its anti-corrosion Performance to N80 steel was investigated by static weight loss measurement.The results showed that the corrosive rate of N80 steel at 90℃ in 15%hydrochloric acid was reduced to 3.0g ? m~2 ? h~1 at 0.05%concentration of BQD,while the corrosive rate of N80 steel was 249.1 g ? m~2 ? h~1 at 1%concentration of BQC in 15%hydrochloric acid at 90℃.The possible structure and property of BQD was researched by IR,elemental analysis and LC-MS.
A new kind of substance(BQD) with effective anti-corrosion Performance was separated from the synthesis of N-Benzylquinolinium chloride(BQC) and its anti-corrosion Performance to N80 steel was investigated by static weight loss measurement.The results showed that the corrosive rate of N80 steel at 90℃ in 15%hydrochloric acid was reduced to 3.0g ? m~2 ? h~1 at 0.05%concentration of BQD,while the corrosive rate of N80 steel was 249.1 g ? m~2 ? h~1 at 1%concentration of BQC in 15%hydrochloric acid at 90℃.The possible structure and property of BQD was researched by IR,elemental analysis and LC-MS.
引文
[1]赵福麟.油田化学(第二版)[M].山东东营:中国石油大学出版社,2010,175.
[2]郑家燊.酸化液缓蚀剂的研究和发展[J].油田化学,1988,5(3):234-239.
[3]赵福麟.采油用剂[M].山东东营:石油大学出版社,1997:175.
[4]郑家燊,张琼玖,丁诗键,等.“7701”酸化缓蚀剂的研究[J].华中科技大学学报(自然科学版),1982,10(1):47-56.
[5]刘洁,刘峥,陈世亮.石油生产中腐蚀的原因及缓蚀剂的应用[J].腐蚀与防护,2012,33(8):657-663.
[6]BECKER K W,STRUBELT C E,SULLIVAN S.High temperature corrosion inhibitor;U.S.Patent 4,028,268[P].1977-6-7.
[7]BREZINSKI M M,DESAI B.Method and composition for acidizing subterranean formations utilizing corrosion inhibitor intensifiers:U.S.Patent5,697,443[P].1997-12-16.
[8]FRENIER W W.Methods for preparing quaternary ammonium salts:U.S.Patent 6,118,000[P].2000-9-12.
[9]FRENIER W W.Low hazard corrosion inhibitors and cleaning solutions using quaternary ammonium salts:U.S.Patent 6,521,028[P].2003-2-18.
[10]TREYBIG D S,WILLIAMS D A.Method of inhibiting corrosion of metal equipment which is cleaned with an inorganic acid:U.S.Patent 6,540,943[P].2003-4-1.
[11]SCHMITT G,BEDBUR K.Investigations on structural and electronic effects in acid inhibitors by AC impedance[J].Materials and Corrosion,1985,36(6):273-278.
[12]ZHANG D,LI L,CAO L,et al.Studies of corrosion inhibitors for zinc-manganese batteries:quinoline quaternary ammonium phenolates[J].Corrosion Science,2001,43(9):1627-1636.
[13]王蓉沙,邓皓.季铵盐复合型缓蚀剂的研制[J].油气田环境保护,1996,6(3):14-18.
[14]郑家燊.缓蚀剂的研究现状及其应用第三讲油井酸化缓蚀剂的研究及其应用概况[J].腐蚀与防护,1997,18(3):132-136.
[15]宗鹏.季铵盐型酸化缓蚀剂的合成及其缓蚀机理研究[D].青岛:中国石油大学(华东)硕士学位论文,2008.
[16]蒋平,赵力云,万朝晖,等.喹啉型季铵盐缓蚀性能评价[J].油田化学,2011,28(2):219-223.
[17]李恒娟.高温盐酸缓蚀剂合成及应用研究[D].西安:西安石油大学硕士学位论文,2011.
[2]郑家燊.酸化液缓蚀剂的研究和发展[J].油田化学,1988,5(3):234-239.
[3]赵福麟.采油用剂[M].山东东营:石油大学出版社,1997:175.
[4]郑家燊,张琼玖,丁诗键,等.“7701”酸化缓蚀剂的研究[J].华中科技大学学报(自然科学版),1982,10(1):47-56.
[5]刘洁,刘峥,陈世亮.石油生产中腐蚀的原因及缓蚀剂的应用[J].腐蚀与防护,2012,33(8):657-663.
[6]BECKER K W,STRUBELT C E,SULLIVAN S.High temperature corrosion inhibitor;U.S.Patent 4,028,268[P].1977-6-7.
[7]BREZINSKI M M,DESAI B.Method and composition for acidizing subterranean formations utilizing corrosion inhibitor intensifiers:U.S.Patent5,697,443[P].1997-12-16.
[8]FRENIER W W.Methods for preparing quaternary ammonium salts:U.S.Patent 6,118,000[P].2000-9-12.
[9]FRENIER W W.Low hazard corrosion inhibitors and cleaning solutions using quaternary ammonium salts:U.S.Patent 6,521,028[P].2003-2-18.
[10]TREYBIG D S,WILLIAMS D A.Method of inhibiting corrosion of metal equipment which is cleaned with an inorganic acid:U.S.Patent 6,540,943[P].2003-4-1.
[11]SCHMITT G,BEDBUR K.Investigations on structural and electronic effects in acid inhibitors by AC impedance[J].Materials and Corrosion,1985,36(6):273-278.
[12]ZHANG D,LI L,CAO L,et al.Studies of corrosion inhibitors for zinc-manganese batteries:quinoline quaternary ammonium phenolates[J].Corrosion Science,2001,43(9):1627-1636.
[13]王蓉沙,邓皓.季铵盐复合型缓蚀剂的研制[J].油气田环境保护,1996,6(3):14-18.
[14]郑家燊.缓蚀剂的研究现状及其应用第三讲油井酸化缓蚀剂的研究及其应用概况[J].腐蚀与防护,1997,18(3):132-136.
[15]宗鹏.季铵盐型酸化缓蚀剂的合成及其缓蚀机理研究[D].青岛:中国石油大学(华东)硕士学位论文,2008.
[16]蒋平,赵力云,万朝晖,等.喹啉型季铵盐缓蚀性能评价[J].油田化学,2011,28(2):219-223.
[17]李恒娟.高温盐酸缓蚀剂合成及应用研究[D].西安:西安石油大学硕士学位论文,2011.
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