陶瓷空气反应钎焊研究综述
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摘要
高温电化学装置技术优势明显,市场潜力巨大,其特殊的服役环境对钎焊接头提出了更高要求,空气反应钎焊连接方法应运而生。综述了目前常用于RAB连接的钎料种类和已成功实现RAB连接的陶瓷/金属体系,并对相关接头界面组织和综合性能进行了分析。迄今为止,Ag-Cu O钎料使用最广。利用空气反应钎焊方法能够成功实现氧化物、钙钛矿陶瓷自身及其与部分耐高温不锈钢的可靠连接,结合界面成形良好,接头性能稳定。常用于RAB连接的氧化物陶瓷以YSZ和Al_2O_3为代表,LSCF/BSCF/BCFN/BCFZ等典型钙钛矿陶瓷也可利用RAB进行连接。Crofer22 APU,AISI310S和AISI314等耐高温不锈钢与上述钙钛矿陶瓷进行RAB连接后,接头的力学性能、抗氧化能力和气密性均能满足使用需求。在此基础上,对空气反应钎焊的连接特性与研究现状进行了总结。最后,对其发展前景和未来研究方向进行了展望。
High-temperature electrochemical devices have great market potential due to their technological superiority. Reliable joints are required because of the harsh operational conditions. Based on this background, a kind of new bonding technology called reactive air brazing(RAB) was introduced. This article reviewed brazing fillers commonly used in RAB and ceramic/metal joining systems obtained by RAB. The interfacial microstructure and properties of relevant joints were analyzed. Currently, the most widely used brazing filler in RAB is Ag-Cu O. Oxides such as YSZ and Al_2O_3 and perovskite ceramics including LSCF, BSCF, BCFN and BCFZ could be successfully brazed with high-temperature stainless steel using this joining method and reliable joints can be achieved. Joints between perovskite ceramics and Crofer22 APU, AISI310 S and AISI314 stainless steel could meet service demands on mechanical property, oxidation resistance and gas tightness. On this basis, this paper summarized joining characteristics and current research status of reactive air brazing. Finally, the development prospects and future research directions were presented.
High-temperature electrochemical devices have great market potential due to their technological superiority. Reliable joints are required because of the harsh operational conditions. Based on this background, a kind of new bonding technology called reactive air brazing(RAB) was introduced. This article reviewed brazing fillers commonly used in RAB and ceramic/metal joining systems obtained by RAB. The interfacial microstructure and properties of relevant joints were analyzed. Currently, the most widely used brazing filler in RAB is Ag-Cu O. Oxides such as YSZ and Al_2O_3 and perovskite ceramics including LSCF, BSCF, BCFN and BCFZ could be successfully brazed with high-temperature stainless steel using this joining method and reliable joints can be achieved. Joints between perovskite ceramics and Crofer22 APU, AISI310 S and AISI314 stainless steel could meet service demands on mechanical property, oxidation resistance and gas tightness. On this basis, this paper summarized joining characteristics and current research status of reactive air brazing. Finally, the development prospects and future research directions were presented.
引文
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[10]FERGUS J W.Sealants for Solid Oxide Fuel Cells[J].Journal of Power Sources,2005,147(1):46—57.
[11]CHAO Chi-long,CHU Chun-lin,FUH Yiin-kuen,et al.Interfacial Characterization of Nickel-yttria-stabilized Zirconia Cermet Anode/Interconnect Joints with Ag-Pd-Ga Active Filler for Use in Solid-oxide Fuel Cells[J].International Journal of Hydrogen Energy,2015,40(3):1523—1533.
[12]HARDY J S,JIN Y K,WEIL K S.Joining Mixed Conducting Oxides Using an Air-Fired Electrically Conductive Braze[J].Journal of the Electrochemical Society,2004,151(8):43—49.
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[15]TUCKER M C,JACOBSON C P,JONGHE L C D,et al.A Braze System for Sealing Metal-supported Solid Oxide Fuel Cells[J].Journal of Power Sources,2006,160(2):1049—1057.
[16]SOFIE S W,GANN-ON P,GOROKHOVSKY V.Silver-chromium Oxide Interactions in SOFC Environments[J].Journal of Power Sources,2009,191(2):465—472.
[17]MEIER A M,CHIDAMBARAM P,EDWARDS G R.A Comparison of the Wettability of Copper-copper Oxide and Silver-copper Oxide on Polycrystalline Alumina[J].Journal of Materials Science,1995,30(19):4781—4786.
[18]KUHN B,WETZEL F J,MALZBENDER J,et al.Mechanical Performance of Reactive-air-brazed(RAB)Ceramic/metal Joints for Solid Oxide Fuel Cells at Ambient Temperature[J].Journal of Power Sources,2009,193(1):199—202.
[19]KIM J Y,HARDY J S,WEIL K S.Silver-copper Oxide Based Reactive Air Braze for Joining Yttria-stabilized Zirconia[J].Journal of Materials Research,2005,20(3):636—643.
[20]SI Xiao-qing,CAO Jian,SONG Xiao-guo,et al.Reactive Air Brazing of YSZ Ceramic with Novel Al2O3 Nanoparticles Reinforced Ag-Cu O-Al2O3 Composite Filler:Microstructure and Joint Properties[J].Materials&Design,2017,114:176—184.
[21]RIANT J R,MEIER A,DARSELL J T,et al.Transitions in Wetting Behavior Between Liquid Ag–Cu O Alloys and Al2O3 Substrates[J].Journal of the American Ceramic Society,2012,95(5):1549—1555.
[22]CAO Jian,SI Xiao-qing,LI Wang-jin,et al.Reactive Air Brazing of YSZ-electrolyte and Al2O3-substrate for Gas Sensor Sealing:Interfacial Microstructure and Mechanical Properties[J].International Journal of Hydrogen Energy,2017,42(15):10683—10694.
[23]WEIL K S,HARDY J S.Development of a New Ceramic-to-Metal Brazing Technique for Oxygen Separation/Generation Applications[J].Quade,2002,6(5):485—495.
[24]RAJU K,MUKSIN,KIM S,et al.Joining of Metal-ceramic Using Reactive Air Brazing for Oxygen Transport Membrane Applications[J].Materials&Design,2016,109:233—241.
[25]JOSHI V V,MEIER A,DARSELL J,et al.Trends in Wetting Behavior for Ag-Cu O Braze Alloys on Ba0.5Sr0.5Co0.8Fe0.2O3-δat Elevated Temperatures in Air[J].Journal of Materials Science,2013,48(20):7153—7161.
[26]KALETSCH A,BEZOLD A,PFAFF E M,et al.Effects of Copper Oxide Content in Ag-Cu O Braze Alloy on Microstructure and Mechanical Properties of Reactive-airbrazed Ba0.5Sr0.5Co0.8Fe0.2O3-δ(BSCF)[J].Journal of Ceramic Science and Technology,2012,3(2):95—103.
[27]KALETSCH A,HUMMES J,PFAFF E M,et al.Joining Oxygen Transport Membranes by Reactive Air Brazing[C]//Proceedings of the 5th International Brazing and Soldering Conference,ASM International,Materials Park,2012:437.
[28]KALETSCH A,PFAFF E M,BROECKMANN C.Effect of Aging on Microstructure and Mechanical Strength of Reactive Air Brazed BSCF/AISI 314-Joints[J].Advanced Engineering Materials,2015,16(12):1430—1436.
[29]CHEN Hong,LI Lei-jun,KEMPSR,et al.Reactive Air Brazing for Sealing Mixed Ionic Electronic Conducting Hollow Fibre Membranes[J].Acta Materialia,2015,88:74—82.
[30]ZHANG Yu-wen,ZHANG Li-li,GUO Wei,et al.Interfacial Reaction and Microstructural Evolution of Ag-Cu Braze on Ba Co0.7Fe0.2Nb0.1O3-δat High Temperature in Air[J].Ceramics International,2017,43(1):810—819.
[31]JENS F B,RASMUSSEN,HAGEN A.The Effect of H2S on the Performance of Ni-YSZ Anodes in Solid Oxide Fuel Cells[J].Journal of Power Source,2009,191:534—541.
[32]NIKOOYEH K,CLEMMER R,ALZATE-RESTREPO V,et al.Effect of Hydrogen on Carbon Formation on Ni/YSZ Composites Exposed to Methane[J].Applied Catalysis A:General,2008,347(1):6—111.
[33]KIM S D,MOON H,HYUN S H,et al.Performance and Durability of Ni-coated YSZ Anodes for Intermediate Temperature Solid Oxide Fuel Cells[J].Solid State Ionics,2006,177(9):931—938.
[34]JIANG Q,FARAJI S,SLADE D A,et al.A Review of Mixed Ionic and Electronic Conducting Ceramic Membranes as Oxygen Sources for High-temperature Reactors[J].Membrane Science and Technology,2011,14:235—273.
[35]TUCKER M C.Progress in Metal-supported Solid Oxide Fuel Cells:A Review[J].Journal of Power Sources,2010,195(15):4570—4582.
[36]YAMAMOTO O.Solid Oxide Fuel Cells:Fundamental Aspects and Prospects[J].Electrochimica Acta,2000,45(15):2423—2435.
[37]JIANG Wen-chun,ZHANG Yu-cai,WOOW,et al.Three-dimensional Simulation to Study the Influence of Foil Thickness on Residual Stress in the Bonded Compliant Seal Design of Planar Solid Oxide Fuel Cell[J].Journal of Power Sources,2012,209:65—71.
[38]LIN Kun-lin,SINGH M,ASTHANA R,et al.Interfacial and Mechanical Characterization of Yttria-stabilized Zirconia(YSZ)to Stainless Steel Joints Fabricated Using Ag-Cu-Ti Interlayers[J].Ceramics International,2014,40(1):2063—2071.
[39]ZHOU Xiao-liang,SUN K,YAN Y,et al.Investigation on Silver Electric Adhesive Doped with Al2O3Ceramic Particles for Sealing Planar Solid Oxide Fuel Cell[J].Journal of Power Sources,2009,192(2):408—413.
[40]KIEBACH R,ENGELBRECHT K,GRAHL-MADSENL,et al.An Ag Based Brazing System with a Tunable Thermal Expansion for the Use as Sealant for Solid Oxide Cells[J].Journal of Power Sources,2016,315:339—350.
[41]INGENITO A,AGRESTA A,ANDRIANI R,et al.NOxReduction Strategies for High Speed Hydrogen Fuelled Vehicles[J].International Journal of Hydrogen Energy,2015,40(15):5186—5196.
[42]YIN Cheng-guo,GUAN Ying-zhou,ZHU Zhe,et al.Highly Sensitive Mixed-potential-type NO2 Sensor Using Porous Double-layer YSZ Substrate[J].Sensors and Actuators B:Chemical,2013,183:474—477.
[43]PLASHNITSA V V,GUPTA V,MIURA N.Mechanochemical Approach for Fabrication of a Nano-structured Ni O-sensing Electrode Used in a Zirconia-based NO2Sensor[J].Electrochimica Acta,2010,55(23):6941—6945.
[44]WANG Shao-rong,KATSUKI M,DOKIYA M,et al.High Temperature Properties of La0.6Sr0.4Co0.8Fe0.2O3-δOxygen Nonstoichiometry and Chemical Diffusion Constant[J].Solid State Ionics,2003,156(3):453—461.
[45]CZYPEREK M,ZAPP P,BOUWMEESTER H J M,et al.Gas Separation Membranes for Zero-emission Fossil Power Plants:MEM-BRAIN[J].Journal of Membrane Science,2010,359(1):149—159.
[46]YUAN Zou,ZHOU Wei,LIU Shao-min,et al.Sintering and Oxygen Permeation Studies of La0.6Sr0.4Co0.2Fe0.8O3-δCeramic Membranes with Improved Purity[J].Journal of the European Ceramic Society,2011,31(15):2931—2938.
[47]JOO J H,YUN K S,LEE Y,et al.Dramatically Enhanced Oxygen Fluxes in Fluorite-rich Dual-phase Membrane by Surface Modification[J].Chemistry of Materials,2014,26(15):4387—4394.
[48]VENTE J F,HAIJE W G,RAK Z S.Performance of Functional Perovskite Membranes for Oxygen Production[J].Journal of Membrane Science,2006,276(1):178—184.
[49]SHAO Zong-ping,YANG Wei-shen,YOU Cong,et al.Investigation of the Permeation Behavior and Stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-δOxygen Membrane[J].Journal of Membrane Science,2000,172(1):177—188.
[50]LIANG Fang-yi,JIANG He-qing,LUO Hui-xia,et al.Phase Stability and Permeation Behavior of a Dead-end Ba0.5Sr0.5Co0.8Fe0.2O3-δTube Membrane in High-purity Oxygen Production[J].Chemistry of Materials,2011,23(21):4765—4772.
[51]GEFFROY P M,FOULETIER J,RICHET N,et al.Rational Selection of MIEC Materials in Energy Production Processes[J].Chemical Engineering Science,2013,87:408—433.
[52]ZHANG Yu-wen,LIU Jiao,DING Wei-zhong,et al.Performance of an Oxygen-permeable Membrane Reactor for Partial Oxidation of Methane in Coke Oven Gas to Syngas[J].Fuel,2011,90(1):324—330.
[53]ZHANG Yu-wen,CHENG Hong-wei,LIU Jiao,et al.Performance of a Tubular Oxygen-permeable Membrane Reactor for Partial Oxidation of CH4 in Coke Oven Gas to Syngas[J].Journal of Natural Gas Chemistry,2010,19(3):280—283.
[2]ZHANG Kun,SUNARSO J,SHAO Zong-ping,et al.Research Progress and Materials Selection Guidelines on Mixed Conducting Perovskite-type Ceramic Membranes for Oxygen Production[J].RSC Advances,2011,1(9):1661—1676.
[3]WEIL K S,HARDY J S,RICE J P,et al.Brazing as a Means of Sealing Ceramic Membranes for Use in Advanced Coal Gasification Processes[J].Fuel,2006,85(2):156—162.
[4]PARK S,VOHS J M,GORTE R J.Direct Oxidation of Hydrocarbons in a Solid Oxide Fuel Cell[J].Nature,2000,404:265—267.
[5]SIMNERS P,ANDERSON M D,COLEMAN J E,et al.Performance of a Novel La(Sr)Fe(Co)O3-Ag SOFC Cathode[J].Journal of Power Sources,2006,161(1).
[6]LEO A,LIU Shao-min,COSTA J C D.Development of Mixed Conducting Membranes for Clean Coal Energy Delivery[J].International Journal of Greenhouse Gas Control,2009,3(4):357—367.
[7]SUNARSO J,BAUMANN S,SERRA J M,et al.Mixed Ionic-electronic Conducting(MIEC)Ceramic-based Membranes for Oxygen Separation[J].Journal of Membrane Science,2008,320(1):13—41.
[8]EICHLER K,SOLOW G,OTSCHIKP,et al.Degradation Effects at Sealing Glasses for the SOFC[C]//Proceedings of the Fourth European Solid Oxide Fuel Cell Forum,2000:899.
[9]SMEACETTO F,SALVO M,FERRARIS M,et al.Glass-ceramic Seal to Join Crofer 22 APU Alloy to YSZ Ceramic in Planar SOFCs[J].Journal of the European Ceramic Society,2008,28(1):61—68.
[10]FERGUS J W.Sealants for Solid Oxide Fuel Cells[J].Journal of Power Sources,2005,147(1):46—57.
[11]CHAO Chi-long,CHU Chun-lin,FUH Yiin-kuen,et al.Interfacial Characterization of Nickel-yttria-stabilized Zirconia Cermet Anode/Interconnect Joints with Ag-Pd-Ga Active Filler for Use in Solid-oxide Fuel Cells[J].International Journal of Hydrogen Energy,2015,40(3):1523—1533.
[12]HARDY J S,JIN Y K,WEIL K S.Joining Mixed Conducting Oxides Using an Air-Fired Electrically Conductive Braze[J].Journal of the Electrochemical Society,2004,151(8):43—49.
[13]WEIL K S,JIN Y K,HARDY J S.Reactive Air Brazing:A Novel Method of Sealing SOFCs and Other Solid-state Electrochemical Devices[J].Electrochemical and SolidState Letters,2005,8(2):133—136.
[14]WEIL S K,HARDY J S,KIM J Y.Oxidation Ceramic to Metal Braze Seals for Applications in High Temperature Electrochemical Devices and Method of Making:U.S.7055733[P].2006-6-6.
[15]TUCKER M C,JACOBSON C P,JONGHE L C D,et al.A Braze System for Sealing Metal-supported Solid Oxide Fuel Cells[J].Journal of Power Sources,2006,160(2):1049—1057.
[16]SOFIE S W,GANN-ON P,GOROKHOVSKY V.Silver-chromium Oxide Interactions in SOFC Environments[J].Journal of Power Sources,2009,191(2):465—472.
[17]MEIER A M,CHIDAMBARAM P,EDWARDS G R.A Comparison of the Wettability of Copper-copper Oxide and Silver-copper Oxide on Polycrystalline Alumina[J].Journal of Materials Science,1995,30(19):4781—4786.
[18]KUHN B,WETZEL F J,MALZBENDER J,et al.Mechanical Performance of Reactive-air-brazed(RAB)Ceramic/metal Joints for Solid Oxide Fuel Cells at Ambient Temperature[J].Journal of Power Sources,2009,193(1):199—202.
[19]KIM J Y,HARDY J S,WEIL K S.Silver-copper Oxide Based Reactive Air Braze for Joining Yttria-stabilized Zirconia[J].Journal of Materials Research,2005,20(3):636—643.
[20]SI Xiao-qing,CAO Jian,SONG Xiao-guo,et al.Reactive Air Brazing of YSZ Ceramic with Novel Al2O3 Nanoparticles Reinforced Ag-Cu O-Al2O3 Composite Filler:Microstructure and Joint Properties[J].Materials&Design,2017,114:176—184.
[21]RIANT J R,MEIER A,DARSELL J T,et al.Transitions in Wetting Behavior Between Liquid Ag–Cu O Alloys and Al2O3 Substrates[J].Journal of the American Ceramic Society,2012,95(5):1549—1555.
[22]CAO Jian,SI Xiao-qing,LI Wang-jin,et al.Reactive Air Brazing of YSZ-electrolyte and Al2O3-substrate for Gas Sensor Sealing:Interfacial Microstructure and Mechanical Properties[J].International Journal of Hydrogen Energy,2017,42(15):10683—10694.
[23]WEIL K S,HARDY J S.Development of a New Ceramic-to-Metal Brazing Technique for Oxygen Separation/Generation Applications[J].Quade,2002,6(5):485—495.
[24]RAJU K,MUKSIN,KIM S,et al.Joining of Metal-ceramic Using Reactive Air Brazing for Oxygen Transport Membrane Applications[J].Materials&Design,2016,109:233—241.
[25]JOSHI V V,MEIER A,DARSELL J,et al.Trends in Wetting Behavior for Ag-Cu O Braze Alloys on Ba0.5Sr0.5Co0.8Fe0.2O3-δat Elevated Temperatures in Air[J].Journal of Materials Science,2013,48(20):7153—7161.
[26]KALETSCH A,BEZOLD A,PFAFF E M,et al.Effects of Copper Oxide Content in Ag-Cu O Braze Alloy on Microstructure and Mechanical Properties of Reactive-airbrazed Ba0.5Sr0.5Co0.8Fe0.2O3-δ(BSCF)[J].Journal of Ceramic Science and Technology,2012,3(2):95—103.
[27]KALETSCH A,HUMMES J,PFAFF E M,et al.Joining Oxygen Transport Membranes by Reactive Air Brazing[C]//Proceedings of the 5th International Brazing and Soldering Conference,ASM International,Materials Park,2012:437.
[28]KALETSCH A,PFAFF E M,BROECKMANN C.Effect of Aging on Microstructure and Mechanical Strength of Reactive Air Brazed BSCF/AISI 314-Joints[J].Advanced Engineering Materials,2015,16(12):1430—1436.
[29]CHEN Hong,LI Lei-jun,KEMPSR,et al.Reactive Air Brazing for Sealing Mixed Ionic Electronic Conducting Hollow Fibre Membranes[J].Acta Materialia,2015,88:74—82.
[30]ZHANG Yu-wen,ZHANG Li-li,GUO Wei,et al.Interfacial Reaction and Microstructural Evolution of Ag-Cu Braze on Ba Co0.7Fe0.2Nb0.1O3-δat High Temperature in Air[J].Ceramics International,2017,43(1):810—819.
[31]JENS F B,RASMUSSEN,HAGEN A.The Effect of H2S on the Performance of Ni-YSZ Anodes in Solid Oxide Fuel Cells[J].Journal of Power Source,2009,191:534—541.
[32]NIKOOYEH K,CLEMMER R,ALZATE-RESTREPO V,et al.Effect of Hydrogen on Carbon Formation on Ni/YSZ Composites Exposed to Methane[J].Applied Catalysis A:General,2008,347(1):6—111.
[33]KIM S D,MOON H,HYUN S H,et al.Performance and Durability of Ni-coated YSZ Anodes for Intermediate Temperature Solid Oxide Fuel Cells[J].Solid State Ionics,2006,177(9):931—938.
[34]JIANG Q,FARAJI S,SLADE D A,et al.A Review of Mixed Ionic and Electronic Conducting Ceramic Membranes as Oxygen Sources for High-temperature Reactors[J].Membrane Science and Technology,2011,14:235—273.
[35]TUCKER M C.Progress in Metal-supported Solid Oxide Fuel Cells:A Review[J].Journal of Power Sources,2010,195(15):4570—4582.
[36]YAMAMOTO O.Solid Oxide Fuel Cells:Fundamental Aspects and Prospects[J].Electrochimica Acta,2000,45(15):2423—2435.
[37]JIANG Wen-chun,ZHANG Yu-cai,WOOW,et al.Three-dimensional Simulation to Study the Influence of Foil Thickness on Residual Stress in the Bonded Compliant Seal Design of Planar Solid Oxide Fuel Cell[J].Journal of Power Sources,2012,209:65—71.
[38]LIN Kun-lin,SINGH M,ASTHANA R,et al.Interfacial and Mechanical Characterization of Yttria-stabilized Zirconia(YSZ)to Stainless Steel Joints Fabricated Using Ag-Cu-Ti Interlayers[J].Ceramics International,2014,40(1):2063—2071.
[39]ZHOU Xiao-liang,SUN K,YAN Y,et al.Investigation on Silver Electric Adhesive Doped with Al2O3Ceramic Particles for Sealing Planar Solid Oxide Fuel Cell[J].Journal of Power Sources,2009,192(2):408—413.
[40]KIEBACH R,ENGELBRECHT K,GRAHL-MADSENL,et al.An Ag Based Brazing System with a Tunable Thermal Expansion for the Use as Sealant for Solid Oxide Cells[J].Journal of Power Sources,2016,315:339—350.
[41]INGENITO A,AGRESTA A,ANDRIANI R,et al.NOxReduction Strategies for High Speed Hydrogen Fuelled Vehicles[J].International Journal of Hydrogen Energy,2015,40(15):5186—5196.
[42]YIN Cheng-guo,GUAN Ying-zhou,ZHU Zhe,et al.Highly Sensitive Mixed-potential-type NO2 Sensor Using Porous Double-layer YSZ Substrate[J].Sensors and Actuators B:Chemical,2013,183:474—477.
[43]PLASHNITSA V V,GUPTA V,MIURA N.Mechanochemical Approach for Fabrication of a Nano-structured Ni O-sensing Electrode Used in a Zirconia-based NO2Sensor[J].Electrochimica Acta,2010,55(23):6941—6945.
[44]WANG Shao-rong,KATSUKI M,DOKIYA M,et al.High Temperature Properties of La0.6Sr0.4Co0.8Fe0.2O3-δOxygen Nonstoichiometry and Chemical Diffusion Constant[J].Solid State Ionics,2003,156(3):453—461.
[45]CZYPEREK M,ZAPP P,BOUWMEESTER H J M,et al.Gas Separation Membranes for Zero-emission Fossil Power Plants:MEM-BRAIN[J].Journal of Membrane Science,2010,359(1):149—159.
[46]YUAN Zou,ZHOU Wei,LIU Shao-min,et al.Sintering and Oxygen Permeation Studies of La0.6Sr0.4Co0.2Fe0.8O3-δCeramic Membranes with Improved Purity[J].Journal of the European Ceramic Society,2011,31(15):2931—2938.
[47]JOO J H,YUN K S,LEE Y,et al.Dramatically Enhanced Oxygen Fluxes in Fluorite-rich Dual-phase Membrane by Surface Modification[J].Chemistry of Materials,2014,26(15):4387—4394.
[48]VENTE J F,HAIJE W G,RAK Z S.Performance of Functional Perovskite Membranes for Oxygen Production[J].Journal of Membrane Science,2006,276(1):178—184.
[49]SHAO Zong-ping,YANG Wei-shen,YOU Cong,et al.Investigation of the Permeation Behavior and Stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-δOxygen Membrane[J].Journal of Membrane Science,2000,172(1):177—188.
[50]LIANG Fang-yi,JIANG He-qing,LUO Hui-xia,et al.Phase Stability and Permeation Behavior of a Dead-end Ba0.5Sr0.5Co0.8Fe0.2O3-δTube Membrane in High-purity Oxygen Production[J].Chemistry of Materials,2011,23(21):4765—4772.
[51]GEFFROY P M,FOULETIER J,RICHET N,et al.Rational Selection of MIEC Materials in Energy Production Processes[J].Chemical Engineering Science,2013,87:408—433.
[52]ZHANG Yu-wen,LIU Jiao,DING Wei-zhong,et al.Performance of an Oxygen-permeable Membrane Reactor for Partial Oxidation of Methane in Coke Oven Gas to Syngas[J].Fuel,2011,90(1):324—330.
[53]ZHANG Yu-wen,CHENG Hong-wei,LIU Jiao,et al.Performance of a Tubular Oxygen-permeable Membrane Reactor for Partial Oxidation of CH4 in Coke Oven Gas to Syngas[J].Journal of Natural Gas Chemistry,2010,19(3):280—283.
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