爆轰法合成纳米金刚石的分散技术研究进展
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摘要
纳米金刚石兼具金刚石的优异特性和纳米材料的小尺寸效应,是一种重要的新型纳米粉体材料,但是纳米粉体本身的团聚问题限制其更广泛的应用。为改善此问题,科研人员利用物理分散、化学处理等技术进行了大量的探索与研究。本文概述了近年来国内外对改善爆轰法合成纳米金刚石的团聚问题所提出的技术和方法,归纳主要研究思路,为进一步研究纳米金刚石分散技术及应用提供参考。
Nano-diamond, which not only possesses the ultrahard characters of diamond but also the small size effect of nano-materials, is an important nano-powder material and has wide development space. However, its agglomeration limits the wide application of nano-diamond. To solve this problem, the industry has conducted a lot of research through physical dispersing methods and chemical treatments to disperse the diamonds. Hereby, the progress of research on the dispersion of detonation-synthesized nano-diamond in recent years are summarized, and the main mentality is concluded to provide reference for further development of dispersing nano-diamond.
Nano-diamond, which not only possesses the ultrahard characters of diamond but also the small size effect of nano-materials, is an important nano-powder material and has wide development space. However, its agglomeration limits the wide application of nano-diamond. To solve this problem, the industry has conducted a lot of research through physical dispersing methods and chemical treatments to disperse the diamonds. Hereby, the progress of research on the dispersion of detonation-synthesized nano-diamond in recent years are summarized, and the main mentality is concluded to provide reference for further development of dispersing nano-diamond.
引文
[1] 王光祖, 张运生, 郭留希, 等. 纳米金刚石的应用 [J]. 金刚石与磨料磨具工程, 2003(4): 41–44.WANG Guangzu, ZHANG Yunsheng, GUO Liuxi, et al. Applications of nanodiamond [J]. Diamond & Abrasives Engineering, 2003(4): 41-44.
[2] 华丽. 纳米金刚石的开发与应用概述 [J]. 金刚石与磨料磨具工程, 2006(3): 76–78.HUA Li. Developments and applications of nanodiamonds [J]. Diamond & Abrasives Engineering, 2006(3): 76-78.
[3] 李敏, 栗正新, 惠明, 等. 纳米金刚石在功能材料领域中的应用 [J]. 金刚石与磨料磨具工程, 2016, 36(4): 68–74.LI Min, LI Zhengxin, HUI Ming, et al. Application status and development trend of nanodiamond in the field of functional materials [J]. Diamond & Abrasives Engineering, 2016, 36(4): 68-74.
[4] 邹芹, 王明智, 王艳辉. 纳米金刚石的性能与应用前景 [J]. 金刚石与磨料磨具工程, 2003(2): 54–58.ZOU Qin, WANG Mingzhi, WANG Yanhui. Properties and application prospects of nanometer sized diamond [J]. Diamond & Abrasives Engineering, 2003(2): 54-58.
[5] 熊礼威, 崔晓慧, 汪建华, 等. 纳米金刚石薄膜的应用及其研究进展 [J]. 表面技术, 2013, 42(5): 98–102.XIONG Liwei, CUI Xiaohui, WANG Jianhua, et al. Application of nano-crystalline diamond thin film and its development [J].Surface Technology, 2013, 42(5): 98-102.
[6] 王森. 金刚石精密研磨制品的研制 [D]. 郑州: 郑州大学, 2009.WANG Sen. Development of diamond precision grinding products [D]. Zhengzhou: Zhengzhou University, 2009.
[7] 高攀, 马志斌, 吴超, 等. 纳米金刚石膜真空窗口的制备 [J]. 金刚石与磨料磨具工程, 2016, 36(2): 24–26.GAO Pan, MA Zhibin, WU Chao, et al. Preparation of nanocrystalline diamond film vacuum window [J]. Diamond & Abrasives Engineering, 2016, 36(2): 24-26.
[8] 胡志孟, 雒建斌, 温诗铸, 等. 纳米金刚石用作磁头抛光材料的研究 [J]. 材料保护, 2001, 34(12): 11.HU Zhimeng, LUO Jianbin, WEN Shizhu, et al. Study of nanoscale diamond using as abrasive for magnetic heady [J]. Journal of Materials Protection, 2001, 34(12): 11.
[9] XU X, YU Z, ZHU Y, et al. Influence of surface modification adopting thermal treatments on dispersion of detonation nanodiamond [J]. Journal of Solid State Chemistry, 2005, 178(3): 688-693.
[10] 蔡云鹏, 曾黎明, 叶晓川, 等. 纳米金刚石悬浮液制备的研究进展 [J]. 金刚石与磨料磨具工程, 2011, 31(3): 68–72.CAI Yunpeng, ZENG Liming, YE Xiaochuan, et al. Technique progress in preparation of nano-diamond suspension [J]. Diamond & Abrasives Engineering, 2011, 31(3): 68-72.
[11] 王沛, 朱峰, 王志强. 超声波以及分散剂对纳米金刚石在水性介质中分散行为的影响 [J]. 金刚石与磨料磨具工程, 2015, 35(2): 46–50.WANG Pei, ZHU Feng, WANG Zhiqiang. Effect of dispersion of nanodiamond in aqueous medium by ultrasonic and dispersants [J]. Diamond & Abrasives Engineering, 2015, 35(2): 46-50.
[12] 李颖, 李变晓, 赵盟月, 等. 水性介质中纳米金刚石分散行为研究 [J]. 超硬材料工程, 2010, 22(2): 5–9.LI Ying, LI Bianxiao, ZHAO Mengyue, et al. The dispersion behavior of nano-diamond in aqueous medium [J]. Superhard Material Engineering, 2010, 22(2): 5-9.
[13] 张泰平. 纳米金刚石的激光分散及发光机理研究 [D]. 天津: 天津大学, 2009.ZHANG Taiping. Research of deagglomeration of detonation nanodiamond by laser ablation and its mechanism of fluorescence [D]. Tianjin: Tianjin University, 2009.
[14] KHALILNEZHAD P, SAJJADI S A, ZEBARJAD S M. Effect of nanodiamond surface functionalization using oleylamine on the scratch behavior of polyacrylic/nanodiamond nanocomposite [J]. Diamond & Related Materials, 2014, 45: 7-11.
[15] 王柏春, 朱永伟, 许向阳, 等. 纳米金刚石硬团聚体的超细粉碎机械化学解聚研究 [J]. 矿冶工程, 2003, 23(6): 86–88.WANG Baichun, ZHU Yongwei, XU Xiangyang, et al. Disaggregation of nanodiamond hard-aggregates by mechano-chemical superfine crushing [J]. Mining and Metallurgy Engineering, 2003, 23(6): 86-88.
[16] KRUGER A, KATAOKA F, OZAWA M, et al. Unusually tight aggregation in detonation nanodiamond: identification and disintegration [J]. Carbon, 2005, 43(8): 1722-1730.
[17] LIANG Y, OZAWA M, KRUEGER A. A general procedure to functionalize agglomerating nanoparticles demonstrated on nanodiamond [J]. Acs Nano, 2009, 3(8): 2288-2296.
[18] 许向阳. 纳米金刚石的解团聚与稳定分散研究 [D]. 长沙: 中南大学, 2007.XU Xiangyang. Deagglomeration and stable dispersion of detonation nanodiamond particles [D]. Changsha: Central South University, 2007.
[19] 李敏. 固定化葡萄糖氧化酶用纳米金刚石的分散及改性研究 [D]. 郑州: 河南工业大学, 2017.LI Min. Study on dispersing and modifying of nano-diamond applied to immobilization of glucose oxidase [D]. Zhengzhou: Henan University of Technology, 2017.
[20] 彭雪峰. 季铵化卤胺聚合物改性纳米金刚石的制备与性能研究 [D]. 南京: 南京理工大学, 2017.PENG Xuefeng. Research on preparation and performance of quaternarized N-halamine polymer-functionalized nanodiamonds [D]. Nanjing: Nanjing University of Science and Technology, 2017.
[21] XU X, YU Z, ZHU Y, et al. Effect of sodium oleate adsorption on the colloidal stability and zeta potential of detonation synthesized diamond particles in aqueous solutions [J]. Diamond & Related Materials, 2005, 14(2): 206-212.
[22] 柯刚, 浣石, 黄风雷. 1,3–丙二胺–纳米金刚石衍生物的合成与分散性研究[J]. 功能材料, 2009, 40(5): 863–866.KE Gang, HUAN Shi, HUANG Fenglei. Synthesis and dispersibility of derivative of 1,3-propanediamine with nanodiamond [J]. Functional Materials, 2009, 40(5): 863-866.
[23] PENG X, CAO W, JIN F, et al. Immobilization of N-halamine based polycation on nanodiamonds for high dispersity and enhanced biocidal activity [J]. Journal of Nanoscience & Nanotechnology, 2018, 18(5): 3126-3133.
[24] 万隆, 时丹, 王俊沙, 等. 硅烷偶联剂对金刚石表面改性研究 [J]. 湖南大学学报(自然科学版), 2013, 40(4): 71–74.WAN Long, SHI Dan, WANG Junsha, et al. Research on the surface modification of diamond with silane coupling agent [J]. Journal of Hunan University(Natural Sciences), 2013, 40(4): 71-74.
[25] ZHAO D, WANG Z, XI Y, et al. Preparation of silica-coated ultrafine diamond and dispersion in ceramic matrix [J]. Materials Letters, 2013, 113: 134-137.
[26] 王丽萍. 超细金刚石SiO2包覆及在多组元盐溶液中分散稳定性 [D]. 秦皇岛: 燕山大学, 2015.WANG Liping. Silica coated ultrafine diamond and its dispersion stability in multi-component salt solutions [D]. Qinhuangdao: Yanshan University, 2015.
[27] 张艳, 臧建兵, 徐汉青, 等. 纳米金刚石及相关材料的真空镀覆及应用进展 [J]. 金刚石与磨料磨具工程, 2017, 37(4): 67–72.ZHANG Yan, ZANG Jianbing, XU Hanqing, et al. Application progress on the vacuum plating of nanodiamond and related materials [J]. Diamond & Abrasives Engineering, 2017, 37(4): 67-72.
[2] 华丽. 纳米金刚石的开发与应用概述 [J]. 金刚石与磨料磨具工程, 2006(3): 76–78.HUA Li. Developments and applications of nanodiamonds [J]. Diamond & Abrasives Engineering, 2006(3): 76-78.
[3] 李敏, 栗正新, 惠明, 等. 纳米金刚石在功能材料领域中的应用 [J]. 金刚石与磨料磨具工程, 2016, 36(4): 68–74.LI Min, LI Zhengxin, HUI Ming, et al. Application status and development trend of nanodiamond in the field of functional materials [J]. Diamond & Abrasives Engineering, 2016, 36(4): 68-74.
[4] 邹芹, 王明智, 王艳辉. 纳米金刚石的性能与应用前景 [J]. 金刚石与磨料磨具工程, 2003(2): 54–58.ZOU Qin, WANG Mingzhi, WANG Yanhui. Properties and application prospects of nanometer sized diamond [J]. Diamond & Abrasives Engineering, 2003(2): 54-58.
[5] 熊礼威, 崔晓慧, 汪建华, 等. 纳米金刚石薄膜的应用及其研究进展 [J]. 表面技术, 2013, 42(5): 98–102.XIONG Liwei, CUI Xiaohui, WANG Jianhua, et al. Application of nano-crystalline diamond thin film and its development [J].Surface Technology, 2013, 42(5): 98-102.
[6] 王森. 金刚石精密研磨制品的研制 [D]. 郑州: 郑州大学, 2009.WANG Sen. Development of diamond precision grinding products [D]. Zhengzhou: Zhengzhou University, 2009.
[7] 高攀, 马志斌, 吴超, 等. 纳米金刚石膜真空窗口的制备 [J]. 金刚石与磨料磨具工程, 2016, 36(2): 24–26.GAO Pan, MA Zhibin, WU Chao, et al. Preparation of nanocrystalline diamond film vacuum window [J]. Diamond & Abrasives Engineering, 2016, 36(2): 24-26.
[8] 胡志孟, 雒建斌, 温诗铸, 等. 纳米金刚石用作磁头抛光材料的研究 [J]. 材料保护, 2001, 34(12): 11.HU Zhimeng, LUO Jianbin, WEN Shizhu, et al. Study of nanoscale diamond using as abrasive for magnetic heady [J]. Journal of Materials Protection, 2001, 34(12): 11.
[9] XU X, YU Z, ZHU Y, et al. Influence of surface modification adopting thermal treatments on dispersion of detonation nanodiamond [J]. Journal of Solid State Chemistry, 2005, 178(3): 688-693.
[10] 蔡云鹏, 曾黎明, 叶晓川, 等. 纳米金刚石悬浮液制备的研究进展 [J]. 金刚石与磨料磨具工程, 2011, 31(3): 68–72.CAI Yunpeng, ZENG Liming, YE Xiaochuan, et al. Technique progress in preparation of nano-diamond suspension [J]. Diamond & Abrasives Engineering, 2011, 31(3): 68-72.
[11] 王沛, 朱峰, 王志强. 超声波以及分散剂对纳米金刚石在水性介质中分散行为的影响 [J]. 金刚石与磨料磨具工程, 2015, 35(2): 46–50.WANG Pei, ZHU Feng, WANG Zhiqiang. Effect of dispersion of nanodiamond in aqueous medium by ultrasonic and dispersants [J]. Diamond & Abrasives Engineering, 2015, 35(2): 46-50.
[12] 李颖, 李变晓, 赵盟月, 等. 水性介质中纳米金刚石分散行为研究 [J]. 超硬材料工程, 2010, 22(2): 5–9.LI Ying, LI Bianxiao, ZHAO Mengyue, et al. The dispersion behavior of nano-diamond in aqueous medium [J]. Superhard Material Engineering, 2010, 22(2): 5-9.
[13] 张泰平. 纳米金刚石的激光分散及发光机理研究 [D]. 天津: 天津大学, 2009.ZHANG Taiping. Research of deagglomeration of detonation nanodiamond by laser ablation and its mechanism of fluorescence [D]. Tianjin: Tianjin University, 2009.
[14] KHALILNEZHAD P, SAJJADI S A, ZEBARJAD S M. Effect of nanodiamond surface functionalization using oleylamine on the scratch behavior of polyacrylic/nanodiamond nanocomposite [J]. Diamond & Related Materials, 2014, 45: 7-11.
[15] 王柏春, 朱永伟, 许向阳, 等. 纳米金刚石硬团聚体的超细粉碎机械化学解聚研究 [J]. 矿冶工程, 2003, 23(6): 86–88.WANG Baichun, ZHU Yongwei, XU Xiangyang, et al. Disaggregation of nanodiamond hard-aggregates by mechano-chemical superfine crushing [J]. Mining and Metallurgy Engineering, 2003, 23(6): 86-88.
[16] KRUGER A, KATAOKA F, OZAWA M, et al. Unusually tight aggregation in detonation nanodiamond: identification and disintegration [J]. Carbon, 2005, 43(8): 1722-1730.
[17] LIANG Y, OZAWA M, KRUEGER A. A general procedure to functionalize agglomerating nanoparticles demonstrated on nanodiamond [J]. Acs Nano, 2009, 3(8): 2288-2296.
[18] 许向阳. 纳米金刚石的解团聚与稳定分散研究 [D]. 长沙: 中南大学, 2007.XU Xiangyang. Deagglomeration and stable dispersion of detonation nanodiamond particles [D]. Changsha: Central South University, 2007.
[19] 李敏. 固定化葡萄糖氧化酶用纳米金刚石的分散及改性研究 [D]. 郑州: 河南工业大学, 2017.LI Min. Study on dispersing and modifying of nano-diamond applied to immobilization of glucose oxidase [D]. Zhengzhou: Henan University of Technology, 2017.
[20] 彭雪峰. 季铵化卤胺聚合物改性纳米金刚石的制备与性能研究 [D]. 南京: 南京理工大学, 2017.PENG Xuefeng. Research on preparation and performance of quaternarized N-halamine polymer-functionalized nanodiamonds [D]. Nanjing: Nanjing University of Science and Technology, 2017.
[21] XU X, YU Z, ZHU Y, et al. Effect of sodium oleate adsorption on the colloidal stability and zeta potential of detonation synthesized diamond particles in aqueous solutions [J]. Diamond & Related Materials, 2005, 14(2): 206-212.
[22] 柯刚, 浣石, 黄风雷. 1,3–丙二胺–纳米金刚石衍生物的合成与分散性研究[J]. 功能材料, 2009, 40(5): 863–866.KE Gang, HUAN Shi, HUANG Fenglei. Synthesis and dispersibility of derivative of 1,3-propanediamine with nanodiamond [J]. Functional Materials, 2009, 40(5): 863-866.
[23] PENG X, CAO W, JIN F, et al. Immobilization of N-halamine based polycation on nanodiamonds for high dispersity and enhanced biocidal activity [J]. Journal of Nanoscience & Nanotechnology, 2018, 18(5): 3126-3133.
[24] 万隆, 时丹, 王俊沙, 等. 硅烷偶联剂对金刚石表面改性研究 [J]. 湖南大学学报(自然科学版), 2013, 40(4): 71–74.WAN Long, SHI Dan, WANG Junsha, et al. Research on the surface modification of diamond with silane coupling agent [J]. Journal of Hunan University(Natural Sciences), 2013, 40(4): 71-74.
[25] ZHAO D, WANG Z, XI Y, et al. Preparation of silica-coated ultrafine diamond and dispersion in ceramic matrix [J]. Materials Letters, 2013, 113: 134-137.
[26] 王丽萍. 超细金刚石SiO2包覆及在多组元盐溶液中分散稳定性 [D]. 秦皇岛: 燕山大学, 2015.WANG Liping. Silica coated ultrafine diamond and its dispersion stability in multi-component salt solutions [D]. Qinhuangdao: Yanshan University, 2015.
[27] 张艳, 臧建兵, 徐汉青, 等. 纳米金刚石及相关材料的真空镀覆及应用进展 [J]. 金刚石与磨料磨具工程, 2017, 37(4): 67–72.ZHANG Yan, ZANG Jianbing, XU Hanqing, et al. Application progress on the vacuum plating of nanodiamond and related materials [J]. Diamond & Abrasives Engineering, 2017, 37(4): 67-72.