巯基-烯点击一锅法制备咪唑基聚合物整体柱及其液相色谱性能研究
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- 英文论文题名：Facile one-pot preparation of a novel imidazolium-based monolith by thiol-ene click chemistry for capillary liquid chromatography
- 论文作者：张鹏 ; 杨海观 ; 苏林静 ; 熊裕豪 ; 叶芳贵
- 英文论文作者：Peng Zhang ; Haiguan Yang ; Linjing Su ; Yuhao Xiong ; Fanggui Ye ; State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources ; College of Chemistry and Pharmaceutical Science ; Guangxi Normal University
- 年：2016
- 作者机构：广西师范大学化学与药学学院省部共建药用资源化学与药物分子工程国家重点实验室;
- 论文关键词：巯基-烯点击化学 ; 一锅法 ; 毛细管整体柱 ; 毛细管液相色谱
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十三分会：复杂样品分离分析
- 语种：中文
- 分类号：O633.5;O657.72
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十三分会 ; 复杂样品分离分析
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：301k
- 原文格式：D
- 会议级别：全国
摘要
基于一种简单快速的方法制备咪唑基聚合物整体柱。实验以1-乙烯基-3-十八烷基咪唑溴盐及乙二醇二甲基丙烯酸酯作单体,季戊四醇四巯基乙酸酯作交联剂,偶氮二异丁腈作引发剂,采用巯基-烯点击反应一锅法快速制备咪唑基聚合物整体柱。选用烷基苯同系物、多环芳烃、苯胺类、苯酚类物质作为分析物,在毛细管液相色谱模式下,对所制备的整体柱的色谱性能进行评价。实验表明,巯基-烯点击反应为制备咪唑基聚合物整体柱提供了一种可靠的方法。
In this study,a novel imidazolium-based hybrid monolith was prepared through a simple route.With1-vinyl-3-octadecylimidazolium bromide and ethylene dimethacrylate as monomers,pentaerythritol tetra-(3-mercaptopropionate) as cross-linker,azodiisobutyronitrile as thermal initiator,the monolith was facilely prepared via a one-pot process based on thiol-ene click chemistry.High-efficiency separation of alkylbenzenes,polycyclic aromatic hydrocarbon,phenols and anilines was achieved.All results indicate that the thiol-ene click chemistry provides a simple route for the preparation of a imidazolium-based monolith.
In this study,a novel imidazolium-based hybrid monolith was prepared through a simple route.With1-vinyl-3-octadecylimidazolium bromide and ethylene dimethacrylate as monomers,pentaerythritol tetra-(3-mercaptopropionate) as cross-linker,azodiisobutyronitrile as thermal initiator,the monolith was facilely prepared via a one-pot process based on thiol-ene click chemistry.High-efficiency separation of alkylbenzenes,polycyclic aromatic hydrocarbon,phenols and anilines was achieved.All results indicate that the thiol-ene click chemistry provides a simple route for the preparation of a imidazolium-based monolith.
引文
[1]M.Wu,R.Wu,F.Wang,L.Ren,J.Dong,Z.Liu,H.Zou,Anal.Chem.,2009,81,3529.
[2]Z.Lin,X.Tan,R.Yu,J.Lin,X.Yin,L.Zhang and H.Yang,J.Chromatogr.A,2014,1355,228-237.
[2]Z.Lin,X.Tan,R.Yu,J.Lin,X.Yin,L.Zhang and H.Yang,J.Chromatogr.A,2014,1355,228-237.