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纳米比亚欢乐谷地区白岗岩型铀矿成矿流体成分与稳定同位素特征
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摘要
本文通过对纳米比亚欢乐谷地区流体包裹体成分和C-H-O稳定同位素的系统研究,厘定了成矿流体的类型及成分,并对该区成矿流体来源及铀的迁移形式进行了初步探讨。研究结果表明,白岗岩型铀矿主成矿期铀主要来源于前达马拉富铀基底,成矿流体阴离子成分以Cl~-、F~-、HCO_3~-和SO_4~(2-)为主,气相成分主要为H_2O和CO_2,铀以铀氧络离子基团(UO_n~(4-2n))和铀的卤化物(UCl_4和UF_4)形式迁移;后期热液主要来自深部流体与大气水的混合,阴离子成分以Cl~-和CO_3~-为主,含少量F~-和SO_4~(2-),气相成分也主要为H_2O和CO_2,铀主要来自之前铀矿物的活化,并以碳酸铀酰络离子(UO_2(CO_3)_2~(2-)和UO_2(CO_3)_3~(4-)迁移。
On the basis of field survey,comparative study of component and C-H-0 stable isotopes geochemistry of fluid inclusions,the authors find out the basic characteristics(temperature,salinity and ingredients etc.) of fluid inclusions of alaskite-type uranium deposit in the Gaudeanmus area,Namibia.And the sources of ore-forming fluids are discussed.The results indicate that uranium mainly comes from the pre-Damaran uranium-rich basement in the main metallogenetic epoch of alaskite-type uranium deposit.Uranium migrates in forms of UO_n~(4-2n),UCl_4 and UF_4.The late hydrothermal fluids are originated from the combination of deep fluids and atmospheric water.Uranium mainly comes from the remobilization of former uranium minerals and is transported in forms of UO_2(CO_3)_2~(2-)and UO_2(CO_3)_3~(4-).
引文
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