碱减量废水资源化回收与处理技术研究进展
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摘要
概括了碱减量废水资源化回收与处理技术的国内外研究现状,总结了当前对苯二甲酸的资源化回收途径(酸析法、碱析法和结晶法),以及常用的碱减量废水物化处理方法(化学混凝法和电化学法)和生物处理方法(好氧生物处理和厌氧生物处理),并对已有回收途径和处理方法进行技术评价,指出基于资源化回收的废水处理技术是今后解决碱减量废水的发展方向。
The research status of alkali-minimization wastewater resource recycling and treatment in China and aborad were elaborated, the resource recycling paths of terephthalic acid — acid precipitation method, alkali out method, and crystallization method; the commonly used physical-chemical method — chemical coagulation process and electrochemical process; as well as the biological treatment method — aerobic biological treatment and anaerobic biological treatment, were summarized. Besides, the currently used recycling paths and treatment methods were technically evaluated, it was pointed out that, wastewater treatment technology based on resource recycling was the development direction of alkali-minimization wastewater treatment in the future.
The research status of alkali-minimization wastewater resource recycling and treatment in China and aborad were elaborated, the resource recycling paths of terephthalic acid — acid precipitation method, alkali out method, and crystallization method; the commonly used physical-chemical method — chemical coagulation process and electrochemical process; as well as the biological treatment method — aerobic biological treatment and anaerobic biological treatment, were summarized. Besides, the currently used recycling paths and treatment methods were technically evaluated, it was pointed out that, wastewater treatment technology based on resource recycling was the development direction of alkali-minimization wastewater treatment in the future.
引文
[1]王锐刚,金漫彤,张雁秋.碱减量废水处理试验研究[J].丝绸, 2007,(10):31-33.
[2]蒋源隆.从碱减量废水中回收对苯二甲酸的实践[J].污染防治技术, 2003,(2):63-64.
[3]杨期勇,杨涛,陈季华.碱减量废水对苯二甲酸回收工艺的影响因素[J].印染, 2010, 36(2):30-33.
[4]郭茂新,周慧华.碱减量废水处理技术试验研究[J].工业用水与废水, 2000, 31(2):23-25.
[5]杨平平,常宏宏.涤纶织物碱减量工艺废水处理研究[J].水处理技术, 2016, 42(12):96-98.
[6]范立海,潘培堂,陈欢林,等.碱减量废水膜法集成处理技术[J].水处理技术, 2008, 34(2):63-66.
[7]李永贵,贺永林,陈东生.超滤-混凝-酸析法回收涤纶碱减量废水中对苯二甲酸[J].山东纺织科技, 2014, 55(5):53-56.
[8]贺永林,李永贵,葛明桥.有机溶剂对回收涤纶碱减量废渣中苯二甲酸的影响[J].纺织学报, 2013, 34(12):12-15.
[9]李永贵,刘春雨,贺永林,等.应用加合结晶的涤纶碱减量废渣中对苯二甲酸回收[J].纺织学报, 2014, 35(10):67-71.
[10]曹丽红,姜佩华.碱减量废水碱析法回收对苯二甲酸[J].污染防治技术, 2004,(1):95-96.
[11]马国文,陆永生,郑乐平.某企业高浓度碱减量废水预处理方案探讨与分析[J].环境科学与管理, 2013, 38(10):147-152.
[12]王淑影,杨俞,闫龙.碱减量废水的处理现状[J].科技资讯,2017, 15(21):99-100.
[13] WEN Y Z, TONG S P, ZHENG K F, et al. Removal of terephthalic acid in alkalized wastewater by ferric chloride[J]. Journal of Hazardous Materials, 2006, 138(1):169-172.
[14]顾孙.含碱减量混合废水处理工程案例分析[J].黑龙江科技信息, 2014,(2):55-55.
[15]崔小明.一种资源再利用碱减量废水中对苯二甲酸的方法[J].聚酯工业, 2016, 29(6):49-49.
[16] ANAND M V, SRIVASTAVA V C, SINHG S, et al. Electrochemical treatment of alkali decrement wastewater containing terephthalic acid using iron electrodes[J]. Journal of the Taiwan Institute of Chemical Engineers, 2014, 45(3):908-913.
[17] SANDHWAR V K, PRASAD B. Terephthalic acid removal from aqueous solution by electrocoagulation and electro-Fenton methods:Process optimization through response surface methodology[J].Process Safety and Environmental Protection, 2017, 107:269-280.
[18] SANDHWAR V K, PRASAD B. A comparative study of electrochemical degradation of benzoic acid and terephthalic acid from aqueous solution of purified terephthalic acid(PTA)wastewater[J]. Journal of Water Process Engineering. http://dx.doi.org/10.1016/j.jwpe.2017.03.006.
[19]陈岗,刘荣琼,钱福国. Fenton-A2O工艺在制药工业废水深度处理中的应用[J].工业用水与废水, 2015, 46(6):46-49.
[20]金艳.碱减量废水处理工程实例[J].工业用水与废水, 2017,48(4):68-71.
[21]刘鹏程,杜佳丽,郑凤娟,等.三元耐盐复合菌种在碱减量废水处理中的应用[J].印染, 2017, 43(7):10-13.
[22]孙选举,陈季华,杨期勇,等.复合式MBR处理涤纶碱减量废水的试验研究[J].工业水处理, 2006, 26(3):36-38.
[23]杨波,魏爽,田晴,等.上流式曝气生物滤池深度处理碱减量印染废水[J].环境工程, 2013, 31(1):30-34.
[24]金诚,杨波,李方,等.好氧颗粒污泥自生动态膜生物反应器处理碱减量印染废水[J].环境工程学报, 2014, 8(9):3819-3824.
[25]杨波,钟启俊,李方,等.反应器处理碱减量印染废水的启动研究[J].环境科学, 2013, 34(3):968-973.
[26]杨波,张冉冉,李方,等.强化循环厌氧反应器处理碱减量废水的启动特性[J].环境工程学报, 2017, 11(1):322-328.
[27] LIU M M, WANG S Q, NOBU M K, et al. Impacts of biostimulation and bioaugmentation on the performance and microbial ecology in methanogenic reactors treating purified terephthalic acid wastewater[J]. Water Research, 2017, 122:308-316.
[28] YEN F C, CHANG T C, HU C C, et al. Feasibility of combined upflow anaerobic sludge blanket-aerobic membrane bioreactor system in treating purified terephthalic acid wastewater and polyimide membrane for biogas purification[J]. Journal of Environmental Chemical Engineering, 2016, 4(4):4113-4119.
[2]蒋源隆.从碱减量废水中回收对苯二甲酸的实践[J].污染防治技术, 2003,(2):63-64.
[3]杨期勇,杨涛,陈季华.碱减量废水对苯二甲酸回收工艺的影响因素[J].印染, 2010, 36(2):30-33.
[4]郭茂新,周慧华.碱减量废水处理技术试验研究[J].工业用水与废水, 2000, 31(2):23-25.
[5]杨平平,常宏宏.涤纶织物碱减量工艺废水处理研究[J].水处理技术, 2016, 42(12):96-98.
[6]范立海,潘培堂,陈欢林,等.碱减量废水膜法集成处理技术[J].水处理技术, 2008, 34(2):63-66.
[7]李永贵,贺永林,陈东生.超滤-混凝-酸析法回收涤纶碱减量废水中对苯二甲酸[J].山东纺织科技, 2014, 55(5):53-56.
[8]贺永林,李永贵,葛明桥.有机溶剂对回收涤纶碱减量废渣中苯二甲酸的影响[J].纺织学报, 2013, 34(12):12-15.
[9]李永贵,刘春雨,贺永林,等.应用加合结晶的涤纶碱减量废渣中对苯二甲酸回收[J].纺织学报, 2014, 35(10):67-71.
[10]曹丽红,姜佩华.碱减量废水碱析法回收对苯二甲酸[J].污染防治技术, 2004,(1):95-96.
[11]马国文,陆永生,郑乐平.某企业高浓度碱减量废水预处理方案探讨与分析[J].环境科学与管理, 2013, 38(10):147-152.
[12]王淑影,杨俞,闫龙.碱减量废水的处理现状[J].科技资讯,2017, 15(21):99-100.
[13] WEN Y Z, TONG S P, ZHENG K F, et al. Removal of terephthalic acid in alkalized wastewater by ferric chloride[J]. Journal of Hazardous Materials, 2006, 138(1):169-172.
[14]顾孙.含碱减量混合废水处理工程案例分析[J].黑龙江科技信息, 2014,(2):55-55.
[15]崔小明.一种资源再利用碱减量废水中对苯二甲酸的方法[J].聚酯工业, 2016, 29(6):49-49.
[16] ANAND M V, SRIVASTAVA V C, SINHG S, et al. Electrochemical treatment of alkali decrement wastewater containing terephthalic acid using iron electrodes[J]. Journal of the Taiwan Institute of Chemical Engineers, 2014, 45(3):908-913.
[17] SANDHWAR V K, PRASAD B. Terephthalic acid removal from aqueous solution by electrocoagulation and electro-Fenton methods:Process optimization through response surface methodology[J].Process Safety and Environmental Protection, 2017, 107:269-280.
[18] SANDHWAR V K, PRASAD B. A comparative study of electrochemical degradation of benzoic acid and terephthalic acid from aqueous solution of purified terephthalic acid(PTA)wastewater[J]. Journal of Water Process Engineering. http://dx.doi.org/10.1016/j.jwpe.2017.03.006.
[19]陈岗,刘荣琼,钱福国. Fenton-A2O工艺在制药工业废水深度处理中的应用[J].工业用水与废水, 2015, 46(6):46-49.
[20]金艳.碱减量废水处理工程实例[J].工业用水与废水, 2017,48(4):68-71.
[21]刘鹏程,杜佳丽,郑凤娟,等.三元耐盐复合菌种在碱减量废水处理中的应用[J].印染, 2017, 43(7):10-13.
[22]孙选举,陈季华,杨期勇,等.复合式MBR处理涤纶碱减量废水的试验研究[J].工业水处理, 2006, 26(3):36-38.
[23]杨波,魏爽,田晴,等.上流式曝气生物滤池深度处理碱减量印染废水[J].环境工程, 2013, 31(1):30-34.
[24]金诚,杨波,李方,等.好氧颗粒污泥自生动态膜生物反应器处理碱减量印染废水[J].环境工程学报, 2014, 8(9):3819-3824.
[25]杨波,钟启俊,李方,等.反应器处理碱减量印染废水的启动研究[J].环境科学, 2013, 34(3):968-973.
[26]杨波,张冉冉,李方,等.强化循环厌氧反应器处理碱减量废水的启动特性[J].环境工程学报, 2017, 11(1):322-328.
[27] LIU M M, WANG S Q, NOBU M K, et al. Impacts of biostimulation and bioaugmentation on the performance and microbial ecology in methanogenic reactors treating purified terephthalic acid wastewater[J]. Water Research, 2017, 122:308-316.
[28] YEN F C, CHANG T C, HU C C, et al. Feasibility of combined upflow anaerobic sludge blanket-aerobic membrane bioreactor system in treating purified terephthalic acid wastewater and polyimide membrane for biogas purification[J]. Journal of Environmental Chemical Engineering, 2016, 4(4):4113-4119.