苯酚废水净化研究进展
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摘要
苯酚废水难降解、毒性强、来源广,直接排放给环境带来不可估量危害。回收苯酚不仅能够节约资源,还可以保护环境,含苯酚废水要严格按照国家排放标准来进行处理。因此,该类废水一直是研究热点。从物理处理法,生物处理法和化学处理法三大层面综述了苯酚废水净化研究进展,又对湿式催化氧化法,超声化学氧化法,电化学氧化法进行了介绍,并展望了综合联用技术将是未来苯酚废水净化的研究趋势,为苯酚废水的净化提供新的思路。
With the hard degradation,strong toxicity and extensive sources,the wastewater of phenol will bring immeasurable harm to our environment if discharged directly. Recycling phenol can not only save resources,but also protect the environment. The wastewater containing phenol should be treated in strict accordance with the national emission standards. Therefore,this kind of wastewater has been the hot area of research. The research progress on purification of phenol wastewater from three aspects of physical treatment,biological treatment and chemical treatment method were summarized. The wet catalytic oxidation,ultrasonic chemical oxidation and electrochemical oxidation process were also introduced. It was forecasted that the combined technology would be the research trend of purification of phenol wastewater in the future,providing a new idea for purifying phenol wastewater.
With the hard degradation,strong toxicity and extensive sources,the wastewater of phenol will bring immeasurable harm to our environment if discharged directly. Recycling phenol can not only save resources,but also protect the environment. The wastewater containing phenol should be treated in strict accordance with the national emission standards. Therefore,this kind of wastewater has been the hot area of research. The research progress on purification of phenol wastewater from three aspects of physical treatment,biological treatment and chemical treatment method were summarized. The wet catalytic oxidation,ultrasonic chemical oxidation and electrochemical oxidation process were also introduced. It was forecasted that the combined technology would be the research trend of purification of phenol wastewater in the future,providing a new idea for purifying phenol wastewater.
引文
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[25]Marla Hijosa-Valsero,Ricardo Molina,Hendrik Schikora,et al.Removal of cyanide from water by means of plasma discharge technology[J].Water research,2013(47):1701-1707.
[26]李桂菊,朱丽香,何迎春,等.湿式催化氧化法处理含酚清洗废水的研究[J].工业水处理,2010,30(5):38-41.
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[28]张静.超声降解酚类污染物[D].石家庄:河北师范大学,2014.
[29]谢向东.电催化氧化法处理苯酚废水的实验研究[J].环境与生活,2014(6):74-76.
[30]Guifen Lv,Dingcai Wu,Ruowen Fu.Performance of carbon aerogels particle electrodes for the aqueous phase electro-catalytic oxidation of simulated phenol wastewaters[J].Journal of Hazardous Materials,2009,165:961-966.
[31]Hongzhu Ma,Xinhai Zhang,Qingliang Mab,et al.Electrochemical catalytic treatment of phenol wastewater[J].Journal of Hazardous Materials,2009,165:475-480.
[32]刘力郡.低温等离子体结合光催化降解全氟辛酸废水的研究[D].济南:山东大学,2016.
[33]冯婕,王岽,郦和生.Fenton试剂氧化—活性炭吸附处理炼油厂循环水排污水[J].化工环保,2012,32(4):343-346.
[34]P T Almazán-Sánchez,I Linares-Hernández,V MartínezMiranda,et al.Wastewater treatment of methyl methacrylate(MMA)by Fenton's reagent and adsorption[J].Catalysis Today,2014,220-222:39-48.
[35]金玲.等离子体协同光催化剂处理微污染水[D].天津:天津大学,2011.
[36]P M K Reddy,B R Raju,J Karuppiah,et al.Degradation and mineralization of methylene blue by dielectric barrier discharge nonthermal plasma reactor[J].Chemical Engineering Journal,2013,217:41-47.
[37]成笠萌.超声波与臭氧技术对焦化废水中难降解有机物处理研究[D].北京交通大学,2016.
[38]袁飞宇.微波-Fenton设备预处理抗生素废水实验研究[D].沈阳:沈阳工业大学,2016.
[39]倪鑫鑫.电化学-生化组合工艺处理高浓度有机废水研究[D].上海:华东师范大学,2015.
[40]扶海立.厌氧-好氧-Fenton氧化工艺处理阿维菌素废水的研究[D].长沙:湖南农业大学,2014.
[41]易斌.活性炭吸附-Fenton氧化处理高盐有机废水的研究[D].长沙:湖南大学,2012.
[42]Bo Jiang,Jingtang Zheng,Xiu Lu,et al.Degradation of organic dye by pulsed discharge non-thermal plasma technology assisted with modified activated carbon fibers[J].Chemical Engineering Journal,2013,215-216:969-978.
[43]荣俊锋,陆雪玉,张帅,等.填料吸附-等离子体氧化协同处理苯酚废水研究[J].环境工程,2016,45(12):53-57.
[44]余水情.低温等离子体协同填料循环净化苯酚废水[D].合肥:安徽理工大学,2015.
[45]方敏.低温等离子体技术净化苯酚废水[D].合肥:安徽理工大学,2016.
[46]荣俊锋,陈明功,曹晶晶,等.高浓度煤化工有机废水净化研究进展[J].广州化工,2015,43(4):14-16.
[2]范俊刚,李志超,王欢,等.苯酚在活性炭纤维上的吸附平衡及动力学研究[J].应用化工,2014,43(4):632-635.
[3]崔云帆.焦化废水中COD的树脂吸附研究[D].山西大学,2013.
[4]王琤,李风亭,吴胜举,等.Fenton试剂-改性粉煤灰处理苯酚废水的研究[J].无机盐工业,2011,43(3):50-53.
[5]雷春生,李英柳,姚倩,等.微波改性凹凸棒滤料对微污染苯酚废水动态吸附研究[J].水处理技术,2012,38(11):90-93.
[6]郑宾国,姜灵彦,梁丽珍,等.无机改性膨润土制备及吸附苯酚废水的研究[J].化工新型材料,2011,39(7):120-122.
[7]耿新华,李娇.乳状液膜法处理陶瓷业水煤气污水里的苯酚[J].焦作大学学报,2010,24(2):94-96.
[8]张海燕,罗海军,宁英男,等.乳化液膜法脱除废水中酚的正交实验研究[J].化工科技,2012,20(5):28-30.
[9]王旭,杜启云,王韬,等.活性污泥法处理高浓度苯酚废水的研究[J].天津工业大学学报,2007,26(6):32-35.
[10]张金利,李韦华,袁兵,等.生物流化床法处理高浓度含酚废水的研究[J].化学反应工程与工艺,2001,17(2):148-152.
[11]宋玉栋,杨健,杨婧晖,等.曝气生物流化床处理高负荷含酚废水的研究//国家科技重大专项“水体污染控制与治理”河流主题“流域行业点源水污染控制技术”研讨会论文集[C].2009:480-484.
[12]陶洁.金属离子沉淀法处理含酚废水及回收酚类物质的研究[J].科技咨询导报,2007(23):116-117.
[13]耿新华,黄伟娜,李晓,等.沉淀法回收陶瓷业废水中酚类物质的研究[J].山东化工,2011(7):13-15.
[14]胡文伟,高亚岳.焚烧法处理含酚废水[J].工业用水与废水,2000,4:28-29.
[15]丁峰.臭氧氧化法处理苯酚废水的影响因素分析[J].污染防治技术,2010,3:4-6.
[16]贲永光,钟红茂,孔繁晟,等.超声协同H2O2降解模拟废水中苯酚的影响因素试验研究[J].土木建筑与环境工程,2012,34(1):96-101.
[17]郑志军.二氧化氯催化氧化处理工业废水的研究[D].石家庄:河北科技大学,2009.
[18]李超,钟宏,周立,等.氧化法处理模拟含酚废水的实验研究[J].应用化工,2009,38(11):1556-1560.
[19]陈明功,齐永涛,张鑫敏,等.低温等离子体与絮凝剂处理印染废水的协同效应[J].中国环境科学,2012,30(9):1207-1211.
[20]屈广周,李杰,梁冬丽,等.低温等离子体技术处理难降解有机废水的研究进展[J].化工进展,2012,31(3):662-670.
[21]Biljana P Dojcinovic,Goran M Roglic,Bratislav M Obradovi'c,et al.Decolorization of reactive textile dyes using water falling film dielectric barrier discharge[J].Journal of Hazardous Materials,2011(192):763-771.
[22]Xiaoyan Wang,Minghua Zhou,Xinglong Jin.Application of glowdischarge plasma for wastewater treatment[J].Electrochimica Acta,2012(83):501-512.
[23]陈静.低温等离子体处理腈纶废水的研究[D].合肥:安徽理工大学,2012.
[24]Yuezhong Wen,Chensi Shena,Yanyan Ni,et al.Glow discharge plasma in water:A green approach to enhancing ability of chitosan for dye removal[J].Journal of Hazardous Materials,2012(201-202):162-169.
[25]Marla Hijosa-Valsero,Ricardo Molina,Hendrik Schikora,et al.Removal of cyanide from water by means of plasma discharge technology[J].Water research,2013(47):1701-1707.
[26]李桂菊,朱丽香,何迎春,等.湿式催化氧化法处理含酚清洗废水的研究[J].工业水处理,2010,30(5):38-41.
[27]孙莉,王丽华,陈杰.超声波-光催化降解处理苯酚的实验研究[J].辽宁工程技术大学学报(自然科学版),2009(s2):160-162.
[28]张静.超声降解酚类污染物[D].石家庄:河北师范大学,2014.
[29]谢向东.电催化氧化法处理苯酚废水的实验研究[J].环境与生活,2014(6):74-76.
[30]Guifen Lv,Dingcai Wu,Ruowen Fu.Performance of carbon aerogels particle electrodes for the aqueous phase electro-catalytic oxidation of simulated phenol wastewaters[J].Journal of Hazardous Materials,2009,165:961-966.
[31]Hongzhu Ma,Xinhai Zhang,Qingliang Mab,et al.Electrochemical catalytic treatment of phenol wastewater[J].Journal of Hazardous Materials,2009,165:475-480.
[32]刘力郡.低温等离子体结合光催化降解全氟辛酸废水的研究[D].济南:山东大学,2016.
[33]冯婕,王岽,郦和生.Fenton试剂氧化—活性炭吸附处理炼油厂循环水排污水[J].化工环保,2012,32(4):343-346.
[34]P T Almazán-Sánchez,I Linares-Hernández,V MartínezMiranda,et al.Wastewater treatment of methyl methacrylate(MMA)by Fenton's reagent and adsorption[J].Catalysis Today,2014,220-222:39-48.
[35]金玲.等离子体协同光催化剂处理微污染水[D].天津:天津大学,2011.
[36]P M K Reddy,B R Raju,J Karuppiah,et al.Degradation and mineralization of methylene blue by dielectric barrier discharge nonthermal plasma reactor[J].Chemical Engineering Journal,2013,217:41-47.
[37]成笠萌.超声波与臭氧技术对焦化废水中难降解有机物处理研究[D].北京交通大学,2016.
[38]袁飞宇.微波-Fenton设备预处理抗生素废水实验研究[D].沈阳:沈阳工业大学,2016.
[39]倪鑫鑫.电化学-生化组合工艺处理高浓度有机废水研究[D].上海:华东师范大学,2015.
[40]扶海立.厌氧-好氧-Fenton氧化工艺处理阿维菌素废水的研究[D].长沙:湖南农业大学,2014.
[41]易斌.活性炭吸附-Fenton氧化处理高盐有机废水的研究[D].长沙:湖南大学,2012.
[42]Bo Jiang,Jingtang Zheng,Xiu Lu,et al.Degradation of organic dye by pulsed discharge non-thermal plasma technology assisted with modified activated carbon fibers[J].Chemical Engineering Journal,2013,215-216:969-978.
[43]荣俊锋,陆雪玉,张帅,等.填料吸附-等离子体氧化协同处理苯酚废水研究[J].环境工程,2016,45(12):53-57.
[44]余水情.低温等离子体协同填料循环净化苯酚废水[D].合肥:安徽理工大学,2015.
[45]方敏.低温等离子体技术净化苯酚废水[D].合肥:安徽理工大学,2016.
[46]荣俊锋,陈明功,曹晶晶,等.高浓度煤化工有机废水净化研究进展[J].广州化工,2015,43(4):14-16.
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