我国餐厨废物生化处理设施恶臭排放特征分析
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- 英文论文题名：Odor Emission Characteristics from Biochemical Treatment Facilities of Kichen Waste in China
- 论文作者：张妍 ; 王元刚 ; 卢志强 ; 韩萌 ; 商细彬 ; 曹阳 ; 张君
- 英文论文作者：ZHANG Yan ; WANG Yuan-gang ; LU Zhi-qiang ; Han Meng ; SHANG Xi-bin ; CAO Yan ; ZHANG Jun ; State Key Laboratory on Odor Pollution Control ; Tianjin Academy of Environmental Sciences ; Environmental Science and Technology Development Co. ; Ltd.in Tianjin
- 年：2016
- 作者机构：天津市环境保护科学研究院国家环境保护恶臭污染控制重点实验室;天津迪兰奥特环保科技开发有限公司;
- 论文关键词：餐厨垃圾 ; 臭气浓度 ; 阈稀释倍数 ; 典型恶臭物质
- 英文论文关键词：kichen waste ; odor concertration ; threshold of diluted multiples ; typical odorants
- 会议召开时间：2016-11-17
- 会议录名称：第六届全国恶臭污染测试与控制技术研讨会论文集
- 语种：中文
- 分类号：X512
- 学会代码：GJHB
- 会议名称：第六届全国恶臭污染测试与控制技术研讨会
- 会议地点：中国上海
- 主办单位：国家环境保护恶臭污染控制重点实验室
- 学会名称：国家环境保护恶臭污染控制重点实验室
- 页数：13
- 文件大小：904k
- 原文格式：D
- 会议级别：全国
摘要
选择目前国内餐厨废物成功进行资源化处理的代表性城市——西宁、北京和宁波,分别对其处理处置情况进行调研并设置采样点,采用气相色谱-质谱连用(GC/MS)对各企业主要恶臭排放工段的恶臭物质进行定性定量分析,采用三点比较式臭袋法对各企业主要恶臭排放工段的臭气浓度进行测试分析。结果表明,餐厨垃圾生化处理企业的排放物质种类主要为醇、醛、酮、酯的含氧烃类,但对恶臭贡献最大的是含硫化合物,其次是萜烯类物质;综合西宁、宁波和北京的调研及分析结果,可初步考虑餐厨垃圾生化处理设施典型恶臭物质为乙醇、柠檬烯、硫化氢、甲硫醇、甲硫醚、二甲二硫醚、乙醛、乙酸乙酯。
Xining,Ningbo and Beijing were closen as the representative cities about biochemical treatment of kichen waste.The treatment facilities of this cities were investigated and set as the sampling points.The main compositions and the material contents were analyzed by GC/MS,the odor concertration were gotten by the Triangle odor bag method.The results show that oxygenated hydrocarbons including alcohol,aldehyde,ketone,ester were higher than others in the odor gases,however,the largest contribution to odor pollution were sulfocompounds and the 2nd materials were terpenes;According to the research of the three enterprises,ethyl alcohol,limonene,sulfuretted hydrogen,methyl mercaptan,dimethyl sulfide,dimethyl disulfide,acetaldehyde and ethyl acetate were likely to considered as the typical odorants from the biochemical treatment facilities of kichen waste.
Xining,Ningbo and Beijing were closen as the representative cities about biochemical treatment of kichen waste.The treatment facilities of this cities were investigated and set as the sampling points.The main compositions and the material contents were analyzed by GC/MS,the odor concertration were gotten by the Triangle odor bag method.The results show that oxygenated hydrocarbons including alcohol,aldehyde,ketone,ester were higher than others in the odor gases,however,the largest contribution to odor pollution were sulfocompounds and the 2nd materials were terpenes;According to the research of the three enterprises,ethyl alcohol,limonene,sulfuretted hydrogen,methyl mercaptan,dimethyl sulfide,dimethyl disulfide,acetaldehyde and ethyl acetate were likely to considered as the typical odorants from the biochemical treatment facilities of kichen waste.
引文
[1]CJJ 184-2012,餐厨垃圾处理技术规范[S].
[2]Zhu H G,Aaron S,Michel B,et al.Co-production of hydrogen and methane from potato waste using a two-stage anaerobic digestion process[J].Bioresource Technology,2008,99(11):5078-5084.
[3]张红玉,邹克华,杨金兵,等.厨余垃圾堆肥过程中恶臭物质分析[J].环境科学,2012,33(8):2563-2568.
[4]王攀,黄燕冰,袁传胜,等.国内成功运营的餐厨垃圾处理厂臭气排放特征研究[J].环境工程学报,2014,8(2):625-630
[5]胡新军,张敏,余俊峰,等.中国餐厨垃圾处理的现状、问题和对策[J].生态学报,2012,32(14):4575-4584.
[6]Komilis D P,Ham R K,Park J K.Emission of volatile organic compounds during composting of municipal solid wastes[J].Water Research,2004,38(7):1707-1714.
[7]孙杰,王跃思,吴方堃,等.唐山市和北京市夏秋季节大气VOCs组成及浓度变化[J].环境科学,2010,31(7):1438-1443.
[8]Delgado-Rodríguez M,Ruiz-Montoya M,Giraldez I,et al.Effect of aeration rate and moisture content on the emissions of selected VOCs during municipal solid waste composting[J].Journal of Material Cycles and Waste Management,2012,14(4):371-378.
[9]Gutiérrez M C,Chica A F,Martín M A,et al.Compost Pile Monitoring Using Different Approaches:GC–MS,E-nose and Dynamic Olfactometry[J].Waste and Biomass Valorization,2014,5(3):469-479.
[10]Duan Z H,Lu W J,Li D,et al.Temporal variation of trace compound emission on the working surface of a landfill in Beijing,China[J].Atmospheric Environment,2014,88:230-238.
[11]路鹏,苏昭辉,王亘,等.填埋场大气中化合物分析与恶臭指示物筛选[J].环境科学,2011,32(4):936-942.
[12]Orzi V,Cadena E D,Imporzano G,et al.Potential odour emission measurement in organic fraction of municipal solid waste during anaerobic digestion:Relationship with process and biologicalstability parameters[J].Bioresource Technology,2010,101(19):7330–7337.
[13]Scaglia B,Orzi V,Artola A,et al.Odours and volatile organic compounds emitted from municipal solid waste at different stage of decomposition and relationship with biological stability[J].Bioresource Technology,2011,102(7):4638-4645.
[14]Kaeppler K,Mueller F.Odor classification:a review of factors influencing perception-based odor arrangements[J].Chemical senses,2013,38(3):189-209.
[15]Phan N T,Kim K H,Jeon E C,et al.Analysis of volatile organic compounds released during food decaying processes[J].Environmental Monitoring and Assessment,2012,184(3):1683-1692.
[16]Liu J G,Wang X W,Nie X Q,et al.In-situ emission characteristics of odorous gases from two food waste processing plants[J].Journal of Material Cycles and Waste Management,2013.15(4):510-515.
[17]宋剑飞,李灵周,朱洁.西宁、宁波、苏州餐厨垃圾管理及处置模式对比分析与经验借鉴[J].北方环境,2012,27(5):93-97
[18]王磊,李振山,焦安英,等.北京市生活垃圾堆肥设施耗能、排污及影响因素[J].环境科学研究,2013,26(11):1212-1218
[19]张锐.餐厨垃圾转化为生物质能的“宁波模式”与效益评价[D].宁波:宁波大学,2014.17-22.
[20]GB/T 14675-93,空气质量恶臭的测定三点比较式臭袋法[S].
[21]U.S.EPA.EPA/625/R-96/010b.Method TO-15,Determination of volatile organic compounds(VOCs)in air collected in specially-prepared canisters and analyzed by gas chromatography/mass spectrometry(GC-MS)[S].
[22]赵淑莉,谭培功.空气和废气监测分析方法(第四版)[M].北京:中国环境科学出版社,2003.679-682,730-734.
[23]黄丽丽,张妍,商细彬,等.餐厨垃圾两相厌氧发酵产甲烷相恶臭排放规律[J].环境工程学报,2014,8(10):4386-4392.
[24]Nagata Y.Measurement of odor threshold by triangular odor bag method[R].Japan Ministry of the Environment,Tokyo,2003.
[25]包景岭,邹克华,王连生.恶臭环境管理与污染控制[M].北京:中国环境科学出版社,2009.244-246.
[26]赵岩,陆文静,王洪涛,等.城市固体废物处理处置设施恶臭污染评估指标体系研究[J].中国环境科学,2014,34(7):1804-1810.
[27]环境保护部.国家污染物环境健康风险名录[M].北京:中国环境科学出版社,2009.
[28]GB 14554-1993,恶臭污染物排放标准[S].
[2]Zhu H G,Aaron S,Michel B,et al.Co-production of hydrogen and methane from potato waste using a two-stage anaerobic digestion process[J].Bioresource Technology,2008,99(11):5078-5084.
[3]张红玉,邹克华,杨金兵,等.厨余垃圾堆肥过程中恶臭物质分析[J].环境科学,2012,33(8):2563-2568.
[4]王攀,黄燕冰,袁传胜,等.国内成功运营的餐厨垃圾处理厂臭气排放特征研究[J].环境工程学报,2014,8(2):625-630
[5]胡新军,张敏,余俊峰,等.中国餐厨垃圾处理的现状、问题和对策[J].生态学报,2012,32(14):4575-4584.
[6]Komilis D P,Ham R K,Park J K.Emission of volatile organic compounds during composting of municipal solid wastes[J].Water Research,2004,38(7):1707-1714.
[7]孙杰,王跃思,吴方堃,等.唐山市和北京市夏秋季节大气VOCs组成及浓度变化[J].环境科学,2010,31(7):1438-1443.
[8]Delgado-Rodríguez M,Ruiz-Montoya M,Giraldez I,et al.Effect of aeration rate and moisture content on the emissions of selected VOCs during municipal solid waste composting[J].Journal of Material Cycles and Waste Management,2012,14(4):371-378.
[9]Gutiérrez M C,Chica A F,Martín M A,et al.Compost Pile Monitoring Using Different Approaches:GC–MS,E-nose and Dynamic Olfactometry[J].Waste and Biomass Valorization,2014,5(3):469-479.
[10]Duan Z H,Lu W J,Li D,et al.Temporal variation of trace compound emission on the working surface of a landfill in Beijing,China[J].Atmospheric Environment,2014,88:230-238.
[11]路鹏,苏昭辉,王亘,等.填埋场大气中化合物分析与恶臭指示物筛选[J].环境科学,2011,32(4):936-942.
[12]Orzi V,Cadena E D,Imporzano G,et al.Potential odour emission measurement in organic fraction of municipal solid waste during anaerobic digestion:Relationship with process and biologicalstability parameters[J].Bioresource Technology,2010,101(19):7330–7337.
[13]Scaglia B,Orzi V,Artola A,et al.Odours and volatile organic compounds emitted from municipal solid waste at different stage of decomposition and relationship with biological stability[J].Bioresource Technology,2011,102(7):4638-4645.
[14]Kaeppler K,Mueller F.Odor classification:a review of factors influencing perception-based odor arrangements[J].Chemical senses,2013,38(3):189-209.
[15]Phan N T,Kim K H,Jeon E C,et al.Analysis of volatile organic compounds released during food decaying processes[J].Environmental Monitoring and Assessment,2012,184(3):1683-1692.
[16]Liu J G,Wang X W,Nie X Q,et al.In-situ emission characteristics of odorous gases from two food waste processing plants[J].Journal of Material Cycles and Waste Management,2013.15(4):510-515.
[17]宋剑飞,李灵周,朱洁.西宁、宁波、苏州餐厨垃圾管理及处置模式对比分析与经验借鉴[J].北方环境,2012,27(5):93-97
[18]王磊,李振山,焦安英,等.北京市生活垃圾堆肥设施耗能、排污及影响因素[J].环境科学研究,2013,26(11):1212-1218
[19]张锐.餐厨垃圾转化为生物质能的“宁波模式”与效益评价[D].宁波:宁波大学,2014.17-22.
[20]GB/T 14675-93,空气质量恶臭的测定三点比较式臭袋法[S].
[21]U.S.EPA.EPA/625/R-96/010b.Method TO-15,Determination of volatile organic compounds(VOCs)in air collected in specially-prepared canisters and analyzed by gas chromatography/mass spectrometry(GC-MS)[S].
[22]赵淑莉,谭培功.空气和废气监测分析方法(第四版)[M].北京:中国环境科学出版社,2003.679-682,730-734.
[23]黄丽丽,张妍,商细彬,等.餐厨垃圾两相厌氧发酵产甲烷相恶臭排放规律[J].环境工程学报,2014,8(10):4386-4392.
[24]Nagata Y.Measurement of odor threshold by triangular odor bag method[R].Japan Ministry of the Environment,Tokyo,2003.
[25]包景岭,邹克华,王连生.恶臭环境管理与污染控制[M].北京:中国环境科学出版社,2009.244-246.
[26]赵岩,陆文静,王洪涛,等.城市固体废物处理处置设施恶臭污染评估指标体系研究[J].中国环境科学,2014,34(7):1804-1810.
[27]环境保护部.国家污染物环境健康风险名录[M].北京:中国环境科学出版社,2009.
[28]GB 14554-1993,恶臭污染物排放标准[S].