石墨烯基催化剂用于生物质转化的研究进展
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摘要
在介绍石墨烯基催化剂的结构和性质的基础上,重点综述了石墨烯基催化剂在催化生物质转化为高附加值化学品方面的最新研究进展,并展望了其在Pickering乳液界面催化体系中的应用前景。
Based on introduction to the structure and properties of graphene-based catalysts,the latest research progress of graphene-based catalysts in the conversion of biomass to high value-added chemicals is reviewed. The application of the catalysts in the Pickering emulsion interface are also prospected.
Based on introduction to the structure and properties of graphene-based catalysts,the latest research progress of graphene-based catalysts in the conversion of biomass to high value-added chemicals is reviewed. The application of the catalysts in the Pickering emulsion interface are also prospected.
引文
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[13]Wang H,Kong Q,Wang Y,et al.Graphene oxide catalyzed dehydration of fructose into 5-hydroxymethylfurfural with isopropanol as cosolvent[J].Chem Cat Chem,2014,6(3):728-732.
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[18]Blandez J F,Navalón S,Alvaro M,et al. Graphenes as metal-free catalysts for the oxidative depolymerization of lignin models[J].Chem Cat Chem,2015,7(18):3020-3026.
[19]Zhang T,Li W,Xu Z,et al.Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst inγ-valerolactone[J].Bioresource Technology,2016,209:108-114.
[20]Fukuhara K,Nakajima K,Kitano M,et al.Transesterification of triolein over hydrophobic microporous carbon with SO3H Groups[J].Chem Cat Chem,2015,7(23):3945-3950.
[21]Zhu S,Wang J,Fan W.Graphene-based catalysis for biomass conversion[J].Catalysis Science&Technology,2015,5(8):3845-3858.
[22]Wei Z,Yang Y,Hou Y,et al.A new approach towards acid catalysts with high reactivity based on graphene nanosheets[J]. Chem Cat Chem,2014,6(8):2354-2363.
[23]Upare P P,Hong D Y,Kwak J,et al.Direct chemical conversion of xylan into furfural over sulfonated graphene oxide[J].Catalysis Today,2019,324:66-72.
[24]Liu F,Kong W,Wang L,et al.Efficient biomass transformations catalyzed by graphene-like nanoporous carbons functionalized with strong acid ionic liquids and sulfonic groups[J].Green Chemistry,2015,17(1):480-489.
[25]Wang Y,De S,Yan N.Rational control of nano-scale metal-catalysts for biomass conversion[J]. Chemical Communications,2016,52(37):6210-6224.
[26]Chen C C,Lin C L,Chen L C.Functionalized carbon nanomaterial supported palladium nano-catalysts for electrocatalytic glucose oxidation reaction[J].Electrochimica Acta,2015,152:408-416.
[27]Wang D,Niu W,Tan M,et al. Pt nanocatalysts supported on reduced graphene oxide for selective conversion of cellulose or cellobiose to sorbitol[J].Chem Sus Chem,2014,7(5):1398-1406.
[28]Zhang M,Su K,Song H,et al.The excellent performance of amorphous Cr2O3,SnO2,SrO and graphene oxide-ferric oxide in glucose conversion into 5-HMF[J]. Catalysis Communications,2015,69:76-80.
[29]Shi J,Wang Y,Yu X,et al.Production of 2,5-dimethylfuran from 5-hydroxymethylfurfural over reduced graphene oxides supported Pt catalyst under mild conditions[J].Fuel,2016,163:74-79.
[2]Zhang T,Li W,Xu Z,et al.Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst inγ-valerolactone[J].Bioresource Technology,2016,209:108-114.
[3]Zhang L,Alvarez N T,Zhang M,et al.Preparation and characterization of graphene paper for electromagnetic interference shielding[J].Carbon,2015,82(30):353-359.
[4]Yin P T,Shah S,Chhowalla M,et al.Design,synthesis,and characterization of graphene-nanoparticle hybrid materials for bioapplications[J].Chemical Reviews,2015,115(7):2483-2531.
[5]Georgakilas V,Tiwari J N,Kemp K C,et al.Noncovalent functionalization of graphene and graphene oxide for energy materials,biosensing,catalytic,and biomedical applications[J]. Chemical Reviews,2016,116(9):5464-5519.
[6]Xing C,Tan R,Hao P,et al. Graphene oxide supported chlorostannate(Ⅳ)ionic liquid:Brnsted-Lewis acidic combined catalyst for highly efficient Baeyer-Villiger oxidation in water[J].Molecular Catalysis,2017,433:37-47.
[7]Navalon S,Dhakshinamoorthy A,Alvaro M,et al.Carbocatalysis by graphene-based materials[J]. Chemical Reviews,2014,114(12):6179-6212.
[8]Zhao X,Wang J,Chen C,et al.Graphene oxide for cellulose hydrolysis:How it works as a highly active catalyst[J].Chemical Communications,2014,50(26):3439-3442.
[9]Hu L,Lin L,Wu Z,et al.Chemocatalytic hydrolysis of cellulose into glucose over solid acid catalysts[J]. Applied Catalysis B Environmental,2015,46(22):225-243.
[10]Zhang M,Wu M,Liu Q,et al.Graphene oxide mediated cellulosederived carbon as a highly selective catalyst for the hydrolysis of cellulose to glucose[J]. Applied Catalysis A:General,2017,543:218-224.
[11]Mission E G,Quitain A T,Hirano Y,et al.Integrating reduced graphene oxide with microwave-subcritical water for cellulose depolymerization[J]. Catalysis Science&Technology,2018,8(21):5434-5444.
[12]Deng W,Zhang Q,Wang Y. Catalytic transformations of cellulose and its derived carbohydrates into 5-hydroxymethylfurfural,levulinic acid,and lactic acid[J]. Science China Chemistry,2015,58(1):29-46.
[13]Wang H,Kong Q,Wang Y,et al.Graphene oxide catalyzed dehydration of fructose into 5-hydroxymethylfurfural with isopropanol as cosolvent[J].Chem Cat Chem,2014,6(3):728-732.
[14]Mondal D,Chaudhary J P,Sharma M,et al. Simultaneous dehydration of biomass-derived sugars to 5-hydroxymethyl furfural(HMF)and reduction of graphene oxide in ethyl lactate:One pot dual chemistry[J].RSC Advances,2014,4(56):29834-29839.
[15]Sedrpoushan A,Heidari M,Akhavan O. Nanoscale graphene oxide sheets as highly efficient carbocatalysts in green oxidation of benzylic alcohols and aromatic aldehydes[J]. Chinese Journal of Catalysis,2017,38(4):745-757.
[16]Xiong H,Schwartz T J,Andersen N I,et al.Graphitic-carbon layers on oxides:Toward stable heterogeneous catalysts for biomass conversion reactions[J]. Angewandte Chemie International Edition,2015,54(27):7939-7943.
[17]Dhakshinamoorthy A,Latorre-Sanchez M,Asiri A M,et al.Sulphurdoped graphene as metal-free carbocatalysts for the solventless aerobic oxidation of styrenes[J]. Catalysis Communications,2015,65:10-13.
[18]Blandez J F,Navalón S,Alvaro M,et al. Graphenes as metal-free catalysts for the oxidative depolymerization of lignin models[J].Chem Cat Chem,2015,7(18):3020-3026.
[19]Zhang T,Li W,Xu Z,et al.Catalytic conversion of xylose and corn stalk into furfural over carbon solid acid catalyst inγ-valerolactone[J].Bioresource Technology,2016,209:108-114.
[20]Fukuhara K,Nakajima K,Kitano M,et al.Transesterification of triolein over hydrophobic microporous carbon with SO3H Groups[J].Chem Cat Chem,2015,7(23):3945-3950.
[21]Zhu S,Wang J,Fan W.Graphene-based catalysis for biomass conversion[J].Catalysis Science&Technology,2015,5(8):3845-3858.
[22]Wei Z,Yang Y,Hou Y,et al.A new approach towards acid catalysts with high reactivity based on graphene nanosheets[J]. Chem Cat Chem,2014,6(8):2354-2363.
[23]Upare P P,Hong D Y,Kwak J,et al.Direct chemical conversion of xylan into furfural over sulfonated graphene oxide[J].Catalysis Today,2019,324:66-72.
[24]Liu F,Kong W,Wang L,et al.Efficient biomass transformations catalyzed by graphene-like nanoporous carbons functionalized with strong acid ionic liquids and sulfonic groups[J].Green Chemistry,2015,17(1):480-489.
[25]Wang Y,De S,Yan N.Rational control of nano-scale metal-catalysts for biomass conversion[J]. Chemical Communications,2016,52(37):6210-6224.
[26]Chen C C,Lin C L,Chen L C.Functionalized carbon nanomaterial supported palladium nano-catalysts for electrocatalytic glucose oxidation reaction[J].Electrochimica Acta,2015,152:408-416.
[27]Wang D,Niu W,Tan M,et al. Pt nanocatalysts supported on reduced graphene oxide for selective conversion of cellulose or cellobiose to sorbitol[J].Chem Sus Chem,2014,7(5):1398-1406.
[28]Zhang M,Su K,Song H,et al.The excellent performance of amorphous Cr2O3,SnO2,SrO and graphene oxide-ferric oxide in glucose conversion into 5-HMF[J]. Catalysis Communications,2015,69:76-80.
[29]Shi J,Wang Y,Yu X,et al.Production of 2,5-dimethylfuran from 5-hydroxymethylfurfural over reduced graphene oxides supported Pt catalyst under mild conditions[J].Fuel,2016,163:74-79.
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