凹凸棒粘土性能及应用研究
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摘要
凹凸棒石是一种层链状水合镁铝硅酸盐矿物,其独特的棒状纤维结构,使得它具有优异的流变、吸附、耐热、阻燃、增韧、补强等性能。在介绍凹凸棒石性能的基础上,综述了凹凸棒石粘土在众多行业中的应用,以期为凹凸棒石粘土的高附加值应用提供参考。
Attapulgite is a kind of hydrous magnesium silicate mineral of layered chain structure.Due to its unique fibrous crystal construction,attapulgite shows many excellent properties,such as intensive adsorption,flame resistance,effective toughener and strengthening agents,et al. In order to provide some references for the high value-added applications of attapulgite,the crystal structure and performance of attapulgite were introduced. Applications and developments of attapulgite in various industry fields were reviewed.
Attapulgite is a kind of hydrous magnesium silicate mineral of layered chain structure.Due to its unique fibrous crystal construction,attapulgite shows many excellent properties,such as intensive adsorption,flame resistance,effective toughener and strengthening agents,et al. In order to provide some references for the high value-added applications of attapulgite,the crystal structure and performance of attapulgite were introduced. Applications and developments of attapulgite in various industry fields were reviewed.
引文
[1]陈天虎,徐晓春,岳书仓.凹凸棒石黏土纳米矿物学及地球化学[M].北京:北京科学出版社,2004.
[2]Bradley W F.The structure scheme of attapulgite[J].American Mineralogist,1940,25(6):405-410.
[3]王艺洁,任珺,陶玲,等.凹凸棒粘土的结构与组成研究综述[J].矿产保护与利用,2012(4):44-47.
[4]赵英聚.纳米凹土/环氧复合乳液的制备及其在水性防腐涂料中的应用[D].上海:复旦大学,2012.
[5]陈天虎,凹凸棒石粘土吸附废水中污染物机理探讨[J].高校地质学报,2000,6(2):265-270.
[6]李金虎,张先龙,陈天虎,等.凹凸棒石负载锰氧化物低温选择性催化还原催化剂的表征及对氨的吸脱附[J].催化学报,2010,31(4):454-460.
[7]Rui Dong,Yuanfa Liu,Xingguo Wang,et al.Adsorption of sulfate lons from squeous solution by surfactant-modified palygorskite[J].Journal of Chemical&Engineering Data,2011(56):3890-3896.
[8]陈天虎,王健,庆承松,等.热处理对凹凸棒石结构、形貌和表面性质的影响[J].硅酸盐学报,2006,34(11):1406-1410.
[9]管洁.坡缕石复配阻燃剂阻燃EVA的性能研究[D].兰州:西北师范大学,2007.
[10]顾飞,任强,李锦春.凹凸棒土协同膨胀型阻燃剂阻燃聚丙烯的研究[J].现代塑料加工应用,2013,25(4):29-32.
[11]Jong Hyun Park,Sadhan C.Jana,Mechanism of exfoliation of nanoclay particles in epoxy clay nanocomposites[J].Macromolecules,2003(36):2758-2768.
[12]Feng Chen,Di Lou,Jintao Yang,et al.Mechanical and thermal properties of attapulgite clay reinforced[J].Polymers for Advanced Technologies,2011(22):1912-1918.
[13]Siqi Xue,Marc Reinholdt,Thomas J,et al.Palygorskite as an epoxy polymer reinforcement agent[J].Polymer,2006(47):3344-3350.
[14]Ziqiang Lei,Quanlu Yang,Shang Wu,et al.Reinforcement of polyurethane/epoxy inter-penetrating network nanocomposites with an organically modified palygorskite[J].Journal of Applied Polymer Science,2009(111):3150-3162.
[15]Xiang Cai,Jinglin Zhang,Yu Ouyang,et al.Bacteria-adsorbed palygorskite stabilizes the quaternary phosphonium salt with specific-targeting capability,long-term antibacterial activity,and lower cytotoxicity[J].Langmuir,2013(29):5279-5285.
[16]王益庆,张立群,张慧峰,等.凹凸棒土/橡胶纳米复合材料结构和性能研究[J].北京化工大学学报,1999,26(3):25-29.
[17]Manuel Sanchez del Rio,Enrico Boccaleri,Marco Milanesio,et al.A combined synchrotron power diffraction and vibrational study of the thermal treatment of palygorskiteindigo to produce Maya blue[J].Journal of Materials Science,2009(44):5524-5536.
[18]Boli Ni,Shaoyu Lu,Mingzhu Liu.Novel multinutrient fertilizer and its effect on slow release,water holding,and soil amending[J].Industrial&Engineering Chemistry Research,2012(51):12993-13000.
[2]Bradley W F.The structure scheme of attapulgite[J].American Mineralogist,1940,25(6):405-410.
[3]王艺洁,任珺,陶玲,等.凹凸棒粘土的结构与组成研究综述[J].矿产保护与利用,2012(4):44-47.
[4]赵英聚.纳米凹土/环氧复合乳液的制备及其在水性防腐涂料中的应用[D].上海:复旦大学,2012.
[5]陈天虎,凹凸棒石粘土吸附废水中污染物机理探讨[J].高校地质学报,2000,6(2):265-270.
[6]李金虎,张先龙,陈天虎,等.凹凸棒石负载锰氧化物低温选择性催化还原催化剂的表征及对氨的吸脱附[J].催化学报,2010,31(4):454-460.
[7]Rui Dong,Yuanfa Liu,Xingguo Wang,et al.Adsorption of sulfate lons from squeous solution by surfactant-modified palygorskite[J].Journal of Chemical&Engineering Data,2011(56):3890-3896.
[8]陈天虎,王健,庆承松,等.热处理对凹凸棒石结构、形貌和表面性质的影响[J].硅酸盐学报,2006,34(11):1406-1410.
[9]管洁.坡缕石复配阻燃剂阻燃EVA的性能研究[D].兰州:西北师范大学,2007.
[10]顾飞,任强,李锦春.凹凸棒土协同膨胀型阻燃剂阻燃聚丙烯的研究[J].现代塑料加工应用,2013,25(4):29-32.
[11]Jong Hyun Park,Sadhan C.Jana,Mechanism of exfoliation of nanoclay particles in epoxy clay nanocomposites[J].Macromolecules,2003(36):2758-2768.
[12]Feng Chen,Di Lou,Jintao Yang,et al.Mechanical and thermal properties of attapulgite clay reinforced[J].Polymers for Advanced Technologies,2011(22):1912-1918.
[13]Siqi Xue,Marc Reinholdt,Thomas J,et al.Palygorskite as an epoxy polymer reinforcement agent[J].Polymer,2006(47):3344-3350.
[14]Ziqiang Lei,Quanlu Yang,Shang Wu,et al.Reinforcement of polyurethane/epoxy inter-penetrating network nanocomposites with an organically modified palygorskite[J].Journal of Applied Polymer Science,2009(111):3150-3162.
[15]Xiang Cai,Jinglin Zhang,Yu Ouyang,et al.Bacteria-adsorbed palygorskite stabilizes the quaternary phosphonium salt with specific-targeting capability,long-term antibacterial activity,and lower cytotoxicity[J].Langmuir,2013(29):5279-5285.
[16]王益庆,张立群,张慧峰,等.凹凸棒土/橡胶纳米复合材料结构和性能研究[J].北京化工大学学报,1999,26(3):25-29.
[17]Manuel Sanchez del Rio,Enrico Boccaleri,Marco Milanesio,et al.A combined synchrotron power diffraction and vibrational study of the thermal treatment of palygorskiteindigo to produce Maya blue[J].Journal of Materials Science,2009(44):5524-5536.
[18]Boli Ni,Shaoyu Lu,Mingzhu Liu.Novel multinutrient fertilizer and its effect on slow release,water holding,and soil amending[J].Industrial&Engineering Chemistry Research,2012(51):12993-13000.