绿色生物防污剂及控制释放技术研究进展
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摘要
基于传统防污剂的毒性危害和释放不稳定性问题,聚焦于绿色生物防污剂和防污剂缓控释放技术,总结天然生物防污剂和人工合成防污剂近年来的相关研究进展。微纳米管控释技术、微胶囊包覆技术和温敏水凝胶控释技术在控释方面具有显著优势,综述其最新进展,并给出未来开发绿色防污剂和新型防污剂控释技术方面的相关建议。
It is well known that toxic hazards and releasing instability of traditional antifouling agent are urgent problems to be resolved. The latest progresses in green biological antifoulant, both natural biological antifouling agents and synthetic antifouling agents, are summarized and presented in the paper. In addition, the controlled release technologies, including micro nanotube controlled release technology, microencapsulation technology and thermosensitive hydrogel controlled release technology, have significant advantages. Their progresses in recent years are reviewed as well. The suggestions on the researches and developments of green anfouling agents and new controlled release technology are proposed to provide a guide direction.
It is well known that toxic hazards and releasing instability of traditional antifouling agent are urgent problems to be resolved. The latest progresses in green biological antifoulant, both natural biological antifouling agents and synthetic antifouling agents, are summarized and presented in the paper. In addition, the controlled release technologies, including micro nanotube controlled release technology, microencapsulation technology and thermosensitive hydrogel controlled release technology, have significant advantages. Their progresses in recent years are reviewed as well. The suggestions on the researches and developments of green anfouling agents and new controlled release technology are proposed to provide a guide direction.
引文
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[13]纪伟尚,徐怀恕,沈福逊.应用固定化硫杆菌防除海洋污着生物的初步研究[J].海洋湖沼通报,1989,80(3):32-37.
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[15]吕明霞,王锦艳,寇艳,等.可UV固化的辣椒碱型杂萘联苯环氧丙烯酸酯防污涂料[J].化工新型材料,2009,37(1):69-71.
[16]PéREZ M,BLUSTEIN G,GARCIS M,et al.Cupric tannate:A low copper content antifouling pigment[J].Progress in Organic Coatings,2006,55(4):311-315.
[17]RELEASE BELLOTTI N,DEYA C,AMO B,et al.Antifouling Paints with Zinc“Tannate”[J].Industrial&Engineering Chemistry Research,2010,49(7):3386-3390.
[18]王华进,刘登良,王贤明.无毒硅酸盐防污剂及其制备方法[P].CN 1218818 A.1999.
[19]李慧,杨旭石,廖本仁.新型海洋防污剂的研究现状及发展趋势[J].上海化工,2014,39(08):31-34.
[20]王广金,褚良银,陈文梅,等.微生物固定化聚醚砜微囊载体的制备及其性能研究[J].四川大学学报(工程科学版),2005,(3):47-51.
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[22]汪小伟,付玉彬,张经纬,等.纳米钛酸管对防污剂异噻唑酮的控释作用[J].精细化工,2007,24(3):213-216.
[23]Dai,David Junhui,Willingham,et al.Controlled release compositions[P].Patent 6676954,2004.
[24]陈守刚,刘丹,王洪芬,等.改性碳纳米管/壳聚糖复合材料的制备及防污性能[J].化工学报,2015(11)4689-4695.
[25]汪小伟,时清亮,付玉彬.铜微球对防污剂异噻唑酮的控释作用[J].精细化工,2007,24(10):944-947.
[26]Pothakamury U R,Barbosa-Cánovas G V.Fundamental aspects of controlled release in foods[J].Trends in Food Science&Technology,1995,6(12):397-406.
[27]S?RENSEN G,NIELSEN A L,PEDERAEN M M,et al.Controlled release of biocide from silica microparticles in wood paint[J].Progress in Organic Coatings,2010,68(4):299-306.
[28]史航,石建高,陈晓蕾,等.包埋苯甲酸钠微球的制备及在海洋防污涂料中的抑菌研究[J].高分子通报,2011(1):65-70.
[29]宋福来,邵凯,刘万顺,等.壳聚糖即型水凝胶的理化性质、止血功能和生物相容性研究[J].功能材料,2014(9):65-69.
[30]PENG Z,CHEN F.Synthesis and Properties of TemperatureSensitive Hydrogel Based on Hydroxyethyl Cellulose[J].International Journal of Polymeric Materials,2010,59(6):450-461.
[31]SERRA M.Adaptable skin-hydrogel gives wetsuit protection[J].Smart Materials Bulletin,2002,2002(8):7-8.
[32]许凤玲,蔺存国,于泓先,等.海洋防污剂及其缓控释技术进展[J].材料开发与应用,2013(3):119-122.
[2]YAMASHITA N,ETOH H,SAKATA K,et al.New acrylated rhaponticin isolared from eucalyptus rubida as a repellent against the blue mussel mytilus edulis[J].Agricultural&Biological Chemistry,1989,53(10):2827-2829.
[3]HODO S.et al.Biosci[J].Biotech.Biochem,1992,56.
[4]ETOH H,KONDOH T,YOSHIOKA N,et al.9-Oxo-neoprocurcumenol from Curcuma aromatica(Zingiberaceae)as an Attachment Inhibitor against the Blue Mussel,Mytilus edulis galloprovincialis(Organic Chemistry)[J].Bioscience Biotechnology&Biochemistry,2003,67(4):911-913.
[5]ETOH H,KONDOH T,NODA R,et al.Shogaols from zingiber officinale as promising antifouling agents[J].Bioscience Biotechnology&Biochemistry,2002,66(8):1748-1750.
[6]GORANSSON U,SJOQREN M E,Claeson P,et al.Reversible antifouling effect of the cyclotide cycloviolacin O2 against barnacles[J].Journal of Natural Products,2004,67(8):1287-1290.
[7]HATTOTI T,SHIZNRIY A.New ceramida from marine sponge haliclone substances against meacroalagae[J].Journal of Natural Products,1998(61):823-826.
[8]STANDING J D,HOOPER I R,COSTLOW J D.Inhibition and induction of barnacle settlement by natural product present in octocorals[J].Chem.Ecol.,1984,10:823-834.
[9]TODD J S,ZIMMERMAN R C,CREWS P,et al.The antifouling activity of natural and synthetic phenol acid sulphate esters[J].Phytochemistry,1993,34(2):401-404.
[10]R De Nys,STEINBERG P D,WILLEMSEN P,et al.Broad spectrum effects of secondary metabolites from the red alga delisea pulchra in antifouling assays[J].Biofouling,1995,8(4):259-271.
[11]PEREIRA R C,DA G B,TEIXEIRA V L,et al.Ecological roles of natural products of the Brazilian red seaweed Laurencia obtusa.[J].Brazilian journal of biology,2003,63(4):665-672.
[12]XU Ying,LI Hong-lei,LI Xian-cui,et al.Inhibitory effects of a branched-chain fatty acid on larval settlement of the polychaete hydroides elegans[J].Marine biotechnology,2009,11(4):495-504.
[13]纪伟尚,徐怀恕,沈福逊.应用固定化硫杆菌防除海洋污着生物的初步研究[J].海洋湖沼通报,1989,80(3):32-37.
[14]LEWIS J A.Marine biofouling and its prevention on underwater surface[J].Materials Forum,1998,(22):41-61.
[15]吕明霞,王锦艳,寇艳,等.可UV固化的辣椒碱型杂萘联苯环氧丙烯酸酯防污涂料[J].化工新型材料,2009,37(1):69-71.
[16]PéREZ M,BLUSTEIN G,GARCIS M,et al.Cupric tannate:A low copper content antifouling pigment[J].Progress in Organic Coatings,2006,55(4):311-315.
[17]RELEASE BELLOTTI N,DEYA C,AMO B,et al.Antifouling Paints with Zinc“Tannate”[J].Industrial&Engineering Chemistry Research,2010,49(7):3386-3390.
[18]王华进,刘登良,王贤明.无毒硅酸盐防污剂及其制备方法[P].CN 1218818 A.1999.
[19]李慧,杨旭石,廖本仁.新型海洋防污剂的研究现状及发展趋势[J].上海化工,2014,39(08):31-34.
[20]王广金,褚良银,陈文梅,等.微生物固定化聚醚砜微囊载体的制备及其性能研究[J].四川大学学报(工程科学版),2005,(3):47-51.
[21]汪小伟,尹卫平,付玉彬,等.镀铜微管对防污剂的控制释放性能[J].材料开发与应用,2005,20(1):19-22.
[22]汪小伟,付玉彬,张经纬,等.纳米钛酸管对防污剂异噻唑酮的控释作用[J].精细化工,2007,24(3):213-216.
[23]Dai,David Junhui,Willingham,et al.Controlled release compositions[P].Patent 6676954,2004.
[24]陈守刚,刘丹,王洪芬,等.改性碳纳米管/壳聚糖复合材料的制备及防污性能[J].化工学报,2015(11)4689-4695.
[25]汪小伟,时清亮,付玉彬.铜微球对防污剂异噻唑酮的控释作用[J].精细化工,2007,24(10):944-947.
[26]Pothakamury U R,Barbosa-Cánovas G V.Fundamental aspects of controlled release in foods[J].Trends in Food Science&Technology,1995,6(12):397-406.
[27]S?RENSEN G,NIELSEN A L,PEDERAEN M M,et al.Controlled release of biocide from silica microparticles in wood paint[J].Progress in Organic Coatings,2010,68(4):299-306.
[28]史航,石建高,陈晓蕾,等.包埋苯甲酸钠微球的制备及在海洋防污涂料中的抑菌研究[J].高分子通报,2011(1):65-70.
[29]宋福来,邵凯,刘万顺,等.壳聚糖即型水凝胶的理化性质、止血功能和生物相容性研究[J].功能材料,2014(9):65-69.
[30]PENG Z,CHEN F.Synthesis and Properties of TemperatureSensitive Hydrogel Based on Hydroxyethyl Cellulose[J].International Journal of Polymeric Materials,2010,59(6):450-461.
[31]SERRA M.Adaptable skin-hydrogel gives wetsuit protection[J].Smart Materials Bulletin,2002,2002(8):7-8.
[32]许凤玲,蔺存国,于泓先,等.海洋防污剂及其缓控释技术进展[J].材料开发与应用,2013(3):119-122.
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