超级电容器在器件设计以及材料合成的研究进展
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摘要
便携电子产品的快速发展以及可再生能源系统的日益扩大,意味着储电系统将在人类社会中扮演着越来越重要的作用.近年来,新一代的超级电容器在材料合成、器件的设计组装以及多功能器件的设计等方面取得了许多重大突破.因此,本文将从新材料的合成、新设备的设计组装以及多功能器件的研发等方面对超级电容器的最新研究进展进行总结.首先,对不同结构的超级电容器及其性能进行详细地讨论,包括三电极(也称半电池)装置、两电极超级电容器、柔性固态超级电容器、纤维超级电容器以及微型(平面)超级电容器等.通过对文献的综合分析,突出介绍了超级电容器的设计原则;其次,对一些新兴电极材料的研发及其储电性能进行了讨论,包括碳材料、双金属氧化物(NiCo_2O_4, Ni_3V_2O_8, Co_3V_2O_8等)、过渡金属硫化物/硒化物/磷化物等正极材料以及VN, Fe_2O_3等负极材料;最后,对下一代的多功能超级电容器,包括自愈合超级电容器、自充电超级电容器、全方位-自适应-自充电超级电容器等器件的研究进展进行总结,概括这一新兴技术领域的未来发展趋势及其关键技术挑战.
Due to the global warming and energy depletion issues, developing sustainable and renewable energy resources has become a critical concern among researchers. The constantly growing demand for energy has urged researchers to develop highly improved energy storage devices. In relation to relevant energy storage systems, supercapacitor technology has drawn burgeoning interest in recent years owing to its environmentally safe and cost effective advantages. Especially, its high power density(>10 kW/kg), fast charge/discharge characteristics, and excellent cycle stability are highly beneficial in storing renewable energy. Currently, the rapid development of portable electronic devices and the expanding renewable energy systems have paved the way for energy storage systems to play an important role in human society. Many significant breakthroughs for the next-generation supercapacitors have been achieved in terms of material synthesis, device innovations, and multifunctional device designs. Therefore, this paper summarizes the latest progress on new materials and novel device assemblies. First, to fully assess the effect of device assembly on supercapacitor performance, five types of supercapacitor structures and their assembly principles are discussed in detail, including the three-electrode(also known as semi-battery) device, two-electrode supercapacitor, flexible solid-state supercapacitor, fiber supercapacitor, and planar(micro-) supercapacitor. Among them, the three-electrode system and the two-electrode device are still the most widely used types at present. The three-electrode cell is suitable for characterizing electrode materials or investigating the electrochemical storage processes. The structure of a two-electrode system is closer to an actual supercapacitor. Other specially designed cells, which are fabricated with the aim of meeting the requirements of flexible and lightweight energy sources, have also been proposed in recent years. The results indicate that the structural innovative design could provide a fascinating way to enhance the energy density of devices while also holding huge potential to enhance the compatibility between supercapacitor component and various portable or wearable electronic devices. A careful interpretation and rigorous scrutiny of the electrochemical characteristics of every supercapacitor is also conducted in this work. Moreover, the design principles for enhancing the supercapacitor performance are highlighted through a comprehensive analysis of the literature. The main challenges in the structural innovations for enhancing the electrochemical performance are analyzed. The solutions to overcome these challenges are proposed. Second, supercapacitors still suffer from a lower energy density compared with Li-ion batteries. Among various efforts to build high-performance supercapacitors in recent years, major improvements have been made in electrode materials with rational designs. This review article also examines the latest methodologies and performance evaluation metrics for several emerging electrode materials in terms of their improved electrochemical properties, including carbon materials, binary transition metal oxides(NiCo_2O_4, Ni_3V_2O_8, and Co_3V_2O_8, among others), transition metal chalcogenides/selenide/phosphide positive electrodes, and VN, Fe_2O_3 negative electrode materials. This paper also highlights the electrode material design principle, which is the fundamental understanding of the relationships between structural design, structural properties and components of electrode materials and their electrochemical performances. Moreover, we also summarized the latest contributions and progress in multifunctional supercapacitors, which include the transparent flexible supercapacitor, self-healable supercapacitor, piezoelectric supercapacitors, self-charging supercapacitors, and so on. Several methods to realize the abilities of transparent, folded, wearable, self-healable, and even self-chargeable supercapacitors with almost no performance degradation are discussed. This paper also analyzes the compatibility of a multifunctional supercapacitor with industrial manufacturing, and offers a paradigm for developing portable and wearable energy storage devices and systems. Furthermore, the operating principles, system design/engineering, and the rational optimization of the multifunctional supercapacitors are also analyzed in this review. Finally, the major challenges faced by next-generation supercapacitors, along with the future research prospects, are discussed at the end of the paper.
Due to the global warming and energy depletion issues, developing sustainable and renewable energy resources has become a critical concern among researchers. The constantly growing demand for energy has urged researchers to develop highly improved energy storage devices. In relation to relevant energy storage systems, supercapacitor technology has drawn burgeoning interest in recent years owing to its environmentally safe and cost effective advantages. Especially, its high power density(>10 kW/kg), fast charge/discharge characteristics, and excellent cycle stability are highly beneficial in storing renewable energy. Currently, the rapid development of portable electronic devices and the expanding renewable energy systems have paved the way for energy storage systems to play an important role in human society. Many significant breakthroughs for the next-generation supercapacitors have been achieved in terms of material synthesis, device innovations, and multifunctional device designs. Therefore, this paper summarizes the latest progress on new materials and novel device assemblies. First, to fully assess the effect of device assembly on supercapacitor performance, five types of supercapacitor structures and their assembly principles are discussed in detail, including the three-electrode(also known as semi-battery) device, two-electrode supercapacitor, flexible solid-state supercapacitor, fiber supercapacitor, and planar(micro-) supercapacitor. Among them, the three-electrode system and the two-electrode device are still the most widely used types at present. The three-electrode cell is suitable for characterizing electrode materials or investigating the electrochemical storage processes. The structure of a two-electrode system is closer to an actual supercapacitor. Other specially designed cells, which are fabricated with the aim of meeting the requirements of flexible and lightweight energy sources, have also been proposed in recent years. The results indicate that the structural innovative design could provide a fascinating way to enhance the energy density of devices while also holding huge potential to enhance the compatibility between supercapacitor component and various portable or wearable electronic devices. A careful interpretation and rigorous scrutiny of the electrochemical characteristics of every supercapacitor is also conducted in this work. Moreover, the design principles for enhancing the supercapacitor performance are highlighted through a comprehensive analysis of the literature. The main challenges in the structural innovations for enhancing the electrochemical performance are analyzed. The solutions to overcome these challenges are proposed. Second, supercapacitors still suffer from a lower energy density compared with Li-ion batteries. Among various efforts to build high-performance supercapacitors in recent years, major improvements have been made in electrode materials with rational designs. This review article also examines the latest methodologies and performance evaluation metrics for several emerging electrode materials in terms of their improved electrochemical properties, including carbon materials, binary transition metal oxides(NiCo_2O_4, Ni_3V_2O_8, and Co_3V_2O_8, among others), transition metal chalcogenides/selenide/phosphide positive electrodes, and VN, Fe_2O_3 negative electrode materials. This paper also highlights the electrode material design principle, which is the fundamental understanding of the relationships between structural design, structural properties and components of electrode materials and their electrochemical performances. Moreover, we also summarized the latest contributions and progress in multifunctional supercapacitors, which include the transparent flexible supercapacitor, self-healable supercapacitor, piezoelectric supercapacitors, self-charging supercapacitors, and so on. Several methods to realize the abilities of transparent, folded, wearable, self-healable, and even self-chargeable supercapacitors with almost no performance degradation are discussed. This paper also analyzes the compatibility of a multifunctional supercapacitor with industrial manufacturing, and offers a paradigm for developing portable and wearable energy storage devices and systems. Furthermore, the operating principles, system design/engineering, and the rational optimization of the multifunctional supercapacitors are also analyzed in this review. Finally, the major challenges faced by next-generation supercapacitors, along with the future research prospects, are discussed at the end of the paper.
引文
1 Zhong C,Deng Y,Hu W,et al.A review of electrolyte materials and compositions for electrochemical supercapacitors.Chem Soc Rev,2015,44:7484-7539
2 Lu X,Yu M,Wang G,et al.Flexible solid-state supercapacitors:Design,fabrication and applications.Energy Environ Sci,2014,7:2160-2181
3 Wu Z,Zhu Y,Ji X.NiCo2O4-based materials for electrochemical supercapacitors.J Mater Chem A,2014,2:14759-14772
4 Wei W,Cui X,Chen W,et al.Manganese oxide-based materials as electrochemical supercapacitor electrodes.Chem Soc Rev,2011,40:1697-1721
5 Zhang L L,Zhao X S.Carbon-based materials as supercapacitor electrodes.Chem Soc Rev,2009,38:2520-2531
6 Wang G,Zhang L,Zhang J.A review of electrode materials for electrochemical supercapacitors.Chem Soc Rev,2012,41:797-828
7 Sun M H,Huang S Z,Chen L H,et al.Applications of hierarchically structured porous materials from energy storage and conversion,catalysis,photocatalysis,adsorption,separation,and sensing to biomedicine.Chem Soc Rev,2016,45:3479-3563
8 Dubal D P,Ayyad O,Ruiz V,et al.Hybrid energy storage:The merging of battery and supercapacitor chemistries.Chem Soc Rev,2015,44:1777-1790
9 Wang Q,Yan J,Fan Z.Carbon materials for high volumetric performance supercapacitors:Design,progress,challenges and opportunities.Energy Environ Sci,2016,9:729-762
10 Wang X,Chen Y,Schmidt O G,et al.Engineered nanomembranes for smart energy storage devices.Chem Soc Rev,2016,45:1308-1330
11 Wang Y,Zeng J,Li J,et al.One-dimensional nanostructures for flexible supercapacitors.J Mater Chem A,2015,3:16382-16392
12 Zhai T,Lu X,Wang F,et al.MnO2 nanomaterials for flexible supercapacitors:Performance enhancement via intrinsic and extrinsic modification.Nanoscale Horiz,2016,1:109-124
13 Cai X,Peng M,Yu X,et al.Flexible planar/fiber-architectured supercapacitors for wearable energy storage.J Mater Chem C,2014,2:1184-1200
14 Peng X,Peng L,Wu C,et al.Two dimensional nanomaterials for flexible supercapacitors.Chem Soc Rev,2014,43:3303-3323
15 Zheng Y,Yang Y,Chen S,et al.Smart,stretchable and wearable supercapacitors:Prospects and challenges.CrystEngComm,2016,18:4218-4235
16 Tyagi A,Tripathi K M,Gupta R K.Recent progress in micro-scale energy storage devices and future aspects.J Mater Chem A,2015,3:22507-22541
17 Chen D,Wang Q,Wang R,et al.Ternary oxide nanostructured materials for supercapacitors:A review.J Mater Chem A,2015,3:10158-10173
18 He Y,Chen W,Gao C,et al.An overview of carbon materials for flexible electrochemical capacitors.Nanoscale,2013,5:8799-8820
19 Salunkhe R R,Kaneti Y V,Kim J,et al.Nanoarchitectures for metal-organic framework-derived nanoporous carbons toward supercapacitor applications.Acc Chem Res,2016,49:2796-2806
20 Tan Y B,Lee J M.Graphene for supercapacitor applications.J Mater Chem A,2013,1:14814-14843
21 Xia X,Zhang Y,Chao D,et al.Solution synthesis of metal oxides for electrochemical energy storage applications.Nanoscale,2014,6:5008-5048
22 Gulzar U,Goriparti S,Miele E,et al.Next-generation textiles:From embedded supercapacitors to lithium ion batteries.J Mater Chem A,2016,4:16771-16800
23 Yu D,Qian Q,Wei L,et al.Emergence of fiber supercapacitors.Chem Soc Rev,2015,44:647-662
24 Shao Y,El Kady M F,Wang L J,et al.Graphene-based materials for flexible supercapacitors.Chem Soc Rev,2015,44:3639-3665
25 Wang Y,Song Y,Xia Y.Electrochemical capacitors:Mechanism,materials,systems,characterization and applications.Chem Soc Rev,2016,45:5925-5950
26 Li L,Wu Z,Yuan S,et al.Advances and challenges for flexible energy storage and conversion devices and systems.Energy Environ Sci,2014,7:2101-2122
27 Liu L,Niu Z,Chen J.Unconventional supercapacitors from nanocarbon-based electrode materials to device configurations.Chem Soc Rev,2016,45:4340-4363
28 Winter M,Brodd R J.What are batteries,fuel cells,and supercapacitors?Chem Rev,2004,104:4245-4270
29 Bose S,Kuila T,Mishra A K,et al.Carbon-based nanostructured materials and their composites as supercapacitor electrodes.J Mater Chem,2012,22:767-784
30 Huang X,Qi X,Boey F,et al.Graphene-based composites.Chem Soc Rev,2012,41:666-686
31 Lei Z,Zhang J,Zhang L L,et al.Functionalization of chemically derived graphene for improving its electrocapacitive energy storage properties.Energy Environ Sci,2016,9:1891-1930
32 Zhang Y,Sun C,Lu P,et al.Crystallization design of MnO2 towards better supercapacitance.CrystEngComm,2012,14:5892-5897
33 Yu Z,Tetard L,Zhai L,et al.Supercapacitor electrode materials:Nanostructures from 0 to 3 dimensions.Energy Environ Sci,2015,8:702-730
34 Huang M,Li F,Dong F,et al.MnO2-based nanostructures for high-performance supercapacitors.J Mater Chem A,2015,3:21380-21423
35 Zhang YZ,Wang Y,Cheng T,et al.Flexible supercapacitors based on paper substrates:A new paradigm for low-cost energy storage.Chem Soc Rev,2015,44:5181-5199
36 Cong H P,Chen J F,Yu S H.Graphene-based macroscopic assemblies and architectures:An emerging material system.Chem Soc Rev,2014,43:7295-7325
37 Fan Z,Yan J,Wei T,et al.Asymmetric supercapacitors based on graphene-MnO2 and activated carbon nanofiber electrodes with high power and energy density.Adv Funct Mater,2011,21:2366-2375
38 Zhang L L,Zhou R,Zhao X S.Graphene-based materials as supercapacitor electrodes.J Mater Chem,2010,20:5983-5992
39 Zhang M,Hou C,Halder A,et al.Graphene papers:Smart architecture and specific functionalization for biomimetics,electrocatalytic sensing and energy storage.Mater Chem Front,2017,1:37-60
40 Yan J,Fan Z,Sun W,et al.Advanced asymmetric supercapacitors based on Ni(OH)2 graphene and porous graphene electrodes with high energy density.Adv Funct Mater,2012,22:2632-2641
41 Choi B G,Yang M,Hong W H,et al.3D macroporous graphene frameworks for supercapacitors with high energy and power densities.ACS Nano,2012,6:4020-4028
42 Wang X,Shi G.Flexible graphene devices related to energy conversion and storage.Energy Environ Sci,2015,8:790-823
43 Mao S,Lu G,Chen J.Three-dimensional graphene-based composites for energy applications.Nanoscale,2015,7:6924-6943
44 Choi B G,Chang S J,Kang H W,et al.High performance of a solid-state flexible asymmetric supercapacitor based on graphene films.Nanoscale,2012,4:4983-4988
45 El-Kady M F,Strong V,Dubin S,et al.Laser scribing of high-performance and flexible graphene-based electrochemical capacitors.Science,2012,335:1326-1330
46 Wu C,Lu X,Peng L,et al.Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors.Nat Commun,2013,4:2431-2437
47 Dong L,Xu C,Li Y,et al.Flexible electrodes and supercapacitors for wearable energy storage a review by category.J Mater Chem A,2016,4:4659-4685
48 Liang Y,Wang Z,Huang J,et al.Series of in-fiber graphene supercapacitors for flexible wearable devices.J Mater Chem A,2015,3:2547-2551
49 Meng Y,Zhao Y,Hu C,et al.All-graphene core-sheath microfibers for all-solid-state,stretchable fibriform supercapacitors and wearable electronic textiles.Adv Mater,2013,25:2326-2331
50 Wang Z,Cheng J,Guan Q,et al.All-in-one fiber for stretchable fiber-shaped tandem supercapacitors.Nano Energy,2018,45:210-219
51 Kou L,Huang T,Zheng B,et al.Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics.Nat Commun,2014,5:3754
52 Pu X,Li L,Liu M,et al.Wearable self-charging power textile based on flexible yarn supercapacitors and fabric nanogenerators.Adv Mater,2016,28:98-105
53 El-Kady M F,Kaner R B.Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage.Nat Commun,2013,4:1475-1483
54 Chen K,Xue D.Materials chemistry toward electrochemical energy storage.J Mater Chem A,2016,4:7522-7537
55 Xu Y,Shi G,Duan X.Self-assembled three-dimensional graphene macrostructures:Synthesis and applications in supercapacitors.Acc Chem Res,2015,48:1666-1675
56 Zhu Y,Murali S,Stoller M D,et al.Carbon-based supercapacitors produced by activation of graphene.Science,2011,332:1537-1541
57 Xu Y,Sheng K,Li C,et al.Self-assembled graphene hydrogel via a one-step hydrothermal process.ACS Nano,2010,4:4324-4330
58 Futaba D N,Kenjihata T,Yamada T,et al.Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes.Nat Mater,2006,5:987-994
59 Yu J,Lu W,Pei S,et al.Omnidirectionally stretchable high-performance supercapacitor based on isotropic buckled carbon nanotube films.ACS Nano,2016,10:5204-5211
60 Zhang K,Han X,Hu Z,et al.Nanostructured Mn-based oxides for electrochemical energy storage and conversion.Chem Soc Rev,2015,44:699-728
61 Yang P,Xiao X,Li Y,et al.Hydrogenated ZnO core-shell nanocables for flexible supercapacitors and self-powered systems.ACS Nano,2013,7:2617-2626
62 Nithya V D,Arul N S.Review onα-Fe2O3 based negative electrode for high performance supercapacitors.J Power Sources,2016,327:297-318
63 Chen S,Zhu J,Wang X.From graphene to metal oxide nanolamellas:A phenomenon of morphology transmission.ACS Nano,2010,4:6212-6218
64 Zhao G,Li J,Jiang L,et al.Synthesizing MnO2 nanosheets from graphene oxide templates for high performance pseudosupercapacitors.Chem Sci,2012,3:433-437
65 Xie X,Zhang C,Wu M B,et al.Porous MnO2 for use in a high performance supercapacitor:Replication of a 3D graphene network as a reactive template.Chem Commun,2013,49:11092-11094
66 Wang Y,Cheng K,Cao D,et al.Preparation of NiCo2O4 nanosheet arrays and its high catalytic performance for H2O2 electroreduction.Fuel Cells,2015,15:298-305
67 Wang Q,Liu B,Wang X,et al.Morphology evolution of urchin-like NiCo2O4 nanostructures and their applications as psuedocapacitors and photoelectrochemical cells.J Mater Chem,2012,22:21647-21653
68 Wang Q,Wang X,Liu B,et al.NiCo2O4 nanowire arrays supported on Ni foam for high-performance flexible all-solid-state supercapacitors.J Mater Chem A,2013,1:2468-2473
69 Yuan C Z,Li J,Hou L,et al.Polymer-assisted synthesis of a 3D hierarchical porous network-like spinel NiCo2O4 framework towards high-performance electrochemical capacitors.J Mater Chem A,2013,1:11145-11151
70 Lu Q,Chen Y,Li W,et al.Ordered mesoporous nickel cobaltite spinel with ultra-high supercapacitance.J Mater Chem A,2013,1:2331-2336
71 Liu X,Shi S,Xiong Q,et al.Hierarchical NiCo2O4@NiCo2O4 core/shell nanoflake arrays as high-performance supercapacitor materials.ACS Appl Mater Interfaces,2013,5:8790-8795
72 Zhang G,Lou X W.Controlled growth of NiCo2O4 nanorods and ultrathin nanosheets on carbon nanofibers for high-performance supercapacitors.Sci Rep,2013,3:1470-1475
73 Lei Y,Li J,Wang Y,et al.Rapid microwave-assisted green synthesis of 3D hierarchical flower-shaped NiCo2O4 microsphere for high-performance supercapacitor.ACS Appl Mater Interfaces,2014,6:1773-1780
74 Ji C,Liu F,Xu L,et al.Urchin-like NiCo2O4 hollow microspheres and FeSe2 micro-snowflake for flexible solid-state asymmetric supercapacitor.J Mater Chem A,2017,5:5568-5576
75 Butt F K,Tahir M,Cao C,et al.Synthesis of novel ZnV2O4 hierarchical nanospheres and their applications as electrochemical supercapacitor and hydrogen storage material.ACS Appl Mater Interfaces,2014,6:13635-13641
76 Liu M C,Kong L B,Kang L,et al.Synthesis and characterization of M3V2O8(M=Ni or Co)based nanostructures:A new family of high performance pseudocapacitive materials.J Mater Chem A,2014,2:4919-4926
77 Zhang J,Yuan B,Cui S,et al.Facile synthesis of 3D porous Co3V2O8 nanoroses and 2D NiCo2V2O8 nanoplates for high performance supercapacitors and their electrocatalytic oxygen evolution reaction properties.Dalton Trans,2017,46:3295-3302
78 Niu L,Li Z,Xu Y,et al.Simple synthesis of amorphous NiWO4 nanostructure and its application as a novel cathode material for asymmetric supercapacitors.ACS Appl Mater Interfaces,2013,5:8044-8052
79 Yu Z Y,Chen L F,Yu S H.Growth of NiFe2O4 nanoparticles on carbon cloth for high performance flexible supercapacitors.J Mater Chem A,2014,2:10889-10894
80 Banerjee A,Bhatnagar S,Upadhyay K K,et al.Hollow Co0.85Se nanowire array on carbon fiber paper for high rate pseudocapacitor.ACSAppl Mater Interfaces,2014,6:18844-18852
81 Lu T,Dong S,Zhang C,et al.Fabrication of transition metal selenides and their applications in energy storage.Coord Chem Rev,2017,332:75-99
82 Gao Y,Mi L,Wei W,et al.Double metal ions synergistic effect in hierarchical multiple sulfide microflowers for enhanced supercapacitor performance.ACS Appl Mater Interfaces,2015,7:4311-4319
83 Mi L,Wei W,Huang S,et al.A nest-like Ni@Ni1.4Co1.6S2 electrode for flexible high-performance rolling supercapacitor device design.JMater Chem A,2015,3:20973-20982
84 Shen L,Yu L,Wu H B,et al.Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties.Nat Commun,2015,6:6694-6701
85 Wei W,Mi L,Gao Y,et al.Partial ion-exchange of nickel-sulfide-derived electrodes for high performance supercapacitors.Chem Mater,2014,26:3418-3426
86 Guo K,Cui S,Hou H,et al.Hierarchical ternary Ni-Co-Se nanowires for high-performance supercapacitor device design.Dalton Trans,2016,45:19458-19465
87 Yang J,Yuan Y,Wang W,et al.Interconnected Co0.85Se nanosheets as cathode materials for asymmetric supercapacitors.J Power Sources,2017,340:6-13
88 Xia C,Jiang Q,Zhao C,et al.Asymmetric supercapacitors with metal-like ternary selenides and porous graphene electrodes.Nano Energy,2016,24:78-86
89 Liang H,Xia C,Jiang Q,et al.Low temperature synthesis of ternary metal phosphides using plasma for asymmetric supercapacitors.Nano Energy,2017,35:331-340
90 Tang Q,Wang W,Wang G.The perfect matching between the low-cost Fe2O3 nanowire anode and the NiO nanoflake cathode significantly enhances the energy density of asymmetric supercapacitors.J Mater Chem A,2015,3:6662-6670
91 Hou Y,Chen L,Liu P,et al.Nanoporous metal based flexible asymmetric pseudocapacitors.J Mater Chem A,2014,2:10910-10916
92 Zhang B H,Liu Y,Chang Z,et al.Nanowire Na0.35 MnO2 from a hydrothermal method as a cathode material for aqueous asymmetric supercapacitors.J Power Sources,2014,253:98-103
93 Luan F,Wang G,Ling Y,et al.High energy density asymmetric supercapacitors with a nickel oxide nanoflake cathode and a 3D reduced graphene oxide anode.Nanoscale,2013,5:7984-7990
94 Gao H,Xiao F,Ching C B,et al.High-performance asymmetric supercapacitor based on graphene hydrogel and nanostructured MnO2.ACS Appl Mater Interfaces,2012,4:2801-2810
95 Long C,Qi D,Wei T,et al.Nitrogen-doped carbon networks for high energy density supercapacitors derived from polyaniline coated bacterial cellulose.Adv Funct Mater,2014,24:3953-3961
96 Wang R,Yan X B,Lang J,et al.A hybrid supercapacitor based on flower-like Co(OH)2 and urchin-like VN electrode materials.J Mater Chem A,2014,2:12724-12732
97 Lu X,Yu M,Zhai T,et al.High energy density asymmetric quasi-solid-state supercapacitor based on porous vanadium nitride nanowire anode.Nano Lett,2013,13:2628-2633
98 Ji C,Bi J,Wang S,et al.Ni nanoparticle doped porous VN nanoflakes assembled into hierarchical hollow microspheres with a structural inheritance from the Ni1-xVxO2 cathode material for high performance asymmetric supercapacitors.J Mater Chem A,2016,4:2158-2168
99 Yang P,Ding Y,Lin Z,et al.Low-cost high-performance solid-state asymmetric supercapacitors based on MnO2 nanowires and Fe2O3nanotubes.Nano Lett,2014,14:731-736
100 Peng H,Ma G,Mu J J,et al.Low-cost and high energy density asymmetric supercapacitors based on polyaniline nanotubes and MoO3nanobelts.J Mater Chem A,2014,2:10384-10388
101 Shinde N M,Xia Q X,Yun J M,et al.Polycrystalline and mesoporous 3-D Bi2O3 nanostructured negatrodes for high-energy and power-asymmetric supercapacitors:Superfast room-temperature direct wet chemical growth.ACS Appl Mater Interfaces,2018,10:11037-11047
102 Li N,Yang G,Sun Y,et al.Free-standing and transparent graphene membrane of polyhedron box-shaped basic building units directly grown using a NaCl template for flexible transparent and stretchable solid-state supercapacitors.Nano Lett,2015,15:3195-3203
103 Huang Y,Huang Y,Zhu M,et al.Magnetic-assisted,self-healable,yarn-based supercapacitor.ACS Nano,2015,9:6242-6251
104 Jung S,Lee J,Hyeon T,et al.Fabric-based integrated energy devices for wearable activity monitors.Adv Mater,2014,26:6329-6334
105 Ramadoss A,Saravanakumar B,Lee S W,et al.Piezoelectric-driven self-charging supercapacitor power cell.ACS Nano,2015,9:4337-4345
106 Guo H,Yeh M H,Lai Y C,et al.All-in-one shape-adaptive self-charging power package for wearable electronics.ACS Nano,2016,10:10580-10588
107 Hwang B U,Lee J H,Trung T Q,et al.Transparent stretchable self-powered patchable sensor platform with ultrasensitive recognition of human activities.ACS Nano,2015,9:8801-8810
108 Fu Y P,Wu H G,Ye S,et al.Integrated power fiber for energy conversion and storage.Energy Environ Sci,2013,6:805-812
109 Chen T,Qiu L,Yang Z,et al.An integrated“energy wire”for both photoelectric conversion and energy storage.Angew Chem Int Ed,2012,51:11977-11980
2 Lu X,Yu M,Wang G,et al.Flexible solid-state supercapacitors:Design,fabrication and applications.Energy Environ Sci,2014,7:2160-2181
3 Wu Z,Zhu Y,Ji X.NiCo2O4-based materials for electrochemical supercapacitors.J Mater Chem A,2014,2:14759-14772
4 Wei W,Cui X,Chen W,et al.Manganese oxide-based materials as electrochemical supercapacitor electrodes.Chem Soc Rev,2011,40:1697-1721
5 Zhang L L,Zhao X S.Carbon-based materials as supercapacitor electrodes.Chem Soc Rev,2009,38:2520-2531
6 Wang G,Zhang L,Zhang J.A review of electrode materials for electrochemical supercapacitors.Chem Soc Rev,2012,41:797-828
7 Sun M H,Huang S Z,Chen L H,et al.Applications of hierarchically structured porous materials from energy storage and conversion,catalysis,photocatalysis,adsorption,separation,and sensing to biomedicine.Chem Soc Rev,2016,45:3479-3563
8 Dubal D P,Ayyad O,Ruiz V,et al.Hybrid energy storage:The merging of battery and supercapacitor chemistries.Chem Soc Rev,2015,44:1777-1790
9 Wang Q,Yan J,Fan Z.Carbon materials for high volumetric performance supercapacitors:Design,progress,challenges and opportunities.Energy Environ Sci,2016,9:729-762
10 Wang X,Chen Y,Schmidt O G,et al.Engineered nanomembranes for smart energy storage devices.Chem Soc Rev,2016,45:1308-1330
11 Wang Y,Zeng J,Li J,et al.One-dimensional nanostructures for flexible supercapacitors.J Mater Chem A,2015,3:16382-16392
12 Zhai T,Lu X,Wang F,et al.MnO2 nanomaterials for flexible supercapacitors:Performance enhancement via intrinsic and extrinsic modification.Nanoscale Horiz,2016,1:109-124
13 Cai X,Peng M,Yu X,et al.Flexible planar/fiber-architectured supercapacitors for wearable energy storage.J Mater Chem C,2014,2:1184-1200
14 Peng X,Peng L,Wu C,et al.Two dimensional nanomaterials for flexible supercapacitors.Chem Soc Rev,2014,43:3303-3323
15 Zheng Y,Yang Y,Chen S,et al.Smart,stretchable and wearable supercapacitors:Prospects and challenges.CrystEngComm,2016,18:4218-4235
16 Tyagi A,Tripathi K M,Gupta R K.Recent progress in micro-scale energy storage devices and future aspects.J Mater Chem A,2015,3:22507-22541
17 Chen D,Wang Q,Wang R,et al.Ternary oxide nanostructured materials for supercapacitors:A review.J Mater Chem A,2015,3:10158-10173
18 He Y,Chen W,Gao C,et al.An overview of carbon materials for flexible electrochemical capacitors.Nanoscale,2013,5:8799-8820
19 Salunkhe R R,Kaneti Y V,Kim J,et al.Nanoarchitectures for metal-organic framework-derived nanoporous carbons toward supercapacitor applications.Acc Chem Res,2016,49:2796-2806
20 Tan Y B,Lee J M.Graphene for supercapacitor applications.J Mater Chem A,2013,1:14814-14843
21 Xia X,Zhang Y,Chao D,et al.Solution synthesis of metal oxides for electrochemical energy storage applications.Nanoscale,2014,6:5008-5048
22 Gulzar U,Goriparti S,Miele E,et al.Next-generation textiles:From embedded supercapacitors to lithium ion batteries.J Mater Chem A,2016,4:16771-16800
23 Yu D,Qian Q,Wei L,et al.Emergence of fiber supercapacitors.Chem Soc Rev,2015,44:647-662
24 Shao Y,El Kady M F,Wang L J,et al.Graphene-based materials for flexible supercapacitors.Chem Soc Rev,2015,44:3639-3665
25 Wang Y,Song Y,Xia Y.Electrochemical capacitors:Mechanism,materials,systems,characterization and applications.Chem Soc Rev,2016,45:5925-5950
26 Li L,Wu Z,Yuan S,et al.Advances and challenges for flexible energy storage and conversion devices and systems.Energy Environ Sci,2014,7:2101-2122
27 Liu L,Niu Z,Chen J.Unconventional supercapacitors from nanocarbon-based electrode materials to device configurations.Chem Soc Rev,2016,45:4340-4363
28 Winter M,Brodd R J.What are batteries,fuel cells,and supercapacitors?Chem Rev,2004,104:4245-4270
29 Bose S,Kuila T,Mishra A K,et al.Carbon-based nanostructured materials and their composites as supercapacitor electrodes.J Mater Chem,2012,22:767-784
30 Huang X,Qi X,Boey F,et al.Graphene-based composites.Chem Soc Rev,2012,41:666-686
31 Lei Z,Zhang J,Zhang L L,et al.Functionalization of chemically derived graphene for improving its electrocapacitive energy storage properties.Energy Environ Sci,2016,9:1891-1930
32 Zhang Y,Sun C,Lu P,et al.Crystallization design of MnO2 towards better supercapacitance.CrystEngComm,2012,14:5892-5897
33 Yu Z,Tetard L,Zhai L,et al.Supercapacitor electrode materials:Nanostructures from 0 to 3 dimensions.Energy Environ Sci,2015,8:702-730
34 Huang M,Li F,Dong F,et al.MnO2-based nanostructures for high-performance supercapacitors.J Mater Chem A,2015,3:21380-21423
35 Zhang YZ,Wang Y,Cheng T,et al.Flexible supercapacitors based on paper substrates:A new paradigm for low-cost energy storage.Chem Soc Rev,2015,44:5181-5199
36 Cong H P,Chen J F,Yu S H.Graphene-based macroscopic assemblies and architectures:An emerging material system.Chem Soc Rev,2014,43:7295-7325
37 Fan Z,Yan J,Wei T,et al.Asymmetric supercapacitors based on graphene-MnO2 and activated carbon nanofiber electrodes with high power and energy density.Adv Funct Mater,2011,21:2366-2375
38 Zhang L L,Zhou R,Zhao X S.Graphene-based materials as supercapacitor electrodes.J Mater Chem,2010,20:5983-5992
39 Zhang M,Hou C,Halder A,et al.Graphene papers:Smart architecture and specific functionalization for biomimetics,electrocatalytic sensing and energy storage.Mater Chem Front,2017,1:37-60
40 Yan J,Fan Z,Sun W,et al.Advanced asymmetric supercapacitors based on Ni(OH)2 graphene and porous graphene electrodes with high energy density.Adv Funct Mater,2012,22:2632-2641
41 Choi B G,Yang M,Hong W H,et al.3D macroporous graphene frameworks for supercapacitors with high energy and power densities.ACS Nano,2012,6:4020-4028
42 Wang X,Shi G.Flexible graphene devices related to energy conversion and storage.Energy Environ Sci,2015,8:790-823
43 Mao S,Lu G,Chen J.Three-dimensional graphene-based composites for energy applications.Nanoscale,2015,7:6924-6943
44 Choi B G,Chang S J,Kang H W,et al.High performance of a solid-state flexible asymmetric supercapacitor based on graphene films.Nanoscale,2012,4:4983-4988
45 El-Kady M F,Strong V,Dubin S,et al.Laser scribing of high-performance and flexible graphene-based electrochemical capacitors.Science,2012,335:1326-1330
46 Wu C,Lu X,Peng L,et al.Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors.Nat Commun,2013,4:2431-2437
47 Dong L,Xu C,Li Y,et al.Flexible electrodes and supercapacitors for wearable energy storage a review by category.J Mater Chem A,2016,4:4659-4685
48 Liang Y,Wang Z,Huang J,et al.Series of in-fiber graphene supercapacitors for flexible wearable devices.J Mater Chem A,2015,3:2547-2551
49 Meng Y,Zhao Y,Hu C,et al.All-graphene core-sheath microfibers for all-solid-state,stretchable fibriform supercapacitors and wearable electronic textiles.Adv Mater,2013,25:2326-2331
50 Wang Z,Cheng J,Guan Q,et al.All-in-one fiber for stretchable fiber-shaped tandem supercapacitors.Nano Energy,2018,45:210-219
51 Kou L,Huang T,Zheng B,et al.Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics.Nat Commun,2014,5:3754
52 Pu X,Li L,Liu M,et al.Wearable self-charging power textile based on flexible yarn supercapacitors and fabric nanogenerators.Adv Mater,2016,28:98-105
53 El-Kady M F,Kaner R B.Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage.Nat Commun,2013,4:1475-1483
54 Chen K,Xue D.Materials chemistry toward electrochemical energy storage.J Mater Chem A,2016,4:7522-7537
55 Xu Y,Shi G,Duan X.Self-assembled three-dimensional graphene macrostructures:Synthesis and applications in supercapacitors.Acc Chem Res,2015,48:1666-1675
56 Zhu Y,Murali S,Stoller M D,et al.Carbon-based supercapacitors produced by activation of graphene.Science,2011,332:1537-1541
57 Xu Y,Sheng K,Li C,et al.Self-assembled graphene hydrogel via a one-step hydrothermal process.ACS Nano,2010,4:4324-4330
58 Futaba D N,Kenjihata T,Yamada T,et al.Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes.Nat Mater,2006,5:987-994
59 Yu J,Lu W,Pei S,et al.Omnidirectionally stretchable high-performance supercapacitor based on isotropic buckled carbon nanotube films.ACS Nano,2016,10:5204-5211
60 Zhang K,Han X,Hu Z,et al.Nanostructured Mn-based oxides for electrochemical energy storage and conversion.Chem Soc Rev,2015,44:699-728
61 Yang P,Xiao X,Li Y,et al.Hydrogenated ZnO core-shell nanocables for flexible supercapacitors and self-powered systems.ACS Nano,2013,7:2617-2626
62 Nithya V D,Arul N S.Review onα-Fe2O3 based negative electrode for high performance supercapacitors.J Power Sources,2016,327:297-318
63 Chen S,Zhu J,Wang X.From graphene to metal oxide nanolamellas:A phenomenon of morphology transmission.ACS Nano,2010,4:6212-6218
64 Zhao G,Li J,Jiang L,et al.Synthesizing MnO2 nanosheets from graphene oxide templates for high performance pseudosupercapacitors.Chem Sci,2012,3:433-437
65 Xie X,Zhang C,Wu M B,et al.Porous MnO2 for use in a high performance supercapacitor:Replication of a 3D graphene network as a reactive template.Chem Commun,2013,49:11092-11094
66 Wang Y,Cheng K,Cao D,et al.Preparation of NiCo2O4 nanosheet arrays and its high catalytic performance for H2O2 electroreduction.Fuel Cells,2015,15:298-305
67 Wang Q,Liu B,Wang X,et al.Morphology evolution of urchin-like NiCo2O4 nanostructures and their applications as psuedocapacitors and photoelectrochemical cells.J Mater Chem,2012,22:21647-21653
68 Wang Q,Wang X,Liu B,et al.NiCo2O4 nanowire arrays supported on Ni foam for high-performance flexible all-solid-state supercapacitors.J Mater Chem A,2013,1:2468-2473
69 Yuan C Z,Li J,Hou L,et al.Polymer-assisted synthesis of a 3D hierarchical porous network-like spinel NiCo2O4 framework towards high-performance electrochemical capacitors.J Mater Chem A,2013,1:11145-11151
70 Lu Q,Chen Y,Li W,et al.Ordered mesoporous nickel cobaltite spinel with ultra-high supercapacitance.J Mater Chem A,2013,1:2331-2336
71 Liu X,Shi S,Xiong Q,et al.Hierarchical NiCo2O4@NiCo2O4 core/shell nanoflake arrays as high-performance supercapacitor materials.ACS Appl Mater Interfaces,2013,5:8790-8795
72 Zhang G,Lou X W.Controlled growth of NiCo2O4 nanorods and ultrathin nanosheets on carbon nanofibers for high-performance supercapacitors.Sci Rep,2013,3:1470-1475
73 Lei Y,Li J,Wang Y,et al.Rapid microwave-assisted green synthesis of 3D hierarchical flower-shaped NiCo2O4 microsphere for high-performance supercapacitor.ACS Appl Mater Interfaces,2014,6:1773-1780
74 Ji C,Liu F,Xu L,et al.Urchin-like NiCo2O4 hollow microspheres and FeSe2 micro-snowflake for flexible solid-state asymmetric supercapacitor.J Mater Chem A,2017,5:5568-5576
75 Butt F K,Tahir M,Cao C,et al.Synthesis of novel ZnV2O4 hierarchical nanospheres and their applications as electrochemical supercapacitor and hydrogen storage material.ACS Appl Mater Interfaces,2014,6:13635-13641
76 Liu M C,Kong L B,Kang L,et al.Synthesis and characterization of M3V2O8(M=Ni or Co)based nanostructures:A new family of high performance pseudocapacitive materials.J Mater Chem A,2014,2:4919-4926
77 Zhang J,Yuan B,Cui S,et al.Facile synthesis of 3D porous Co3V2O8 nanoroses and 2D NiCo2V2O8 nanoplates for high performance supercapacitors and their electrocatalytic oxygen evolution reaction properties.Dalton Trans,2017,46:3295-3302
78 Niu L,Li Z,Xu Y,et al.Simple synthesis of amorphous NiWO4 nanostructure and its application as a novel cathode material for asymmetric supercapacitors.ACS Appl Mater Interfaces,2013,5:8044-8052
79 Yu Z Y,Chen L F,Yu S H.Growth of NiFe2O4 nanoparticles on carbon cloth for high performance flexible supercapacitors.J Mater Chem A,2014,2:10889-10894
80 Banerjee A,Bhatnagar S,Upadhyay K K,et al.Hollow Co0.85Se nanowire array on carbon fiber paper for high rate pseudocapacitor.ACSAppl Mater Interfaces,2014,6:18844-18852
81 Lu T,Dong S,Zhang C,et al.Fabrication of transition metal selenides and their applications in energy storage.Coord Chem Rev,2017,332:75-99
82 Gao Y,Mi L,Wei W,et al.Double metal ions synergistic effect in hierarchical multiple sulfide microflowers for enhanced supercapacitor performance.ACS Appl Mater Interfaces,2015,7:4311-4319
83 Mi L,Wei W,Huang S,et al.A nest-like Ni@Ni1.4Co1.6S2 electrode for flexible high-performance rolling supercapacitor device design.JMater Chem A,2015,3:20973-20982
84 Shen L,Yu L,Wu H B,et al.Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties.Nat Commun,2015,6:6694-6701
85 Wei W,Mi L,Gao Y,et al.Partial ion-exchange of nickel-sulfide-derived electrodes for high performance supercapacitors.Chem Mater,2014,26:3418-3426
86 Guo K,Cui S,Hou H,et al.Hierarchical ternary Ni-Co-Se nanowires for high-performance supercapacitor device design.Dalton Trans,2016,45:19458-19465
87 Yang J,Yuan Y,Wang W,et al.Interconnected Co0.85Se nanosheets as cathode materials for asymmetric supercapacitors.J Power Sources,2017,340:6-13
88 Xia C,Jiang Q,Zhao C,et al.Asymmetric supercapacitors with metal-like ternary selenides and porous graphene electrodes.Nano Energy,2016,24:78-86
89 Liang H,Xia C,Jiang Q,et al.Low temperature synthesis of ternary metal phosphides using plasma for asymmetric supercapacitors.Nano Energy,2017,35:331-340
90 Tang Q,Wang W,Wang G.The perfect matching between the low-cost Fe2O3 nanowire anode and the NiO nanoflake cathode significantly enhances the energy density of asymmetric supercapacitors.J Mater Chem A,2015,3:6662-6670
91 Hou Y,Chen L,Liu P,et al.Nanoporous metal based flexible asymmetric pseudocapacitors.J Mater Chem A,2014,2:10910-10916
92 Zhang B H,Liu Y,Chang Z,et al.Nanowire Na0.35 MnO2 from a hydrothermal method as a cathode material for aqueous asymmetric supercapacitors.J Power Sources,2014,253:98-103
93 Luan F,Wang G,Ling Y,et al.High energy density asymmetric supercapacitors with a nickel oxide nanoflake cathode and a 3D reduced graphene oxide anode.Nanoscale,2013,5:7984-7990
94 Gao H,Xiao F,Ching C B,et al.High-performance asymmetric supercapacitor based on graphene hydrogel and nanostructured MnO2.ACS Appl Mater Interfaces,2012,4:2801-2810
95 Long C,Qi D,Wei T,et al.Nitrogen-doped carbon networks for high energy density supercapacitors derived from polyaniline coated bacterial cellulose.Adv Funct Mater,2014,24:3953-3961
96 Wang R,Yan X B,Lang J,et al.A hybrid supercapacitor based on flower-like Co(OH)2 and urchin-like VN electrode materials.J Mater Chem A,2014,2:12724-12732
97 Lu X,Yu M,Zhai T,et al.High energy density asymmetric quasi-solid-state supercapacitor based on porous vanadium nitride nanowire anode.Nano Lett,2013,13:2628-2633
98 Ji C,Bi J,Wang S,et al.Ni nanoparticle doped porous VN nanoflakes assembled into hierarchical hollow microspheres with a structural inheritance from the Ni1-xVxO2 cathode material for high performance asymmetric supercapacitors.J Mater Chem A,2016,4:2158-2168
99 Yang P,Ding Y,Lin Z,et al.Low-cost high-performance solid-state asymmetric supercapacitors based on MnO2 nanowires and Fe2O3nanotubes.Nano Lett,2014,14:731-736
100 Peng H,Ma G,Mu J J,et al.Low-cost and high energy density asymmetric supercapacitors based on polyaniline nanotubes and MoO3nanobelts.J Mater Chem A,2014,2:10384-10388
101 Shinde N M,Xia Q X,Yun J M,et al.Polycrystalline and mesoporous 3-D Bi2O3 nanostructured negatrodes for high-energy and power-asymmetric supercapacitors:Superfast room-temperature direct wet chemical growth.ACS Appl Mater Interfaces,2018,10:11037-11047
102 Li N,Yang G,Sun Y,et al.Free-standing and transparent graphene membrane of polyhedron box-shaped basic building units directly grown using a NaCl template for flexible transparent and stretchable solid-state supercapacitors.Nano Lett,2015,15:3195-3203
103 Huang Y,Huang Y,Zhu M,et al.Magnetic-assisted,self-healable,yarn-based supercapacitor.ACS Nano,2015,9:6242-6251
104 Jung S,Lee J,Hyeon T,et al.Fabric-based integrated energy devices for wearable activity monitors.Adv Mater,2014,26:6329-6334
105 Ramadoss A,Saravanakumar B,Lee S W,et al.Piezoelectric-driven self-charging supercapacitor power cell.ACS Nano,2015,9:4337-4345
106 Guo H,Yeh M H,Lai Y C,et al.All-in-one shape-adaptive self-charging power package for wearable electronics.ACS Nano,2016,10:10580-10588
107 Hwang B U,Lee J H,Trung T Q,et al.Transparent stretchable self-powered patchable sensor platform with ultrasensitive recognition of human activities.ACS Nano,2015,9:8801-8810
108 Fu Y P,Wu H G,Ye S,et al.Integrated power fiber for energy conversion and storage.Energy Environ Sci,2013,6:805-812
109 Chen T,Qiu L,Yang Z,et al.An integrated“energy wire”for both photoelectric conversion and energy storage.Angew Chem Int Ed,2012,51:11977-11980
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