利用制革污泥制备陶瓷色料
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- 英文论文题名：Preparation of Ceramic Pigment with Tannery Sludge as Raw Material
- 论文作者：杜毅 ; 李中付 ; 陈忠涛 ; 杜民兴
- 英文论文作者：Yi Du ; Zhongfu Li ; Zhongtao Chen ; Minxing Du ; Qilu University of Technology ; School of Materials Science and Engineering
- 年：2016
- 作者机构：齐鲁工业大学材料科学与工程学院;
- 会议召开时间：2016-11-05
- 会议录名称：2016中国硅酸盐学会陶瓷分会学术年会会刊
- 语种：中文
- 分类号：X794;TQ174.45
- 学会代码：EUGQ
- 会议名称：2016中国硅酸盐学会陶瓷分会学术年会
- 会议地点：中国辽宁沈阳
- 主办单位：中国硅酸盐学会陶瓷分会、辽宁省沈阳市法库县政府、辽宁省轻工科学研究院
- 学会名称：中国硅酸盐学会
- 页数：9
- 文件大小：2167k
- 原文格式：O
- 会议级别：全国
摘要
本文主要介绍了以球磨洗涤干燥后的制革污泥残渣作为色料原料,添加少量的化工原料,通过固相烧结法合成黑色和绿色陶瓷色料的工艺方案。探究铬渣加入量以及金属氧化物比例对合成色料性能的影响。通过XRD、SEM、XRF以及测色仪等手段对所制备色料的性能进行表征。结果表明,加入45wt%的铬渣,在1200℃下合成的黑色色料,具有结晶度好,颗粒尺寸分布均匀,晶粒较小,釉面呈色效果好等特点。黄色晶体相(Mg(FeAl)O_4)对合成绿色颜料显色具有影响,可以通过添加Co2O3解决这一问题。随着Co_2O_3用量的增加,色料颜色逐渐由黄绿色向蓝绿色过渡,当Co_2O_3添加量为~2wt%时,色料样品显色与以纯Cr_2O_3为原料制备色料显色相近。该工艺方案绿色环保,对资源循环利用以及经济社会的可持续发展具有重要的意义。
This paper mainly introduces the process to prepare black and green ceramic pigment by solid state sintering method with tannery sludge and other chemical resources as raw material.We studied the dffect of chromium slag and metal oxide ratio on the properties of synthetic pigments.The performance of prepared pigment were characterized by XRD,SEM,XRF and color measurement instrument.The results showed that the black pigment chromium with 45wt%slag added and prepared at 1200 Celsius degree,processed good crystallinity,particle size distribution,smaller grain size,good glaze color.Yellow crystal phase(Mg(FeAl)O_4) has a significant effect on the synthesis of green pigments,which can be solved by the addition of CO_2O_3.With the increase of Co_2O_3,pigment color gradually transformed from yellow green to blue green.When the cobalt content was ~2wt%,the color developed was similar with the color produced from pure Cr_2O_3.This process was environmental and has important significance for the recycling of resources and social development.
This paper mainly introduces the process to prepare black and green ceramic pigment by solid state sintering method with tannery sludge and other chemical resources as raw material.We studied the dffect of chromium slag and metal oxide ratio on the properties of synthetic pigments.The performance of prepared pigment were characterized by XRD,SEM,XRF and color measurement instrument.The results showed that the black pigment chromium with 45wt%slag added and prepared at 1200 Celsius degree,processed good crystallinity,particle size distribution,smaller grain size,good glaze color.Yellow crystal phase(Mg(FeAl)O_4) has a significant effect on the synthesis of green pigments,which can be solved by the addition of CO_2O_3.With the increase of Co_2O_3,pigment color gradually transformed from yellow green to blue green.When the cobalt content was ~2wt%,the color developed was similar with the color produced from pure Cr_2O_3.This process was environmental and has important significance for the recycling of resources and social development.
引文
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[9]董伟霞,包启富,顾幸勇,等.Fe-Cr-Zn-Al系尖晶石棕色料的制备[J].中国陶瓷,2015,51(8):58-61
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[11]Hajjaji W,Seabra M P,Labrincha J A.Evaluation of metal-ions containing sludges in the preparation of black inorganic pigments[J].Journal of hazardous materials,2011,185(2):619-625.
[12]Shen L,Qiao Y,Guo Y,et al.Preparation of nanometer-sized black iron oxide pigment by recycling of blast furnace flue dust[J].Journal of hazardous materials,2010,177(1):495-500.
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[15]Andreola F,Barbieri L,Bondioli F.Agricultural waste in the synthesis of coral ceramic pigment[J].Dyes and Pigments,2012,94(2):207-211.
[16]Hajjaji W,Pullar R C,Zanelli C,et al.Compositional and chromatic properties of strontium hexaferrite as pigment for ceramic bodies and alternative synthesis from wiredrawing sludge[J].Dyes and Pigments,2013,96(3):659-664.
[17]叶昌,夏清,鲁伟明,匡加才.利用铬盐废渣生产陶瓷色料的研究[J].中国陶瓷.2005,41(4):33-36
[18]刘华锋,王慧,曾令可.黑色陶瓷色料的研究现状与展望[J].中国陶瓷工业.2013,20(6):32-34
[19]徐杰,靳映霞,王庆辉,张瑾,刘清菊,吴兴惠.黑色颜料的制备及其性能的研究[J].中国陶瓷,2004,40(2):50-52
[2]W.E.P.Avelar,F.Roma,L.L.Longo,Heavy-Metal Pollution in Basin of Sapucai-Mirim River(Northeast of Sa~o Paulo State,Brazil),by Hide Industry,Revista Arquivos do Institute Biolo'gico,1997,40(1):205-212.
[3]M.M.Taylor,L.F.Cabeza,G.L.Dimaio,E.M.Brown,W.N.Marmer,Processing of leather waste:pilot scale studies on chrome shavings.Part I.Isolation and characterization of protein products and separation of protein products and separation of chrome cake[J],ALCA Journal,1998,93:61-82.
[4]D.Blowes,Tracking hexavalent Cr in groundwater[J],Science,2002,295:2024-2025.
[5]彭静,李玉平,竺保成,等.棕色尖晶石色料的微波合成与呈色性能研究[J].硅酸盐通报,2011,30(3):719-723.
[6]彭静,李玉平,高朋召,等.氧化物含量对电瓷釉用棕色料及釉呈色的影响[J].中国陶瓷,2011,47(6):50-53.
[7]李玉书,刘宁亦,刘延祥,等.棕色尖晶石颜料的合成[J].湖南大学学报:自然科学版,2003,30(2):32-34.
[8]杨柯,刘世杰,汪永清,等.高强度棕色电瓷釉的研制[J].中国陶瓷,2014,2:016.
[9]董伟霞,包启富,顾幸勇,等.Fe-Cr-Zn-Al系尖晶石棕色料的制备[J].中国陶瓷,2015,51(8):58-61
[10]Tanisan B,Turan S.Black ceramic pigments for porcelain tile bodies produced with chromite ores and iron oxide waste[J].Journal of Ceramic Processing Research,2011,12(4):462-467.
[11]Hajjaji W,Seabra M P,Labrincha J A.Evaluation of metal-ions containing sludges in the preparation of black inorganic pigments[J].Journal of hazardous materials,2011,185(2):619-625.
[12]Shen L,Qiao Y,Guo Y,et al.Preparation of nanometer-sized black iron oxide pigment by recycling of blast furnace flue dust[J].Journal of hazardous materials,2010,177(1):495-500.
[13]Prim S R,Folgueras M V,de Lima M A,et al.Synthesis and characterization of hematite pigment obtained from a steel waste industry[J].Journal of hazardous materials,2011,192(3):1307-1313.
[14]Andreola F,Barbieri L,Bondioli F,et al.Synthesis of chromium containing pigments from chromium galvanic sludges[J].Journal of hazardous materials,2008,156(1):466-471.
[15]Andreola F,Barbieri L,Bondioli F.Agricultural waste in the synthesis of coral ceramic pigment[J].Dyes and Pigments,2012,94(2):207-211.
[16]Hajjaji W,Pullar R C,Zanelli C,et al.Compositional and chromatic properties of strontium hexaferrite as pigment for ceramic bodies and alternative synthesis from wiredrawing sludge[J].Dyes and Pigments,2013,96(3):659-664.
[17]叶昌,夏清,鲁伟明,匡加才.利用铬盐废渣生产陶瓷色料的研究[J].中国陶瓷.2005,41(4):33-36
[18]刘华锋,王慧,曾令可.黑色陶瓷色料的研究现状与展望[J].中国陶瓷工业.2013,20(6):32-34
[19]徐杰,靳映霞,王庆辉,张瑾,刘清菊,吴兴惠.黑色颜料的制备及其性能的研究[J].中国陶瓷,2004,40(2):50-52