超声水处理中锌基催化剂的研究进展
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摘要
介绍了常用的锌基催化剂,包括零价锌、氧化锌、过渡金属离子掺杂的氧化锌等;叙述了其主要的制备方法,如沉淀法、浸渍法等;探讨了反应关键影响因素,包括超声参数、水质条件及催化剂的种类和用量;分析了超声催化降解机理,即通过空化效应引发高温高压及声致发光,进而降解污染物;分析表明,定量研究各机理的贡献的必要性。认为未来研究应寻找反应活性和选择性更好的锌基催化剂,并考虑其制备工艺的改进;注重催化剂的经济性和安全性;寻找更温和的反应条件,进一步节约成本;定量分析超声水处理中各机理的贡献,方便后续对其进行改性。
Commonly used Zn-based catalysts, including zero-valent zinc, zinc oxide, transition metal ion-doped zinc oxide were introduced. The mainly preparation methods were briefly described, such as methods of precipitation, impregnation and etc. The key influencing factors of the reaction, including ultrasonic parameters, water quality, catalyst types and its dosing quantity, were discussed. The mechanism of the ultrasonic catalytic reaction was analyzed,which is to degrade pollutants by high temperature, high pressure and sonoluminescence induced by cavitation effects. Analysis indicated that quantitative research on contributions of each mechanism would be necessary. And it proposed that Zn-based catalysts with better reactivity and selectivity should be found in the future. It is considered that the preparation technology should be improved, pay attention to the economy and safety of catalyst and search more mild reaction conditions to save cost further. The quantitative analysis of the contribution of each mechanism on ultrasonic water treatment should be carried out, which convenient for it modification.
Commonly used Zn-based catalysts, including zero-valent zinc, zinc oxide, transition metal ion-doped zinc oxide were introduced. The mainly preparation methods were briefly described, such as methods of precipitation, impregnation and etc. The key influencing factors of the reaction, including ultrasonic parameters, water quality, catalyst types and its dosing quantity, were discussed. The mechanism of the ultrasonic catalytic reaction was analyzed,which is to degrade pollutants by high temperature, high pressure and sonoluminescence induced by cavitation effects. Analysis indicated that quantitative research on contributions of each mechanism would be necessary. And it proposed that Zn-based catalysts with better reactivity and selectivity should be found in the future. It is considered that the preparation technology should be improved, pay attention to the economy and safety of catalyst and search more mild reaction conditions to save cost further. The quantitative analysis of the contribution of each mechanism on ultrasonic water treatment should be carried out, which convenient for it modification.
引文
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[16]TAGHIZADEH M T,SEIFI-AGHJEKOHAL P.Sonocatalytic degradation of 2-hydroxyethyl cellulose in the presence of some nanoparticles[J].Ultrasonics Sonochemistry,2015,26:265-272.
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[20]HU S B,LI L,LUO M Y,et al.Aqueous norfloxacin sonocatalytic degradation with multilayer flower-like ZnO in the presence of peroxydisulfate[J].Ultrasonics Sonochemistry,2017,38:446-454.
[21]KHATAEE A,SAADI S,VAHID B.Kinetic modeling of sonocatalytic degradation of reactive orange 29 in the presence of lanthanide-doped Zn O nanoparticles[J].Ultrasonics Sonochemistry,2017,34:98-106.
[22]KHATAEE A,KARIMI A,AREFIOSKOUI S,et al.Sonochemical synthesis of Pr-doped Zn O nanoparticles for sonocatalytic degradation of Acid Red 17[J].Ultrasonics Sonochemistry,2015,22:371-381.
[23]KHATAEE A,VAHID B,SAADI S,et al.Development of an empirical kinetic model for sonocatalytic process using neodymium doped zinc oxide nanoparticles[J].Ultrasonics Sonochemistry,2016,29:146-155.
[24]SOLTANI R D C,JORFI S,RAMEZANI H,et al.Ultrasonically induced ZnO-biosilica nanocomposite for degradation of a textile dye in aqueous phase[J].Ultrasonics Sonochemistry,2016,28:69-78.
[25]GAO J,JIANG R,WANG J,et al.The investigation of sonocatalytic activity of Er3+:YAlO3/TiO2-ZnO composite in azo dyes degradation[J].Ultrasonics Sonochemistry,2011,18(2):541-548.
[26]LEI Z,JO S B,SHU Y,et al.Rhodamine B degradation and reactive oxygen species generation by a ZnSe-graphene/TiO2sonocatalyst[J].Chinese Journal of Catalysis,2014,35(11):1825-1832.
[27]ESKANDARLOO H,BADIEI A,BEHNAJADY M A,et al.Ultrasonicassisted synthesis of Ce doped cubic-hexagonal ZnTiO3with highly efficient sonocatalytic activity[J].Ultrasonics Sonochemistry,2016,29:258-269.
[28]HUNGE Y M,YADAV A A,MATHE V L.Ultrasound assisted synthesis of WO3-Zn O nanocomposites for brilliant blue dye degradation[J].Ultrasonics Sonochemistry,2018,45:116-122.
[29]张晖,高洪,王雪,等.活性炭负载氧化锌催化剂及其在降解有机污染物中应用:CN102744055A[P].2012-10-24.
[30]SOLTANI R D C,JORFI S,SAFARI M,et al.Enhanced sonocatalysis of textile wastewater using bentonite-supported ZnO nanoparticles:Response surface methodological approach[J].Journal of Environmental Management,2016,179:47-57.
[31]NUENGMATCHA P,CHANTHAI S,MAHACHAI R,et al.Sonocatalytic performance of ZnO/graphene/TiO2nanocomposite for degradation of dye pollutants(methylene blue,texbrite BAC-L,texbrite BBU-L and texbrite NFW-L)under ultrasonic irradiation[J].Dyes&Pigments,2016,134:487-497.
[32]ELSHAFEI G M S,AL-SABAGH A M,YEHIA F Z,et al.Metal oxychlorides as robust heterogeneous Fenton catalysts for the sonophotocatalytic degradation of 2-nitrophenol[J].Applied Catalysis B:Environmental,2018,224:681-691
[33]KHATAEE A,AREFIOSKOUI S,SAMAEI L.Zn Fe-Cl nanolayered double hydroxide as a novel catalyst for sonocatalytic degradation of an organic dye[J].Ultrasonics Sonochemistry,2018,40:703-713.
[34]宋诚,陈集,王川.Cu-Zn O/膨润土光催化氧化处理钻井废水实验研究[J].水处理技术,2015,41(2):85-88.
[35]邹晓丽.超声协同零价铁/过硫酸盐Fenton-like体系降解磺胺类药物及应用研究[D].武汉:华中科技大学,2016.
[36]ESKANDARLOO H,BADIEI A,BEHNAJADY M A,et al.Ultrasonicassisted degradation of phenazopyridine with a combination of Smdoped ZnO nanoparticles and inorganic oxidants[J].Ultrasonics Sonochemistry,2016,28:169-177.
[37]SOLTANI R D C,JORFI S,RAMEZANI H,ET al.Ultrasonically induced ZnO-biosilica nanocomposite for degradation of a textile dye in aqueous phase[J].Ultrasonics Sonochemistry,2016,28:69-78.
[38]ZHOU M,YANG H,XIAN T,et al.Sonocatalytic degradation of RhB over LuFeO3particles under ultrasonic irradiation.[J].Journal of Hazardous Materials,2015,289:149-157.
[39]PANG Y L,BHATIA S,ABDULLAH A Z.Process behavior of Ti O2nanotube-enhanced sonocatalytic degradation of Rhodamine B in aqueous solution[J].Separation&Purification Technology,2011,77(3):331-338.
[40]MALEKI A.Synthesis of Zn O nano-sono-catalyst for degradation of reactive dye focusing on energy consumption:operational parameters influence,modeling,and optimization[J].Desalination&Water Treatment,2014,52(34/36):6745-6755.
[41]ZHAO H,ZHANG G,ZHANG Q.Mn O2/Ce O2for catalytic ultrasonic degradation of methyl orange[J].Ultrason Sonochem,2014,21(3):991-996.
[42]KHATAEE A,KARIMI A,ZAREI M,et al.Eu-doped ZnO nanoparticles:Sonochemical synthesis,characterization,and sonocatalytic application[J].Ultrasonics Sonochemistry,10.1016/j.ultsonch.2015.03.016.
[43]戴丽雅,张宏波,王谦,等.超声-芬顿法降解工业染料中间体废水[J].水处理技术,2017,43(4):70-72.
[44]GHOSH A,MONDAL A.Fabrication of stable,efficient and recyclable p-Cu O/n-Zn O thin film heterojunction for visible light driven photocatalytic degradation of organic dyes[J].Materials Letters,2016,164:221-224.
[45]赵霞,ISMOILOV B,李亚斌,等.污水高级氧化技术的研究现状及其新进展[J].水处理技术,2018,44(4):7-10.
[46]ZHANG N,XIAN G,LI X,et al.Iron based catalysts used in water treatment assisted by ultrasound:A mini review[J].Frontiers in Chemistry,2018,6(12):1-6.
[47]QIU P,PARK B,CHOI J,et al.A review on heterogeneous sonocatalyst for treatment of organic pollutants in aqueous phase based on catalytic mechanism[J].Ultrasonics Sonochemistry,2018,45:29-49.
[2]ZHENG J,ZENG R,KAN J,et al.Effects of ultrasonic treatment on gel rheological properties and gel Formation of high-methoxyl pectin[J].Journal of Food Engineering,2018,231:83-90.
[3]GAGOL M,PRZYJAZNY A,BOCZKAJ G.Wastewater treatment by means of advanced oxidation processes based on cavitation-AReview[J].Chemical Engineering Journal,2018,338:599-627.
[4]PVL R,KIM K H,KAVITHA B,et al.Photocatalytic degradation of bisphenol A in aqueous media:A review[J].Journal of Environmental Management,2018,213:189-205.
[5]宋亚丽.水中硝基苯类化合物的超声波/锌降解效果及机理[D].哈尔滨:哈尔滨工业大学,2013.
[6]宋亚丽,张光明,常爱敏,等.US/Zn0体系降解水中的对硝基苯甲酸[J].环境工程学报,2014,8(5):1797-1801.
[7]张怡,张光明,万甜,等.常见金属及金属氧化物催化超声降解间苯二酚[J].环境科学与技术,2012,35(9):1-3.
[8]TALEBIAN N,NILFOROUSHAN M R,MOGADDAS F J.Comparative study on the sonophotocatalytic degradation of hazardous waste[J].Ceramics International,2013,39(5):4913-4921.
[9]陈珊珊,万霞,铁绍龙.超声协同作用下亚微米掺铝氧化锌催化降解亚甲基蓝的研究[J].华南师范大学学报(自然科学版),2012,44(1):76-81
[10]KHATAEE A,SAADI S,VAHID B,et al.Sonocatalytic degradation of Acid Blue 92 using sonochemically prepared samarium doped zinc oxide nanostructures[J].Ultrasonics Sonochemistry,2016,29:27-38.
[11]KHATAEE A,SOLTANI R D C,KARIMI A,et al.Sonocatalytic degradation of a textile dye over Gd-doped Zn O nanoparticles synthesized through sonochemical process[J].Ultrasonics Sonochemistry,2015,23:219-230.
[12]ESKANDARLOO H,BADIEI A,BEHNAJADY M A,et al.Ultrasonicassisted degradation of phenazopyridine with a combination of Smdoped ZnO nanoparticles and inorganic oxidants[J].Ultrasonics Sonochemistry,2016,28:169-177.
[13]KARACA M,KIRAN?AN M,KARACA S,et al.Sonocatalytic removal of naproxen by synthesized zinc oxide nanoparticles on montmorillonite[J].Ultrasonics Sonochemistry,2016,31:250-256.
[14]刘诗丽,邢国秀,姜华,等.超声波协同纳米锌催化降解染料废水[J].广东化工,2016,43(20):143-144.
[15]宋亚丽,张光明,吴盼.超声-单质锌耦合降解水中对硝基苯胺[J].环境科学与技术,2013,36(S1):163-166.
[16]TAGHIZADEH M T,SEIFI-AGHJEKOHAL P.Sonocatalytic degradation of 2-hydroxyethyl cellulose in the presence of some nanoparticles[J].Ultrasonics Sonochemistry,2015,26:265-272.
[17]CHAKMA S,MOHOLKAR V S.Investigation in mechanistic issues of sonocatalysis and sonophotocatalysis using pure and doped photocatalysts[J].Ultrasonics Sonochemistry,2015,22:287-299.
[18]BRAHIM I O,BELMEDANI M,HADDAD A,et al.Degradation of C.I.Acid Red 51 and C.I.Acid Blue 74 in aqueous solution by combination of hydrogen peroxide,nanocrystallite zinc oxide and ultrasound irradiation[J].Journal of Advanced Oxidation Technologies,2018,21(1):26-43.
[19]黄艳芹.超声协同纳米Zn O光催化降解亚甲基蓝研究[J].河南师范大学学报(自然科学版),2012,40(5):106-109.
[20]HU S B,LI L,LUO M Y,et al.Aqueous norfloxacin sonocatalytic degradation with multilayer flower-like ZnO in the presence of peroxydisulfate[J].Ultrasonics Sonochemistry,2017,38:446-454.
[21]KHATAEE A,SAADI S,VAHID B.Kinetic modeling of sonocatalytic degradation of reactive orange 29 in the presence of lanthanide-doped Zn O nanoparticles[J].Ultrasonics Sonochemistry,2017,34:98-106.
[22]KHATAEE A,KARIMI A,AREFIOSKOUI S,et al.Sonochemical synthesis of Pr-doped Zn O nanoparticles for sonocatalytic degradation of Acid Red 17[J].Ultrasonics Sonochemistry,2015,22:371-381.
[23]KHATAEE A,VAHID B,SAADI S,et al.Development of an empirical kinetic model for sonocatalytic process using neodymium doped zinc oxide nanoparticles[J].Ultrasonics Sonochemistry,2016,29:146-155.
[24]SOLTANI R D C,JORFI S,RAMEZANI H,et al.Ultrasonically induced ZnO-biosilica nanocomposite for degradation of a textile dye in aqueous phase[J].Ultrasonics Sonochemistry,2016,28:69-78.
[25]GAO J,JIANG R,WANG J,et al.The investigation of sonocatalytic activity of Er3+:YAlO3/TiO2-ZnO composite in azo dyes degradation[J].Ultrasonics Sonochemistry,2011,18(2):541-548.
[26]LEI Z,JO S B,SHU Y,et al.Rhodamine B degradation and reactive oxygen species generation by a ZnSe-graphene/TiO2sonocatalyst[J].Chinese Journal of Catalysis,2014,35(11):1825-1832.
[27]ESKANDARLOO H,BADIEI A,BEHNAJADY M A,et al.Ultrasonicassisted synthesis of Ce doped cubic-hexagonal ZnTiO3with highly efficient sonocatalytic activity[J].Ultrasonics Sonochemistry,2016,29:258-269.
[28]HUNGE Y M,YADAV A A,MATHE V L.Ultrasound assisted synthesis of WO3-Zn O nanocomposites for brilliant blue dye degradation[J].Ultrasonics Sonochemistry,2018,45:116-122.
[29]张晖,高洪,王雪,等.活性炭负载氧化锌催化剂及其在降解有机污染物中应用:CN102744055A[P].2012-10-24.
[30]SOLTANI R D C,JORFI S,SAFARI M,et al.Enhanced sonocatalysis of textile wastewater using bentonite-supported ZnO nanoparticles:Response surface methodological approach[J].Journal of Environmental Management,2016,179:47-57.
[31]NUENGMATCHA P,CHANTHAI S,MAHACHAI R,et al.Sonocatalytic performance of ZnO/graphene/TiO2nanocomposite for degradation of dye pollutants(methylene blue,texbrite BAC-L,texbrite BBU-L and texbrite NFW-L)under ultrasonic irradiation[J].Dyes&Pigments,2016,134:487-497.
[32]ELSHAFEI G M S,AL-SABAGH A M,YEHIA F Z,et al.Metal oxychlorides as robust heterogeneous Fenton catalysts for the sonophotocatalytic degradation of 2-nitrophenol[J].Applied Catalysis B:Environmental,2018,224:681-691
[33]KHATAEE A,AREFIOSKOUI S,SAMAEI L.Zn Fe-Cl nanolayered double hydroxide as a novel catalyst for sonocatalytic degradation of an organic dye[J].Ultrasonics Sonochemistry,2018,40:703-713.
[34]宋诚,陈集,王川.Cu-Zn O/膨润土光催化氧化处理钻井废水实验研究[J].水处理技术,2015,41(2):85-88.
[35]邹晓丽.超声协同零价铁/过硫酸盐Fenton-like体系降解磺胺类药物及应用研究[D].武汉:华中科技大学,2016.
[36]ESKANDARLOO H,BADIEI A,BEHNAJADY M A,et al.Ultrasonicassisted degradation of phenazopyridine with a combination of Smdoped ZnO nanoparticles and inorganic oxidants[J].Ultrasonics Sonochemistry,2016,28:169-177.
[37]SOLTANI R D C,JORFI S,RAMEZANI H,ET al.Ultrasonically induced ZnO-biosilica nanocomposite for degradation of a textile dye in aqueous phase[J].Ultrasonics Sonochemistry,2016,28:69-78.
[38]ZHOU M,YANG H,XIAN T,et al.Sonocatalytic degradation of RhB over LuFeO3particles under ultrasonic irradiation.[J].Journal of Hazardous Materials,2015,289:149-157.
[39]PANG Y L,BHATIA S,ABDULLAH A Z.Process behavior of Ti O2nanotube-enhanced sonocatalytic degradation of Rhodamine B in aqueous solution[J].Separation&Purification Technology,2011,77(3):331-338.
[40]MALEKI A.Synthesis of Zn O nano-sono-catalyst for degradation of reactive dye focusing on energy consumption:operational parameters influence,modeling,and optimization[J].Desalination&Water Treatment,2014,52(34/36):6745-6755.
[41]ZHAO H,ZHANG G,ZHANG Q.Mn O2/Ce O2for catalytic ultrasonic degradation of methyl orange[J].Ultrason Sonochem,2014,21(3):991-996.
[42]KHATAEE A,KARIMI A,ZAREI M,et al.Eu-doped ZnO nanoparticles:Sonochemical synthesis,characterization,and sonocatalytic application[J].Ultrasonics Sonochemistry,10.1016/j.ultsonch.2015.03.016.
[43]戴丽雅,张宏波,王谦,等.超声-芬顿法降解工业染料中间体废水[J].水处理技术,2017,43(4):70-72.
[44]GHOSH A,MONDAL A.Fabrication of stable,efficient and recyclable p-Cu O/n-Zn O thin film heterojunction for visible light driven photocatalytic degradation of organic dyes[J].Materials Letters,2016,164:221-224.
[45]赵霞,ISMOILOV B,李亚斌,等.污水高级氧化技术的研究现状及其新进展[J].水处理技术,2018,44(4):7-10.
[46]ZHANG N,XIAN G,LI X,et al.Iron based catalysts used in water treatment assisted by ultrasound:A mini review[J].Frontiers in Chemistry,2018,6(12):1-6.
[47]QIU P,PARK B,CHOI J,et al.A review on heterogeneous sonocatalyst for treatment of organic pollutants in aqueous phase based on catalytic mechanism[J].Ultrasonics Sonochemistry,2018,45:29-49.
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