氧化石墨烯在提高包装材料阻隔性能方面的应用
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摘要
高分子材料由于耗能低、成本低和加工性好的优点在包装材料领域得到越来越多的关注,但高分子材料的气体阻隔性能不够理想,极大限制了其在包装行业的应用。氧化石墨烯由于具有良好的阻隔性能而在改善高分子包装材料气体阻隔性能方面得到广泛应用。介绍了氧化石墨烯/高分子材料用于气体阻隔膜的制备方法:混合法、喷涂法和层层自组装法,并指出3种方法的优缺点。还对氧化石墨烯在改善高分子包装材料的气体阻隔性能方面的发展前景做了展望,并提出提高氧化石墨烯的剥离程度和控制其在膜中的取向是提高高分子材料阻隔性能的关键。
Polymer materials were more and more widely used in packaging industry because of its low energy consumption,low cost and good processability.However,the gas barrier performance of polymer materials is not ideal,which greatly limits the application of polymer materials.Graphene oxide(GO)has been widely used in improving the gas barrier performance of polymer packaging material due to its good barrier performance.The preparation of graphene oxide in improving gas barrier of polymer materials in recent years and the advantages and disadvantages of each method were focused.The preparation methods of graphene/polymer composite materials in the field of gas barrier mainly included mixing method,spray-coating method and layer-by-layer assembly method.Furthermore,the current challenges and future research directions were also presented in terms of the application of graphene oxide in improving polymer packaging material.It was pointed out that increasing the exfoliation degree of graphene oxide and controlling its orientation in the film was the key to improve the barrier performance.
Polymer materials were more and more widely used in packaging industry because of its low energy consumption,low cost and good processability.However,the gas barrier performance of polymer materials is not ideal,which greatly limits the application of polymer materials.Graphene oxide(GO)has been widely used in improving the gas barrier performance of polymer packaging material due to its good barrier performance.The preparation of graphene oxide in improving gas barrier of polymer materials in recent years and the advantages and disadvantages of each method were focused.The preparation methods of graphene/polymer composite materials in the field of gas barrier mainly included mixing method,spray-coating method and layer-by-layer assembly method.Furthermore,the current challenges and future research directions were also presented in terms of the application of graphene oxide in improving polymer packaging material.It was pointed out that increasing the exfoliation degree of graphene oxide and controlling its orientation in the film was the key to improve the barrier performance.
引文
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[3]Choudhari S K,Kariduraganavar M Y.Development of novel composite membranes using quaternized chitosan and Na+-MMT clay for the pervaporation dehydration of isopropanol[J].Journal of Colloid and Interface Science,2009,338(1):111-120.
[4]Nazarenko S,Meneghetti P,Julmon P,et al.Gas barrier of polystyrene montmorillonite clay nanocomposites:effect of mineral layer aggregation[J].Journal of Polymer Science,Part B:Polymer Physics,2007,45(13):1733-1753.
[5]Novoselo K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[6]袁菁菁,董国材,刘兵.石墨烯改性富锂镍钴锰酸锂正极材料的制备及表征[J].化工新型材料,2015,43(10):91-93.
[7]Zhao X,Zhang Q H,Chen D J.Enhanced mechanical properties of graphene-based poly(vinyl alcohol)composites[J].Macromolecules,2010,43(5):2357-2363.
[8]Palermo V.Not a molecule,not a polymer,not a substrate…the many faces of graphene as a chemical platform[J].Chemical Communications,2013,49(28):2848-2857.
[9]Berry V.Impermeability of graphene and its applications[J].Carbon,2013,62:1-10.
[10]Cao M W,Wang N N,Wang L,et al.Direct exfoliation of graphite into graphene in aqueous solutions of amphiphilic peptides[J].Journal of Materials Chemistry B,2016(1):1-29.
[11]Seo H T,Lee S,Cho H,et al.Tailored CVD graphene coating as a transparent and flexible gas barrier[J].Scientific Reports,2016,6:24143.
[12]Robert M J,Brian K,Matthieu F D,et al.Direct oriented growth of armchair graphene nanoribbons on germanium[J].Nature Communications,2015,6:8006.
[13]Paraense M O,Cunha T H R D,Ferlauto A S,et al.Monolayer and bilayer graphene on polydimethylsiloxane as a composite membrane for gas-barrier applications[J].Journal of Applied Polymer Science,2017,134(47):45521-45529.
[14]Joshi M,Adak B,Butola B S.Polyurethane nanocomposite based gas barrier films,membranes and coatings:a review on synthesis,characterization and potential applications[J].Progress in Materials Science,2018,97:230-282.
[15]Kim H,Miura Y,Macosko C W.Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity[J].Chemistry of Materials,2010,22:3441-3450.
[16]Chen J T,Fu Y J,An Q F,et al.Enhancing polymer/graphene oxide gas barrier film properties by introducing new crystals[J].Carbon,2014,75:443-451.
[17]Kaveh P,Mortezaei M,Barikani M.Low-temperature flexible polyurethane/graphene oxide nanocomposites:effect of polyols and graphene oxide on physicomechanical properties and gas permeability[J].Polymer-Plastics Technology and Engineering,2014,53(3):278-289.
[18]Xiang C,Cox P J,Kukovecz A,et al.Functionalized low defect graphene nanoribbons and polyurethane composite film for improved gas barrier and mechanical performances[J].ACS Nano,2013,7(11):10380-10386.
[19]Yoo B M,Shin H J,Yoon H W,et al.Graphene and graphene oxide and their uses in barrier polymers[J].Journal of Applied Polymer Science,2013,131(1):39628.
[20]Gavgani J N,Adelnia H,Gudarzi M M.Intumescent flame retardant PU/reduced graphene oxide composites with improved mechanical,thermal,and barrier properties[J].Journal of Materials Science,2014,49:243-254.
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[22]Wei W,Zhang W Q,Jiang Q,et al.Preparation of non-oxide SiC membrane for gas purification by spray coating[J].Journal of Membrane Science,2017,540:381-390.
[23]Layek R K,Das A K,Park U M,et al.Layer-structured graphene oxide/polyvinyl alcohol nanocomposites:dramatic enhancement of hydrogen gas barrier properties[J].Journal of Materials Chemistry A,2014,2:12158-12161.
[24]Bandyopadhyay P,Nguyen T T,Li X,et al.Enhanced hydrogen gas barrier performance of diaminoalkane functionalized stitched graphene oxide/polyurethane composites[J].Composites Part B:Engineering,2017,117:101-110.
[25]Poon Z,Chang D,Zhao X,et al.Layer-by-layer nanoparticles with a pH-sheddable layer for in vivo targeting of tumor hypoxia[J].ACS Nano,2011,5(6):4284-4292.
[26]Kotov N A,Dékány I,Fendler J H.Ultrathin graphite oxidepolyelectrolyte composites prepared by self-assembly:transition between conductive and non-conductive states[J].Advanced Material,1996,8(8):637-641.
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