细粒锡石浮选组合药剂研究与应用进展
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摘要
采用浮选工艺回收细粒锡石,药剂是关键。大量的研究与生产实践表明,浮选药剂的组合能提升锡石的综合回收指标。为了系统、全面地了解细粒锡石浮选组合药剂的研究与应用进展,综述了细粒锡石浮选的组合捕收剂、组合调整剂以及捕收剂+调整剂组合的优点、作用机理及应用现状,指出使用组合药剂能取得较理想的浮选指标与药剂间的协同作用密不可分。
The reagent is the key for the recovery of fine cassiterite by flotation. A large number of research and production practices have shown that the combination of reagents can promote the comprehensive recovery of cassiterite. In order to systematically and comprehensively understand the research and application of reagent of fine cassiterite,the use status of combined collectors,combined regulators,collectors and regulator for fine cassiterite flotation are reviewed,The advantages,mechanism and application status of combined reagents are introduced,and it is pointed out that achieving a better production target by using combined reagent is inseparable to the synergy between the reagents.
The reagent is the key for the recovery of fine cassiterite by flotation. A large number of research and production practices have shown that the combination of reagents can promote the comprehensive recovery of cassiterite. In order to systematically and comprehensively understand the research and application of reagent of fine cassiterite,the use status of combined collectors,combined regulators,collectors and regulator for fine cassiterite flotation are reviewed,The advantages,mechanism and application status of combined reagents are introduced,and it is pointed out that achieving a better production target by using combined reagent is inseparable to the synergy between the reagents.
引文
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[2]李瑞生.锡石浮选工艺试验与应用情况[J].锡业科技,2001(5):57-61.Li Ruisheng.Technology test and application situation for cassiterite flotation[J].Science&Technology of Tin Industry,2001(5):57-61
[3]Fuerstenau D W.Fine particle flotation[J].Fine Particles Processing,1980(1):669-705.
[4]许道刚,张雪峰,陈伟丽,等.我国锡石选矿研究现状与发展趋势[J].矿山机械,2015(6):8-12.Xu Daogang,Zhang Xuefeng,Chen Weili,et al.Research status and development tendency of cassiterite beneficiation in China[J].Mining&Processing Equipment,2015(6):8-12
[5]吕中海,胡卫波,张俊,等.锡矿石选矿工艺研究现状与进展[J].现代矿业,2009(10):19-22.Lyu Zhonghai,Hu Weibo,Zhang Jun,et al.Study status and progress of Tin ore dressing process[J].Modern Mining,2009(10:)19-22.
[6]孙爱辉,彭志兵.某摇床尾矿中细粒锡石的回收试验[J].有色金属(选矿部分),2013(6):40-44.Sun Aihui,Peng Zhibing.Experimental research on recovery of fine cassiterite from the tailings of shaking table[J].Nonferrous Metals(Mineral Processing Section),2013(6):40-44.
[7]Angadi S I,Sreenivas T.A review of cassiterite beneficiation fundamentals and plant practices[J].Minerals Engineering,2015,70:178-200.
[8]Leistner T,Embrechts M,Lei?ner T,et al.A study of the reprocessing of fine and ultrafine cassiterite from gravity tailing residues byusing various flotation techniques[J].Minerals Engineering,2016,96 /97:94-98.
[9]刘述忠,李晓阳,徐晓军.捕收剂组合使用的研究概况[J].云南冶金,2002(4):17-20.Liu Shuzhong,Li Xiaoyang,Xu Xiaojun.General situation on research of application of combinated collectors[J].Yunnan Metallurgy,2002(4):17-20.
[10]Gao Yuesheng,Gao Zhiyong,Sun Wei,et al.Selective flotation of scheelite from calcite:A novel reagent scheme[J].International Journal of Mineral Processing.2016,154:10-15.
[11]刘子帅,李宁钧.微细粒钨锡矿物选矿技术研究现状及进展[J].矿产综合利用,2017(2):12-14.Liu Zishuai,Li Ningjun.Research status and development of mineral processing technology of fine grain tungsten tin ore[J].Multipurpose Utilization of Mineral Resources,2017(2):12-14.
[12]陈瑜.都龙微细粒级锡石浮选试验研究[D].昆明:昆明理工大学,2017.Chen Yu.Experimental Research on Flotation of Fine-grain Cassiterite from Dulong Mine[D].Kunming:Kunming University of Science and Technology,2017
[13]何东,兰希雄,陈华萍.一种高效捕收剂浮选细粒级锡石的试验研究[J].有色金属(选矿部分),2015(2):91-95.He Dong,Lan Xixiong,Chen Huaping.An efficient collector for experimental study of flotation of fine-grade cassiterite[J].Nonferrous Metals(Mineral Processing Section),2015(2):91-95.
[14]周德炎,韦丽广.某低品位微细泥锡石浮选新工艺研究[J].大众科技,2015(11):46-49.Zhou Deyan,Wei Liguang.Study on new technology of a low grade fine mud flotation of cassiterite[J].Popular Science&Technology,2015(11):46-49.
[15]莫峰,何庆浪,兰希雄.都龙矿区细粒锡石浮选实验研究[J].矿冶工程,2012(4):59-61.Mo Feng,He Qinglang,Lan Xixiong.Experimental research on flotation of fine-grain cassiterite from dulong mine[J]Mining and Metallurgical Engineering,2012(4):59-61.
[16]胡真,王成行,童雄,等.多金属硫化矿中回收微细粒锡石的选矿试验研究[J].矿山机械,2012(1):81-85.Hu Zhen,Wang Chenghang,Tong Xiong,et al.Experimental study on beneficiation of fine cassiterite from polymetallic sulphide ore[J].Mining&Processing Equipment,2012(1):81-85.
[17]何名飞,罗朝艳,陈玉平,等.细粒锡石浮选研究[J].矿冶工程,2008(4):29-31.He Mingfei,Luo Chaoyan,Chen Yuping,et al.Flotation study of fine cassiterite[J].Mining and Metallurgical Engineering,2008(4):29-31.
[18]Sun Lei,Hu Yuehua,Sun Wei.Effect and mechanism of octanol in cassiterite flotation using benzohydroxamic acid as collector[J].Transactions of Nonferrous Metals Society of China,2016(12):3253-3257.
[19]周泰来.细粒锡石选矿的研究与生产实践[J].国外金属选矿,1998(7):18-21.Zhou Tailai.Research and production practice of fine-grained cassiterite beneficiation[J].Metallic Ore Dressing Abroad,1998(7):18-21.
[20]农升勤,邓位鹏,姚贵明,等.低品位细粒锡石浮选试验研究[J].有色金属(选矿部分),2014(3):37-40.Nong Shengqin,Deng Weipeng,Yao Guiming,et al.Experimental study of a low grade fine-grained cassiterite flotation[J].Nonferrous Metals(Mineral Processing Section),2014(3):37-40.
[21]肖巧斌.云锡大马芦细粒锡石浮选药剂优化研究[D].昆明:昆明理工大学,2005.Xiao Qiaobin.Research on Optimization of Fine Cassiterite Flotation Reagent in Damalu,Yunxi[D].Kunming:Kunming University of Science and Technology,2005
[22]刘杰,韩跃新,朱一民.细粒锡石选矿技术研究进展及展望[J].金属矿山,2014(10):76-81Liu Jie,Han Yuexin,Zhu Yimin,et al.Research status and prospective on separation technology of fine cassiterite[J].Metal Mine,2014(10):76-81.
[23]Qin Wenqing,Ren Liuyi,Xu Yangbao,et al.Adsorption mechanism of mixed salicylhydroxamic acid and tributyl phosphate collectors in fine cassiterite electro-flotation system[J].Journal of Central South University,2012(6):1711-1717.
[24]梁瑞释,石大新.浮选药剂的混合使用及其协同效应[J].国外金属矿选矿,1989(4):18-29.Liang Ruishi,Shi Daxin.Mixed use of flotation reagents and their synergistic effects[J].Metallic Ore Dressing Abroad,1989(4):18-29.
[25]刘德全,周春来,王淀佐.铜铁灵与苯异羟肟酸浮选锡石的交互作用及其机理[J].中国有色金属学报,1994(4):46-49.Liu Dequan,Zhou Chunlai,Wang Dianzuo.Interaction and mechanism of cupferron and benzhydroxamic acid in the cassiterite flotation[J].The Chinese Journal of Nonferrous Metals,1994(4):46-49
[26]吕晋芳,童雄,周永诚.微细粒锡石浮选药剂研究概况[J].湿法冶金,2010(2):71-74.Lyu Jinfang,Tong Xiong,Zhou Yongcheng.Research status on flotation reagents for fine cassiterite[J].Hydrometallurgy of China,2010(2):71-74.
[27]林培基.铁山垅钨矿白钨与锡石分离工艺改进及生产实践[J].中国钨业,2001(2):22-25.Lin Peiji.Improvement and productive practice of separation technology of scheelite and SnO2in Tieshanlong tungsten mine[J].China Tungsten Industry,2001(2):22-25.
[28]孙伟,柯丽芳,孙磊.苯甲羟肟酸在锡石浮选中的应用及作用机理研究[J].中国矿业大学学报,2013(1):62-68.Sun Wei,Ke Lifang,Sun Lei.Study of the application and mechanism of benzohydroxamic acid in the flotation of cassiterite[J].Journal of China University of Mining&Technology,2013(1):62-68.
[29]Bulatovic S,Silvio E D.Process development for impurity removal from a tin gravity concentrate[J].Minerals Engineering,2000(8):871-879.
[30]斯雷尼瓦司·T.从印度低品位锡矿石重选尾矿中浮选回收锡的捕收剂研究[J].国外金属矿选矿,2002(2):33-38.Srenivas T.Study on collectors for flotation of Tin from low grade gravity tailings in India[J].Metallic Ore Dressing Abroad,2002(2):33-38.
[31]周少珍,孙传尧.锡石选矿进展[J].国外金属矿选矿,2002(8):10-14.Zhou Shaozhen,Sun Chuanyao.Progress in cassiterite beneficiation[J].Metallic Ore Dressing Abroad,2002(8):10-14.
[32]韦世强,舒亚汝,谭运金,等.从某钨矿选厂细泥中回收钨、锡的试验研究[J].中国钨业,2011(3):23-26.Wei Shiqiang,Shu Yaru,Tan Yunjin,et al.Tungsten and Tin recovery from tungsten fine mud in a tungsten processing plant[J].China Tungsten Industry,2011(3):23-26.
[33]朱玉霜,朱建光.F203-TBP混合捕收剂浮选锡石细泥[J].中南矿冶学院学报,1994(1):122-125.Zhu Yushuang,Zhu Jianguang.The mixture of F203and TBP as collector for the flotation of cassiterite slime[J].Journal of Central South University(Science and Technology),1994(1):122-125.
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