紫外联用高级氧化技术处理饮用水应用进展
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摘要
叙述了紫外-过氧化氢、紫外-芬顿、紫外-过氧化氢-臭氧、紫外-硫酸盐、紫外-氯、紫外-二氧化钛等紫外联用高级氧化技术在饮用水处理领域中的国内外科学研究及工程应用现状,比较了各组合技术的作用原理、处理特性及优缺点。为避免高级氧化工艺存在的缺陷,如氧化剂、催化剂消耗量大、易受水质影响、运行费用高、存在二次污染等,应针对价格低廉、稳定高效的新型氧化剂、催化剂及催化剂载体进行专项研发,降低该技术的应用成本;加强基于实际水体有机难降解污染物的降解动力学及传质机理研究,设计开发适于不同水质条件的紫外联用高级氧化一体化集成工艺的系统化光反应器,推进紫外联用的高级氧化技术实现实际工程化应用。
The present situation of scientific research along with engineering application of ultraviolet(UV) combined advanced oxidation technologies including UV-hydrogen peroxide, UV-Fenton, UV-hydrogen peroxide-ozone, UV-sulfate, UV-chlorine, and UV-titanium dioxide in drinking water treatment field at home and abroad were described. The action principle, treatment characteristics as well as strengths and weaknesses of each technology were compared. In order to avoid the defects of advanced oxidation processes, such as high oxidant/catalyst consumption, vulnerability to water quality,costly running expense, secondary pollution and so on, special research and development on a new type of oxidant, catalyst and catalyst carrier which are cheap, stable and efficient should be carried out to reduce the application cost of the technology. Strengthening the study on degradation kinetics and mass transfer mechanism of organic refractory pollutants in real water, and designing and developing systematic photoreactors of UV integrated advanced oxidation process for different water quality conditions are urgently needed to promote the achievement of practical engineering application of UV combined advanced oxidation technology.
The present situation of scientific research along with engineering application of ultraviolet(UV) combined advanced oxidation technologies including UV-hydrogen peroxide, UV-Fenton, UV-hydrogen peroxide-ozone, UV-sulfate, UV-chlorine, and UV-titanium dioxide in drinking water treatment field at home and abroad were described. The action principle, treatment characteristics as well as strengths and weaknesses of each technology were compared. In order to avoid the defects of advanced oxidation processes, such as high oxidant/catalyst consumption, vulnerability to water quality,costly running expense, secondary pollution and so on, special research and development on a new type of oxidant, catalyst and catalyst carrier which are cheap, stable and efficient should be carried out to reduce the application cost of the technology. Strengthening the study on degradation kinetics and mass transfer mechanism of organic refractory pollutants in real water, and designing and developing systematic photoreactors of UV integrated advanced oxidation process for different water quality conditions are urgently needed to promote the achievement of practical engineering application of UV combined advanced oxidation technology.
引文
[1]CHU W H,GAO N Y,TEMPLETON M R,et al.Comparison of inclined plate sedimentation and dissolved air flotation for the minimisation of subsequent nitrogenous disinfection by-product formation[J].Chemosphere,2011,83:647-651.
[2]DEWIL R,MANTZAVINOS D,POULIOS I,et al.New perspectives for advanced oxidation processes[J].Journal of Environmental Management,2017,195:93-99.
[3]GAO Z C,LIN Y L,XU B,et al.Degradation of acrylamide by the UV/chlorine advanced oxidation process[J].Chemosphere,2017,187:268-276.
[4]GLAZE W H,KANG J W.Advanced oxidation process.description of a kinetic model for the oxidation of hazardous materials in aqueous media with ozone and hydrogen peroxide[J].Industrial&Engineering Chemistry Research,1989,28(11):1580-1587.
[5]LEE M,MERLE T,RENTSCH D,et al.Abatement of polychoro-1,3-butadienes in aqueous solution by ozone,UV-photolysis,and advanced oxidation processes(O3/H2O2and UV/H2O2)[J].Environmental Science&Technology,2017,51(1):497-505.
[6]JIA P,ZHOU Y,ZHANG X,et al.Cyanobacterium removal and control of algal organic matter(AOM)release by UV/H2O2preoxidation enhanced Fe(II)coagulation[J].Water Research,2018,131(1):122-130.
[7]ZHU Y,WU M,GAO N,et al.Degradation of phenacetin by the UV/chlorine advanced oxidation process:Kinetics,pathways,and toxicity evaluation[J].Chemical Engineering Journal,2018,335:520-529.
[8]YI Y,PIGNATELLO J J,MA J,et al.Effect of matrix components on UV/H2O2,and UV/S2O82-,advanced oxidation processes for trace organic degradation in reverse osmosis brines from municipal wastewater reuse facilities[J].Water Research,2016,89:192-200.
[9]TAK S Y,KIM M K,LEE J E,et al.Kinetics and degradation mechanism of Anatoxin-a during in UV-C/H2O2reaction[J].Chemical Engineering Journal,2018,334:1016-1022.
[10]Chuang Y H,Parker K M,Mitch W A.Development of predictive models for the degradation of halogenated disinfection byproducts during the UV/H2O2Advanced Oxidation Process[J].Environmental Science&Technology,2016,50:11209-11217.
[11]ROZAS O,VIDAL C,BAEZA C,et al.Organic micropollutants(OMPs)in natural waters:Oxidation by UV/H2O2treatment and toxicity assessment[J].Water Research,2016,98:109-118.
[12]YAO H,SUN P,MINAKATA D,et al.Kinetics and modeling of degradation of ionophore antibiotics by UV and UV/H2O2[J].Environmental Science&Technology,2013,47(9):4581-4589.
[13]罗从伟,马军,江进,等UV/H2O2降解三氯生动力学及反应机理[J].哈尔滨工业大学学报,2017,49(2):26-31.
[14]JIN Q,WANG H,HU C,et al.Effects of NOM on the degradation of chloramphenicol by UV/H2O2and the characteristics of degradation products[J].Separation&Purification Technology,2018,191:108-115..
[15]罗从伟,马军,江进,等.UV/H2O2降解2,4,6-三氯苯甲醚动力学及产物研究[J].中国环境科学,2017,37(5):1831-1837.
[16]VELO-GALA I,PIRAN-MONTANO J A,RIVERA-UTRILLA J,et al.Advanced oxidation processes based on the use of UVC and simulated solar radiation to remove the antibiotic tinidazole from water[J].Chemical Engineering Journal,2017,323:606-617.
[17]TSIAPOU S S,TEMPLETON M R,GRAHAM N J,et al.Low pressure UV/H2O2treatment for the degradation of the pesticides metaldehyde,clopyralid and mecoprop-Kinetics and reaction product formation[J].Water Research,2016,91:285-294.
[18]ALMQUIST C,FYDA S,GODBY N,et al.An investigation on the use of ultraviolet light emitting diodes(UV LEDs)in a plug-flow reactor for water treatment[J].Environmental Progress&Sustainable Energy,2017,36:857-863.
[19]PARK J A,NAM H L,CHOI J W,et al.Oxidation of geosmin and2-methylisoborneol by the photo-fenton process:kinetics,degradation intermediates,and the removal of microcystin-LR and trihalomethane from Nak-Dong River water,South Korea[J].Chemical Engineering Journal,2017,313:345-354.
[20]GONZSALEZ G C,JULCOUR C,CHAUMAT H,et al.Degradation~of 2,4-dichlorophenoxyacetic acid by photolysis and photo Fenton oxidation[J].Journal of Environmental Chemical Engineering,2018,6:874-882.
[21]DAVIDIDOU K,MONTEAGUDO J M,CHATZISYMEON E,et al.Degradation and mineralization of antipyrine by UV-A LED photoFenton reaction intensified by ferrioxalate with addition of persulfate[J].Separation&Purification Technology,2017,172:227-235.
[22]BOURGIN M,BOROWSKA E,HELBING J,et al.Effect of operational and water quality parameters on conventional ozonation and the advanced oxidation process O3/H2O2:Kinetics of micropollutant abatement,transformation product and bromate formation in a surface water[J].Water Research,2017,122:234-245.
[23]杨子增.UV/O3降解水中磺胺嘧啶的效能和机理研究[D].哈尔滨:哈尔滨工业大学,2016.
[24]ARSLAN A,TOPKAYA E,BING魻L D,et al.Removal of anionic surfactant sodium dodecyl sulfate from aqueous solutions by O3/UV/H2O2,advanced oxidation process:Process optimization with response surface methodology approach[J].Sustainable Environment Research,2018,28:65-71.
[25]YANG Y,LU X,JIANG J,et al.Degradation of sulfamethoxazole by UV,UV/H2O2and UV/persulfate(PDS):Formation of oxidation products and effect of bicarbonate.[J].Water Research,2017,118:196-207.
[26]罗从伟.紫外/过硫酸盐高级氧化降解典型有机微污染物效能及作用机制[D].哈尔滨:哈尔滨工业大学,2017.
[27]HOU S,LING L,SHANG C,et al.Degradation kinetics and pathways of haloacetonitriles by the UV/persulfate process[J].Chemical Engineering Journal,2017,320:478-484.
[28]VERMA S,NAKAMURA S,SILLANP魧魧M.Application of UV-CLED activated PMS for the degradation of anatoxin-a[J].Chemical Engineering Journal,2016,284:122-129.
[29]TIAN J,WU C,YU H,et al.Applying ultraviolet/persulfate(UV/PS)pre-oxidation for controlling ultrafiltration membrane fouling by natural organic matter(NOM)in surface water[J].Water Research,2018,132:190-199.
[30]LU X,SHAO Y,GAO N,Et al.Investigation of clofibric acid removal by UV/persulfate and UV/chlorine processes:Kinetics and formation of disinfection byproducts during subsequent chlor(am)ination[J].Chemical Engineering Journal,2018,331:364-371.
[31]LUO C,JIANG J,MA J,et al.Oxidation of the odorous compound2,4,6-trichloroanisole by UV activated persulfate:Kinetics,products,and pathways[J].Water Research,2016,96:12-21.
[32]XIAO Y,ZHANG L,WEI Z,et al.Comparative evaluation of iodoacids removal by UV/persulfate and UV/H2O2,processes[J].Water Research,2016,102:629-639.
[33]WANG F,WANG W,YUAN S,et al.Comparison of UV/H2O2,and UV/PS processes for the degradation of thiamphenicol in aqueous solution[J].Journal of Photochemistry&Photobiology A Chemistry,2017,348:79-88.
[34]骆靖宇,李学艳,李青松,等.紫外活化过硫酸钠去除水体中的三氯卡班[J].中国环境科学,2017,37(9):3324-3331.
[35]GAO Z C,LIN Y L,XU B,et al.Degradation of acrylamide by the UV/chlorine advanced oxidation process[J].Chemosphere,2017,187:268-276.
[36]KONG X,JIN J,MA J,et al.Degradation of atrazine by UV/chlorine:Efficiency,influencing factors,and products[J].Water Research,2016,90:15-23.
[37]KIM T K,MOON B R,KIM T,et al.Degradation mechanisms of geosmin and 2-MIB during UV photolysis and UV/chlorine reactions[J].Chemosphere,2016,162:157-164.
[38]孙昕,张燚,史路肖,等.真空紫外/氯处理饮用水典型致嗅物质[J].环境科学,2017,38(4):1-9.
[39]KONG X,JIANG J,MA J,et al.Comparative investigation of X-ray contrast medium degradation by UV/chlorine and UV/H2O2[J].Chemosphere,2018,193:655-663.
[40]MATAFONOVA G,BATOEV V.Recent advances in application of UV light-emitting diodes for degrading organic pollutants in water through advanced oxidation processes:A review[J].Water Research,2018,132:177-189.
[41]AUTIN O,ROMELOT C,RUST L,et al.Evaluation of a UV-light emitting diodes unit for the removal of micropollutants in water for low energy advanced oxidation processes[J].Chemosphere,2013,92(6):745-751.
[42]CAI Q,HU J.Decomposition of sulfamethoxazole and trimethoprim by continuous UVA/LED/TiO2,photocatalysis:Decomposition pathways,residual antibacterial activity and toxicity[J].Journal of Hazardous Materials,2017,323:527-536.
[43]LI S,HU J.Photolytic and photocatalytic degradation of tetracycline:Effect of humic acid on degradation kinetics and mechanisms[J].Journal of Hazardous Materials,2016,318:134-144.
[44]HOSSAINI H,MOUSSAVI G,FARROKHI M.The investigation of the LED-activated FeFNS-TiO2nanocatalyst for photocatalytic degradation and mineralization of organophosphate pesticides in water[J].Water Research,2014,59(4):130-144.
[45]ESKANDARIAN M R,CHOI H,FAZLI M,et al.Effect of UV-LEDwavelengths on direct photolytic and Ti O2,photocatalytic degradation of emerging contaminants in water[J].Chemical Engineering Journal,2016,300:414-422.
[46]KU Y,SHIU S J,WU H C.Decomposition of dimethyl phthalate in aqueous solution by UV-LED/Ti O2,process under periodic illumination[J].Journal of Photochemistry&Photobiology A Chemistry,2017,332:299-305.
[47]ESCUDERO C J,IGLESIAS O,DOMINGUEZ S,et al.Performance of electrochemical oxidation and photocatalysis in terms of kinetics and energy consumption.New insights into the p-cresol degradation[J].Journal of Environmental Management,2017,195:117-124.
[48]JALLOULI N,PASTRANA-MART魱NEZ L M,RIBEIRO A R,et al.Heterogeneous photocatalytic degradation of ibuprofen in ultrapure water,municipal and pharmaceutical industry wastewaters using a TiO2/UV-LED system[J].Chemical Engineering Journal,2018,334:976-984.
[49]ARLOS M J,LIANG R,HATAT-FRAILE M M,et al.Photocatalytic decomposition of selected estrogens and their estrogenic activity by UV-LED irradiated TiO2,immobilized on porous titanium sheets via thermal-chemical oxidation[J].Journal of Hazardous Materials,2016,318:541-550.
[2]DEWIL R,MANTZAVINOS D,POULIOS I,et al.New perspectives for advanced oxidation processes[J].Journal of Environmental Management,2017,195:93-99.
[3]GAO Z C,LIN Y L,XU B,et al.Degradation of acrylamide by the UV/chlorine advanced oxidation process[J].Chemosphere,2017,187:268-276.
[4]GLAZE W H,KANG J W.Advanced oxidation process.description of a kinetic model for the oxidation of hazardous materials in aqueous media with ozone and hydrogen peroxide[J].Industrial&Engineering Chemistry Research,1989,28(11):1580-1587.
[5]LEE M,MERLE T,RENTSCH D,et al.Abatement of polychoro-1,3-butadienes in aqueous solution by ozone,UV-photolysis,and advanced oxidation processes(O3/H2O2and UV/H2O2)[J].Environmental Science&Technology,2017,51(1):497-505.
[6]JIA P,ZHOU Y,ZHANG X,et al.Cyanobacterium removal and control of algal organic matter(AOM)release by UV/H2O2preoxidation enhanced Fe(II)coagulation[J].Water Research,2018,131(1):122-130.
[7]ZHU Y,WU M,GAO N,et al.Degradation of phenacetin by the UV/chlorine advanced oxidation process:Kinetics,pathways,and toxicity evaluation[J].Chemical Engineering Journal,2018,335:520-529.
[8]YI Y,PIGNATELLO J J,MA J,et al.Effect of matrix components on UV/H2O2,and UV/S2O82-,advanced oxidation processes for trace organic degradation in reverse osmosis brines from municipal wastewater reuse facilities[J].Water Research,2016,89:192-200.
[9]TAK S Y,KIM M K,LEE J E,et al.Kinetics and degradation mechanism of Anatoxin-a during in UV-C/H2O2reaction[J].Chemical Engineering Journal,2018,334:1016-1022.
[10]Chuang Y H,Parker K M,Mitch W A.Development of predictive models for the degradation of halogenated disinfection byproducts during the UV/H2O2Advanced Oxidation Process[J].Environmental Science&Technology,2016,50:11209-11217.
[11]ROZAS O,VIDAL C,BAEZA C,et al.Organic micropollutants(OMPs)in natural waters:Oxidation by UV/H2O2treatment and toxicity assessment[J].Water Research,2016,98:109-118.
[12]YAO H,SUN P,MINAKATA D,et al.Kinetics and modeling of degradation of ionophore antibiotics by UV and UV/H2O2[J].Environmental Science&Technology,2013,47(9):4581-4589.
[13]罗从伟,马军,江进,等UV/H2O2降解三氯生动力学及反应机理[J].哈尔滨工业大学学报,2017,49(2):26-31.
[14]JIN Q,WANG H,HU C,et al.Effects of NOM on the degradation of chloramphenicol by UV/H2O2and the characteristics of degradation products[J].Separation&Purification Technology,2018,191:108-115..
[15]罗从伟,马军,江进,等.UV/H2O2降解2,4,6-三氯苯甲醚动力学及产物研究[J].中国环境科学,2017,37(5):1831-1837.
[16]VELO-GALA I,PIRAN-MONTANO J A,RIVERA-UTRILLA J,et al.Advanced oxidation processes based on the use of UVC and simulated solar radiation to remove the antibiotic tinidazole from water[J].Chemical Engineering Journal,2017,323:606-617.
[17]TSIAPOU S S,TEMPLETON M R,GRAHAM N J,et al.Low pressure UV/H2O2treatment for the degradation of the pesticides metaldehyde,clopyralid and mecoprop-Kinetics and reaction product formation[J].Water Research,2016,91:285-294.
[18]ALMQUIST C,FYDA S,GODBY N,et al.An investigation on the use of ultraviolet light emitting diodes(UV LEDs)in a plug-flow reactor for water treatment[J].Environmental Progress&Sustainable Energy,2017,36:857-863.
[19]PARK J A,NAM H L,CHOI J W,et al.Oxidation of geosmin and2-methylisoborneol by the photo-fenton process:kinetics,degradation intermediates,and the removal of microcystin-LR and trihalomethane from Nak-Dong River water,South Korea[J].Chemical Engineering Journal,2017,313:345-354.
[20]GONZSALEZ G C,JULCOUR C,CHAUMAT H,et al.Degradation~of 2,4-dichlorophenoxyacetic acid by photolysis and photo Fenton oxidation[J].Journal of Environmental Chemical Engineering,2018,6:874-882.
[21]DAVIDIDOU K,MONTEAGUDO J M,CHATZISYMEON E,et al.Degradation and mineralization of antipyrine by UV-A LED photoFenton reaction intensified by ferrioxalate with addition of persulfate[J].Separation&Purification Technology,2017,172:227-235.
[22]BOURGIN M,BOROWSKA E,HELBING J,et al.Effect of operational and water quality parameters on conventional ozonation and the advanced oxidation process O3/H2O2:Kinetics of micropollutant abatement,transformation product and bromate formation in a surface water[J].Water Research,2017,122:234-245.
[23]杨子增.UV/O3降解水中磺胺嘧啶的效能和机理研究[D].哈尔滨:哈尔滨工业大学,2016.
[24]ARSLAN A,TOPKAYA E,BING魻L D,et al.Removal of anionic surfactant sodium dodecyl sulfate from aqueous solutions by O3/UV/H2O2,advanced oxidation process:Process optimization with response surface methodology approach[J].Sustainable Environment Research,2018,28:65-71.
[25]YANG Y,LU X,JIANG J,et al.Degradation of sulfamethoxazole by UV,UV/H2O2and UV/persulfate(PDS):Formation of oxidation products and effect of bicarbonate.[J].Water Research,2017,118:196-207.
[26]罗从伟.紫外/过硫酸盐高级氧化降解典型有机微污染物效能及作用机制[D].哈尔滨:哈尔滨工业大学,2017.
[27]HOU S,LING L,SHANG C,et al.Degradation kinetics and pathways of haloacetonitriles by the UV/persulfate process[J].Chemical Engineering Journal,2017,320:478-484.
[28]VERMA S,NAKAMURA S,SILLANP魧魧M.Application of UV-CLED activated PMS for the degradation of anatoxin-a[J].Chemical Engineering Journal,2016,284:122-129.
[29]TIAN J,WU C,YU H,et al.Applying ultraviolet/persulfate(UV/PS)pre-oxidation for controlling ultrafiltration membrane fouling by natural organic matter(NOM)in surface water[J].Water Research,2018,132:190-199.
[30]LU X,SHAO Y,GAO N,Et al.Investigation of clofibric acid removal by UV/persulfate and UV/chlorine processes:Kinetics and formation of disinfection byproducts during subsequent chlor(am)ination[J].Chemical Engineering Journal,2018,331:364-371.
[31]LUO C,JIANG J,MA J,et al.Oxidation of the odorous compound2,4,6-trichloroanisole by UV activated persulfate:Kinetics,products,and pathways[J].Water Research,2016,96:12-21.
[32]XIAO Y,ZHANG L,WEI Z,et al.Comparative evaluation of iodoacids removal by UV/persulfate and UV/H2O2,processes[J].Water Research,2016,102:629-639.
[33]WANG F,WANG W,YUAN S,et al.Comparison of UV/H2O2,and UV/PS processes for the degradation of thiamphenicol in aqueous solution[J].Journal of Photochemistry&Photobiology A Chemistry,2017,348:79-88.
[34]骆靖宇,李学艳,李青松,等.紫外活化过硫酸钠去除水体中的三氯卡班[J].中国环境科学,2017,37(9):3324-3331.
[35]GAO Z C,LIN Y L,XU B,et al.Degradation of acrylamide by the UV/chlorine advanced oxidation process[J].Chemosphere,2017,187:268-276.
[36]KONG X,JIN J,MA J,et al.Degradation of atrazine by UV/chlorine:Efficiency,influencing factors,and products[J].Water Research,2016,90:15-23.
[37]KIM T K,MOON B R,KIM T,et al.Degradation mechanisms of geosmin and 2-MIB during UV photolysis and UV/chlorine reactions[J].Chemosphere,2016,162:157-164.
[38]孙昕,张燚,史路肖,等.真空紫外/氯处理饮用水典型致嗅物质[J].环境科学,2017,38(4):1-9.
[39]KONG X,JIANG J,MA J,et al.Comparative investigation of X-ray contrast medium degradation by UV/chlorine and UV/H2O2[J].Chemosphere,2018,193:655-663.
[40]MATAFONOVA G,BATOEV V.Recent advances in application of UV light-emitting diodes for degrading organic pollutants in water through advanced oxidation processes:A review[J].Water Research,2018,132:177-189.
[41]AUTIN O,ROMELOT C,RUST L,et al.Evaluation of a UV-light emitting diodes unit for the removal of micropollutants in water for low energy advanced oxidation processes[J].Chemosphere,2013,92(6):745-751.
[42]CAI Q,HU J.Decomposition of sulfamethoxazole and trimethoprim by continuous UVA/LED/TiO2,photocatalysis:Decomposition pathways,residual antibacterial activity and toxicity[J].Journal of Hazardous Materials,2017,323:527-536.
[43]LI S,HU J.Photolytic and photocatalytic degradation of tetracycline:Effect of humic acid on degradation kinetics and mechanisms[J].Journal of Hazardous Materials,2016,318:134-144.
[44]HOSSAINI H,MOUSSAVI G,FARROKHI M.The investigation of the LED-activated FeFNS-TiO2nanocatalyst for photocatalytic degradation and mineralization of organophosphate pesticides in water[J].Water Research,2014,59(4):130-144.
[45]ESKANDARIAN M R,CHOI H,FAZLI M,et al.Effect of UV-LEDwavelengths on direct photolytic and Ti O2,photocatalytic degradation of emerging contaminants in water[J].Chemical Engineering Journal,2016,300:414-422.
[46]KU Y,SHIU S J,WU H C.Decomposition of dimethyl phthalate in aqueous solution by UV-LED/Ti O2,process under periodic illumination[J].Journal of Photochemistry&Photobiology A Chemistry,2017,332:299-305.
[47]ESCUDERO C J,IGLESIAS O,DOMINGUEZ S,et al.Performance of electrochemical oxidation and photocatalysis in terms of kinetics and energy consumption.New insights into the p-cresol degradation[J].Journal of Environmental Management,2017,195:117-124.
[48]JALLOULI N,PASTRANA-MART魱NEZ L M,RIBEIRO A R,et al.Heterogeneous photocatalytic degradation of ibuprofen in ultrapure water,municipal and pharmaceutical industry wastewaters using a TiO2/UV-LED system[J].Chemical Engineering Journal,2018,334:976-984.
[49]ARLOS M J,LIANG R,HATAT-FRAILE M M,et al.Photocatalytic decomposition of selected estrogens and their estrogenic activity by UV-LED irradiated TiO2,immobilized on porous titanium sheets via thermal-chemical oxidation[J].Journal of Hazardous Materials,2016,318:541-550.
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