用户名: 密码: 验证码:
二氧化碳还原技术研究进展
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:RESEARCH PROGRESS IN THE REDUCTION TECHNOLOGY OF CARBON DIOXIDE
  • 作者:李军 ; 崔凤霞 ; 李荣
  • 英文作者:Li Jun;Cui Fengxia;Li Rong;Research Institute of Tianjin Branch,SINOPEC;
  • 关键词:二氧化碳 ; 还原 ; 催化氢化 ; 电催化 ; 光催化 ; 光电催化 ; 饱和烃氧化
  • 英文关键词:carbon dioxide;;reduction;;catalytic hydrogenation;;electrocatalytic;;photocatalytic;;photoelectrocatalytic;;oxidation of saturated hydrocarbon
  • 中文刊名:JXSY
  • 英文刊名:Speciality Petrochemicals
  • 机构:中国石油化工股份有限公司天津分公司研究院;
  • 出版日期:2017-03-18
  • 出版单位:精细石油化工
  • 年:2017
  • 期:v.34;No.197
  • 语种:中文;
  • 页:JXSY201702019
  • 页数:8
  • CN:02
  • ISSN:12-1179/TQ T
  • 分类号:79-86
摘要
综述了CO_2催化氢化、电化学还原、光催化还原、光电催化还原以及饱和烃类氧化脱氢等CO_2还原技术的研究进展,并指出CO_2还原技术今后的研究方向。
        Various typical CO_2 reduction technologies were reviewed,such as catalytic hydrogenation of CO_2,electrocatalytic CO_2 reduction,photocatalytic CO_2 reduction,photoelectrocatalytic CO_2 reduction and oxidation of saturated hydrocarbon by CO_2,and also shows the research directions of CO_2 reduction technologies in the future.
引文
[1]Nicola K,Christopher J W,Arjan W K.Stereoselective Synthesis with Carbon Dioxide[J].Adv Synth Catal,2013,355:2115-2138.
    [2]Chihiro M,Yuki M,Tadashi E.Recent progress in catalytic conversions of carbon dioxide[J].Catal Sci Technol,2014,4:1482-1497.
    [3]Ioanna D,Pelayo G G,Rachael H E,et al.Carbon dioxide utilization for production of transport fuels:process and economic analysis[J].Energy Environ Sci,2015,8:1775-1789.
    [4]Rosa M C,Adisa A.Carbon capture,storage and utilisation technologies:A critical analysis and comparison of their life cycle environmental impacts[J].Journal of CO_2Utilization,2015,9:82-102.
    [5]Farnaz T Z,Saeed S,Maryam T R.Conversion of carbon dioxide to valuable petrochemicals:An approach to clean development mechanism[J].Journal of Natural Gas Chemistry,2011,20(3):219-231.
    [6]孙洪志,王倩,宋名秀,等.CO_2化学利用的研究进展[J].化工进展,2013,32(7):1666-1672.
    [7]Morris A J,Meyer G J,Fujita E.Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels[J].Acc Chem Res,2009,42(12):1983-1994.
    [8]Gao J J,Wang Y L,Ping Y,et al.A thermodynamic analysis of methanation reactions of carbon oxides for the production of synthetic natural gas[J].RSC Advances,2012,2:2358-2368.
    [9]Lu B W,Kawamoto K.Preparation of the highly loaded and well-dispersed NiO/SBA-15for methanation of producer gas[J].Fuel,2013,103:699-704.
    [10]Zhou G L,Wu T,Zhang H B,et al.Carbon dioxide methanation on ordered mesoporous Co/KIT-6catalyst[J].Chem Eng Commun,2014,201(2):233-240.
    [11]Karelovic A,Ruiz P.Mechanistic study of low temperature CO_2 methanation over Rh/TiO2 catalysts[J].J Catal,2013,301:141-153.
    [12]Tada S,Ochieng O J,Kikuchi R,et al.Promotion of CO_2methanation activity and CH4selectivity at low temperatures over Ru/CeO2/Al2O3catalysts[J].Int J Hydrogen Energy,2014,39:10090-10100.
    [13]Park J N,McFarland E W.A highly dispersed Pd-Mg/SiO2catalyst active for methanation of CO_2[J].J Catal,2009,266:92-97.
    [14]刘华平,叶素芳,孔丽萍,等.镍基催化剂的二氧化碳甲烷化催化性能[J].化工生产与技术,2015,22(6):41-49.
    [15]职国娟,王英勇,靳国强,等.第二金属组分对Ni/SiC催化剂CO_2甲烷化性能的影响[J].天然气化工(C1化学与化工),2016,41(1):24-28.
    [16]Wilkinson S K,van de Water L G A,Miller B.Understanding the generation of methanol synthesis and water gas shift activity over copper-based catalysts—A spatially resolved experimental kinetic study using steady and nonsteady state operation under CO/CO_2/H2 feeds[J].J Catal,2016,337:208-220.
    [17]常佳,阮艳军.二氧化碳加氢催化合成甲醇的研究进展[J].当代化工,2015,40(11):2621-2624.
    [18]郭晓明,毛东森,卢冠忠,等.CO_2加氢合成甲醇催化剂的研究进展[J].化工进展,2012,31(3):477-488.
    [19]于杨.轻稀土元素改性Cu/ZnO/Al2O3催化剂对CO_2加氢制甲醇反应的催化性能[J].石油化工,2016,45(1):24-30.
    [20]Zhang Y P,Fei J H,Yu Y M,et al.Study of CO_2hydrogenation to methanol over Cu-V/γ-Al2O3 catalyst[J].Journal of Natural Gas Chemistry,2007,16:12-15.
    [21]Stoczynski J,Grabowski R,Olszewski P,et al.Effect of metal oxide additives on the activity and stability of Cu/ZnO/ZrO2catalysts in the synthesis of methanol from CO_2and H2[J].Applied Catalysis:General,2006,310:127-137.
    [22]梁雪莲.CO_2加氢制甲醇用Pd-修饰MWCNTs-促进高效新型Pd-ZnO催化剂的研究[D].厦门大学,2009.
    [23]Ota A,Kunkes E L,Kasatkin I,et al.Comparative study of hydrotalcite-derived supported Pd2Ga and PdZn intermetallic nanoparticles as methanol synthesis and methanol steam reforming catalysts[J].J Catal,2012,293:27-38.
    [24]秦祖赠,刘瑞雯,纪红兵,等.二氧化碳的活化及其催化加氢制二甲醚的研究进展[J].化工进展,2015,34(1):119-126.
    [25]Yang Y X,White M G,Liu P.Theoretical Study of Methanol Synthesis from CO_2 Hydrogenation on Metal-Doped Cu(Ⅲ)Surfaces[J].J Phys Chem C,2012,116(1):248-256.
    [26]Flores J H,Peixoto D P B,Appel L G,et al.The influence of different methanol synthesis catalysts on direct synthesis of DME from syngas[J].Catal Today,2011,172(1):218-225.
    [27]梁兵连,段洪敏,侯宝林,等.二氧化碳加氢合成低碳烯烃的研究进展[J].化工进展,2015,34(10):3746-3754.
    [28]向航,李静,曹建新,等.CO_2绿色化合成低碳烯烃Fe基催化剂研究进展[J].现代化工,2015,35(2):27-32.
    [29]丁凡舒,聂小娃,刘民,等.Fe基催化剂上二氧化碳加氢制C+2烃的研究进展[J].应用化学,2016,33(2):123-132.
    [30]王影,彭闯,蒋登高.电化学方法固定二氧化碳的研究进展[J].现代化工,2013,33(10):37-41.
    [31]Wang C C,Zhang Y Q,Li J,et al.Photocatalytic CO_2reduction in metal-organic frameworks:A mini review[J].J Mol Struct,2015,1083(5):127-136.
    [32]吴改,程军,张梦,等.太阳能光电催化还原CO_2的最新研究进展[J].浙江大学学报:工学版,2013,47(4):680-687.
    [33]Qiao J,Liu Y,Hong F,et al.A review of catalysts for the electroreduction ofcarbon dioxide to produce low-carbon fuels[J].Chem Soc Rev,2014,43(2):631-675.
    [34]Shoko A,Kentaro Me,Kei O,et al.Selective electrochemical reduction of CO_2 to CO with a cobalt chlorin complex adsorbed on multi-walled carbon nanotubes in water[J].Chem Commun,2015,51:10226-10228.
    [35]Kang X H,Zhu Q G,Sun X F,et al.Highly efficient electrochemical reduction of CO_2to CH4in an ionic liquid using a metal–organic framework cathode[J].Chem Sci,2016,7:266-273.
    [36]Varela A S,Kroschel M,Reier T,et al.Controlling the selectivity of CO_2electroreduction on copper:The effect of the electrolyte concentration and the importance of the local pH[J].Catal Today,2016,260:8-13.
    [37]张现萍,黄海燕,靳红利,等.水溶液中电化学还原CO_2研究进展[J].化工进展,2015,34(12):4139-4144.
    [38]王静.多孔锡电极的制备及其用于CO_2电化学还原性能的研究[D].天津大学,2014.
    [39]Chai G L,Guo Z X.Highly effective sites and selectivity of nitrogen-doped graphene/CNT catalysts for CO_2 electrochemical reduction[J].Chem Sci,2016,7:1268-1275.
    [40]范梦阳.纳米氧化铜、氧化锡及其复合物(CuO-Cu2O、SnO2、SnO2-CuO)的制备及CO_2电催化还原性能[D].东华大学,2015.
    [41]赵晨辰,何向明,王莉,等.电化学还原CO_2阴极材料研究进展[J].化工进展,2013,32(2):373-380.
    [42]秦军荣.基于金属纳米粒子修饰电极在吡啶水溶液中电催化还原CO_2的研究[D].上海师范大学,2015.
    [43]吕伟欣.二氧化碳在乙腈和水中的电化学还原[D].东南大学,2014.
    [44]Kumar R S,Kumar S S,Kulandainathan M A.Highly selective electrochemical reduction of carbon dioxide usin g Cu based metal organic framework as an electrocatalyst[J].Electrochem Commun,2012,25:70-73.
    [45]Kaneco S,Katsumata H,Suzuki T,et al.Electrochemical reduction of carbon dioxide to ethylene at a copper electrode in methanol using potassium hydroxide and rubidium hydroxide supporting electrolytes[J].Electrochim Acta,2006,51(16):3316-3321.
    [46]Oh Y J,H X l.Organic molecules as mediators and catalysts for photocatalytic and electrocatalytic CO_2reduction[J].Chem Soc Rev,2013,42(6):2253-2261.
    [47]Carlesi C,Carvajal D,Vasquez D,et al.Analysis of carbon dioxide-to-methanol direct electrochemical conversion mediated by an ionic liquid[J].Chem Eng Process,2014,85(11):48-56.
    [48]Zhou F,Liu S M,Yang B Q,et al.Highly selective and stable electro-catalytic system with ionic liquids for the reduction of carbon dioxide to carbon monoxide[J].Electrochem.Commun.,2015,55(6):43-46.
    [49]王超,陈达,刘姝,等.TiO2光催化还原CO_2研究进展.材料导报:A,2011,25(7):38-4 6.
    [50]Lo C C,Hung C H,Yuan C S,et al.Photoreduction of carbon dioxide with H2and H2O over TiO2arid ZrO2in a circulated photocatalytic reactor[J].Sol Energy Mater Sol Cells,2007,91(19):1765.
    [51]Dey G R,Belapurkarb A D,Kishore K.Photocatalytic reduction of carbon dioxide to methane using TiO2as suspension in water[J].J Photochem Photobiol,A:Chem,2004,163:503-508.
    [52]Kocf K,ZatloukalováK,ObalováL,et al.Wave length effect on photocatalytic reduction of CO_2by Ag/TiO2catalyst[J].Chin J Catal,2011,32(5):812-815.
    [53]Li X Z,Li F B,Yan g C L,et al.Photo-cata lytic activ ity of WOx-TiO2under visible light Irradiation[J].J Photochem Photobiol,A:Chem,2001,141:209-217.
    [54]李娜.石墨烯基半导体纳米复合材料的制备及其在光催化还原CO_2中的应用[D].中北大学,2015.
    [55]徐金凤.基于TiO2和CuO高效光电催化剂的构建及其光电协同催化还原CO_2的研究[D].山东农业大学,2014.
    [56]Li P,Zhao G,Zhao K,Gao J,et al.An efficient and energy saving approach to photocatalytic degradation of opaque high-chroma methylene blue wastewater by electrocatalytic pre-oxidation[J].Dyes and Pigment,2012,92:923-928.
    [57]Kaneco S,Katsumata H,Suzuki T,et al.Photoelectrochemical reduction of carbon dioxide at p-type gallium arsenide and p-type indium phosphide electrodes in methano1[J].Chem Eng J,2006,116:227-231.
    [58]Hirota K,Tryk D A,Yamamoto T,et al.Photoelectrochemical reduction of CO_2in a high-pressure CO_2 plus methano1medium at p-type semiconductor electrodes[J].J Phys Chem B,1998,102(49):9834-9843.
    [59]Flaisher H,Tenne R,Halmann M.Photo-electrochemical reduction of carbon dioxide in aqueous solutions on p-GaP electrodes:an ac impedance study with phase-sensitive detection[J].J Electroanal Chem,1996,402(1/2):97-105.
    [60]Kumar B,Llorente M,Froehlich J,et al.Photochemical and photoelectrochemical reduction of CO_2[J].Annu Rev Phys Chem,2012,63:541-569.
    [61]Le M,Ren M,Zhang Z,et al.Electrochemical reduction of CO_2to CH3OH at copper oxide surfaces[J].J Electrochem Soc,2011,158:E45-E49.
    [62]Barton E E,Rampulla D M,Bocarsly A B.Selective solar-driven reduction of CO_2to methanol using a catalyzed P-GaP based photoelectrochemical cell[J].J Am Chem Soc,2008,130:6342-6344.
    [63]Chai S,Zhao G,Li P,Lei Y,et al.Novel sieve-like SnO2/TiO2nanotubes with integrated photoelectrocatalysis:fabrication and application for efficient toxicity elimination of nitrophenol wastewater[J].J Phys Chem C,2011,115:18261-18269.
    [64]Wang S B,Liu G Q.Reforming of methane with carbon dioxide over Ni/Al2O3catalysts:effect of nickel precursor[J].Appl Phys A:General,1998,169(2):271-280.
    [65]Li J M,Huang F Y,Weng W Z,et al.Effect of Rh loading on the performance of Rh/Al2O3for methane partial oxidation to synthesis gas[J].Catal Today,2008,131(1-4):179-187.
    [66]OConnor A M,Ross J R.The effect of O2addition on the carbon dioxide reforming of methane over Pt/ZrO2catalysts[J].Catal Today,1998,46(2-3):203-210.
    [67]Wilcox E M,Roberts G W,Spivey J J.Direct catalytic formation of acetic acid from CO_2and methane[J].Catal Today,2003,88(1-2):83-90.
    [68]Rostrup-Nielsen J R,Bak Hansen J H.CO_2-reforming of methane over transition metals[J].J Catal,1993,144(1):38-49.
    [69]Qin D,Lapszewicz J.Study of mixed steam and CO_2reforming of CH4to syngas on MgO-supported metals[J].Catal Today,1994,1(2-3):551-560.
    [70]李建发.中孔镍基催化材料调控制备及在CH4/CO_2重整反应中的性能研究[D].天津大学,2014.
    [71]Wang S B,Murata K,Hayakawa T,et al.Dehydrogenation of ethane with carbon dioxide over supported chromium oxide catalysts[J].Appl Catal,A:General,2000,196(1):1-8.
    [72]Mimura N,Takahara I,Inaba M,et al.High-performance Cr/H-ZSM-5catalysts for oxidative dehydrogenation of ethane to ethylene with CO_2as an oxidant[J].Catal Commun,2002,3(6):257-262.
    [73]Fujdala K,Tilley T D.Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane[J].J Catal,2003,218(1):123-134.
    [74]Takehira K,Ohishi Y,Shishido T,et al.Behavior of active sites on Cr-MCM-41catalysts during the dehydrogenation of propane with CO_2[J].J Catal,2004,224(2):404-416.
    [75]赵新红,李顺清,王晓来,等.制备方法对Cr/Si-2催化剂在CO_2氧化乙烷脱氢制乙烯反应中的催化性能的影响[J].分子催化,2007,21(2):132-138.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700