用户名: 密码: 验证码:
钢中元素偏聚的研究现状及其发展趋势
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Research status and development trend of elemental segregation in steel
  • 作者:曹建春 ; 刘铖霖 ; 高鹏 ; 周晓龙 ; 周煌
  • 英文作者:CAO Jian-chun;LIU Cheng-lin;GAO Peng;ZHOU Xiao-long;ZHOU Huang;School of Materials Science and Engineering,Kunming University of Science and Technology;
  • 关键词:晶界偏聚 ; 非平衡偏聚 ; ; ; ;
  • 英文关键词:grain boundary segregation;;non-equilibrium segregation;;P;;S;;B;;Nb
  • 中文刊名:GANT
  • 英文刊名:Iron & Steel
  • 机构:昆明理工大学材料科学与工程学院;
  • 出版日期:2019-06-15
  • 出版单位:钢铁
  • 年:2019
  • 期:v.54
  • 基金:中信金属-CBMM铌钢研究与开发项目的基金支持和帮助
  • 语种:中文;
  • 页:GANT201906002
  • 页数:9
  • CN:06
  • ISSN:11-2118/TF
  • 分类号:17-25
摘要
固溶状态下,钢中合金元素会在晶界、缺陷等处优先出现偏聚现象,对钢材的组织和性能产生显著影响。由于元素在钢中的偏聚量小,不易观察,而且影响偏聚的因素很多,导致钢中元素偏聚的理论研究进展缓慢。为了揭示不同元素在钢中的偏聚机理,充分发挥钢中元素偏聚的积极作用,从偏聚类型出发,总结分析了元素偏聚的影响因素和控制手段,重点介绍了几种常见元素的偏聚现象,深入分析其偏聚量及位置对钢材性能的影响,同时还介绍了几种观察元素偏聚的手段。期望能为揭示钢中偏聚行为、发挥其作用提供参考,也为后续偏聚行为的研究提供一些参考。
        In the solid solution state,the alloying elements in the steel preferentially exhibit segregation at grain boundaries and defects,which have a significant effect on the microstructure and properties of the steel.Due to the small amount of segregation of elements in steel,it is difficult to observe,and there are many factors affecting segregation.The theoretical research on the segregation of elements in steel is slow.In order to reveal the segregation mechanism of different elements in steel and give full play to the positive effect of element segregation in steel,starting from the type of segregation,the influencing factors and control methods of element segregation were summarized,and several common elements were highlighted.The phenomenon of segregation and the influence of the amount of segregation and position on the properties of steel were also deeply analyzed.At the same time,several methods for observing the segregation of elements were also introduced.It is expected to reveal the segregation behavior in steel,and provide a reference for its role and some references for the study of subsequent segregation behavior.
引文
[1]张明义,杨坤,陈铮,等.晶界元素偏聚及其机理的研究进展[J].稀有金属材料与工程,2013,42(7):1531.(ZHANG Ming-yi,YANG Kun,CHEN Zheng,et al.Review of atomistic scale studies on solute segregation and its mechanism at grain boundary[J].Rare Metal Materials and Engineering,2013,42(7):1531.)
    [2]林文松.微量溶质元素在金属晶界的偏聚[J].热处理,2004(2):18.(LIN Wen-song.Segregation of solute elements on metal grain boundaries[J].Heat Treatment,2004(2):18.)
    [3] SONG S H,WU J,WENG L Q,et al.Phosphorus grain boundary segregation under different applied tensile stress levels in a Cr-Mo low alloy steel[J].Materials Letters,2010,64(7):849.
    [4]凌纯,姚智颖.结构钢的回火脆性综述[J].热加工工艺,2018(2):11.(LING Chun,YAO Zhi-ying.A summarize of tempering brittleness of structual steel[J].Hot Working Technology,2018(2):11.)
    [5]吴承建,汤晓丽.铈、钼和磷在钢中的晶界偏聚行为与高温回火脆性[J].钢铁,1991,26(12):31.(WU Cheng-jian,TANG Xiao-li.Grain boundary segregation of Ce,Mo and temper embrittlement of steel[J].Iron and steel,1991,26(12):31.)
    [6]张灶利,刘键,林清英,等.磷在钢回火脆性发展时的非平衡偏聚及钼的影响[J].钢铁研究学报,1999,11(5):26.(ZHANG Zao-li,LIU Jian,LIN Qing-ying,et al.Investigation on non-equilibrium segregation of P and influence of Mo for steel having temper embrittlement[J].Journal of Iron and Steel Research,1999,11(5):26.)
    [7] Mclean D,Maradudin A.Grain boundaries in metals[J].Physics Today,1958,11(7):35.
    [8] Guttmann M.Equilibrium segregation in a ternary solution:A model for temper embrittlement[J].Surface Science,1975,53(1):213.
    [9] Ogura T,Makino A,Masumoto T.A grain boundary etching method for the analysis of intergranular P-segregation in ironbased alloys[J]. Metallurgical Transactions A,1984,15(8):1563.
    [10] Guttmann M.The link between equilibrium segregation and precipitation in ternary solutions exhibiting temper embrittlement[J].Metal Science Journal,1976,10(10):337.
    [11]吴平,贺信莱.晶界非平衡偏聚研究的回顾与展望[J].金属学报,1999(10):1009.(WU Ping,HE Xin-lai.Grand boundary non-equilibrium segregation:Retrospect/prospect[J].Acta Metallrugica Sinica,1999(10):1009.)
    [12] Hanneman R E,Anthony T R.Effects of non-equilibrium segregation on near-surface diffusion[J].Acta Metallurgica,1969,17(9):1133.
    [13] Anthony T R.Solute segregation in vacancy gradients generated by sintering and temperature changes[J].Acta Metallurgica,1969,17(5):603.
    [14] Aust K T.Lattice Defects in Quenched Metals[M].New York:Academic Press,1965.
    [15]徐庭栋,郑磊.非平衡晶界偏聚和晶间脆性断裂研究的进展[J].材料导报,2004,18(1):1.(XU Ting-dong,ZHENG Lei.Progress in study of non-equilibrium grain boundary segregation and embrittlement[J]. Materials Review,2004,18(1):1.)
    [16]杨尚林,李莉,田无边,等.12Cr1 MoV钢连续冷却过程中P的晶界偏聚[J].金属热处理学报,2003(4):33.(YANG Shang-lin,LI Li,TIAN Wu-bian,et al.Segregation of P at grain-boundary of 12Cr1MoV steel in continuous cooling process[J].Transactions of Metal Heat Treatment,2003(4):33.)
    [17]朱微微.含P高强IF钢中P的偏聚及析出行为[D].武汉:武汉科技大学,2014.(ZHU Wei-wei.Segregation and Precipitation Behaviors of Phosphorus and Phosphides in Phosphorus-bearing Interstitial Free High Strength Steel[D].Wuhan:Wuhan University of Science and Technology,2014.)
    [18]张海龙,高怡斐,徐庭栋.钢的晶界区弹性模量计算[J].钢铁研究学报,2017,29(4):329.(ZHANG Hai-long,GAO Yi-fei,XU Ting-dong.Computation of grain-boundary elastic modulus of steel[J].Journal of Iron and Steel Research,2017,29(4):329.)
    [19]马植甄,万兰凤.Gleeble模拟热轧工艺对磷非平衡晶界偏聚的影响[J].钢铁,2016,51(2):67.(MA Zhi-zhen,WAN Lanfeng.Influence of hot rolling process on non-equilibrium grain boundary segregation of phosphorus by Gleeble thermal simulation[J].Iron and Steel,2016,51(2):67.)
    [20]赵守田,吴平,陈森,等.超低碳微合金钢中硼的偏聚[J].材料工程,2009(4):6.(ZHAO Shou-tian,WU Ping,CHEN Sen,et al.Segregation of boron in ultra low-carbon microalloy steels[J].Journal of Materials Engineering,2009(4):6.)
    [21]王凯,司红,徐庭栋.晶间脆性断裂的非平衡偏聚机理研究[J].钢铁研究学报,2009,21(12):1.(WANG Kai,SI Hong,XU Ting-dong.Nonequilibrium grain boundary segregation mechanism of intergranular embrittlement[J].Journal of Iron and Steel Research,2009,21(12):1.)
    [22]杨小平.钢中残余铜元素对钢热加工性能的影响研究[D].贵阳:贵州大学,2009.(YANG Xiao-ping.Study on the Influence of Residual Copper in Steel to the Hot-Working Performance of Steel[D].Guiyang:Guizhou University,2009.)
    [23]徐野威.杂质元素磷及硫对T/P92铁素体耐热钢高温塑性的影响[D].哈尔滨:哈尔滨工业大学,2012.(XU Ye-wei.Effect of Phosphorus and Sulphur on High Temperature Ductility of T/P92Ferritic Heat Resistant Steel[D].Harbin:Harbin Institute of Technology,2012.)
    [24]张明义,杨坤,陈铮,等.晶界元素偏聚及其机理的研究进展[J].稀有金属材料与工程,2013(7):1531.(ZHANG Mingyi,YANG Kun,CHEN Zheng,et al.Review of atomistic scale studies on solute segregation and its mechanism at grain boundary[J].Rare Metal Materials and Engineering,2013(7):1531.)
    [25]郑磊,徐庭栋,邓群,等.高温合金GH4169(Inconel 718)中磷晶界偏聚特性的实验研究[J].金属学报,2007(8):893.(ZHENG Lei,XU Ting-dong,DENG Qun,et al.Experimental study of the characteristic of phosphorous segregation at grain boundary in superalloy GH4169(inconel718)[J].Acta Metallurgica Sinica,2007(8):893.)
    [26] PING D H,GU Y F,CUI C Y,et al.Grain boundary segregation in a Ni-Fe-based(Alloy 718)superalloy[J].Materials Science and Engineering A,2007,456(1/2):99.
    [27] WANG K,SI H,YANG C,et al.Non-equilibrium grainboundary segregation of phosphorus in an Ni-Cr steel[J].Heat Treatment of Metals,2011,65(11):1639.
    [28]徐庭栋,王凯,邵冲.奥氏体不锈钢晶间腐蚀脆性的非平衡晶界偏聚机理[C]//第八届(2011)中国钢铁年会论文集(大会报告与分会场特邀报告).北京:中国金属学会,2011:5.(XU Ting-dong,WANG Kai,SHAO Chong.A new mechanism of intergranular corrosion embrittlement of 304stainless steel based on non-equilibrium grain-boundary segregation[C]//Proceedings of the 8th(2011)China Iron and Steel Annual Conference(Special Report of the Conference Report and Session).Beijing:The Chinese Society for Metals,2011:5.)
    [29]武建.2.25Cr1Mo钢中磷的平衡及应力引起的非平衡晶界偏聚[D].哈尔滨:哈尔滨工业大学,2010.(WU Jian.Equilibrium and Stress-Induced Non-Equilibrium Grain Boundary Segregations of Phosphorus in a 2.25Cr1Mo Steel[D].Harbin:Harbin Institute of Technology,2010.)
    [30]张喜亮,刘涛,崔国华,等.2.25Cr-1Mo钢后续热处理中的磷偏聚行为[J].材料工程,2014(10):59.(ZHANG Xi-liang,LIU Tao,CUI Guo-hua,et al.Segregation behavior of phosphorus for 2.25Cr-1Mo steel at subsequent heat treatment process[J].Journal of Materials Engineering,2014(10):59.)
    [31]万兰凤,马植甄.磷元素的非平衡晶界偏聚对A690M海洋环境用钢耐海水腐蚀性能的影响[J].腐蚀与防护,2017,38(10):747.(WAN Lan-feng,MA Zhi-zhen.Influence of nonequilibrium grain boundary segregation of phosphorus on corrosion resistance of marine steel A690Min seawater[J].Corrosion and Protection,2017,38(10):747.)
    [32]于洋,惠亚军,王畅,等.高强IF钢第二相粒子的应变诱导析出行为[J].中国冶金,2018,28(7):13.(YU Yang,HUI Yajun,WANG Chang,et al.Strain-induced precipitation behavior of second phase particles in high strength IF steel[J].China Metallurgy,2018,28(7):13.)
    [33] WANG Kai,SI Hong,YANG Chun,et al.Nonequilibrium grain boundary segregation of phosphorus in Ni-Cr-Fe superalloy[J].Journal of Iron and Steel Research,International,2011,18(1):61.
    [34]刘珍君,于鸿垚,王凯,等.不锈钢热塑性降低的非平衡偏聚机理[J].钢铁研究学报,2015,27(4):42.(LIU Zhen-jun,YU Hong-yao,WANG Kai,et al.Non-equilibrium grain boundary segregation mechanism for reduction of hot ductility of stainless steel[J].Journal of Iron and Steel Research,2015,27(4):42.)
    [35]郭爱民,袁泽喜,黄静,等.微量磷及硼的晶界偏聚及其对热塑性的影响[C]//2005年全国计算材料、模拟与图像分析学术会议论文集.秦皇岛:中国金属学会材料科学分会,2005:9.(GUO Ai-min,YUAN Ze-xi,HUANG Jing,et al.Grain boundary segregation of trace phosphorus and boron and its effect on thermoplasticity[C]//2005National Computing Materials,Simulation Proceedings of the Conference on Image Analysis and Conference. Qinhuangdao:Materials Science Branch of The Chinese Society for Metals,2005:9.)
    [36] LI L,LIU E B,LI Q F,et al.Non-equilibrium grain boundary cosegregation of Mo and P[J].Applied Surface Science,2006,252(11):3989.
    [37] WU J,SONG S H,WENG L Q,et al.An Auger electron spectroscopy study of phosphorus and molybdenum grain boundary segregation in a 2.25Cr1Mo steel[J].Materials Characterization,2008,59(3):261.
    [38]杨金侠,李金国,金涛,等.P在DD6单晶高温合金中的存在形态和作用[J].稀有金属材料与工程,2016(5):1253.(YANG Jin-xia,LI Jin-guo,JIN Tao,et al.Distribution and roles of P in DD6alloy[J].Rare Metal Materials and Engineering,2016(5):1253.)
    [39]贺信莱,褚幼义,柯俊.硼钢淬透性与硼偏聚[J].北京钢铁学院学报,1983(1):155.(HE Xin-lai,CHU You-yi,KE Jun.The hardenability of boron steel and boron segregation[J].Journal of University of Science and Technology Beijing,1983(1):155.)
    [40]于庆波,张仲波,李子林,等.Nb对低碳钢奥氏体晶粒长大的影响[J].钢铁,2006,41(12):70.(YU Qing-bo,ZHANG Zhong-bo,LI Zi-lin,et al.Effect of Nb on austenite grain growth of low carbon steel[J].Iron and Steel,2006,41(12):70.)
    [41]于彦冲,陈伟庆,郑宏光.硼对Fe-36Ni因瓦合金热塑性的影响[J].金属热处理,2014,39(9):117.(YU Yan-chong,CHEN Wei-qing,ZHENG Hong-guang.Effect of boron on hot ductility of Fe-36Ni invar alloy[J].Heat Treatment of Metals,2014,39(9):117.)
    [42]赵海强.微量元素B和P对GH2984组织和性能的影响[D].沈阳:沈阳理工大学,2013.(ZHAO Hai-qiang.Effects of B and P on Microstructure and Properties of GH2984Alloy[D].Shenyang:Shenyang Ligong University,2013.)
    [43]张崴,杨善武,贺信莱.硼偏聚对超低碳微合金钢腐蚀行为的影响[J].材料热处理学报,2009(1):45.(ZHANG Wei,YANG Shan-wu,HE Xin-lai.Influence of boron segregation on corrosion behavior of weathering steel[J].Transactions of Materials and Heat Treatment,2009(1):45.)
    [44]罗迪,邢国华,邹惠良.微量硫对高速钢热塑性的影响[J].金属学报,1983(4):117.(LUO Di,XING Guo-hua,ZOU Hui-liang.Effect of trace sulphur on hot plasticity of high speed steels[J].Acta Metallrugica Sinica,1983(4):117.)
    [45] WANG K,WANG M,SI H,et al.Critical time for non-equilibrium grain boundary segregation of phosphorus in 304L stainless steel[J]. Materials Science and Engineering A,2008,485(1/2):347.
    [46] WANG K,XU T D,SHAO C,et al.Nonequilibrium grain boundary segregation of sulfur and its effect on intergranular corrosion for 304stainless steel[J].Journal of Iron and Steel Research,International,2011,18(6):61.
    [47]王凯,刘浏,徐庭栋,等.2.25Cr1Mo合金高温低塑性的非平衡偏聚机理研究[J].金属学报,2017(3):345.(WANG Kai,LIU Liu,XU Ting-dong,et al.Mechanism study on hot ductility of 2.25Cr1Mo alloy based on non-equilibrium grainboundary segregation[J].Acta Metallurgica Sinica,2017(3):345.)
    [48]李晓源,孙颖.硫、磷晶界偏聚对40CrNi2Mo钢冲击性能的影响[J].金属热处理,2013(4):16.(LI Xiao-yuan,SUN Ying.Influence of sulphur and phosphorus grain-boundary segregation on impact property for 40CrNi2Mo steel[J].Heat Treatment of Metals,2013(4):16.)
    [49]李梦龙,王福明,孟庆勇,等.硫含量对中碳非调质钢中硫化物及组织的影响[J].工程科学学报,2015(2):168.(LI Meng-long,WANG Fu-ming,MENG Qing-yong,et al.Effect of sulfur content on sulfide inclusions and microstructure in medium carbon non-quenched and tempered steel[J].Chinese Journal of Engineering,2015(2):168.)
    [50] CAO J C,LIU Q Y,YONG Q L,et al.Effect of niobium on isothermal transformation of austenite to ferrite in HSLA lowcarbon steel[J].Journal of Iron and Steel Research,International,2007,14(3):52.
    [51] YONG Q L,ZHANG Z Y,SUN X J,et al.Effect of dissolved niobium on eutectoid transformation behavior[J].Journal of Iron and Steel Research,International,2017,24(9):973.
    [52] ZHANG Z Y,YONG Q L,SUN X J,et al.Microstructure and mechanical properties of precipitation strengthened fire resistant steel containing high Nb and low Mo[J].Journal of Iron and Steel Research,International,2015,22(4):337.
    [53]吴晓东,陈瑞泷,掌道新,等.含铌60Si2CrVAT弹簧钢凝固过程铌偏聚的研究[J].铸造,2013,62(11):1111.(WU Xiaodong,CHEN Rui-long,ZHANG Dao-xin,et al.Study on the niobium segregation of 60Si2CrVAT spring steel with niobium during solidification[J].Foundry,2013,62(11):1111.)
    [54] SONG S H,ZHAO Y,SI H.Non-equilibrium phosphorus grain boundary segregation and its effect on embrittlement in a niobium-stabilized interstitial-free steel[J].Materials Letters,2015,140:20.
    [55]董建新,张麦仓,曾燕屏.含铌高温合金液相中铌偏聚行为[J].工程科学学报,2005,27(2):71.(DONG Jian-xin,ZHANG Mai-cang,ZENG Yan-ping.Calculation of Nb segregation behavior in liquid phase for Nb-rich superalloys[J].Chinese Journal of Engineering,2005,27(2):71.)
    [56] Takahashi J,Kawakami K,Hamada J I,et al.Direct observation of niobium segregation to dislocations in steel[J].Acta Materialia,2016,107:415.
    [57]曹建春,雍岐龙,刘清友,等.含铌钼钢中微合金碳氮化物沉淀析出及其强化机制[J].材料热处理学报,2006,27(5):51.(CAO Jian-chun,YONG Qi-long,LIU Qing-you,et al.Precipitation of microalloyed carbonitride and its strengthening mechanism in low carbon steels containing Nb and Mo[J].Transactions of Materials and Heat Treatment,2006,27(5):51.)
    [58]李鸿美,曹建春,孙力军,等.含铌微合金钢碳氮化物析出行为研究的现状及发展[J].材料导报,2010,24(17):84.(LI Hong-mei,CAO Jian-chun,SUN Li-jun,et al.Current situation and development of Nb microalloyed steel carbonitride precipitation behavior[J]. Materials Review,2010,24(17):84.)
    [59]黄小莉.残留元素As、Sn、Sb的晶界偏聚对连铸钢热塑性的影响[D].武汉:武汉科技大学,2006.(HUANG Xiao-li.Influence of Tramp Elements Arsenic,Tin and Antimony Segregation to Grain Boundary on Hot Ductility of CC Steels[D].Wuhan:Wuhan University of Science and Technology,2006.)
    [60]贾涓.Sn的晶界偏聚行为与低碳钢的热塑性[D].武汉:武汉科技大学,2003.(JIA Juan.Tin Segregation Behavior to Grain-Boundary and the Hot Ductility of Low Carbon Steel[D].Wuhan:Wuhan University of Science and Technology,2003.)
    [61]赵秉军,王继饶,杜云慧,等.砷,锡,锑对30CrMnSiA钢回火脆性的影响[J].金属热处理学报,1995(1):13.(ZHAO Bing-jun,WANG Ji-rao,DU Yun-hui,et al.Effect of As,Sn and Sb on temper brittleness of 30CrMnSiA steel[J].Transactions of Metal Heat Treatment,1995(1):13.)
    [62]郭巧能.晶界偏聚与材料脆断间关系的理论研究进展[J].材料导报,2002,16(3):15.(GUO Qiao-neng.Advances in theoretical study of relationship between grain-boundary segregation and embrittlement fracture[J]. Materials Review,2002,16(3):15.)
    [63]赵禹.无间隙原子钢中磷的晶界偏聚及其对材料脆性的影响[D].哈尔滨:哈尔滨工业大学,2014.(ZHAO Yu.Grain Boundary Segregation of Phosphorus and Its Influence on Brittleness in Interstitial Free Steel[D].Harbin:Harbin Institute of Technology,2014.)

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700