摘要
利用等温饱和法研究温度和熔盐组分对Cr_2O_3在NaCl-KCl-NaF熔盐体系中溶解度的影响。并利用热力学计算软件HSC对熔盐体系各组分之间可能发生的化学反应进行计算,结合X射线衍射对熔盐急冷试样做了分析,确定了Cr_2O_3的溶解机理。结果表明:700℃时,Cr_2O_3在该熔盐体系中的溶解饱和时间为5 h左右,继续升高温度至30℃,达到再饱和需要80 min左右;Cr_2O_3在该熔盐体系中的溶解度随温度的升高而增大,随NaF含量的增加而增大,其溶解机理为物理溶解。
The effect of temperature and molten salt composition on the solubility of Cr_2O_3 in NaCl-KCl-NaF molten salt system was studied by isothermal saturation method.The thermodynamic calculation software HSC was used to calculate the possible chemical reactions between the components of the molten salt system.X-ray diffraction was used to analyze the molten salt quenched samples to determine the dissolution mechanism of Cr_2O_3.The results showed that the dissolution saturation time of Cr_2O_3 in the molten salt system was about 5 h at 700 ℃,and the temperature continued to rise to 30 ℃,and the saturation needed about 80 min.The solubility of Cr_2O_3 in the molten salt system increased both with the increase of temperature and NaF content,and its dissolution mechanism was physical dissolution.
引文
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