新型金属有机骨架材料催化剂选择性催化还原氮氧化物研究进展
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摘要
综述新型有机金属骨架材料和复合金属骨架材料催化剂在选择性催化还原氮氧化物方面的研究进展,讨论金属有机骨架材料催化剂的低温脱硝活性和抗硫抗水性能,介绍脱硝反应过程中氮氧化物的反应机理。针对金属有机骨架材料表现出的良好低温脱硝活性,认为其有可能替代传统脱硝催化剂。
The research progresses on new type metal organic materials( MOFs) and composed MOFs catalyst for selective catalytic reduction( SCR) of NOx were reviewed. Low temperature activity,performance on resistance to SO_2 and H_2 O and the mechanism in the SCR reaction over MOFs catalysts havd been discussed. The MOFs catalysts were considered to be the potential alternative for the conventional SCR catalysts for its good deNOx catalytic activity at low temperature.
The research progresses on new type metal organic materials( MOFs) and composed MOFs catalyst for selective catalytic reduction( SCR) of NOx were reviewed. Low temperature activity,performance on resistance to SO_2 and H_2 O and the mechanism in the SCR reaction over MOFs catalysts havd been discussed. The MOFs catalysts were considered to be the potential alternative for the conventional SCR catalysts for its good deNOx catalytic activity at low temperature.
引文
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[10]Sun X Y,Shi Y,Zhang W,et al. A new type Ni-MOF catalyst with high stability for selective catalytic reduction of NOx with NH3[J]. Catalysis Communications,2018,114:104-108.
[11]侯鑫,李飞,仵静,等.锰基NH3-SCR低温脱硝催化剂研究进展[J].工业催化,2017,25(6):1-8.Hou Xin,Li Fei,Wu Jing,et al. Studies of the behaviors of De NOx low-temperature NH3-SCR catalysts[J]. Industrial Catalysis,2017,25(6):1-8.
[12]Jiang H X,Zhou J L,Wang C X,et al. Effect of cosolvent and temperature on the structures and properties of CuMOF-74 in low-temperature NH3-SCR[J]. Industrial&Engineering Chemistry Research,2017,56(13):3542–3550.
[13]Yoon J W,Seo Y K,Hwang Y K,et al. Controlled reducibility of a metal-organic framework with coordinatively unsaturated sites for preferential gas sorption[J]. Angewandte Chemie International Edition,2010,(49):5949-5952.
[14]Zhang W,Shi Y,Li C Y,et al. Synthesis of bimetallic MOFs MIL-100(Fe-Mn)as an efficient catalyst for selective catalytic reduction of NOx with NH3[J]. Catalysis Letters,2016,146(10):1956-1964.
[15]Jiang H,Niu Y,Wang Q,et al. Single-phase SO2-resistant to poisoning Co/Mn-MOF-74 catalysts for NH3-SCR[J]. Catalysis Communications,2018,113(10):46-50.
[16]Wang P,Sun H,Quan X,et al. Enhanced catalytic activity over MIL-100(Fe)loaded ceria catalysts for the selective catalytic reduction of NOx with NH3at low temperature[J]. Journal of Hazardous Materials,2016,301(15):512-521.
[17]Lietti L,Ramis G,Berti F,et al. Chemical,structural and mechanistic aspects on NOx SCR over commercial and model oxide catalysts[J]. Catalysis Today,1998,139(42):101-116.
[18]Liu F D,He H,Zhang C B,et al. Mechanism of the selective catalytic reduction of NOx with NH3over environmentalfriendly iron titanate catalyst[J]. Catalysis Today,2011,175:18-25.
[19]Jiang B Q,Wu Z B,Liu Y,et al. DRIFT study of the SO2effect on low-temperature SCR reaction over Fe-Mn/Ti O2[J]. The Journal of Physical Chemistry C,2010,114(11):4961-4965.
[20]Boubnov A,Carvalho H W P,Doronkin D E,et al. Selective catalytic reduction of NO over Fe-ZSM-5:mechanistic insights by operando HERFD-XANES and valence-tocore X-ray Emission spectroscopy[J]. Journal of the American Chemical Society,2014,136(37):13006-13015.
[21]Paolucci C,Verma A A,Bates S A,et al. Isolation of the copper redox steps in the standard selective catalytic reduction on Cu-SSZ-13[J]. Angewandte Chemie International Edition,2014,53:11828-11833.
[2]朱小方,周华兰,臧涵,等. SCR脱除NOx催化剂的研究进展[J].工业催化,2017,25(10):1-4.Zhu Xiaofang,Zhou Hualan,Zang Han,et al. Research advance in SCR denitration catalyst[J]. Industrial Catalysis,2017,25(10):1-4.
[3]Lietti L,Nova I,Forzatti P. Selective catalytic reduction(SCR)of NO by NH3over Ti O2-supported V2O5-WO3and V2O5-MoO3catalysts[J]. Topics in Catalysis,2000,(11/12):111-122.
[4]姚小江,张雷,孔婷婷,等.低温氨-选择性催化还原氮氧化物催化剂的研究进展[J].工业催化,2016,24(6):1-9.Yao Xiaojiang,Zhang Lei,Kong Tingting,et al. Research progress in selective catalytic reduction of nitrogen oxides by ammonia at low temperature[J]. Industrial Catalysis,2016,24(6):1-9.
[5]Laurier K G,Vermoortele F,Ameloot R,et al. Iron(Ⅲ)-based metal-organic frameworks as visible light photocatalysts[J]. Journal of the American Chemical Society,2013,(135):14488-14491.
[6]Chizallet C,Lazare S,Bazer-Bachi D,et al. Catalysis of transesterification by a nonfunctionalized metal-organic framework:acido-basicity at the external surface of ZIF-8 probed by FTIR and ab initio calculations[J]. Journal of the American Chemical Society,2010,(132):12365-12377.
[7]Zhao Y G,Padmanabhan M,Gong Q H,et al. CO catalytic oxidation by a metal organic framework containing high density of reactive coper sites[J]. Chemical Communications,2011,(47):6377-6379.
[8]Wang P,Zhao H M,Sun H,et al. Porous metal-organic framework MIL-100(Fe)as an efficient catalyst for the selective catalytic reduction of NOx with NH3[J]. RSC Advances,2014,(90):48912-48919.
[9]Jiang H X,Wang Q Y,Wang H Q,et al. MOF-74 as an efficient catalyst for the low-temperature selective catalytic reduction of NOx with NH3[J]. ACS Applied Materials&Interfaces,2016,(8):26817-26826.
[10]Sun X Y,Shi Y,Zhang W,et al. A new type Ni-MOF catalyst with high stability for selective catalytic reduction of NOx with NH3[J]. Catalysis Communications,2018,114:104-108.
[11]侯鑫,李飞,仵静,等.锰基NH3-SCR低温脱硝催化剂研究进展[J].工业催化,2017,25(6):1-8.Hou Xin,Li Fei,Wu Jing,et al. Studies of the behaviors of De NOx low-temperature NH3-SCR catalysts[J]. Industrial Catalysis,2017,25(6):1-8.
[12]Jiang H X,Zhou J L,Wang C X,et al. Effect of cosolvent and temperature on the structures and properties of CuMOF-74 in low-temperature NH3-SCR[J]. Industrial&Engineering Chemistry Research,2017,56(13):3542–3550.
[13]Yoon J W,Seo Y K,Hwang Y K,et al. Controlled reducibility of a metal-organic framework with coordinatively unsaturated sites for preferential gas sorption[J]. Angewandte Chemie International Edition,2010,(49):5949-5952.
[14]Zhang W,Shi Y,Li C Y,et al. Synthesis of bimetallic MOFs MIL-100(Fe-Mn)as an efficient catalyst for selective catalytic reduction of NOx with NH3[J]. Catalysis Letters,2016,146(10):1956-1964.
[15]Jiang H,Niu Y,Wang Q,et al. Single-phase SO2-resistant to poisoning Co/Mn-MOF-74 catalysts for NH3-SCR[J]. Catalysis Communications,2018,113(10):46-50.
[16]Wang P,Sun H,Quan X,et al. Enhanced catalytic activity over MIL-100(Fe)loaded ceria catalysts for the selective catalytic reduction of NOx with NH3at low temperature[J]. Journal of Hazardous Materials,2016,301(15):512-521.
[17]Lietti L,Ramis G,Berti F,et al. Chemical,structural and mechanistic aspects on NOx SCR over commercial and model oxide catalysts[J]. Catalysis Today,1998,139(42):101-116.
[18]Liu F D,He H,Zhang C B,et al. Mechanism of the selective catalytic reduction of NOx with NH3over environmentalfriendly iron titanate catalyst[J]. Catalysis Today,2011,175:18-25.
[19]Jiang B Q,Wu Z B,Liu Y,et al. DRIFT study of the SO2effect on low-temperature SCR reaction over Fe-Mn/Ti O2[J]. The Journal of Physical Chemistry C,2010,114(11):4961-4965.
[20]Boubnov A,Carvalho H W P,Doronkin D E,et al. Selective catalytic reduction of NO over Fe-ZSM-5:mechanistic insights by operando HERFD-XANES and valence-tocore X-ray Emission spectroscopy[J]. Journal of the American Chemical Society,2014,136(37):13006-13015.
[21]Paolucci C,Verma A A,Bates S A,et al. Isolation of the copper redox steps in the standard selective catalytic reduction on Cu-SSZ-13[J]. Angewandte Chemie International Edition,2014,53:11828-11833.
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