核工业含铀废水处理技术进展
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摘要
随着核能技术与核能应用的迅速发展,作为核工业中至关重要的原料铀与其化合物在不断地消耗,从而产生了大量不同类型的含铀放射性废水。如何深度高效地处理含铀废水成为核能技术发展中最为关键的问题。简述了现行含铀废水的处理技术及其特征,并认为多重技术的协同作用将是未来含铀废水处理技术的发展趋势。
With the rapid development of nuclear technology,raw uranium and its compounds,as the most important raw materials in nuclear industry, are consumed continuously,resulting in a large number of different types of radioactive uranium-bearing wastewater. Moreover, people pay more and more attention to the ecological environment and their personal health. How to treat uranium-bearing wastewater efficiently and deeply becomes the most critical issues in the development of nuclear technology. This paper briefly describes the current treatment technology of uraniumbearing wastewater and its characteristics. And,it is considered that the synergy of multiple technology will be the future development trend towards the treatment technology of uranium-bearing wastewater.
With the rapid development of nuclear technology,raw uranium and its compounds,as the most important raw materials in nuclear industry, are consumed continuously,resulting in a large number of different types of radioactive uranium-bearing wastewater. Moreover, people pay more and more attention to the ecological environment and their personal health. How to treat uranium-bearing wastewater efficiently and deeply becomes the most critical issues in the development of nuclear technology. This paper briefly describes the current treatment technology of uraniumbearing wastewater and its characteristics. And,it is considered that the synergy of multiple technology will be the future development trend towards the treatment technology of uranium-bearing wastewater.
引文
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[2]柏云.含铀废水微生物处理方法研究[D].成都:四川大学,2003.
[3]汪爱河,胡凯光. ZVI-SRB协同处理铀废水的实验研究[D].衡阳:南华大学,2008.
[4]刘岳林,谢水波. Cu2+对硫酸盐还原菌处理低浓度含铀废水的影响与机理实验研究[D].衡阳:南华大学,2011.
[5]林莹,高柏,李元锋.核工业低浓度含铀废水处理技术进展[J].山东化工,2009,38(3):35-38.
[6]路艳,汪兆金,张寅杰,等.浅谈含铀废水处理技术[J].甘肃科技纵横,2014,43(6):33-36.
[7]罗明标,刘淑娟,余亨华.氢氧化镁处理含铀放射性废水的研究[J].水处理技术,2002,28(5):274-277.
[8]任俊树,牟涛,杨胜亚,等.絮凝沉淀处理含盐量较高的铀、钚低放废水[J].核化学与放射化学,2008,30(4):201-205.
[9]张汉铭.内电解工艺在废水处理中的研究进展[J].广东化工,2010,37(9):118-119.
[10] Bhalara P D,Punetha D,Balasubramanian K,et al. A review of potential remediation techniques for uranium(Ⅵ)ion retrieval from contaminated aqueous environment[J]. Journal of Environmental Chemical Engineering,2014,2(3):1621-1634.
[11]赵素芬,史梦洁,安小刚,等.零价铁处理含铀废水的试验研究[J].工业水处理,2011,31(7):71-73.
[12]万小刚,杨胜亚.纳米级零价铁处理含铀废水初步实验研究[J].工业水处理,2012,32(3):42-44.
[13] Zhu K,Chen C,Xu M,et al. In situ carbothermal reduction synthesis of Fe nanocrystals embedded into N-doped carbon nanospheres for highly efficient U(Ⅵ)adsorption and reduction[J]. Chemical Engineering Journal,2018,331:395-405.
[14]余丽胜,李晓霞,焦纬洲,等.超声协同Fenton法处理有机废水的研究进展[J].化工环保,2017,37(1):38-42.
[15] Li J,Zhang L,Peng J,et al. Removal of uranium from uranium plant wastewater using zero-valent iron in an ultrasonic field[J]. Nuclear Engineering&Technology,2016,48(3):744-750.
[16] Barton C S,Stewart D I,Morris K,et al. Performance of three resinbased materials for treating uranium-contaminated groundwater within a PRB[J]. Journal of Hazardous Materials,2004,116(3):191-204.
[17] Simon F G,Biermann V. Groundwater remediation using permeable reactive barriers[J]. Land Contamination&Reclamation,2007,15(1):31-39.
[18]李绪忠,王水云.用生物活性渗滤墙技术处理铀尾矿地下水[J].铀矿冶,2010,29(3):149-152.
[19]李乐乐,张卫民.渗透反应墙技术处理铀尾矿库渗漏水的研究现状[J].环境工程,2016,34(1):168-172.
[20]张小燕,张叶.放射性废水处理技术研究进展[M].抚州:东华理工大学,2010,29(3):153-156.
[21] Decker D J,Folens K,Clercq J D,et al. Ship-in-a-bottle CMPO in MIL-101(Cr)for selective uranium recovery from aqueous streams through adsorption[J]. Journal of Hazardous Materials,2017,335:1-9.
[22] Chen B,Wang J,Kong L,et al. Adsorption of uranium from uranium mine contaminated water using phosphate rock apatite(PRA):Isotherm,kinetic and characterization studies[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,520:612-621.
[23]左天明,左魏铭,李金莲.放射性废水处理技术研究进展[J].四川地质学报,2015,35(3):473-475.
[24] Wang X,Liu Q,Liu J,et al. 3D self-assembly polyethyleneimine modified graphene oxide hydrogel for the extraction of uranium from aqueous solution[J]. Applied Surface Science,2017,426:1063-1074.
[25] Torkabad M G,Keshtkar A R,Safdari S J. Comparison of polyethersulfone and polyamide nanofiltration membranes for uranium removal from aqueous solution[J]. Progress in Nuclear Energy,2017,94:93-100.
[26] Roach J D,Zapien J H. Inorganic ligand-modified,colloid-enhanced ultrafiltration:A novel method for removing uranium from aqueous solution[J].Water Research,2009,43(18):4751-4759.
[27] Shen J,Schafer A. Removal of fluoride and uranium by nanofiltration and reverse osmosis:A review[J]. Chemosphere,2014,117(1):679-691.
[28]汪萍,吕彩霞,盛青,等.含铀废水处理技术的研究进展[J].现代化工,2016(12):23-27.
[29]胡鄂明,张皖桂,王清良,等.离子交换树脂对铀的静态和动态吸附行为研究[J].南华大学学报(自然科学版),2015(2):42-46.
[30] Rahmati A,Ghaemi A,Samadfam M. Kinetic and thermodynamic studies of uranium(Ⅵ)adsorption using Amberlite IRA-910 resin[J]. Annals of Nuclear Energy,2012,39(1):42-48.
[31]万小岗,王东文.四钛酸钾晶须处理含铀废水实验研究[J].环境科学与技术,2007,30(10):67-70.
[32]平爱东,罗明标,刘建亮,等. D231强碱性环氧系阴离子交换树脂吸附铀性能研究[J].东华理工大学学报(自然科学版),2013,36(1):69-75.
[33]李建华,王红英,程威,等.离子交换纤维处理含铀矿井水[J].铀矿冶,2012,31(2):100-102.
[34]黄崇元,李伟才,张玉泰,等.伊宁铀矿硝酸根废水自然蒸发处理可行性探讨[J].铀矿冶,2000,19(4):243-249.
[35]李冠华,张超,何广昌.低放射性废水蒸发处理及反渗透处理比选分析[J].科技视界,2016(7):132-132.
[36]鄢枭,杨雪峰,车建业,等.处理低水平放射性废液热泵蒸发技术的工程应用研究[C]∥中国核科学技术进展报告. 2011.
[37] Zarrougui R,Mdimagh R,Raouafi N. Highly efficient extraction and selective separation of uranium(Ⅵ)from transition metals using new class of undiluted ionic liquids based on H-phosphonate anions[J]. Journal of Hazardous Materials,2017,342:464-476.
[38] Chen M,Li Z,Li J,et al. The extraction of uranium using graphene aerogel loading organic solution[J]. Talanta,2017,166:284-291.
[39] Khayambashi A,Wang X,Wei Y. Solid phase extraction of uranium(Ⅵ)from phosphoric acid medium using macroporous silica-based D2EHPA-TOPO impregnated polymeric adsorbent[J]. Hydrometallurgy,2016,164:90-96.
[40]张露,刘峙嵘.微生物法处理低浓度含铀废水研究[J].环境工程,2017,35(12):36-40.
[41] Yi Z J,Yao J,Chen H L,et al. Uranium biosorption from aqueous solution onto Eichhornia crassipes[J]. Journal of Environmental Radioactivity,2016,154:43-51.
[42] Zheng X Y,Wang X Y,Shen Y H,et al. Biosorption and biomineralization of uranium(Ⅵ)by Saccharomyces cerevisiae-Crystal formation of chernikovite[J]. Chemosphere,2017,175:161-169.
[43]黄德娟,朱业安,余月,等.铀污染环境治理中的植物修复研究[J].铀矿冶,2012,31(4):202-206.
[44]杨晶,谢水波,王清良,等.微生物吸附铀的机理研究现状[J].铀矿冶,2006,25(4):192-195.
[45] Willscher S, Mirgorodsky D, Jablonski L, et al. Field scale phytoremediation experiments on a heavy metal and uranium contaminated site,and further utilization of the plant residues[J]. Hydrometallurgy,2013,131/132:46-53.
[46] Jagetiya B,Sharma A. Optimization of chelators to enhance uranium uptake from tailings for phytoremediation[J]. Chemosphere,2013,91(5):692-696.
[2]柏云.含铀废水微生物处理方法研究[D].成都:四川大学,2003.
[3]汪爱河,胡凯光. ZVI-SRB协同处理铀废水的实验研究[D].衡阳:南华大学,2008.
[4]刘岳林,谢水波. Cu2+对硫酸盐还原菌处理低浓度含铀废水的影响与机理实验研究[D].衡阳:南华大学,2011.
[5]林莹,高柏,李元锋.核工业低浓度含铀废水处理技术进展[J].山东化工,2009,38(3):35-38.
[6]路艳,汪兆金,张寅杰,等.浅谈含铀废水处理技术[J].甘肃科技纵横,2014,43(6):33-36.
[7]罗明标,刘淑娟,余亨华.氢氧化镁处理含铀放射性废水的研究[J].水处理技术,2002,28(5):274-277.
[8]任俊树,牟涛,杨胜亚,等.絮凝沉淀处理含盐量较高的铀、钚低放废水[J].核化学与放射化学,2008,30(4):201-205.
[9]张汉铭.内电解工艺在废水处理中的研究进展[J].广东化工,2010,37(9):118-119.
[10] Bhalara P D,Punetha D,Balasubramanian K,et al. A review of potential remediation techniques for uranium(Ⅵ)ion retrieval from contaminated aqueous environment[J]. Journal of Environmental Chemical Engineering,2014,2(3):1621-1634.
[11]赵素芬,史梦洁,安小刚,等.零价铁处理含铀废水的试验研究[J].工业水处理,2011,31(7):71-73.
[12]万小刚,杨胜亚.纳米级零价铁处理含铀废水初步实验研究[J].工业水处理,2012,32(3):42-44.
[13] Zhu K,Chen C,Xu M,et al. In situ carbothermal reduction synthesis of Fe nanocrystals embedded into N-doped carbon nanospheres for highly efficient U(Ⅵ)adsorption and reduction[J]. Chemical Engineering Journal,2018,331:395-405.
[14]余丽胜,李晓霞,焦纬洲,等.超声协同Fenton法处理有机废水的研究进展[J].化工环保,2017,37(1):38-42.
[15] Li J,Zhang L,Peng J,et al. Removal of uranium from uranium plant wastewater using zero-valent iron in an ultrasonic field[J]. Nuclear Engineering&Technology,2016,48(3):744-750.
[16] Barton C S,Stewart D I,Morris K,et al. Performance of three resinbased materials for treating uranium-contaminated groundwater within a PRB[J]. Journal of Hazardous Materials,2004,116(3):191-204.
[17] Simon F G,Biermann V. Groundwater remediation using permeable reactive barriers[J]. Land Contamination&Reclamation,2007,15(1):31-39.
[18]李绪忠,王水云.用生物活性渗滤墙技术处理铀尾矿地下水[J].铀矿冶,2010,29(3):149-152.
[19]李乐乐,张卫民.渗透反应墙技术处理铀尾矿库渗漏水的研究现状[J].环境工程,2016,34(1):168-172.
[20]张小燕,张叶.放射性废水处理技术研究进展[M].抚州:东华理工大学,2010,29(3):153-156.
[21] Decker D J,Folens K,Clercq J D,et al. Ship-in-a-bottle CMPO in MIL-101(Cr)for selective uranium recovery from aqueous streams through adsorption[J]. Journal of Hazardous Materials,2017,335:1-9.
[22] Chen B,Wang J,Kong L,et al. Adsorption of uranium from uranium mine contaminated water using phosphate rock apatite(PRA):Isotherm,kinetic and characterization studies[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2017,520:612-621.
[23]左天明,左魏铭,李金莲.放射性废水处理技术研究进展[J].四川地质学报,2015,35(3):473-475.
[24] Wang X,Liu Q,Liu J,et al. 3D self-assembly polyethyleneimine modified graphene oxide hydrogel for the extraction of uranium from aqueous solution[J]. Applied Surface Science,2017,426:1063-1074.
[25] Torkabad M G,Keshtkar A R,Safdari S J. Comparison of polyethersulfone and polyamide nanofiltration membranes for uranium removal from aqueous solution[J]. Progress in Nuclear Energy,2017,94:93-100.
[26] Roach J D,Zapien J H. Inorganic ligand-modified,colloid-enhanced ultrafiltration:A novel method for removing uranium from aqueous solution[J].Water Research,2009,43(18):4751-4759.
[27] Shen J,Schafer A. Removal of fluoride and uranium by nanofiltration and reverse osmosis:A review[J]. Chemosphere,2014,117(1):679-691.
[28]汪萍,吕彩霞,盛青,等.含铀废水处理技术的研究进展[J].现代化工,2016(12):23-27.
[29]胡鄂明,张皖桂,王清良,等.离子交换树脂对铀的静态和动态吸附行为研究[J].南华大学学报(自然科学版),2015(2):42-46.
[30] Rahmati A,Ghaemi A,Samadfam M. Kinetic and thermodynamic studies of uranium(Ⅵ)adsorption using Amberlite IRA-910 resin[J]. Annals of Nuclear Energy,2012,39(1):42-48.
[31]万小岗,王东文.四钛酸钾晶须处理含铀废水实验研究[J].环境科学与技术,2007,30(10):67-70.
[32]平爱东,罗明标,刘建亮,等. D231强碱性环氧系阴离子交换树脂吸附铀性能研究[J].东华理工大学学报(自然科学版),2013,36(1):69-75.
[33]李建华,王红英,程威,等.离子交换纤维处理含铀矿井水[J].铀矿冶,2012,31(2):100-102.
[34]黄崇元,李伟才,张玉泰,等.伊宁铀矿硝酸根废水自然蒸发处理可行性探讨[J].铀矿冶,2000,19(4):243-249.
[35]李冠华,张超,何广昌.低放射性废水蒸发处理及反渗透处理比选分析[J].科技视界,2016(7):132-132.
[36]鄢枭,杨雪峰,车建业,等.处理低水平放射性废液热泵蒸发技术的工程应用研究[C]∥中国核科学技术进展报告. 2011.
[37] Zarrougui R,Mdimagh R,Raouafi N. Highly efficient extraction and selective separation of uranium(Ⅵ)from transition metals using new class of undiluted ionic liquids based on H-phosphonate anions[J]. Journal of Hazardous Materials,2017,342:464-476.
[38] Chen M,Li Z,Li J,et al. The extraction of uranium using graphene aerogel loading organic solution[J]. Talanta,2017,166:284-291.
[39] Khayambashi A,Wang X,Wei Y. Solid phase extraction of uranium(Ⅵ)from phosphoric acid medium using macroporous silica-based D2EHPA-TOPO impregnated polymeric adsorbent[J]. Hydrometallurgy,2016,164:90-96.
[40]张露,刘峙嵘.微生物法处理低浓度含铀废水研究[J].环境工程,2017,35(12):36-40.
[41] Yi Z J,Yao J,Chen H L,et al. Uranium biosorption from aqueous solution onto Eichhornia crassipes[J]. Journal of Environmental Radioactivity,2016,154:43-51.
[42] Zheng X Y,Wang X Y,Shen Y H,et al. Biosorption and biomineralization of uranium(Ⅵ)by Saccharomyces cerevisiae-Crystal formation of chernikovite[J]. Chemosphere,2017,175:161-169.
[43]黄德娟,朱业安,余月,等.铀污染环境治理中的植物修复研究[J].铀矿冶,2012,31(4):202-206.
[44]杨晶,谢水波,王清良,等.微生物吸附铀的机理研究现状[J].铀矿冶,2006,25(4):192-195.
[45] Willscher S, Mirgorodsky D, Jablonski L, et al. Field scale phytoremediation experiments on a heavy metal and uranium contaminated site,and further utilization of the plant residues[J]. Hydrometallurgy,2013,131/132:46-53.
[46] Jagetiya B,Sharma A. Optimization of chelators to enhance uranium uptake from tailings for phytoremediation[J]. Chemosphere,2013,91(5):692-696.
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