氟虫腈检测方法研究进展
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摘要
氟虫腈是含氟吡唑类广谱性杀虫剂,活性高且应用范围广,但是其生物毒性对环境会产生危害。论文综述了目前国内外氟虫腈残留危害及其检测方面的研究方法和成果,用于氟虫腈药物残留检测的方法主要有气相色谱法、液相色谱-串联质谱法、高效液相色谱法、电子捕获和质谱检测的气相色谱法、酶联免疫吸附测定法等,在此基础上进行了合理的展望,以期为今后研究和开发新型氟虫腈药物残留检测方法提供参考。
Fipronil is a broad spectrum insecticide containing pyrazolone,which has high activity and wide application,but its biological toxicity can cause harm to the environment.In this paper,the current research methods and achievements in the determination of fipronil residues in domestic and foreign countries were reviewed.The main methods for the determination of fipronil residues are gas chromatography,liquid chromatography-tandem mass spectrometry,high performance liquid chromatography,gas chromatography with electron capture and mass spectrometry,enzyme-linked immunosorbent assay,etc.Based on this,reasonable expectations were made for the purpose of providing reference for the future research and development of a novel method for the determination of fipronil residues.
Fipronil is a broad spectrum insecticide containing pyrazolone,which has high activity and wide application,but its biological toxicity can cause harm to the environment.In this paper,the current research methods and achievements in the determination of fipronil residues in domestic and foreign countries were reviewed.The main methods for the determination of fipronil residues are gas chromatography,liquid chromatography-tandem mass spectrometry,high performance liquid chromatography,gas chromatography with electron capture and mass spectrometry,enzyme-linked immunosorbent assay,etc.Based on this,reasonable expectations were made for the purpose of providing reference for the future research and development of a novel method for the determination of fipronil residues.
引文
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[2] 张芳芳,洪雅青,张幸.氟虫腈的毒理学研究进展[J].职业与健康,2008,24(20):2211-2213.
[3] 郑仙珏.“毒鸡蛋”事件凸显农药滥用危害[J].生态经济,2017,33(10):2-5.
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[7] Gibbons D,Morrissey C,Mineau P.A review of the direct and indirect effects of neonicotinoidsand fipronil on vertebrate wildlife[J].Environ Sci Pollut Res,2015,22(1):103-118.
[8] Yadla M,Sailaja S,Ahmed N,et al.An unusual case of insecticide poisoning presenting as acute kidney injury[J].Saudi J Kidney Dis Transpl,2017,28(6):1432-1434.
[9] Bonmatin J M,Giorio C,Girolami V,et al.Environmental fate and exposure;neonicotinoids and fipronil[J].Environ SciPollut Res,2015,22(1):35-67.
[10] GB2567-2017,限制使用农药名录[S].
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[12] 武中平,高巍,颜春荣,等.氟虫腈高效液相色谱分析方法的研究[J].现代农药,2006,5(2):21-23.
[13] Hafeez A,Tawab IA,Iqbal S,et al.Development and validation of an HPLC method for the simultaneous determination of fipronil,chlorfenapyr,and pyriproxyfen in insecticide formulations[J].J Aoac Int,2016,99(5):1185-1190.
[14] Li M H,Li P Y,Wang L,et al.Determination and dissipation of fipronil and its metabolites in peanut and soil[J].Agric Food Chem,2015,63:4435-4443.
[15] Wu X H,Yu Y,Xu J,et al.Residue analysis and persistence evaluation of fipronil and its metabolites in cotton using high-performance liquid chromatography-tandem mass spectrometry[J].PLoS One,2017,12(3):e0173690.
[16] Rama R K S,Isha T,Mamunur R,et al.DBS-platform for biomonitoring and toxicokinetics of toxicants:proof of concept using LC-MS/MS analysis of fipronil and its metabolites in blood[J].Sci Rep,2016,6,22447.
[17] Zhang M Y,Bian K,Zhou T,et al.Determination of residual fipronil in chicken egg and muscle by LC-MS/MS[J].J Chromatogr B,2016,1(14):31-36.
[18] 郭德华,时逸吟,李优,等.固相萃取-液相色谱-四极杆飞行时间质谱法快速筛查禽蛋及蛋制品中氟虫腈及其代谢物[J].色谱,2017,35(12):1216-1223.
[19] 吕冰,尹帅星,陈达炜,等.QuEChERS-四极杆/静电场轨道阱高分辨质谱测定动物性食品中氟虫腈及其代谢物残留[J].分析测试学报,2017,36(12):1424-1430.
[20] Jiménez J J,Bernal J L,del Nozal M J,et al.Comparative study of sample preparation procedures to determine fipronil in pollen by gas chromatography with mass spectrometric and electron-capture detection[J].J Chromatogr A,2007,1146(1):8-16.
[21] Bichon E,Richard C A,Le B B.Development and validation of a method for fipronil residue determination in ovine plasma using 96-well plate solid-phase extraction and gas chromatography-tandem mass spectrometry[J].J Chromatogr A,2008,12(01):91-99.
[22] 丁立平,郭菁,郑铃,等.多重吸附同步净化-气相色谱-质谱法测定干性样品中丁烯氟虫腈的残留量[J].色谱,2013,31(8):747-752.
[23] Jiménez J J,Bernal J L,del Nozal M J,et al.Sample preparation methods to analyze fipronil in honey by gas chromatography with electron-capture and mass spectrometric detection[J].J Chromatogr A,2008,1187(1):40-45.
[24] Flores-Ramírez R,Batres-Esquivel L E,Diaz-Barriga Martinez F,et al.Development and validation of an analytical method to determine fipronil and its degradation products in soil samples[J].Bull Environ ContamToxicol,2012,89(4):744-750.
[25] Wang T L,Hu J Y,Liu C L.Simultaneous determination of insecticide fipronil and its metabolites in maize and soil by gas chromatography with electron capture detection[J].Environ Monit Assess,2014,186(5):2767-2774.
[26] Vasylieva N,Ahn K C,Barnych B,et al.Development of an immunoassay for the detection of the phenylpyrazole insecticide fipronil [J].Environ Sci Technol,2015,49(16):10038-10047.
[27] Liu X J,Yan C R,Dong J,et al.Poly-and monoclonal antibody-based ELISAs for fipronil [J].Agric Food Chem,2007,55(2):226-230.
[28] 李盼,张晓帅,邱雨楼,等.有机磷农药广谱特异性单克隆抗体的制备及特性分析[J].Jiangsu J of Agr Sci,2017,33(6):1415-1421.
[29] 史建国,李一苇,张先恩.我国生物传感器研究现状及发展方向[J].山东科学,2015,28(1):28-35.
[30] 王晓骏.磺胺类药物表面等离子共振免疫传感检测研究[D].天津:天津科技大学食品工程系,2015.
[2] 张芳芳,洪雅青,张幸.氟虫腈的毒理学研究进展[J].职业与健康,2008,24(20):2211-2213.
[3] 郑仙珏.“毒鸡蛋”事件凸显农药滥用危害[J].生态经济,2017,33(10):2-5.
[4] van J P,Amaralrogers V,Belzunces L P,et al.Conclusions of the Worldwide Integrated Assessment on the risks of neonicotinoids and fipronil to biodiversity and ecosystem functioning[J].Environ Sci Pollut Res,2015,22(1):148-154.
[5] 徐广春,顾中言,杨玉清,等.氟虫腈的应用和风险研究进展[J].现代农药,2008,7(2):1-5.
[6] Merkowsky K,Sethi R S,Gill J P S,et al.Fipronil induces lung inflammation in vivo and cell death in vitro[J].J Occup Med Toxicol,2016,11(1):1-10.
[7] Gibbons D,Morrissey C,Mineau P.A review of the direct and indirect effects of neonicotinoidsand fipronil on vertebrate wildlife[J].Environ Sci Pollut Res,2015,22(1):103-118.
[8] Yadla M,Sailaja S,Ahmed N,et al.An unusual case of insecticide poisoning presenting as acute kidney injury[J].Saudi J Kidney Dis Transpl,2017,28(6):1432-1434.
[9] Bonmatin J M,Giorio C,Girolami V,et al.Environmental fate and exposure;neonicotinoids and fipronil[J].Environ SciPollut Res,2015,22(1):35-67.
[10] GB2567-2017,限制使用农药名录[S].
[11] GB2763-2016,食品中农药最大残留限量[S].
[12] 武中平,高巍,颜春荣,等.氟虫腈高效液相色谱分析方法的研究[J].现代农药,2006,5(2):21-23.
[13] Hafeez A,Tawab IA,Iqbal S,et al.Development and validation of an HPLC method for the simultaneous determination of fipronil,chlorfenapyr,and pyriproxyfen in insecticide formulations[J].J Aoac Int,2016,99(5):1185-1190.
[14] Li M H,Li P Y,Wang L,et al.Determination and dissipation of fipronil and its metabolites in peanut and soil[J].Agric Food Chem,2015,63:4435-4443.
[15] Wu X H,Yu Y,Xu J,et al.Residue analysis and persistence evaluation of fipronil and its metabolites in cotton using high-performance liquid chromatography-tandem mass spectrometry[J].PLoS One,2017,12(3):e0173690.
[16] Rama R K S,Isha T,Mamunur R,et al.DBS-platform for biomonitoring and toxicokinetics of toxicants:proof of concept using LC-MS/MS analysis of fipronil and its metabolites in blood[J].Sci Rep,2016,6,22447.
[17] Zhang M Y,Bian K,Zhou T,et al.Determination of residual fipronil in chicken egg and muscle by LC-MS/MS[J].J Chromatogr B,2016,1(14):31-36.
[18] 郭德华,时逸吟,李优,等.固相萃取-液相色谱-四极杆飞行时间质谱法快速筛查禽蛋及蛋制品中氟虫腈及其代谢物[J].色谱,2017,35(12):1216-1223.
[19] 吕冰,尹帅星,陈达炜,等.QuEChERS-四极杆/静电场轨道阱高分辨质谱测定动物性食品中氟虫腈及其代谢物残留[J].分析测试学报,2017,36(12):1424-1430.
[20] Jiménez J J,Bernal J L,del Nozal M J,et al.Comparative study of sample preparation procedures to determine fipronil in pollen by gas chromatography with mass spectrometric and electron-capture detection[J].J Chromatogr A,2007,1146(1):8-16.
[21] Bichon E,Richard C A,Le B B.Development and validation of a method for fipronil residue determination in ovine plasma using 96-well plate solid-phase extraction and gas chromatography-tandem mass spectrometry[J].J Chromatogr A,2008,12(01):91-99.
[22] 丁立平,郭菁,郑铃,等.多重吸附同步净化-气相色谱-质谱法测定干性样品中丁烯氟虫腈的残留量[J].色谱,2013,31(8):747-752.
[23] Jiménez J J,Bernal J L,del Nozal M J,et al.Sample preparation methods to analyze fipronil in honey by gas chromatography with electron-capture and mass spectrometric detection[J].J Chromatogr A,2008,1187(1):40-45.
[24] Flores-Ramírez R,Batres-Esquivel L E,Diaz-Barriga Martinez F,et al.Development and validation of an analytical method to determine fipronil and its degradation products in soil samples[J].Bull Environ ContamToxicol,2012,89(4):744-750.
[25] Wang T L,Hu J Y,Liu C L.Simultaneous determination of insecticide fipronil and its metabolites in maize and soil by gas chromatography with electron capture detection[J].Environ Monit Assess,2014,186(5):2767-2774.
[26] Vasylieva N,Ahn K C,Barnych B,et al.Development of an immunoassay for the detection of the phenylpyrazole insecticide fipronil [J].Environ Sci Technol,2015,49(16):10038-10047.
[27] Liu X J,Yan C R,Dong J,et al.Poly-and monoclonal antibody-based ELISAs for fipronil [J].Agric Food Chem,2007,55(2):226-230.
[28] 李盼,张晓帅,邱雨楼,等.有机磷农药广谱特异性单克隆抗体的制备及特性分析[J].Jiangsu J of Agr Sci,2017,33(6):1415-1421.
[29] 史建国,李一苇,张先恩.我国生物传感器研究现状及发展方向[J].山东科学,2015,28(1):28-35.
[30] 王晓骏.磺胺类药物表面等离子共振免疫传感检测研究[D].天津:天津科技大学食品工程系,2015.
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