绿色轮胎用SSBR/SiO_2复合体系的研究技术进展
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- 论文作者：梁爱民
- 年：2016
- 作者机构：中国石油化工股份有限公司北京化工研究院橡塑新型材料合成国家工程研究中心;
- 论文关键词：绿色轮胎 ; SSBR/SiO_2 ; 改性技术
- 会议召开时间：2016-04-22
- 会议录名称：“科迈杯”第12届全国橡胶助剂生产和应用技术研讨会论文集
- 语种：中文
- 分类号：TQ336.1
- 学会代码：ZGHG
- 会议名称：“科迈杯”第12届全国橡胶助剂生产和应用技术研讨会
- 会议地点：中国浙江温州
- 主办单位：中国化工学会橡胶专业委员会、全国橡胶工业信息中心
- 学会名称：中国化工学会
- 页数：6
- 文件大小：492k
- 原文格式：O
- 会议级别：全国
摘要
针对SSBR/SiO_2复合体系在绿色轮胎领域的应用,从SSBR链末端改性、链中接枝改性以及SiO_2表面改性等方面,总结了近期国内外SSBR/SiO_2复合体系应用的研究现状及技术进展。通过改性技术,实现SSBR与白炭黑配合使用,制备低滚动阻力与高抗湿滑性能兼备的轮胎,是未来的发展方向。采用利于环保,对人体伤害小,而且可以实现工业化连续生产的熔融法来实现SSBR或白炭黑的改性目的,进而提高填料与橡胶间的相互作用,也备受关注。未来白炭黑研究应集中在白炭黑的界面属性及改性方面,以进一步发挥白炭黑作为补强填料的优势。
引文
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[18]Takuo Sone,Takaomi Matsumoto.Process for Producing Conjugated Diolefin(Co)Polymer Rubber,Conjugated Diolefin(Co)Polymer Rubber,Rubber Composition,and Tire[P].USA:USP 7893164B2,2011-02-22.
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[22]Ryouji Tanaka,Masahiro Shibata.Method for Producing Modified Conjugated Diene Rubber,Modified Conjugated Diene Rubber,and Rubber Composition[P].WO 2011049180A1,2011-04-28.
[23]Marechal Jean-Marc,De Landtsheer Stephanie.Functionalized Diene Elastomer and Rubber Composition Containing Same[P].WO2011042507A1.2011-04-14.
[24]王彬,马建华,吴友平.复合材料耐磨性方面的应用[J].合成橡胶工业,2013,36(2):123-126.
[25]佟园园,徐利民,白玉,等.用γ-氯丙基三甲氧基硅烷端基改性星形溶聚丁苯橡胶[J].合成橡胶工业,2011,34(2):111-116.
[26]张师军.李庆.几类重要的反应性高分子应用研究进展[J].化工新型材料,1998.26(9):20-25.
[27]杨金娟,栗晓杰,林青峰,等.溶聚丁苯橡胶接枝MAH的性能研究[J].石油化工高等学校学报,2014,27(2):10-14.
[28]Liangliang Qu,Lijing Wang,Ximing Xie.Contribution of SilicaRubber Interactions on the Viscoelastic Behaviors of Modified Solution Polymerized Styrene Butadiene Rubbers(M-S-SBRs)Filled with Silica[J].The Royal Society of Chemistry,2014,4,64354-64363.
[29]谢续明,李颖,张景存,等.马来酸酐-苯乙烯熔融技枝聚丙烯的影响及其性能研究[J].高分子学报,2002(1):7-12.
[30]Lei Caihong,Li Shanliang,Chen Dahua,et al.Melt Grafting of Maleic Anhydride onto Polypropylene with 1-decene as a Second Monomer[J].Journal of Applied Polymer Science,2011,119(1):102-110.
[31]王卫卫,刘媛,周琦,等.POE-g-MAH及其在增韧尼龙6中的应用[J].现代塑料加工应用,2007,19(6):24-26.
[32]向坤,罗筑,夏忠林,等.GMA熔融接枝丁苯橡胶的研究[J].弹性体,2014,24(5):24-27.
[33]龚湛林,陈福林,肖建平,等.工艺和配方对熔融法制备丁苯橡胶接枝马来酸酐的影响[J].弹性体,2013,23(6):28-31.
[34]邹梦娇.熔融法制备SBR-g-MAH及其对白炭黑填充SBR胶料性能的影响[D].广州:广东工业大学,2013.
[35]Saeoui P,Rakdee C,Thanmathom P.Use of Rice Husk Ash as Filler in Natural Rubber Vulcanizates:in Comparison with Other Commercial Fillers[J].Journal of Applied Polymer Science,2002,83(1):2485-2493.
[36]Peng C C,Gopfert A."Smart"Silica-Rubber Nanocomposites in Virtue of Hydrogen Bonding Interaction[J].Polymers for Advanced Technologies,2005,16(11-12):770-782.
[37]Borum L,Wilson Jr O C.Surface Modification of Hydroxyapatite.Part II.Silica[J].Biomaterials,2003,24(21):3681-3688.
[38]刘朋程,张旭东,何文,等.白炭黑制备、改性及应用研宄[J].山东陶瓷,2009,32(6):19-2I.
[39]王佼.白炭黑制备方法及表面改性研究进展[J].北京工业职业技术学院学报,2005,4(4):48-54.
[40]王君,李芬,吉小利,等.白炭黑制备及其表面改性研究[J].非金属矿,2004,27(2):38-40.
[41]刘全章,赵洪国,胡海华,等.表面改性白炭黑增强溶聚丁苯橡胶的性能[J]_合成橡胶工业,2014,37(2):144-148.
[42]燕鹏华,梁滔.白炭黑改性及其在橡胶中的应用研究进展[J].橡胶科技,2015,13(10):9-13.
[43]Meier J G,Fritzsche J,Guy L,et al.Relaxation Dynamics of Hydration Water at Activated Silica Interfaces in High-performance Elastomer Composites[J].Macromolecules,2009,42(6):2127-2134.
[44]Valentin J L,Mora-Barrantes I,Carretero-Gonzalez J,et al.Novel Experimental Approach to Evaluate Filler-Elastomer Interactions!.!].Macromolecules.2010,43(1):334-346.
[45]Ren H,Qu Y X,Zhao S H.Reinforcement of Styrene-Butadiene Rubber with Silica Modified by Silane Coupling Agents:Experimental and Theoretical Chemistry Study[J].Chinese Journal,Chemical Engineering,2006,14(1):93-98.
[46]Tsubokawa N,Ichioka H,Satoh T,et al.Grafting of"Dendrimerlike"Highly Branched Polymer onto Ultrafine Silica Surface[J].Reactive and Functional Polymers,1998,37(1-3):75-82.
[47]韩晓洁,张东岳,刘亚康,等.白炭黑高官能化改性及其填充SBR性能的研究[J].橡胶工业,2010,57(2):76-81.
[48]张帆,管俊芳,邱鑫强.改性白炭黑对NR/BR/SBR并用橡胶力学性能的影响[J].硅酸盐通报,2015,34(2),585-590.
[49]刘全章,赵洪国,胡海华,表面改性白炭黑增强溶聚丁苯橡胶的性能[J].合成橡胶工业,2014,37(2):144-148.
[50]曲亮靓,解希铭,于国柱,等,橡胶-填料相互作用对丁苯橡胶/白炭黑复合材料性能的影响[J].中国科学,2014,4(11):1723-1732.
[2]文涛.白炭黑补强轮胎胎面胶[J].现代橡胶技术,2009,35(4):6-15.
[3]Gerspacher M,O'Farrell C P,Nikiel L,et al.High Frequency Viscoelasticity of Carbon Black Filled Compounds[J].Rubber Chemistry and Technology,1996,69(5):786-800.
[4]Wang M J.New Developments in Carbon Black Dispersion[J].Kautschuk Gummi Kunststoffe,2005,58(12):626-637.
[5]蒋修治.白炭黑/硅烷填料体系的化学与橡胶补强性[J].橡胶参考资料,2006,36(4):3641-3645.
[6]徐春燕,吴友平,赵素合,等.白炭黑增强偶联型溶聚丁苯橡胶的性能[J].合成橡胶工业,2009,32(3):201-205.
[7]Ueda J,Kamigaito M,Sawamoto M.Calixarene-core Multifunctional Initiators for the Ruthenium-mediated Living Radical Polymerization of Methacrylates[J].Macromolecules,1998,31(20):6762-6768.
[8]胡育林,梁滔,张华强,等.溶聚丁苯橡胶改性技术及国内发展趋势[J].橡胶工业,2011,58(8):505-511.
[9]齐玉霞,溶聚丁苯橡胶改性技术研究进展[J].轮胎工业,2015,35(6):323-327.
[10]上坂宪市,国泽铁也.轮胎用橡胶组合物和充气轮胎[P].中国:CN 102212218,2011-10-12.
[11]Marechal Jean-Marc.Novel Initiation System for the Anionic Polymerization of Conjugated Dienes and Method for Preparing Diene Elastomers[P].USA:USP 20110251354A1,2011-10-13.
[12]Yoon Du Weon,Lee Tae Chul.Bifunctional Organic Lithium Initiator and Conjugate Diene System Copolymer Produced Using Same[P].EU:EP 2336137A2,2011-06-22.
[13]铃木英寿,小泽洋一.改性共轭二烯类聚合物、聚合引发剂及其制备方法和橡胶组合物[P].中国:CN 1961011A,2007-05-09.
[14]Chaboche Philippe,Favrot Jean-Michel.Elastomer Mixture Mainly Comprising a Diene Elastomer Coupled by an Amino Alkoxysilane Group,Rubber Compsition including the Same and Methods for Obtaining Same[P].USA:USP 2011178233A1,2011-07-21.
[15]Junichi Yoshida,Shinichi Sekikawa.Production Method for Modified Conjugated Diene Polymer,Modified Conjugated Diene Polymer and Modified Conjugated Diene Polymer Composition[P].WO 2011040312A1,2011-04-07.
[16]Yamada,Haruo.Conjugated Diene Polymer and Process for Production Thereof[P].USA:USP7915349B2,2011-02-22.
[17]曾根卓男,田中了司.橡胶组合物和充气轮胎[P].中国:CN102348748B,2013-09-04.
[18]Takuo Sone,Takaomi Matsumoto.Process for Producing Conjugated Diolefin(Co)Polymer Rubber,Conjugated Diolefin(Co)Polymer Rubber,Rubber Composition,and Tire[P].USA:USP 7893164B2,2011-02-22.
[19]Takeshi Karato,Takeshi Sugimura.Conjugated Diene Rubber,Rubber Composition,Crosslinked Rubber,Tire and Process for Production of Conjugated Diene Rubber[P].WO 2011105362A1,2011-09-01.
[20]Steinhauser Norbert,Gross Thomas.Functionalized Diene Rubber[P].USA:USP201128001Al,2011-11-17.
[21]Hayano Shigetaka,Sugimura Takeshi.Method of Production of Radial Conjugated Diene Rubber[P].JP2015071777A,2015-04-16.
[22]Ryouji Tanaka,Masahiro Shibata.Method for Producing Modified Conjugated Diene Rubber,Modified Conjugated Diene Rubber,and Rubber Composition[P].WO 2011049180A1,2011-04-28.
[23]Marechal Jean-Marc,De Landtsheer Stephanie.Functionalized Diene Elastomer and Rubber Composition Containing Same[P].WO2011042507A1.2011-04-14.
[24]王彬,马建华,吴友平.复合材料耐磨性方面的应用[J].合成橡胶工业,2013,36(2):123-126.
[25]佟园园,徐利民,白玉,等.用γ-氯丙基三甲氧基硅烷端基改性星形溶聚丁苯橡胶[J].合成橡胶工业,2011,34(2):111-116.
[26]张师军.李庆.几类重要的反应性高分子应用研究进展[J].化工新型材料,1998.26(9):20-25.
[27]杨金娟,栗晓杰,林青峰,等.溶聚丁苯橡胶接枝MAH的性能研究[J].石油化工高等学校学报,2014,27(2):10-14.
[28]Liangliang Qu,Lijing Wang,Ximing Xie.Contribution of SilicaRubber Interactions on the Viscoelastic Behaviors of Modified Solution Polymerized Styrene Butadiene Rubbers(M-S-SBRs)Filled with Silica[J].The Royal Society of Chemistry,2014,4,64354-64363.
[29]谢续明,李颖,张景存,等.马来酸酐-苯乙烯熔融技枝聚丙烯的影响及其性能研究[J].高分子学报,2002(1):7-12.
[30]Lei Caihong,Li Shanliang,Chen Dahua,et al.Melt Grafting of Maleic Anhydride onto Polypropylene with 1-decene as a Second Monomer[J].Journal of Applied Polymer Science,2011,119(1):102-110.
[31]王卫卫,刘媛,周琦,等.POE-g-MAH及其在增韧尼龙6中的应用[J].现代塑料加工应用,2007,19(6):24-26.
[32]向坤,罗筑,夏忠林,等.GMA熔融接枝丁苯橡胶的研究[J].弹性体,2014,24(5):24-27.
[33]龚湛林,陈福林,肖建平,等.工艺和配方对熔融法制备丁苯橡胶接枝马来酸酐的影响[J].弹性体,2013,23(6):28-31.
[34]邹梦娇.熔融法制备SBR-g-MAH及其对白炭黑填充SBR胶料性能的影响[D].广州:广东工业大学,2013.
[35]Saeoui P,Rakdee C,Thanmathom P.Use of Rice Husk Ash as Filler in Natural Rubber Vulcanizates:in Comparison with Other Commercial Fillers[J].Journal of Applied Polymer Science,2002,83(1):2485-2493.
[36]Peng C C,Gopfert A."Smart"Silica-Rubber Nanocomposites in Virtue of Hydrogen Bonding Interaction[J].Polymers for Advanced Technologies,2005,16(11-12):770-782.
[37]Borum L,Wilson Jr O C.Surface Modification of Hydroxyapatite.Part II.Silica[J].Biomaterials,2003,24(21):3681-3688.
[38]刘朋程,张旭东,何文,等.白炭黑制备、改性及应用研宄[J].山东陶瓷,2009,32(6):19-2I.
[39]王佼.白炭黑制备方法及表面改性研究进展[J].北京工业职业技术学院学报,2005,4(4):48-54.
[40]王君,李芬,吉小利,等.白炭黑制备及其表面改性研究[J].非金属矿,2004,27(2):38-40.
[41]刘全章,赵洪国,胡海华,等.表面改性白炭黑增强溶聚丁苯橡胶的性能[J]_合成橡胶工业,2014,37(2):144-148.
[42]燕鹏华,梁滔.白炭黑改性及其在橡胶中的应用研究进展[J].橡胶科技,2015,13(10):9-13.
[43]Meier J G,Fritzsche J,Guy L,et al.Relaxation Dynamics of Hydration Water at Activated Silica Interfaces in High-performance Elastomer Composites[J].Macromolecules,2009,42(6):2127-2134.
[44]Valentin J L,Mora-Barrantes I,Carretero-Gonzalez J,et al.Novel Experimental Approach to Evaluate Filler-Elastomer Interactions!.!].Macromolecules.2010,43(1):334-346.
[45]Ren H,Qu Y X,Zhao S H.Reinforcement of Styrene-Butadiene Rubber with Silica Modified by Silane Coupling Agents:Experimental and Theoretical Chemistry Study[J].Chinese Journal,Chemical Engineering,2006,14(1):93-98.
[46]Tsubokawa N,Ichioka H,Satoh T,et al.Grafting of"Dendrimerlike"Highly Branched Polymer onto Ultrafine Silica Surface[J].Reactive and Functional Polymers,1998,37(1-3):75-82.
[47]韩晓洁,张东岳,刘亚康,等.白炭黑高官能化改性及其填充SBR性能的研究[J].橡胶工业,2010,57(2):76-81.
[48]张帆,管俊芳,邱鑫强.改性白炭黑对NR/BR/SBR并用橡胶力学性能的影响[J].硅酸盐通报,2015,34(2),585-590.
[49]刘全章,赵洪国,胡海华,表面改性白炭黑增强溶聚丁苯橡胶的性能[J].合成橡胶工业,2014,37(2):144-148.
[50]曲亮靓,解希铭,于国柱,等,橡胶-填料相互作用对丁苯橡胶/白炭黑复合材料性能的影响[J].中国科学,2014,4(11):1723-1732.