聚合物复鞣加脂剂的研究进展
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摘要
聚合物复鞣加脂剂是一类兼具复鞣和加脂特性的皮革化学品。本文综述了近年来聚合物复鞣加脂剂的各种制备方法,分析了聚合物复鞣加脂剂的组成和应用特性,并对聚合物复鞣加脂剂的发展方向和在制革工业中的应用前景进行了展望。
The polymeric retanning-fatliquoring agent is one of the important chemicals in leather making process. This paper covered various preparation methods for the polymeric retanningfatliquoring agent which had been reported in recent years. The composition and application characteristic of this product were also discussed. Finally, the new improving methods and application prospect of the polymeric retanning-fatliquoring agent were put forward.
The polymeric retanning-fatliquoring agent is one of the important chemicals in leather making process. This paper covered various preparation methods for the polymeric retanningfatliquoring agent which had been reported in recent years. The composition and application characteristic of this product were also discussed. Finally, the new improving methods and application prospect of the polymeric retanning-fatliquoring agent were put forward.
引文
[1] ROHM&HAAS Company. Polymeric retan fatliquor for low fogging upholstery leather[P]. US:650524, 1994-09-20.
[2]王嘉图,席先峰,魏德卿.丙烯酸高级酯共聚物组成与其无皂乳液稳定性研究[J].现代化工, 2004, 24(08):39-41.
[3]王嘉图,席先锋,王碧清,等.丙烯酸酯聚合物加脂剂乳液性质研究[J].精细化工, 2004, 21(04):285-287.
[4]王嘉图,席先锋,孙静,等.吸水剂在甲基丙烯酸十六酯制备中的应用[J].精细化工, 2003, 20(08):489-491.
[5]娄守强,刘红,杨雨滋. WR防水加脂剂的研制[J].中国皮革, 1999, 28(17):13-16.
[6]宋秘钊,张景彬,耿金刚,等.有机硅防水加脂剂的制备[J].中国皮革, 2010, 39(01):41-44.
[7] Du J, Shi L, Peng B. Amphiphilic acrylate copolymer fatliquor for ecological leather:Influence of molecular weight on performances[J]. JAPS, 2016, 133(20):43440.
[8] Nashy E H A, Essa M M, Hussain A I. Synthesis and application of methyl methacrylate/butyl acrylate copolymer nanoemulsions as efficient retanning and lubricating agents for chrome-tanned leather[J]. JAPS, 2012, 124(4):3293-3301.
[9]靳立强,孙友昌,邱化玉,等.润滑型丙烯酸树脂复鞣剂的研究[J].中国皮革, 2001, 30(23):1-4.
[10]马建中,杨宗邃,吕斌,等.乳液接枝共聚法制备皮革用改性淀粉复鞣加脂剂的方法[P]:中国专利,200610042708.9,2006-10-18.
[11] Schieferstein Ludwig DR, Zauns-huber R udolf DR.Aqueous dispersions of new amphiphilic co-oligomers for the washing-and cleaning-resistant oiling of leather and skins and their use[P]. DE:4129244, 1993-03-04.
[12] Allen Adrian Swinburn, Aiston Finlay Derek. Impregnating composition for leather[P]. EP:583973, 1994-02-23.
[13]邹祥龙,兰云军,周建飞.马来酸单酯聚合物复鞣加脂剂的制备与性能[J].精细化工, 2009, 26(08):809-812.
[14]周建飞,邹祥龙,兰云军.十六醇马来酸单酯-丙烯酸聚合物加脂剂的应用性能研究[J].西部皮革, 2007, 29(06):22-24.
[15]任小翠,邹祥龙,崔凯,等.马来酸酯型聚合物复鞣加脂剂的合成研究[J].皮革与化工, 2013, 30(04):1-4.
[16]邹祥龙,兰云军,李剑.马来酸双酯聚合物的合成表征及其复鞣加脂作用研究[J].精细化工, 2009, 26(11):1128-1131.
[17]汪际焱,兰云军,邹祥龙.马来酸单酰胺-甲基丙烯酸酯-丙烯酸共聚物复鞣加脂剂的制备与性能[J].精细化工,2010, 27(09):889-892.
[18]李志强,赵焱,陈敏,等.羧基改性猪油合成新型复鞣-加脂剂的研制[J].四川大学学报(工程科学版), 2003, 35(01):56-58.
[19]彭波,彭必雨.改性牛蹄油制备聚合物加脂剂及其应用的研究[J].中国皮革, 2005, 34(03):51-55.
[20]郑顺姬,张景彬,李鑫炎,等.蓖麻油制备聚合物加脂剂的研究[J].中国油脂, 2008, 33(06):65-67.
[21]张福莲,冷春丽,田玉平,等.磷酸化-马来酸蓖麻油醇酸酯-苯乙烯共聚物的合成[J].皮革化工, 2006, 23(03):33-36.
[22]邹祥龙,兰云军,银德海,等.一种皮革复鞣加脂剂的制备方法[P]:中国专利, 200810163679.0,2012-06-13.
[23]王鸿儒,楼建新.磷脂加脂复鞣剂PMS的制备[J].西部皮革, 2004,26(04):28-30.
[24] Bomer B, Kochta J, Sackmann G, etal. Softening and waterproofing retanning agents[P]. US:5472741. 1995-12-05.
[25]罗朝阳,卢燕,范浩军,等.耐水洗聚合物加脂剂的制备及性能研究[J].中国皮革, 2007, 36(17):39-44.
[26]罗朝阳,范浩军,芦燕,等.含氟聚合物加脂剂的制备及性能研究[J].中国皮革, 2007, 36(23):12-16.
[27]李小华,强西怀,张辉. SMA脂肪醇单酯钠盐的制备及其应用性能[J].中国皮革, 2009, 38(3):40-43.
[28]闫哲,强西怀,张辉,等. SMA脂肪醇醚单酯钠盐的制备及应用性能[J].中国皮革, 2012, 41(07):42-45.
[29]王学川,孙思薇,王海军.含硅树枝状-线型加脂剂的合成及应用[J].高分子材料科学与工程, 2015, 31(12):11-15.
[30]王武生,王宇,曾俊,等.含有长链脂肪烃基团的聚氨酯加脂复鞣剂的合成与应用:2005全国皮革化学品学术交流会[Z].宁波:2005,194-198.
[31] JP Dix. The characteristics and mode of action of modern polymers in post-tanning treatment process[J]. JALCA,1998, 93(9):283-294.
[2]王嘉图,席先峰,魏德卿.丙烯酸高级酯共聚物组成与其无皂乳液稳定性研究[J].现代化工, 2004, 24(08):39-41.
[3]王嘉图,席先锋,王碧清,等.丙烯酸酯聚合物加脂剂乳液性质研究[J].精细化工, 2004, 21(04):285-287.
[4]王嘉图,席先锋,孙静,等.吸水剂在甲基丙烯酸十六酯制备中的应用[J].精细化工, 2003, 20(08):489-491.
[5]娄守强,刘红,杨雨滋. WR防水加脂剂的研制[J].中国皮革, 1999, 28(17):13-16.
[6]宋秘钊,张景彬,耿金刚,等.有机硅防水加脂剂的制备[J].中国皮革, 2010, 39(01):41-44.
[7] Du J, Shi L, Peng B. Amphiphilic acrylate copolymer fatliquor for ecological leather:Influence of molecular weight on performances[J]. JAPS, 2016, 133(20):43440.
[8] Nashy E H A, Essa M M, Hussain A I. Synthesis and application of methyl methacrylate/butyl acrylate copolymer nanoemulsions as efficient retanning and lubricating agents for chrome-tanned leather[J]. JAPS, 2012, 124(4):3293-3301.
[9]靳立强,孙友昌,邱化玉,等.润滑型丙烯酸树脂复鞣剂的研究[J].中国皮革, 2001, 30(23):1-4.
[10]马建中,杨宗邃,吕斌,等.乳液接枝共聚法制备皮革用改性淀粉复鞣加脂剂的方法[P]:中国专利,200610042708.9,2006-10-18.
[11] Schieferstein Ludwig DR, Zauns-huber R udolf DR.Aqueous dispersions of new amphiphilic co-oligomers for the washing-and cleaning-resistant oiling of leather and skins and their use[P]. DE:4129244, 1993-03-04.
[12] Allen Adrian Swinburn, Aiston Finlay Derek. Impregnating composition for leather[P]. EP:583973, 1994-02-23.
[13]邹祥龙,兰云军,周建飞.马来酸单酯聚合物复鞣加脂剂的制备与性能[J].精细化工, 2009, 26(08):809-812.
[14]周建飞,邹祥龙,兰云军.十六醇马来酸单酯-丙烯酸聚合物加脂剂的应用性能研究[J].西部皮革, 2007, 29(06):22-24.
[15]任小翠,邹祥龙,崔凯,等.马来酸酯型聚合物复鞣加脂剂的合成研究[J].皮革与化工, 2013, 30(04):1-4.
[16]邹祥龙,兰云军,李剑.马来酸双酯聚合物的合成表征及其复鞣加脂作用研究[J].精细化工, 2009, 26(11):1128-1131.
[17]汪际焱,兰云军,邹祥龙.马来酸单酰胺-甲基丙烯酸酯-丙烯酸共聚物复鞣加脂剂的制备与性能[J].精细化工,2010, 27(09):889-892.
[18]李志强,赵焱,陈敏,等.羧基改性猪油合成新型复鞣-加脂剂的研制[J].四川大学学报(工程科学版), 2003, 35(01):56-58.
[19]彭波,彭必雨.改性牛蹄油制备聚合物加脂剂及其应用的研究[J].中国皮革, 2005, 34(03):51-55.
[20]郑顺姬,张景彬,李鑫炎,等.蓖麻油制备聚合物加脂剂的研究[J].中国油脂, 2008, 33(06):65-67.
[21]张福莲,冷春丽,田玉平,等.磷酸化-马来酸蓖麻油醇酸酯-苯乙烯共聚物的合成[J].皮革化工, 2006, 23(03):33-36.
[22]邹祥龙,兰云军,银德海,等.一种皮革复鞣加脂剂的制备方法[P]:中国专利, 200810163679.0,2012-06-13.
[23]王鸿儒,楼建新.磷脂加脂复鞣剂PMS的制备[J].西部皮革, 2004,26(04):28-30.
[24] Bomer B, Kochta J, Sackmann G, etal. Softening and waterproofing retanning agents[P]. US:5472741. 1995-12-05.
[25]罗朝阳,卢燕,范浩军,等.耐水洗聚合物加脂剂的制备及性能研究[J].中国皮革, 2007, 36(17):39-44.
[26]罗朝阳,范浩军,芦燕,等.含氟聚合物加脂剂的制备及性能研究[J].中国皮革, 2007, 36(23):12-16.
[27]李小华,强西怀,张辉. SMA脂肪醇单酯钠盐的制备及其应用性能[J].中国皮革, 2009, 38(3):40-43.
[28]闫哲,强西怀,张辉,等. SMA脂肪醇醚单酯钠盐的制备及应用性能[J].中国皮革, 2012, 41(07):42-45.
[29]王学川,孙思薇,王海军.含硅树枝状-线型加脂剂的合成及应用[J].高分子材料科学与工程, 2015, 31(12):11-15.
[30]王武生,王宇,曾俊,等.含有长链脂肪烃基团的聚氨酯加脂复鞣剂的合成与应用:2005全国皮革化学品学术交流会[Z].宁波:2005,194-198.
[31] JP Dix. The characteristics and mode of action of modern polymers in post-tanning treatment process[J]. JALCA,1998, 93(9):283-294.