稠油黏度影响因素研究进展
|
摘要
分析了稠油的黏温性质及流变特性,讨论了稠油黏度的影响因素,稠油胶体体系中由胶质、沥青质缔合形成的大分子聚集体是造成稠油高黏的根本原因,而过渡金属元素(Ni,V等)及杂原子(S,N,O等)在胶质、沥青质中的富集是缔合的主要原因。
Viscosity-temperature properties and rheological properties of heavy oils are analyzed.Influencing factors of viscosity of heavy oil are discussed. It is concluded that the macromolecular aggregation suspended in the colloid system,which is caused by complex interaction forces among resins and asphaltenes,is the major reason of heavy oil's high viscosity. And the transition metals,such as nickel and vanadium,and heteroatoms,such as sulfur,nitrogen and oxygen,which are mainly distributed in resins and asphaltenes,play a considerable role in creating such interaction forces.
Viscosity-temperature properties and rheological properties of heavy oils are analyzed.Influencing factors of viscosity of heavy oil are discussed. It is concluded that the macromolecular aggregation suspended in the colloid system,which is caused by complex interaction forces among resins and asphaltenes,is the major reason of heavy oil's high viscosity. And the transition metals,such as nickel and vanadium,and heteroatoms,such as sulfur,nitrogen and oxygen,which are mainly distributed in resins and asphaltenes,play a considerable role in creating such interaction forces.
引文
[1]李春云,罗全民,刘子胜,等.春光油田超稠油高黏敏感性因素研究[J].长江大学学报:自然科学版,2015(14):78-81.
[2]包木太,范晓宁,曹秋芳,等.稠油降黏开采技术研究进展[J].油田化学,2006,23(3):284-288.
[3]孟科全,唐晓东,邹雯蚊,等.稠油降黏技术研究进展[J].天然气与石油,2009,27(3):30-34.
[4]赵法军,刘永建,王广昀,等.大庆普通稠油黏温及流变性研究[J].科学技术与工程,2010,10(31):7644-7647.
[5]秦积舜,张星,耿宏章,等.油水乳化转相黏度预测实验研究[J].石油勘探与开发,2004,31(4):132-135.
[6]朱静,李传宪,辛培刚.稠油黏温特性及流变特性分析[J].石油化工高等学校学报,2011,24(2):66-72.
[7]赵瑞玉,展学成,张超,等.特超稠油黏度的影响因素研究[J].油田化学,2016,33(2):319-324.
[8]梁文杰.重质油化学[M].东营:石油大学出版社,2000:231.
[9]韩继勇,侯云翌,郑维师.冷家稠油黏温特性及流变特性实验研究[J].西北大学学报:自然科学版,2014,44(4):610-614.
[10]齐超,于欢,吴玉国,等.辽河油田稠油流变特性实验研究[J].辽宁石油化工大学学报,2016,36(5):29-32.
[11]王风岩,嵇锐,王忠伟,等.特(超)稠油流变特性试验研究及应用[J].特种油气藏,2002,9(5):91-93.
[12]申龙涉,王戬丽,李恩田,等.含水超稠油流变性试验与研究[J].油气储运,2007,26(9):24-26.
[13]王孟江,燕收广,王超强,等.春光油田稠油流体特性研究[J].石油地质与工程,2017,31(4):67-69.
[14]范维玉,胡德燕.GL系列特稠油乳化降黏剂及其O/W型乳状液流变性研究[J].中国石油大学学报:自然科学版,1998(2):48-50.
[15]李传宪,杨飞,林名桢,等.草桥稠油O/W乳状液的稳定性与流变性研究[J].高校化学工程学报,2008,22(5):755-761.
[16]王为民,李恩田,申龙涉,等.辽河油田含水超稠油流变特性研究[J].石油化工高等学校学报,2003,16(2):69-75.
[17]贺文媛,郝清滟,李美蓉,等.温度对乳化稠油含水率反相点及增黏倍数的影响[J].石油化工高等学校学报,2016,29(1):6-9.
[18]李美蓉,于光松,张丁涌,等.稠油W/O型乳状液转相特性研究[J].油田化学,2017,34(2):335-339.
[19]Chen Gang,Tang Ying,Zhang Jie.Synthesis and application of polyaminoamide as new paraffin inhibitor from vegetable oil[J].Chem Cent J,2011,5(1):82.
[20]Zhang Jie,Sun Yan,Tang Ying,et al.Wax precipitation research of crude oil by differential scanning calorimeter[J].Adv Mater Res,2012,524/527:1730-1733.
[21]敬加强,罗平亚,朱毅飞.原油组成对其黏度影响的灰色关联分析[J].油气田地面工程,2000,19(6):12-13.
[22]韩超,吴晓南,杜洋.新疆风城稠油高黏实质及其降黏方法探析[J].重庆科技学院学报:自然科学版,2010,12(3):36-38.
[23]张红,沈本贤.蜡晶形态结构对原油降凝的影响[J].石油学报:石油加工,2006,22(5):74-79.
[24]苏慧君,陈刚,栗菁,等.玉门稠油组分特征及其对结蜡行为的影响[J].燃料化学学报,2014,42(2):187-192.
[25]Corbett L W.Composition of asphalt based on generic fractionation,using solvent deasphalting,elution-adsorption chromatography,and densimetric characterization[J].Anal Chem,1969,41(4):576-579.
[26]Peramanu S,Clarke P F,Pruden B B.Flow loop apparatus to study the effect of solvent,temperature and additives on asphaltene precipitation[J].J Pet Sci Eng,1999,23(2):133-143.
[27]Dickie J P,Yen T F.Macrostructures of the asphaltic fractions by various instrumental methods[J].Anal Chem,1967,39(14):1847-1852.
[28]程亮,杨林,邹长军,等.影响稠油黏度的化学组成灰熵分析[J].吉林化工学院学报,2006,23(2):19-23.
[29]盖平原.胜利油田稠油黏度与其组分性质的关系研究[J].油田化学,2011,28(1):54-57.
[30]汪双清,沈斌,林壬子.辽河超稠油的化学组成特征及其致黏因素探讨[J].石油学报:石油加工,2010,26(6):894-900.
[31]朱战军,林壬子,汪双清.稠油主要族组分对其黏度的影响[J].新疆石油地质,2004,25(5):512-513.
[32]汪双清,沈斌,林壬子.稠油黏度与化学组成的关系[J].石油学报:石油加工,2010,26(5):795-799.
[33]苏铁军,郑延成.稠油族组成与黏度关联研究[J].长江大学学报:自然科学版,2007,4(1):60-62.
[34]崔敏,吴乐乐,李传,等.稠油高黏因素的初步研究[J].炼油技术与工程,2013,43(6):53-58.
[35]张庆.沥青质对稠油高黏特性的影响规律研究[D].青岛:中国石油大学(华东),2014.
[36]李莹,赵德智,宋官龙,等.超声波处理对辽河油田稠油黏度的影响[J].当代化工,2016,45(12):2751-2753.
[37]王元庆.低温稠油水热裂解催化降黏研究[D].武汉:中国地质大学,2010.
[38]刘必心.沥青质对塔河稠油黏度的影响机理研究[J].中国科学:化学,2018,48(4):434-441.
[39]王大喜,郭磊,王亮,等.油溶性降黏剂降黏降凝作用机理的理论与实验研究[J].油田化学,2010,27(3):314-319.
[40]崔青,张长桥,修建新,等.稠油沥青质胶质降黏机理的分子动力学模拟[J].山东大学学报:工学版,2017,47(2):123-130.
[41]Pacheco-Sánchez J H,Zaragoza I P,Martínez-Magadán J M.Asphaltene aggregation under vacuum at different temperatures by molecular dynamics[J].Energy Fuels,2003,17(5):1346-1355.
[42]Pacheco-Sánchez J H,Alvarez-Ramirez F,MartínezMagadán J M.Morphology of aggregated asphaltene structural models[J].Energy Fuels,2004,18(6):1676-1686.
[43]Wattana P,Fogler H S,Yen A,et al.Characterization of polarity-based asphaltene subfractions[J].Energy Fuels,2005,19(1):101-110.
[44]Sheu E Y,Mullins O C.Asphaltenes:Fundamentals and Applications[M].New York:Plenum Press,1995:1-52.
[45]Paul M H,Rao B M L.The role of polar species in the aggregation of asphaltenes[J].Fuel Sci Technol Int,1987,5(2):119-168.
[46]Moschopedis S E,Fryer J F,Speight J G.Investigation of asphaltene molecular weights[J].Fuel,1976,55(3):227-232.
[47]Speight J G,Moschopedis S E.Some observations of the molecular“nature”of petroleum asphaltenes[J].Div Petrol Chem,ACS,1979,24(4):910-923.
[48]程亮,杨林,罗陶涛,等.稠油分散体系中黏度与化学组成的灰熵关系分析[J].西安石油大学学报:自然科学版,2007,22(3):92-95.
[49]程玉桥.胜利油田单家寺油区稠油物理化学性质研究[D].杭州:浙江大学,2002.
[50]刘永建,刘喜林.稠油的水热裂解反应及其降黏机理[J].东北石油大学学报,2002,26(3):95-98.
[51]吴川,雷光伦,姚传进,等.双亲催化剂作用超稠油水热裂解降黏机理研究[J].燃料化学学报,2010,38(6):684-690.
[52]林日亿,罗建军,王新伟,等.非含硫金属盐对稠油水热裂解生成硫化氢影响实验[J].石油学报,2016,37(2):237-241.
[53]赵天波,祁鲁梁,汪燮卿.我国一些原油中盐类的组成及脱盐效果的研究[J].石油学报:石油加工,1988(3):80-85.
[54]侯典国,汪燮卿.我国一些原油中钙化合物分布及形态的研究[J].石油学报:石油加工,2000,16(1):54-59.
[55]武本成,黄延召,朱建华.稠油中金属元素含量对其黏度的影响研究[C]//第五届全国化学工程与生物化工年会论文集.西安:西北大学,2008:592.
[56]蒋昌启,朱建华,刘红研,等.超稠油化学降黏脱水技术[J].青岛科技大学学报,2005,26(2):109-113.
[57]Duong A,Chattopadhyaya G,Kwok W Y,et al.An experimental study of heavy oil ultrafiltration using ceramic membranes[J].Fuel,1997,76(9):821-828.
[2]包木太,范晓宁,曹秋芳,等.稠油降黏开采技术研究进展[J].油田化学,2006,23(3):284-288.
[3]孟科全,唐晓东,邹雯蚊,等.稠油降黏技术研究进展[J].天然气与石油,2009,27(3):30-34.
[4]赵法军,刘永建,王广昀,等.大庆普通稠油黏温及流变性研究[J].科学技术与工程,2010,10(31):7644-7647.
[5]秦积舜,张星,耿宏章,等.油水乳化转相黏度预测实验研究[J].石油勘探与开发,2004,31(4):132-135.
[6]朱静,李传宪,辛培刚.稠油黏温特性及流变特性分析[J].石油化工高等学校学报,2011,24(2):66-72.
[7]赵瑞玉,展学成,张超,等.特超稠油黏度的影响因素研究[J].油田化学,2016,33(2):319-324.
[8]梁文杰.重质油化学[M].东营:石油大学出版社,2000:231.
[9]韩继勇,侯云翌,郑维师.冷家稠油黏温特性及流变特性实验研究[J].西北大学学报:自然科学版,2014,44(4):610-614.
[10]齐超,于欢,吴玉国,等.辽河油田稠油流变特性实验研究[J].辽宁石油化工大学学报,2016,36(5):29-32.
[11]王风岩,嵇锐,王忠伟,等.特(超)稠油流变特性试验研究及应用[J].特种油气藏,2002,9(5):91-93.
[12]申龙涉,王戬丽,李恩田,等.含水超稠油流变性试验与研究[J].油气储运,2007,26(9):24-26.
[13]王孟江,燕收广,王超强,等.春光油田稠油流体特性研究[J].石油地质与工程,2017,31(4):67-69.
[14]范维玉,胡德燕.GL系列特稠油乳化降黏剂及其O/W型乳状液流变性研究[J].中国石油大学学报:自然科学版,1998(2):48-50.
[15]李传宪,杨飞,林名桢,等.草桥稠油O/W乳状液的稳定性与流变性研究[J].高校化学工程学报,2008,22(5):755-761.
[16]王为民,李恩田,申龙涉,等.辽河油田含水超稠油流变特性研究[J].石油化工高等学校学报,2003,16(2):69-75.
[17]贺文媛,郝清滟,李美蓉,等.温度对乳化稠油含水率反相点及增黏倍数的影响[J].石油化工高等学校学报,2016,29(1):6-9.
[18]李美蓉,于光松,张丁涌,等.稠油W/O型乳状液转相特性研究[J].油田化学,2017,34(2):335-339.
[19]Chen Gang,Tang Ying,Zhang Jie.Synthesis and application of polyaminoamide as new paraffin inhibitor from vegetable oil[J].Chem Cent J,2011,5(1):82.
[20]Zhang Jie,Sun Yan,Tang Ying,et al.Wax precipitation research of crude oil by differential scanning calorimeter[J].Adv Mater Res,2012,524/527:1730-1733.
[21]敬加强,罗平亚,朱毅飞.原油组成对其黏度影响的灰色关联分析[J].油气田地面工程,2000,19(6):12-13.
[22]韩超,吴晓南,杜洋.新疆风城稠油高黏实质及其降黏方法探析[J].重庆科技学院学报:自然科学版,2010,12(3):36-38.
[23]张红,沈本贤.蜡晶形态结构对原油降凝的影响[J].石油学报:石油加工,2006,22(5):74-79.
[24]苏慧君,陈刚,栗菁,等.玉门稠油组分特征及其对结蜡行为的影响[J].燃料化学学报,2014,42(2):187-192.
[25]Corbett L W.Composition of asphalt based on generic fractionation,using solvent deasphalting,elution-adsorption chromatography,and densimetric characterization[J].Anal Chem,1969,41(4):576-579.
[26]Peramanu S,Clarke P F,Pruden B B.Flow loop apparatus to study the effect of solvent,temperature and additives on asphaltene precipitation[J].J Pet Sci Eng,1999,23(2):133-143.
[27]Dickie J P,Yen T F.Macrostructures of the asphaltic fractions by various instrumental methods[J].Anal Chem,1967,39(14):1847-1852.
[28]程亮,杨林,邹长军,等.影响稠油黏度的化学组成灰熵分析[J].吉林化工学院学报,2006,23(2):19-23.
[29]盖平原.胜利油田稠油黏度与其组分性质的关系研究[J].油田化学,2011,28(1):54-57.
[30]汪双清,沈斌,林壬子.辽河超稠油的化学组成特征及其致黏因素探讨[J].石油学报:石油加工,2010,26(6):894-900.
[31]朱战军,林壬子,汪双清.稠油主要族组分对其黏度的影响[J].新疆石油地质,2004,25(5):512-513.
[32]汪双清,沈斌,林壬子.稠油黏度与化学组成的关系[J].石油学报:石油加工,2010,26(5):795-799.
[33]苏铁军,郑延成.稠油族组成与黏度关联研究[J].长江大学学报:自然科学版,2007,4(1):60-62.
[34]崔敏,吴乐乐,李传,等.稠油高黏因素的初步研究[J].炼油技术与工程,2013,43(6):53-58.
[35]张庆.沥青质对稠油高黏特性的影响规律研究[D].青岛:中国石油大学(华东),2014.
[36]李莹,赵德智,宋官龙,等.超声波处理对辽河油田稠油黏度的影响[J].当代化工,2016,45(12):2751-2753.
[37]王元庆.低温稠油水热裂解催化降黏研究[D].武汉:中国地质大学,2010.
[38]刘必心.沥青质对塔河稠油黏度的影响机理研究[J].中国科学:化学,2018,48(4):434-441.
[39]王大喜,郭磊,王亮,等.油溶性降黏剂降黏降凝作用机理的理论与实验研究[J].油田化学,2010,27(3):314-319.
[40]崔青,张长桥,修建新,等.稠油沥青质胶质降黏机理的分子动力学模拟[J].山东大学学报:工学版,2017,47(2):123-130.
[41]Pacheco-Sánchez J H,Zaragoza I P,Martínez-Magadán J M.Asphaltene aggregation under vacuum at different temperatures by molecular dynamics[J].Energy Fuels,2003,17(5):1346-1355.
[42]Pacheco-Sánchez J H,Alvarez-Ramirez F,MartínezMagadán J M.Morphology of aggregated asphaltene structural models[J].Energy Fuels,2004,18(6):1676-1686.
[43]Wattana P,Fogler H S,Yen A,et al.Characterization of polarity-based asphaltene subfractions[J].Energy Fuels,2005,19(1):101-110.
[44]Sheu E Y,Mullins O C.Asphaltenes:Fundamentals and Applications[M].New York:Plenum Press,1995:1-52.
[45]Paul M H,Rao B M L.The role of polar species in the aggregation of asphaltenes[J].Fuel Sci Technol Int,1987,5(2):119-168.
[46]Moschopedis S E,Fryer J F,Speight J G.Investigation of asphaltene molecular weights[J].Fuel,1976,55(3):227-232.
[47]Speight J G,Moschopedis S E.Some observations of the molecular“nature”of petroleum asphaltenes[J].Div Petrol Chem,ACS,1979,24(4):910-923.
[48]程亮,杨林,罗陶涛,等.稠油分散体系中黏度与化学组成的灰熵关系分析[J].西安石油大学学报:自然科学版,2007,22(3):92-95.
[49]程玉桥.胜利油田单家寺油区稠油物理化学性质研究[D].杭州:浙江大学,2002.
[50]刘永建,刘喜林.稠油的水热裂解反应及其降黏机理[J].东北石油大学学报,2002,26(3):95-98.
[51]吴川,雷光伦,姚传进,等.双亲催化剂作用超稠油水热裂解降黏机理研究[J].燃料化学学报,2010,38(6):684-690.
[52]林日亿,罗建军,王新伟,等.非含硫金属盐对稠油水热裂解生成硫化氢影响实验[J].石油学报,2016,37(2):237-241.
[53]赵天波,祁鲁梁,汪燮卿.我国一些原油中盐类的组成及脱盐效果的研究[J].石油学报:石油加工,1988(3):80-85.
[54]侯典国,汪燮卿.我国一些原油中钙化合物分布及形态的研究[J].石油学报:石油加工,2000,16(1):54-59.
[55]武本成,黄延召,朱建华.稠油中金属元素含量对其黏度的影响研究[C]//第五届全国化学工程与生物化工年会论文集.西安:西北大学,2008:592.
[56]蒋昌启,朱建华,刘红研,等.超稠油化学降黏脱水技术[J].青岛科技大学学报,2005,26(2):109-113.
[57]Duong A,Chattopadhyaya G,Kwok W Y,et al.An experimental study of heavy oil ultrafiltration using ceramic membranes[J].Fuel,1997,76(9):821-828.