膜技术在国防工程隔绝防护消除CO_2中的应用探讨
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摘要
目前国防工程消除CO_2的技术方法属于非再生式措施,吸附剂性能不仅受环境影响大,且保障能力有限.本文介绍了膜技术消除CO_2领域的研究现状,分析膜技术应用于国防工程隔绝防护的可行性.结合国防工程隔绝通风防护时的环境特征和保障技术难点,探讨了工程内部运用膜技术实施分离后再生和直接吸收消除的两种技术方案,拓展了工程内部空气再生的保障技术途径.
At present,the methods employed to eliminate CO_2 in national defense engineering rely on nonregenerative measures.The performance of the adsorbent is affected by the environment,and the adsorbent also has a limited support capacity.This paper reviews the status of research on the use of membrane technology to eliminate CO_2,and analyzes the feasibility of using membrane technology during isolated protection processes in national defense engineering. By considering the environmental characteristics and the technical difficulties associated with isolated ventilation protection processes in national defense engineering,this paper proposes two classes of methods called regeneration and direct absorption after the application of membrane technology separation,and shows how these can ensure effective internal air regeneration.
At present,the methods employed to eliminate CO_2 in national defense engineering rely on nonregenerative measures.The performance of the adsorbent is affected by the environment,and the adsorbent also has a limited support capacity.This paper reviews the status of research on the use of membrane technology to eliminate CO_2,and analyzes the feasibility of using membrane technology during isolated protection processes in national defense engineering. By considering the environmental characteristics and the technical difficulties associated with isolated ventilation protection processes in national defense engineering,this paper proposes two classes of methods called regeneration and direct absorption after the application of membrane technology separation,and shows how these can ensure effective internal air regeneration.
引文
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[6]王学军,张恒,郭玉国,等.膜分离领域相关标准现状与发展需求[J].膜科学与技术,2015,35(2):120-127.
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[20]顾瑾,张鹏,白云翔,等.溶剂挥发法制备聚醚共聚酰胺/乙二醇苯醚凝胶膜及其CO2/N2分离性能研究[J].膜科学与技术,2015,35(5):58-63.
[21]杨平平,丁晓莉,赵红永,等.星形多臂CO2分离膜的制备及性能研究[J].膜科学与技术,2016,36(4):14-18.
[22]张兵,周佳玲,吴永红,等.高渗透性石墨烯杂化炭膜的制备及表征[J].膜科学与技术,2016,36(2):7-12.
[23]李方,孟蝶.氧化石墨烯:膜科学的机遇与挑战[J].膜科学与技术,2015,35(6):106-112.
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[27]Zhao J,Wang Z,Wang J X,et al.High-performance membranes comprising polyaniline nanoparticles incorporated into polyvinylamine matrix for CO2/N2separation[J].J Membr Sci,2012,403/404:203-215.
[28]王志,袁芳,王明,等.分离CO2膜技术[J].膜科学与技术,2011,31(3):11-17.
[29]Feng C,Wang R,Zhang H,et al.Diverse morphologies of PVDF hollow fiber membranes and their performance analysis as gas/liquid contactors[J].J Appl Polym Sci,2011,119(3):1259-1267.
[30]Mansourizadeh,Ismail A F,et al.Effect of operating conditions on the physical and chemical CO2absorption through the PVDF hollow fiber membrane contactor[J].J Membr Sci,2010,353(1):192-200.
[31]舒建辉.聚丙烯中空纤维膜接触器脱除CO2及膜孔润湿影响分析的试验研究[D].南昌:华东交通大学,2014.
[32]孙亮.中空纤维膜基吸收法脱除空气中二氧化碳的研究[D].杭州:浙江大学,2002.
[33]叶向群,孙亮,张林,等.中空纤维膜基吸收法脱除空气中二氧化碳的研究[J].高校化学工程学报,2003,17(3):237-242.
[34]张长金,尹燕华,周旭,等.中空纤维膜吸收低浓度CO2工艺研究[J].舰船科学技术,2010,32(10):91-96.
[35]Mccray S B,Wytcherley R W,Friesen D T,et al.Preliminary evaluation of a membrane-based system for removing CO2 from air[J].Adv Environ/Thermal Control and Life Support Systems,1990:159-166.
[36]张长金,尹燕华,周旭,等.膜基吸收低浓度二氧化碳的研究进展[J].舰船科学技术,2009,31(11):139-143.
[2]Mulder M著,李琳译.膜技术基本原理[M]//北京:清华大学出版社,1999.
[3]王志.二氧化碳分离膜材料规模化制备技术[J].中国科技成果,2016,17(9):13-13.
[4]贾金才.膜分离法空气净化的应用与研究进展[J].深冷技术,2011(4):33-38.
[5]Richard W.Baker,future directions of membrane gas separation technology[J].Ind Eng Chem Res,2002,41(6):1393-1411.
[6]王学军,张恒,郭玉国,等.膜分离领域相关标准现状与发展需求[J].膜科学与技术,2015,35(2):120-127.
[7]茅靳丰,韩旭,张华,等.氢氧化锂-活性炭纤维材料的制备和性能试验[J].解放军理工大学学报(自然科学版),2006,7(1):55-58.
[8]中国人民解放军总装备部军事训练教材工作委员会.航天环境控制与生命保障工程基础[M]//北京:国防工业出版社,2003.
[9]栗婧,金龙哲,汪声,等.密闭救援空间内碱石灰去除二氧化碳效率影响因素分析[J].煤炭学报,2013,(10):1819-1824.
[10]彭海媛,洪凡.膜气体吸收技术脱除电厂烟气二氧化碳的研究进展[J].膜科学与技术,2011,31(1):113-117.
[11]张寅平.建筑环境传质学[M]//北京:中国建筑工业出版社,2006.
[12]张兵,周佳玲,吴永红,等.高渗透性石墨烯杂化炭膜的制备及表征[J].膜科学与技术,2016,36(2):7-12.
[13]Li S,Falconer J L,Noble R D.SAPO-34membranes for CO2/CH4separations:Effect of Si/Al ratio[J].Microp Mesop Mater,2008,110(s2/3):310-317.
[14]Li S,Falconer J,Noble R.Improved SAPO-34membranes for CO2/CH4,separations[J].Adv Mater,2006,18(19):2601-2603.
[15]Li S,Fan C Q.High-flux SAPO-34 membrane for CO2/N2separation[J].Ind Eng Chem Res,2010,49(9):4399-4404.
[16]Himeno S,Tomita T,Suzuki K,et al.Synthesis and permeation properties of a DDR-type zeolite membrane for separation of CO2/CH4 gaseous mixtures[J].Ind Eng Chem Res,2007,46(21):6989-6997.
[17]Cui Y,Kita H,Okamoto K.Preparation and gas separation performance of zeolite T membrane[J].J Mater Chem,2004,14(5):924-932.
[18]曹映玉,杨恩翠,王文举.二氧化碳膜分离技术[J].精细石油化工,2015,32(1):53-60.
[19]陈一民,谢凯,盘毅,等.低压电场驱动下膜分离CO2的研究[J].国防科技大学学报,2000,22(4):40-42.
[20]顾瑾,张鹏,白云翔,等.溶剂挥发法制备聚醚共聚酰胺/乙二醇苯醚凝胶膜及其CO2/N2分离性能研究[J].膜科学与技术,2015,35(5):58-63.
[21]杨平平,丁晓莉,赵红永,等.星形多臂CO2分离膜的制备及性能研究[J].膜科学与技术,2016,36(4):14-18.
[22]张兵,周佳玲,吴永红,等.高渗透性石墨烯杂化炭膜的制备及表征[J].膜科学与技术,2016,36(2):7-12.
[23]李方,孟蝶.氧化石墨烯:膜科学的机遇与挑战[J].膜科学与技术,2015,35(6):106-112.
[24]Salleh W N W,Ismail A F,Abdullah T M M S.Precursor selection and process conditions in the preparation of carbon membrane for gas separation:A review[J].Sep Purif Rev,2011,40(4):261-311.
[25]Ward W J,Robb W L.Carbon dioxide-oxygen separation:facilitated transport of carbon dioxide across a liquid film[J].Science,1967,156(3781):1481-1484.
[26]Sirkar K K.Hollow fiber-contained liquid membranes for separations:An overview[C].ACS Symposium Series,1996.
[27]Zhao J,Wang Z,Wang J X,et al.High-performance membranes comprising polyaniline nanoparticles incorporated into polyvinylamine matrix for CO2/N2separation[J].J Membr Sci,2012,403/404:203-215.
[28]王志,袁芳,王明,等.分离CO2膜技术[J].膜科学与技术,2011,31(3):11-17.
[29]Feng C,Wang R,Zhang H,et al.Diverse morphologies of PVDF hollow fiber membranes and their performance analysis as gas/liquid contactors[J].J Appl Polym Sci,2011,119(3):1259-1267.
[30]Mansourizadeh,Ismail A F,et al.Effect of operating conditions on the physical and chemical CO2absorption through the PVDF hollow fiber membrane contactor[J].J Membr Sci,2010,353(1):192-200.
[31]舒建辉.聚丙烯中空纤维膜接触器脱除CO2及膜孔润湿影响分析的试验研究[D].南昌:华东交通大学,2014.
[32]孙亮.中空纤维膜基吸收法脱除空气中二氧化碳的研究[D].杭州:浙江大学,2002.
[33]叶向群,孙亮,张林,等.中空纤维膜基吸收法脱除空气中二氧化碳的研究[J].高校化学工程学报,2003,17(3):237-242.
[34]张长金,尹燕华,周旭,等.中空纤维膜吸收低浓度CO2工艺研究[J].舰船科学技术,2010,32(10):91-96.
[35]Mccray S B,Wytcherley R W,Friesen D T,et al.Preliminary evaluation of a membrane-based system for removing CO2 from air[J].Adv Environ/Thermal Control and Life Support Systems,1990:159-166.
[36]张长金,尹燕华,周旭,等.膜基吸收低浓度二氧化碳的研究进展[J].舰船科学技术,2009,31(11):139-143.
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