金属配位组装与调控
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摘要
<正>过渡金属配位作用是一种键能较大同时又具有动态特性的特殊非共价作用,通过配位作用进行自组装与调控已得到了应用。我们采用过渡金属配位作用和冠醚主客体化学的协同自组装构筑了多组分索烃、分子项链和能够可逆运动与交联的聚轮烷等机械互锁结构[1,2];采用金属卟啉的配位模板导向法,通过烯烃复分解反应一锅法合成了由柔性链连接的具有复杂
引文
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[5]X.-C.Zhang,Y.-H.Hu,C.-F.Chen,Q.Fang,L.-Y.Yang,Y.-B.Lu,L.-J.Xie,J.Wu,S.Li,W.Fang,Chem.Sci.,2016,7:4594–4599.