电纺纳米纤维在食品分析中的应用
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摘要
电纺纳米纤维因具有快速的吸/脱附特性和较高的吸/脱附效率等独特优势,近年来被广泛用于食品分析检测。本文简述了纳米纤维特性及静电纺丝技术,重点综述了电纺纳米纤维在食品分析检测中的应用,其中着重对聚苯乙烯(PS)、尼龙6等单组份电纺纳米纤维以及聚冠醚/聚苯乙烯(PCE-PS)等混合组份纳米纤维在食品分析中的应用进展做了阐述,同时对其他一些纳米材料如纳米晶簇、碳纳米管、石墨烯、磁性纳米粒子、纳米金属氧化物、量子点在食品分析检测中的某些最新研究成果和应用做了简要介绍;此外还展示了一些纳米纤维固相萃取器件和装置,并对其做了简要说明;最后对电纺纳米纤维在食品分析检测中的应用作了总结和展望。
Electrospinning nanofibers have been used for food analysis and determination in recent years because of their unique advantages, such as high efficiency and fast speed of absorption/desorption. In this paper, nanofiber properties and electrospinning technology are sketched. The application of electrospinning nanofibers on food analysis has been elaborately summarized, especially one-component electrospinning nanofibers, mainly including polystyrene(PS) and nylon 6, and hybrid components electrospinning nanofibers, mainly including polymeric crown ethers/polystyrene(PCE-PS). Some new study results of other nanomaterials, mainly including nanocrystalline clusters, carbon nanotubes, grapheme, magnetic nanoparticles, nanoscale metal oxides, quantum dot, on food analysis are briefly introduced. Additionally, the novel packed-fiber solid-phase extraction devices and apparatus have been also presented and briefly described. At last, the application of the electrospinning nanofibers on food analysis was summarized and forecasted.
Electrospinning nanofibers have been used for food analysis and determination in recent years because of their unique advantages, such as high efficiency and fast speed of absorption/desorption. In this paper, nanofiber properties and electrospinning technology are sketched. The application of electrospinning nanofibers on food analysis has been elaborately summarized, especially one-component electrospinning nanofibers, mainly including polystyrene(PS) and nylon 6, and hybrid components electrospinning nanofibers, mainly including polymeric crown ethers/polystyrene(PCE-PS). Some new study results of other nanomaterials, mainly including nanocrystalline clusters, carbon nanotubes, grapheme, magnetic nanoparticles, nanoscale metal oxides, quantum dot, on food analysis are briefly introduced. Additionally, the novel packed-fiber solid-phase extraction devices and apparatus have been also presented and briefly described. At last, the application of the electrospinning nanofibers on food analysis was summarized and forecasted.
引文
[1]李广庆,马国辉.固相萃取技术在食品痕量残留和污染分析中的应用[J].色谱,2011,29(7):606-612.Li GQ,Ma GH.Application of solid phase extraction technique on the food trace amount residues and pollution analysis[J].J Chromatogr,2011,29(7):606-612.
[2]Kang XJ,Pan C,Zhang YY,et al.Electrospun polymer nanofibers as the solid phase extraction sorbent for the determination of trazodom in human plasma[J].Anal Chim Acta,2007,587:75-81.
[3]Ondarcuhu T,Joachim C.Drawing a single nanofibre over hundreds of microns[J].Europhys Lett,1998,42(2):215.
[4]Feng L,Li S,Li Y,et al.Super‐hydrophobic surfaces:from natural to artificial[J].Adv Mater,2002,14(24):1857-1860.
[5]Martin C R.Membrane-based synthesis of nanomaterials[J].Chem Materials,1996,8(8):1739-1746.
[6]Ma PX,Zhang R.Microtubular architecture of biodegradable polymer scaffolds[J].J Biomed Mat Res,2001,56(4):469-477.
[7]Liu G,Ding J,Qiao L,et al.Polystyrene-block-poly(2-cinnamoylethyl methacrylate)Nanofibers-Preparation,Characterization,and Liquid Crystalline Properties[J].Chem-A Eur J,1999,5(9):2740-2749.
[8]Whitesides GM,Grzybowski B.Self-assembly at all scales[J].Science,2002,295(5564):2418-2421.
[9]Deitzel JM,Kleinmeyer JD,Hirvonen JK,et al.Controlled deposition of electrospun poly(ethylene oxide)fibers[J].Polymer,2001,42(19):8163-8170.
[10]Fong H,Reneker DH.Elastomeric nanofibers of styrene-butadiene-styrene triblock copolymer[J].J Polymer Sci Part B Polymer Physics,1999,37(24):3488-3493.
[11]An H,Shin C,Chase GG.Ion exchanger using electrospun polystyrene nanofibers[J].J Membrane Sci,2006,283(1):84-87.
[12]戚东进,康学军,张逸昀,等.采用纳米纤维富集与测定水样中的环境雌激素[J].中国科技论文在线,2008,3(4):283-287.Qi DJ,Kang XJ,Zhang YY,et al.Enrichment and determination of environmental estrogen in water samples using nanofibers[J].China Sci Technol Papers Online,2008,3(4):283-287.
[13]Zheng J,He A,Li J,et al.Studies on the controlled morphology and wettability of polystyrene surfaces by electrospinning or electrospraying[J].Polymer,2006,47(20):7095-7102.
[14]Fang F,Kang XJ,Liu ZY,et al.Use of packed-fiber solid-phase extraction for sample clean-up and preconcentration of vitamin B12 before determination[J].Chin Chem Lett,2009,20(12):1491-1494.
[15]刘智永,孙静,曲子健,等.基于纳米纤维的食品中脂溶性维生素富集与测定[C].2009年全国高分子学术论文报告会论文摘要集(上册),2009.Liu ZY,Sun J,Qu ZJ,et al.Packed-fiber solid-phase extraction(PFSPE)for enrichment and determination of fat-soluble vitamins in food[C].Paper Abstracts Set of National Polymer Academic Report in 2009(I),2009.
[16]Liu Z,Kang X,Fang F.Solid phase extraction with electrospun nanofibers for determination of retinol andα-tocopherol in plasma[J].Microchim Acta,2010,168(1-2):59-64.
[17]姚志云,杨立刚,郑春慧,等.电纺纳米纤维固相萃取拟除虫菊酯的研究[J].化学通报,2009,(9):845-848.Yao ZY,Yang LG,Zheng CH,et al.Study of solid phase extraction with electrospun nanofibers for pyrethroid[J].Chem Online,2009,(9):845-848.
[18]郑春慧,杨立刚,姚志云,等.白菜中有机磷农药的电纺纳米纤维固相萃取-高效液相色谱法测定[J].分析测试学报,2009,28(8):926-930.Zheng CH,Yao ZY,Yang LG,et al.Solid phase extraction with electrospun nanofibers mass high performance liquid chromatography(HPLC)for detemination of organophosphorus pesticides in cabbage[J].J Instrum Anal,2009,28(8):926-930.
[19]郑春慧,孟范贵,莫小荣,等.纳米纤维在分析菊酯类农药残留中的应用[J].分析试验室,2010,(3):80-84.Zheng CH,Meng FG,Mo XR,et al.Application of nanofibers on the analysis for pyrethroid pesticides residue[J].Chin J Anal Lab,2010,(3):80-84.
[20]郑胜兰,陈利琴,曲子健,等.牛奶中氯霉素的纳米纤维固相萃取快速前处理方法[J].食品科学,2012,33(24):180-184.Zheng SL,Chen LQ,Qu ZJ,et al.Rapid pretreatment of solid phase extraction with electrospun nanofibers for chloramphenicol in milk[J].Food Sci,2012,33(24):180-184.
[21]Sun J,Wang Y,Zhou XL,et al.The Investigation of Electrospun Polymer Nanofibers as a Solid-Phase Extraction Sorbent for the Determination of Benzimidazoles in Pork[J].Adv Mater Res,2013,662:239-242.
[22]Hu W,Kang X,Zhang C,et al.Packed-Fiber Solid-Phase Extraction Coupled with High Performance Liquid Chromatography minus Tandem Mass Spectrometry for Determination of Diethylstilbestrol,Hexestrol,and Dienestrol Residues in Milk Products(2014),http://dx.doi.org/10.1016/j.jchromb.2014.02.036.
[23]孙静,马玉琴,康学军.聚苯乙烯电纺纳米纤维对水中苯系物吸附性能的研究[J].第五届全国环境化学大会摘要集,2009.Sun J,Ma YQ,Kang XJ.Study on polystyrene electrospinning nanofibers adsorption properties of benzenes in water[J].Abstract Sets of The Fifth National Environmental Chemistry Conference,2009.
[24]孙静,马玉琴,康学军.聚苯乙烯电纺纳米纤维对水中苯系物的吸附性能[J].环境化学,2010,(1):105-108.Sun J,Ma YQ,Kang XJ.Adsorption properties of polystyrene electrospinning nanofibers for benzenes in water[J].Environ Chem,2010,(1):105-108.
[25]刘静,曾兴宇,曲子健,等.纳米纤维固相萃取-气相色谱法分析海水中狄氏剂与多氯联苯[J].环境化学,2013,8:025.Liu J,Zeng XY,Qu ZJ,et al.Packed-Fiber Solid-Phase Extraction Coupled with gas chromatography for analysis of dieldrin and polychlorinated biphenyls(PCBS)in seawater[J].Environ Chem,2013,8:025.
[26]黄亮,杨立刚,耿彬彬,等.纳米纤维在辣椒粉中苏丹红Ⅱ测定中的应用[J].分析试验室,2010,11:009.Huang L,Yang LG,Geng BB,et al.Application of nanofibers on the determination for Sudan redⅡin paprika[J].Chin J Anal Lab,2010,11:009.
[27]周小玲,邓晓燕,康学军.纳米纤维固相萃取-气相色谱法检测食品中邻苯二甲酸酯[J].第六届全国环境化学大会暨环境科学仪器与分析仪器展览会摘要集,2011.Zhou XL,Deng XY,Kang XJ.Packed-Fiber Solid-Phase Extraction Coupled with gas chromatography for determination of phthalates in food[J].Abstract Sets of the Sixth National Environmental Chemistry Conference,2011.
[28]夏艳杰.尼龙6/66纳米纤维非织造物的结构与性能[D].苏州:苏州大学,2007.Xia YJ.The structure and properties of nylon 6/66 nanofibers nonwoven fabric[D].Suzhou:Suzhou University,2007.
[29]殷雪琰,许茜,王敏,等.尼龙6纳米纤维膜固相萃取-HPLC法检测环境水样中邻苯二甲酸酯[J].中国化学会第27届学术年会第04分会场摘要集,2010.Yin XY,Xu Q,Wang M,et al.Solid-phase extraction-HPLC with nylon 6 nanofiber membrane for determination of phthalates in environmental water samples[J].Abstract Sets of Chinese Chemical Society 27th Academic Annual Seminar,2010.
[30]吴淑燕,许茜,陈天舒,等.尼龙6纳米纤维膜固相膜萃取-高效液相色谱法测定塑料瓶装矿泉水中双酚A[J].分析化学,2010,38(4):503-507.Wu SY,Xu Q,Chen TS,et al.Solid-phase extraction-HPLC with nylon 6 nanofiber membrane for determination of bisphenol A in mineral water of plastic bottles A[J].Anal Chem,2010,38(4):503-507.
[31]曹阳,殷雪琰,周方晴,等.尼龙6纳米纤维膜固相萃取-液相色谱法测定食用油中邻苯二甲酸酯[J].分析化学,2013,41(12):1837-1843.Cao Y,Yin XY,Zhou FQ,et al.Solid-phase extraction-HPLC with nylon 6 nanofiber membrane for determination of phthalates in cooking oil[J].Anal Chem,2013,41(12):1837-1843.
[32]郑胜兰,陈利琴,曲斌,等.纳米纤维固相萃取应用于猪肉中瘦肉精类药物的检测[J].中国化学会第28届学术年会第9分会场摘要集,2012.Zheng SL.Chen LQ,Qu B,et al.Packed-Fiber Solid-Phase Extraction for determination of clenbuterol drugs in pork[J].Abstract Sets of Chinese Chemical Society 28th Academic Annual Seminar,2012.
[33]Ma Z,Kotaki M,Ramakrishna S.Surface modified nonwoven polysulphone(PSU)fiber mesh by electrospinning:a novel affinity membrane[J].J Membrane Sci,2006,272(1):179-187.
[34]曹阳,许茜.聚吡咯/尼龙6纳米纤维膜的制备及表征[J].中国化学会第28届学术年会第4分会场摘要集,2012.Cao Y,Xu Q.Preparation and characterization of polypyrrole/nylon6 nanofiber membrane[J].Abstract Sets of Chinese Chemical Society 28th Academic Annual Seminar,2012.
[35]靳高岭,张秀芹,王锐,等.PA6/LDPE/PE—g-MAH共混纳米纤维的制备及结构研究[J].合成纤维工业,2013,36(1):1-5.Jin GL,Zhang XQ,Wang R,et al.Preparation and structure research of PA6/LDPE/PE—g-MAH hybrid components nanofibers[J].China Synthetic Fiber Ind,2013,36(1):1-5.
[36]Tian T,Zheng S,Ye B,et al.Poly-3,4-ethylenedioxythiophene nanoclusters for high effective solid phase extraction[J].J Chromatogr A,2013,1275:17-24.
[37]Zhao P,Wang L,Zhou L,et al.Multi-walled carbon nanotubes as alternative reversed-dispersive solid phase extraction materials in pesticide multi-residue analysis with QuEChERS method[J].J Chromatogr A,2012,1225:17-25.
[38]Oliveira TM,Fátima Barroso M,Morais S,et al.Biosensor based on multi-walled carbon nanotubes paste electrode modified with laccase for pirimicarb pesticide quantification[J].Talanta,2013,106:137-143.
[39]Guan W,Li Z,Zhang H,et al.Amine modified graphene as reversed-dispersive solid phase extraction materials combined with liquid chromatography–tandem mass spectrometry for pesticide multi-residue analysis in oil crops[J].J Chromatogr A,2013,1286:1-8.
[40]Liu Y,Yang S,Niu W.Simple,rapid and green one-step strategy to synthesis of graphene/carbon nanotubes/chitosan hybrid as solid-phase extraction for square-wave voltammetric detection of methyl parathion[J].Colloids Surf B:Biointerfaces,2013,108:266-270.
[41]张恒,阳承利,吕敬章,等.Fe3O4@Si-C8/C18复合磁性纳米材料的制备及其在兽药净化中的应用[J].食品科学,2012,33(18):108-112.Zhang H,Yang CL,Lv JZ,et al.Preparation of magnetic composite nanomaterials Fe3O4@Si-C8/C18 and application in veterinary drug purification[J].Food Sci,2012,33(18):108-112.
[42]Saravanan P,Vinod VTP,Sreedhar B,et al.Gum kondagogu modified magnetic nano-adsorbent:An efficient protocol for removal of various toxic metal ions[J].Mater Sci Eng C,2012,32(3):581-586.
[43]Aboufazeli F,Lotfi Zadeh Zhad HR,Sadeghi O,et al.Novel ion imprinted polymer magnetic mesoporous silica nano-particles for selective separation and determination of lead ions in food samples[J].Food Chem,2013,141(4):3459-3465.
[44]Barman G,Maiti S,Laha JK.Bio-fabrication of gold nanoparticles using aqueous extract of red tomato and its use as a colorimetric sensor[J].Nanoscale Res Lett,2013,8(1):1-9.
[45]Fan L,Zhao G,Shi H,et al.A highly selective electrochemical impedance spectroscopy-based aptasensor for sensitive detection of acetamiprid[J].Biosens and Bioelectron,2013,43:12-18.
[46]王仕兴,张晓红,牛华,等.纳米材料应用食品农药残留检测研究进展[J].粮食与油脂,2011,(3):43-47.Wang SX,Zhang XH,Niu H,et al.Application of nanomaterials in detection of food pesticide residues[J].J Cereals&Oils,2011,(3):43-47.
[47]Meng X,Wei J,Ren X,et al.A simple and sensitive fluorescence biosensor for detection of organophosphorus pesticides using H2O2-sensitive quantum dots/bi-enzyme[J].Biosens Bioelectron,2013,47:402-407.
[48]Zhou M,Chen X,Xu Y,et al.Sensitive determination of Sudan dyes in foodstuffs by Mn–ZnS quantum dots[J].Dyes and Pigments,2013,99(1):120-126.
[49]曲子健,康学军,吴玮玮,等.新型纳米纤维固相萃取柱制备及其用于组织样品中柔红霉素测定研究[J].分析化学,2011,39(3):312-316.Qu ZJ,Kang XJ,Wu WW,et al.Preparation of new packed-fiber solid-phase extraction column and its application on the determination of daunorubicin in tissue samples[J].Anal Chem,2011,39(3):312-316.
[50]王羽,康学军,邓剑军,等.静电纺纳米纤维在功能食品关键技术中的应用[J].功能食品关键技术开发与应用研讨会论文集,2013.Wang Y,Kang XJ,Deng JJ,et al.Application of electrospinning nanofibers on functional food key technology[J].Conference Proceedings of Key Technology Development and Application on Functional Food,2013.
[2]Kang XJ,Pan C,Zhang YY,et al.Electrospun polymer nanofibers as the solid phase extraction sorbent for the determination of trazodom in human plasma[J].Anal Chim Acta,2007,587:75-81.
[3]Ondarcuhu T,Joachim C.Drawing a single nanofibre over hundreds of microns[J].Europhys Lett,1998,42(2):215.
[4]Feng L,Li S,Li Y,et al.Super‐hydrophobic surfaces:from natural to artificial[J].Adv Mater,2002,14(24):1857-1860.
[5]Martin C R.Membrane-based synthesis of nanomaterials[J].Chem Materials,1996,8(8):1739-1746.
[6]Ma PX,Zhang R.Microtubular architecture of biodegradable polymer scaffolds[J].J Biomed Mat Res,2001,56(4):469-477.
[7]Liu G,Ding J,Qiao L,et al.Polystyrene-block-poly(2-cinnamoylethyl methacrylate)Nanofibers-Preparation,Characterization,and Liquid Crystalline Properties[J].Chem-A Eur J,1999,5(9):2740-2749.
[8]Whitesides GM,Grzybowski B.Self-assembly at all scales[J].Science,2002,295(5564):2418-2421.
[9]Deitzel JM,Kleinmeyer JD,Hirvonen JK,et al.Controlled deposition of electrospun poly(ethylene oxide)fibers[J].Polymer,2001,42(19):8163-8170.
[10]Fong H,Reneker DH.Elastomeric nanofibers of styrene-butadiene-styrene triblock copolymer[J].J Polymer Sci Part B Polymer Physics,1999,37(24):3488-3493.
[11]An H,Shin C,Chase GG.Ion exchanger using electrospun polystyrene nanofibers[J].J Membrane Sci,2006,283(1):84-87.
[12]戚东进,康学军,张逸昀,等.采用纳米纤维富集与测定水样中的环境雌激素[J].中国科技论文在线,2008,3(4):283-287.Qi DJ,Kang XJ,Zhang YY,et al.Enrichment and determination of environmental estrogen in water samples using nanofibers[J].China Sci Technol Papers Online,2008,3(4):283-287.
[13]Zheng J,He A,Li J,et al.Studies on the controlled morphology and wettability of polystyrene surfaces by electrospinning or electrospraying[J].Polymer,2006,47(20):7095-7102.
[14]Fang F,Kang XJ,Liu ZY,et al.Use of packed-fiber solid-phase extraction for sample clean-up and preconcentration of vitamin B12 before determination[J].Chin Chem Lett,2009,20(12):1491-1494.
[15]刘智永,孙静,曲子健,等.基于纳米纤维的食品中脂溶性维生素富集与测定[C].2009年全国高分子学术论文报告会论文摘要集(上册),2009.Liu ZY,Sun J,Qu ZJ,et al.Packed-fiber solid-phase extraction(PFSPE)for enrichment and determination of fat-soluble vitamins in food[C].Paper Abstracts Set of National Polymer Academic Report in 2009(I),2009.
[16]Liu Z,Kang X,Fang F.Solid phase extraction with electrospun nanofibers for determination of retinol andα-tocopherol in plasma[J].Microchim Acta,2010,168(1-2):59-64.
[17]姚志云,杨立刚,郑春慧,等.电纺纳米纤维固相萃取拟除虫菊酯的研究[J].化学通报,2009,(9):845-848.Yao ZY,Yang LG,Zheng CH,et al.Study of solid phase extraction with electrospun nanofibers for pyrethroid[J].Chem Online,2009,(9):845-848.
[18]郑春慧,杨立刚,姚志云,等.白菜中有机磷农药的电纺纳米纤维固相萃取-高效液相色谱法测定[J].分析测试学报,2009,28(8):926-930.Zheng CH,Yao ZY,Yang LG,et al.Solid phase extraction with electrospun nanofibers mass high performance liquid chromatography(HPLC)for detemination of organophosphorus pesticides in cabbage[J].J Instrum Anal,2009,28(8):926-930.
[19]郑春慧,孟范贵,莫小荣,等.纳米纤维在分析菊酯类农药残留中的应用[J].分析试验室,2010,(3):80-84.Zheng CH,Meng FG,Mo XR,et al.Application of nanofibers on the analysis for pyrethroid pesticides residue[J].Chin J Anal Lab,2010,(3):80-84.
[20]郑胜兰,陈利琴,曲子健,等.牛奶中氯霉素的纳米纤维固相萃取快速前处理方法[J].食品科学,2012,33(24):180-184.Zheng SL,Chen LQ,Qu ZJ,et al.Rapid pretreatment of solid phase extraction with electrospun nanofibers for chloramphenicol in milk[J].Food Sci,2012,33(24):180-184.
[21]Sun J,Wang Y,Zhou XL,et al.The Investigation of Electrospun Polymer Nanofibers as a Solid-Phase Extraction Sorbent for the Determination of Benzimidazoles in Pork[J].Adv Mater Res,2013,662:239-242.
[22]Hu W,Kang X,Zhang C,et al.Packed-Fiber Solid-Phase Extraction Coupled with High Performance Liquid Chromatography minus Tandem Mass Spectrometry for Determination of Diethylstilbestrol,Hexestrol,and Dienestrol Residues in Milk Products(2014),http://dx.doi.org/10.1016/j.jchromb.2014.02.036.
[23]孙静,马玉琴,康学军.聚苯乙烯电纺纳米纤维对水中苯系物吸附性能的研究[J].第五届全国环境化学大会摘要集,2009.Sun J,Ma YQ,Kang XJ.Study on polystyrene electrospinning nanofibers adsorption properties of benzenes in water[J].Abstract Sets of The Fifth National Environmental Chemistry Conference,2009.
[24]孙静,马玉琴,康学军.聚苯乙烯电纺纳米纤维对水中苯系物的吸附性能[J].环境化学,2010,(1):105-108.Sun J,Ma YQ,Kang XJ.Adsorption properties of polystyrene electrospinning nanofibers for benzenes in water[J].Environ Chem,2010,(1):105-108.
[25]刘静,曾兴宇,曲子健,等.纳米纤维固相萃取-气相色谱法分析海水中狄氏剂与多氯联苯[J].环境化学,2013,8:025.Liu J,Zeng XY,Qu ZJ,et al.Packed-Fiber Solid-Phase Extraction Coupled with gas chromatography for analysis of dieldrin and polychlorinated biphenyls(PCBS)in seawater[J].Environ Chem,2013,8:025.
[26]黄亮,杨立刚,耿彬彬,等.纳米纤维在辣椒粉中苏丹红Ⅱ测定中的应用[J].分析试验室,2010,11:009.Huang L,Yang LG,Geng BB,et al.Application of nanofibers on the determination for Sudan redⅡin paprika[J].Chin J Anal Lab,2010,11:009.
[27]周小玲,邓晓燕,康学军.纳米纤维固相萃取-气相色谱法检测食品中邻苯二甲酸酯[J].第六届全国环境化学大会暨环境科学仪器与分析仪器展览会摘要集,2011.Zhou XL,Deng XY,Kang XJ.Packed-Fiber Solid-Phase Extraction Coupled with gas chromatography for determination of phthalates in food[J].Abstract Sets of the Sixth National Environmental Chemistry Conference,2011.
[28]夏艳杰.尼龙6/66纳米纤维非织造物的结构与性能[D].苏州:苏州大学,2007.Xia YJ.The structure and properties of nylon 6/66 nanofibers nonwoven fabric[D].Suzhou:Suzhou University,2007.
[29]殷雪琰,许茜,王敏,等.尼龙6纳米纤维膜固相萃取-HPLC法检测环境水样中邻苯二甲酸酯[J].中国化学会第27届学术年会第04分会场摘要集,2010.Yin XY,Xu Q,Wang M,et al.Solid-phase extraction-HPLC with nylon 6 nanofiber membrane for determination of phthalates in environmental water samples[J].Abstract Sets of Chinese Chemical Society 27th Academic Annual Seminar,2010.
[30]吴淑燕,许茜,陈天舒,等.尼龙6纳米纤维膜固相膜萃取-高效液相色谱法测定塑料瓶装矿泉水中双酚A[J].分析化学,2010,38(4):503-507.Wu SY,Xu Q,Chen TS,et al.Solid-phase extraction-HPLC with nylon 6 nanofiber membrane for determination of bisphenol A in mineral water of plastic bottles A[J].Anal Chem,2010,38(4):503-507.
[31]曹阳,殷雪琰,周方晴,等.尼龙6纳米纤维膜固相萃取-液相色谱法测定食用油中邻苯二甲酸酯[J].分析化学,2013,41(12):1837-1843.Cao Y,Yin XY,Zhou FQ,et al.Solid-phase extraction-HPLC with nylon 6 nanofiber membrane for determination of phthalates in cooking oil[J].Anal Chem,2013,41(12):1837-1843.
[32]郑胜兰,陈利琴,曲斌,等.纳米纤维固相萃取应用于猪肉中瘦肉精类药物的检测[J].中国化学会第28届学术年会第9分会场摘要集,2012.Zheng SL.Chen LQ,Qu B,et al.Packed-Fiber Solid-Phase Extraction for determination of clenbuterol drugs in pork[J].Abstract Sets of Chinese Chemical Society 28th Academic Annual Seminar,2012.
[33]Ma Z,Kotaki M,Ramakrishna S.Surface modified nonwoven polysulphone(PSU)fiber mesh by electrospinning:a novel affinity membrane[J].J Membrane Sci,2006,272(1):179-187.
[34]曹阳,许茜.聚吡咯/尼龙6纳米纤维膜的制备及表征[J].中国化学会第28届学术年会第4分会场摘要集,2012.Cao Y,Xu Q.Preparation and characterization of polypyrrole/nylon6 nanofiber membrane[J].Abstract Sets of Chinese Chemical Society 28th Academic Annual Seminar,2012.
[35]靳高岭,张秀芹,王锐,等.PA6/LDPE/PE—g-MAH共混纳米纤维的制备及结构研究[J].合成纤维工业,2013,36(1):1-5.Jin GL,Zhang XQ,Wang R,et al.Preparation and structure research of PA6/LDPE/PE—g-MAH hybrid components nanofibers[J].China Synthetic Fiber Ind,2013,36(1):1-5.
[36]Tian T,Zheng S,Ye B,et al.Poly-3,4-ethylenedioxythiophene nanoclusters for high effective solid phase extraction[J].J Chromatogr A,2013,1275:17-24.
[37]Zhao P,Wang L,Zhou L,et al.Multi-walled carbon nanotubes as alternative reversed-dispersive solid phase extraction materials in pesticide multi-residue analysis with QuEChERS method[J].J Chromatogr A,2012,1225:17-25.
[38]Oliveira TM,Fátima Barroso M,Morais S,et al.Biosensor based on multi-walled carbon nanotubes paste electrode modified with laccase for pirimicarb pesticide quantification[J].Talanta,2013,106:137-143.
[39]Guan W,Li Z,Zhang H,et al.Amine modified graphene as reversed-dispersive solid phase extraction materials combined with liquid chromatography–tandem mass spectrometry for pesticide multi-residue analysis in oil crops[J].J Chromatogr A,2013,1286:1-8.
[40]Liu Y,Yang S,Niu W.Simple,rapid and green one-step strategy to synthesis of graphene/carbon nanotubes/chitosan hybrid as solid-phase extraction for square-wave voltammetric detection of methyl parathion[J].Colloids Surf B:Biointerfaces,2013,108:266-270.
[41]张恒,阳承利,吕敬章,等.Fe3O4@Si-C8/C18复合磁性纳米材料的制备及其在兽药净化中的应用[J].食品科学,2012,33(18):108-112.Zhang H,Yang CL,Lv JZ,et al.Preparation of magnetic composite nanomaterials Fe3O4@Si-C8/C18 and application in veterinary drug purification[J].Food Sci,2012,33(18):108-112.
[42]Saravanan P,Vinod VTP,Sreedhar B,et al.Gum kondagogu modified magnetic nano-adsorbent:An efficient protocol for removal of various toxic metal ions[J].Mater Sci Eng C,2012,32(3):581-586.
[43]Aboufazeli F,Lotfi Zadeh Zhad HR,Sadeghi O,et al.Novel ion imprinted polymer magnetic mesoporous silica nano-particles for selective separation and determination of lead ions in food samples[J].Food Chem,2013,141(4):3459-3465.
[44]Barman G,Maiti S,Laha JK.Bio-fabrication of gold nanoparticles using aqueous extract of red tomato and its use as a colorimetric sensor[J].Nanoscale Res Lett,2013,8(1):1-9.
[45]Fan L,Zhao G,Shi H,et al.A highly selective electrochemical impedance spectroscopy-based aptasensor for sensitive detection of acetamiprid[J].Biosens and Bioelectron,2013,43:12-18.
[46]王仕兴,张晓红,牛华,等.纳米材料应用食品农药残留检测研究进展[J].粮食与油脂,2011,(3):43-47.Wang SX,Zhang XH,Niu H,et al.Application of nanomaterials in detection of food pesticide residues[J].J Cereals&Oils,2011,(3):43-47.
[47]Meng X,Wei J,Ren X,et al.A simple and sensitive fluorescence biosensor for detection of organophosphorus pesticides using H2O2-sensitive quantum dots/bi-enzyme[J].Biosens Bioelectron,2013,47:402-407.
[48]Zhou M,Chen X,Xu Y,et al.Sensitive determination of Sudan dyes in foodstuffs by Mn–ZnS quantum dots[J].Dyes and Pigments,2013,99(1):120-126.
[49]曲子健,康学军,吴玮玮,等.新型纳米纤维固相萃取柱制备及其用于组织样品中柔红霉素测定研究[J].分析化学,2011,39(3):312-316.Qu ZJ,Kang XJ,Wu WW,et al.Preparation of new packed-fiber solid-phase extraction column and its application on the determination of daunorubicin in tissue samples[J].Anal Chem,2011,39(3):312-316.
[50]王羽,康学军,邓剑军,等.静电纺纳米纤维在功能食品关键技术中的应用[J].功能食品关键技术开发与应用研讨会论文集,2013.Wang Y,Kang XJ,Deng JJ,et al.Application of electrospinning nanofibers on functional food key technology[J].Conference Proceedings of Key Technology Development and Application on Functional Food,2013.