基于电化学反应机理的钠离子电池负极材料研究进展
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摘要
钠离子电池作为一种新型的储能体系,与比较成熟的锂离子电池体系相比,不仅是元素的变化,更重要的是电化学反应机理的变化。简要分析了钠离子电池的优点,以负极材料的电化学反应机理为基础,归纳概括了近期钠离子负极材料的研究进展,主要分为碳材料、合金类材料、过渡金属氧化物和硫化物及有机化合物四类,并介绍了相应材料的电化学性能,为开发综合性能优异的钠离子负极材料提供理论基础。
As a new type of energy storage system,sodium ion battery is not only the change of the element,but also the change of the electrochemical reaction mechanism,compared with the mature lithium ion battery system. This paper briefly analyzes the advantages of sodium ion battery. Based on the electrochemical reaction mechanism of anode materials,the recent progress in the research of anode materials is summarized,mainly divided into four kinds,carbon materials,alloy materials,transition metal oxides and sulfides,organic compounds. And the electrochemical performance of the corresponding materials is introduced. It will provide a theoretical basis for developing anode materials with excellent comprehensive properties in sodium battery.
As a new type of energy storage system,sodium ion battery is not only the change of the element,but also the change of the electrochemical reaction mechanism,compared with the mature lithium ion battery system. This paper briefly analyzes the advantages of sodium ion battery. Based on the electrochemical reaction mechanism of anode materials,the recent progress in the research of anode materials is summarized,mainly divided into four kinds,carbon materials,alloy materials,transition metal oxides and sulfides,organic compounds. And the electrochemical performance of the corresponding materials is introduced. It will provide a theoretical basis for developing anode materials with excellent comprehensive properties in sodium battery.
引文
[1]吴兴隆,梅鹏,郭玉国,等.锂离子电池正极材料的纳米结构设计与性能研究[C].北京:中国化学会学术年会,2014.
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[6]杨旸,严小敏,杨德志,等.普鲁士蓝类钠离子电池正极材料研究进展[J].储能科学与技术,2016,5(3):303-308.
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[12]Alca Ntara R,Lavela P,Ortiz G F,et al.Carbon microspheres obtained from resorcinol-formaldehyde as high-capacity electrodes for sodium-Ion batteries[J].Electrochemical&Solid State Letters,2005,8(4):222-225.
[13]Gu M,Kushima A,Shao Y,et al.Probing the failure mechanism of Sn O2nanowires for sodium-ion batteries.[J].Nano Letters,2013,13(11):5203-11.
[14]Mao J,Fan X,Chao L,et al.Building self-Healing alloy architecture for stable sodium-ion battery anodes:a Case study of Tin anode materials[J].Acs Appl Mater Interfaces,2016,8(11):7147.
[15]Fu Y,Wei Q,Wang X,et al.Porous hollowα-Fe2O3@Ti O2core-shell nanospheres for superior lithium/sodium storage capability[J].Journal of Materials Chemistry A,2015,3(26):13807-13818.
[16]Li Q,Wu J,Xu J,et al.Synergistic sodiation of cobalt oxide Nanoparticles and conductive carbon nanotube(CNT)for sodium-ion battery[J].Journal of Materials Chemistry A,2016,4(22):8669-8675.
[17]Su Q,Du G,Zhang J,et al.In situ transmission electron microscopy observation of electrochemical sodiation of individual Co9S8filled carbon nanotubes[J].Acs Nano,2014,8(4):3620.
[18]Hu M,Jiang Y,Sun W,et al.Reversible conversion-alloying of Sb2O3as a high-capacity,high-rate,and durable anode for sodium ion batteries[J].Acs Applied Materials&Interfaces,2014,6(21):19449.
[19]Wan F,Wu X L,Guo J Z,et al.Nanoeffects promote the electrochemical properties of organic Na2C8H4O4,as anode material for sodium-ion batteries[J].Nano Energy,2015,13:450-457.
[20]Wang S,Wang L,Zhu Z,et al.All organic sodium-Ion batteries with Na4C8H2O6[J].Angewandte Chemie International Edition,2014,53(23):5892-5896.
[2]李慧,吴川,吴锋,等.钠离子电池:储能电池的一种新选择[J].化学学报,2014,72(1):21-29.
[3]蒋礼威.基于晶格振动理论设计高温相Na Mn O2钠离子电池正极材料[D].北京:中国科学院大学,2016.
[4]吴桂贤.锂/钠离子电池层状氧化物正极材料的制备与电化学性能研究[D].北京:中国科学技术大学,2016.
[5]杨绍斌,董伟,沈丁,等.钠离子电池正极材料的研究进展[J].功能材料,2015,46(13):13001-13006.
[6]杨旸,严小敏,杨德志,等.普鲁士蓝类钠离子电池正极材料研究进展[J].储能科学与技术,2016,5(3):303-308.
[7]陈红云.钠离子电池新型电极材料的制备及其电化学性能研究[D].天津:南开大学,2016.
[8]Yang W,Kai H,Zhu Y,et al.Expanded graphite as superior anode for sodium-ion batteries[J].Nature Communications,2014,5:4033.
[9]王磊,胡鹏飞,乔永民,等.大米淀粉硬碳负极材料的制备及其电化学性能研究[J].化工新型材料,2018(1):229-232.
[10]Bommier C,Luo W,Gao W Y,et al.Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements[J].Carbon,2014,76(9):165-174.
[11]Stevens D A,Dahn J R.An in situ small-angle X-ray scattering study of sodium insertion into a nanoporous carbon anode material within an operating electrochemical cell[J].Journal of the Electrochemical Society,2000,147(12):4428-4431.
[12]Alca Ntara R,Lavela P,Ortiz G F,et al.Carbon microspheres obtained from resorcinol-formaldehyde as high-capacity electrodes for sodium-Ion batteries[J].Electrochemical&Solid State Letters,2005,8(4):222-225.
[13]Gu M,Kushima A,Shao Y,et al.Probing the failure mechanism of Sn O2nanowires for sodium-ion batteries.[J].Nano Letters,2013,13(11):5203-11.
[14]Mao J,Fan X,Chao L,et al.Building self-Healing alloy architecture for stable sodium-ion battery anodes:a Case study of Tin anode materials[J].Acs Appl Mater Interfaces,2016,8(11):7147.
[15]Fu Y,Wei Q,Wang X,et al.Porous hollowα-Fe2O3@Ti O2core-shell nanospheres for superior lithium/sodium storage capability[J].Journal of Materials Chemistry A,2015,3(26):13807-13818.
[16]Li Q,Wu J,Xu J,et al.Synergistic sodiation of cobalt oxide Nanoparticles and conductive carbon nanotube(CNT)for sodium-ion battery[J].Journal of Materials Chemistry A,2016,4(22):8669-8675.
[17]Su Q,Du G,Zhang J,et al.In situ transmission electron microscopy observation of electrochemical sodiation of individual Co9S8filled carbon nanotubes[J].Acs Nano,2014,8(4):3620.
[18]Hu M,Jiang Y,Sun W,et al.Reversible conversion-alloying of Sb2O3as a high-capacity,high-rate,and durable anode for sodium ion batteries[J].Acs Applied Materials&Interfaces,2014,6(21):19449.
[19]Wan F,Wu X L,Guo J Z,et al.Nanoeffects promote the electrochemical properties of organic Na2C8H4O4,as anode material for sodium-ion batteries[J].Nano Energy,2015,13:450-457.
[20]Wang S,Wang L,Zhu Z,et al.All organic sodium-Ion batteries with Na4C8H2O6[J].Angewandte Chemie International Edition,2014,53(23):5892-5896.