污水中十二烷基苯磺酸钠处理的新方法研究进展
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摘要
介绍了十二烷基苯磺酸钠的应用情况,综述了含十二烷基苯磺酸钠污水的处理新方法,如生物降解法、物理法、吸附法、超声波法、膜分离法、微电解法和催化氧化法等,并进行了对比。阐述了各方法的应用现状与优缺点,分析了各种技术在科研阶段或应用过程中所存在的问题。对含十二烷基苯磺酸钠污水处理技术的发展进行了展望,认为催化氧化法降解十二烷基苯磺酸钠具有广阔的应用前景,其发展趋势是将多种催化氧化技术相结合,研发出可工业化的反应器和易于操作的废水处理工艺。
The application of sodium dodecyl benzene sulfonate( SDBS) is presented simply. The new methods of treating SDBS in sewage are reviewed and compared including biological degradation method,physical method,adsorption method,ultrasonic method,membrane separation method,micro-electrolysis method and catalytic oxidation method. The application status and merit and demerit of each method are expounded,and the existing problems of various technologies in study and application are analyzed. The development direction of treatment methods of SDBS is also prospected. It is pointed out that degradation of SDBS by catalytic oxidation shows wide application prospect,whose development trend is to combine various catalytic oxidation technologies and study commercial reactor and easy-to-control process for SDBS waste water treatment.
The application of sodium dodecyl benzene sulfonate( SDBS) is presented simply. The new methods of treating SDBS in sewage are reviewed and compared including biological degradation method,physical method,adsorption method,ultrasonic method,membrane separation method,micro-electrolysis method and catalytic oxidation method. The application status and merit and demerit of each method are expounded,and the existing problems of various technologies in study and application are analyzed. The development direction of treatment methods of SDBS is also prospected. It is pointed out that degradation of SDBS by catalytic oxidation shows wide application prospect,whose development trend is to combine various catalytic oxidation technologies and study commercial reactor and easy-to-control process for SDBS waste water treatment.
引文
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[2]纪桂霞,杨继柏,周步轩,等.ABR与UBAF组合工艺处理合成洗涤剂废水试验研究[J].水处理技术,2014,40(1):84-87.
[3]OTHMAN M Z,DING L Q,etal.Effect of anionic and non-ionic surfactants on activated sludge oxygen uptake rate and nitrification[J].International Journal of Civil and Environmental Engineering,2010,2(4):196-202.
[4]张晶,印春生,房建孟.十二烷基苯磺酸钠(SDBS)及消油剂对刺参幼参的急性毒性[J].生态毒理学报,2013,8(6):917-922.
[5]赵红梅,赵文岩,胡瑞生,表面活性剂对链霉素在内蒙古牧区土壤中吸附解吸的影响[J].生态学报,2014,34(16):4549-4554.
[6]张学佳,纪巍,康志军,等.烷基苯磺酸钠在环境中自然降解的研究进展[J].石化技术与应用,2008,26(5):486-491.
[7]董德明,李明,孙家倩,等.光照下自然水体生物膜产生H2O2及其对十二烷基苯磺酸钠降解的影响[J].高等学校化学学报,2014,35(6):1247-1251.
[8]李仓敏.泡沫分离法除去废水中的表面活性剂[D].天津:天津大学,2010.
[9]董红星.泡沫分离水中微量LAS及宏观动力学研究[D].哈尔滨:哈尔滨工程大学,2007.
[10]李青娟.泡沫分离法分离水中表面活性剂的研究[D].天津:天津大学,2008.
[11]王中平,蒋林时,邱峰,等.复合絮凝剂处理烷基苯磺酸盐废水研究[J].石油化工高等学校学报,2002,15(4):21-27.
[12]任刚,崔福义,林涛,等.常规混成沉淡工艺对阴离子表面活性剂的去除研究[J].给水排水,2004,30(7):1-6.
[13]董红星,李占双,李凯峰,等.泡沫分离法除去污水中十二烷基苯磺酸钠的研究[J].应用科技,2003,30(3):48-50.
[14]夏红云,贺敏.废水中的直链烷基苯磺酸钠的混凝气浮处理研究[J].日用化学工业,2009,39(1):29-31.
[15]ZHANG M N,LIAO X P,SHI B.Adsorbption of surfactants on chromum leather waste[J].Journal of the Society of Leather Technologists and Chemists,2005,90:1-6.
[16]HAO X L,WANG M H,ZHANG H Z,et al.Experimental Study on the Degradation of SDBS Using a Small Photocatalytic Filter[J].Advances in Environmental Protection,2013(3):36-39.
[17]ROZZI A,ANTONELLI M,ARCARI M.Membrane treatment of secondary textile effluents for direct reuse[J].Wat Sci Tech,1999,40(4/5):409-416.
[18]向丽君.低强度超声波干预固定化细胞降解直链十二烷基苯磺酸钠的研究[D].重庆:重庆大学,2014.
[19]王效承,许慧平,王玉芬,等.水中烷基苯磺酸钠的催化氧化处理研究[J].环境科学,1993,14(6):43-46.
[20]魏明红,董入源,黄玉明.纳米四氧化三铁粒子催化过氧化氢氧化降解十二烷基苯磺酸钠[J].西南大学学报(自然科学报),2014,36(3):137-140.
[21]单体兴,高先池,杨桂朋.水体系中十二烷基苯磺酸钠的光化学氧化动力学研究[J].海洋环境科学,2010,29(3):387-391.
[22]邵颖,薛宽宏,何春建,等.Ti O2纳米管对十二烷基苯磺酸钠的光催化降解[J].化学世界,2003(4):174-178.
[23]陈玉峰,陈日耀,郑曦,等.电生成Fenton试剂及其对十二烷基苯磺酸钠降解的研究[J].环境污染治理技术与设备,2004,5(11):42-46.