乙酰化半纤维素用于提高涂布纸张的性能
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摘要
从云杉中经热水抽提出的聚半乳糖葡萄糖甘露糖(GGM)乙酰化后具有一定水溶性。将其涂布于食品包装纸上,结果表明GGM和乙酰化GGM均可提高食品包装纸的力学性能,且乙酰化GGM对力学性能的作用更好,涂有GGM和乙酰化GGM的纸有很好的耐油性能,且涂乙酰化GGM比涂GGM的纸具有更好的耐油性。
A hemicellulose, galactosan-glucan-mannan(GGM) extracted from spruce, was acetylized to form acetylated GGM in the suitable condition, which is soluble in water and were coated on food paper board. It was found that GGM and acetylated GGM coated on paper can improve the paper strength properties, and the acetylated GGM performance is better than GGM. The paper coated with GGM or acetylated GGM has good oil barrier ability and strength properties. acetylated GGM performed on paper is much better than GGM did.
A hemicellulose, galactosan-glucan-mannan(GGM) extracted from spruce, was acetylized to form acetylated GGM in the suitable condition, which is soluble in water and were coated on food paper board. It was found that GGM and acetylated GGM coated on paper can improve the paper strength properties, and the acetylated GGM performance is better than GGM. The paper coated with GGM or acetylated GGM has good oil barrier ability and strength properties. acetylated GGM performed on paper is much better than GGM did.
引文
[1] 蒋轩. 羧甲基壳聚糖在纸张阻隔涂布中的应用研究[D].广州,华南理工大学, 2014.
[2] 臧永华, 刘忠, 曹振雷. 一个基于涂层表面形成滤饼层的乳胶/颜料体系涂布纸涂层固化机理[J]. 中国造纸, 2008, 27(2): 34-38. DOI: 10.3969/j.issn.0254-508X.2008.02.009
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[11] SOUSA S, RAMOS A, EVTUGUIN D V, et al. Xylan and xylan derivatives-Their performance in bio-based films and effect of glycerol addition[J]. Industrial Crops and Products, 2016, 94: 682-689. DOI:10.1016/j.indcrop.2016.09.031
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[13] SASSI J F, CHANZY H. Ultrastructural aspects of the acetylation of cellulose[J]. Cellulose, 1995, 2(2): 111-127.
[14] MIKKONEN K S, STEVANIC J S, JOLY C, et al. Composite films from spruce galactoglucomannans with microfibrillated spruce wood cellulose[J]. Cellulose, 2011, 18(3): 713-726. DOI: 10.1007/s10570-011-9524-0
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[17] PARK J H, YONG W C, CHUNG H, et al. Synthesis and characterization of sugar-bearing chitosan derivatives: Aqueous Solubility and Biodegradability[J]. Biomacromolecules, 2003, 4(4):1087-1091. DOI: 10.1021/bm034094r
[18] GAO S, NISHINARI K. Effect of deacetylation rate on gelation kinetics of konjac glucomannan[J]. Colloids & Surfaces B Biointerfaces, 2004,38(3-4):241-249. DOI: 10.1016/j.colsurfb.2004.02.026
[19] PENROJ P, MITCHELL J R, HILL S E, et al. Effect of konjac glucomannan deacetylation on the properties of gels formed from mixtures of kappa carrageenan and konjac glucomannan[J]. Carbohydrate Polymers, 2005, 59(3):367-376. DOI: 10.1016/j.carbpol.2004.10.007
[20] STEPAN A M, HOEIJE A, SCHOLS HA, et al. Arabinsoe content of arabinoxylans contributes to flexibility of acetylated arabinoxylan films[J]. Journal Applied PolymerScience,2012, 125(3): 2348-2355. DOI: 10.1002/app.36458
[21] PENG X W, REN J L, ZHONG L X, et al. Nanocomposite films based on xylan-rich hemicelluloses and cellulose nanofibers with enhanced mechanical properties[J]. Biomacromolecules, 2011, 12(9): 3321-3329. DOI: 10.1021/bm2008795
[22] FARHAT W, VENDITTI R, QUICK A, et al. Hemicellulose extraction and characterization for applications in paper coatings and adhesives[J]. Industrial Crops & Products, 2017, 107: 370-377. DOI: 10.1016/j.indcrop.2017.05.055
[23] KISONEN V, XU C, BOLLSTR?M R, et al. O-Acetyl galactoglucomannan esters for barrier coatings[J]. Cellulose, 2014, 21(6): 4497-4509. DOI: 10.1007/s10570-014-0428-7
[24] 赵梦晓,付时雨.乙酰化半纤维素对涂成膜的粘结性能的影响[J].造纸科学与技术, 2018, 37(2): 58-64.
[25] 李倩钰.氧化醋酸酯淀粉胶黏剂的制备及在白卡纸涂布中的应用[J].造纸科学与技术, 2018, 37(1): 38-42.DOI: 10.19696/j.issn1671-4571.2018.01.009
[2] 臧永华, 刘忠, 曹振雷. 一个基于涂层表面形成滤饼层的乳胶/颜料体系涂布纸涂层固化机理[J]. 中国造纸, 2008, 27(2): 34-38. DOI: 10.3969/j.issn.0254-508X.2008.02.009
[3] 杨淑蕙. 植物纤维化学, 第3版[M].北京,中国轻工业出版社, 2001.
[4] SUN X, SUN R, FOWLER R, BAIRD MS. Extraction and characterization of original lignin and hemicelluloses from wheat straw, Journal of Agriculture and Food Chemistry[J]. 2005, 53(4): 860-870. DOI: 10.1021/jf040456q
[5] TIMELL T E. Recent progress in the chemistry of wood hemicelluloses[J]. Wood Science & Technology, 1967, 1(1): 45-70. DOI: 10.1007/BF00592255
[6] HEINZE T, KOSCHELLA A, EBRINGEROVA A. Chemical functionalization of xylan: A short review. Gatenholm P, Tenhanen M: HEMICELLULOSES: SCIENCE AND TECHNOLOGY[M]. ACS Symposium Series, 2004, 864: 312-325. DOI: 0.1021/bk-2004-0864.ch020
[7] STEPAN A M, H?IJE A, SCHOLS H A, et al. Arabinose content of arabinoxylans contributes to flexibility of acetylated arabinoxylan films[J]. Journal of Applied Polymer Science, 2012,125(3): 2348-2355. DOI: 0.1002/app.36458
[8] STEPAN A M, ANSARI F, BERGLUND L, et al. Nanofibrillated cellulose reinforced acetylated arabinoxylan films [J]. Composites Science & Technology, 2014, 98(16):72-78. DOI: 10.1016/j.compscitech.2014.04.010
[9] HARTMAN J, ALBERTSSON A C, SJ?BERG J. Surface-and bulk-modified galactoglucomannan hemicellulose films and film laminates for versatile oxygen barriers[J]. Biomacromolecules, 2006,7(6):1983-1989. DOI: 10.1021/bm060129m
[10] HARTMAN J, ALBERTSSON A, LINDBLAD M S, et al. Oxygen barrier materials from renewable sources: Material properties of softwood hemicellulose-based films [J]. Journal of Applied Polymer Science, 2006,100(4): 2985-2991. DOI: 10.1002/app.22958
[11] SOUSA S, RAMOS A, EVTUGUIN D V, et al. Xylan and xylan derivatives-Their performance in bio-based films and effect of glycerol addition[J]. Industrial Crops and Products, 2016, 94: 682-689. DOI:10.1016/j.indcrop.2016.09.031
[12] RINAUDO M. Role of substituents on the properties of some polysaccharides[J]. Biomacromolecules, 2004,5(4):1155-1165. DOI: 10.1007/BF00816384
[13] SASSI J F, CHANZY H. Ultrastructural aspects of the acetylation of cellulose[J]. Cellulose, 1995, 2(2): 111-127.
[14] MIKKONEN K S, STEVANIC J S, JOLY C, et al. Composite films from spruce galactoglucomannans with microfibrillated spruce wood cellulose[J]. Cellulose, 2011, 18(3): 713-726. DOI: 10.1007/s10570-011-9524-0
[15] YOUNGQUIST J A, KRZYSIK A, ROWELL R M. Dimensional stability of acetylated aspen flakeboard[J]. Wood & Fiberence, 1986, 18(1): 90-98. DOI:10.1080/02827588609382440
[16] WILLIAMS M A K, FOSTER T J, AND D R M, et al. A molecular description of the gelation mechanism of konjac mannan[J]. Biomacromolecules, 2000, 1(3): 440-450. DOI: 10.1021/bm005525y
[17] PARK J H, YONG W C, CHUNG H, et al. Synthesis and characterization of sugar-bearing chitosan derivatives: Aqueous Solubility and Biodegradability[J]. Biomacromolecules, 2003, 4(4):1087-1091. DOI: 10.1021/bm034094r
[18] GAO S, NISHINARI K. Effect of deacetylation rate on gelation kinetics of konjac glucomannan[J]. Colloids & Surfaces B Biointerfaces, 2004,38(3-4):241-249. DOI: 10.1016/j.colsurfb.2004.02.026
[19] PENROJ P, MITCHELL J R, HILL S E, et al. Effect of konjac glucomannan deacetylation on the properties of gels formed from mixtures of kappa carrageenan and konjac glucomannan[J]. Carbohydrate Polymers, 2005, 59(3):367-376. DOI: 10.1016/j.carbpol.2004.10.007
[20] STEPAN A M, HOEIJE A, SCHOLS HA, et al. Arabinsoe content of arabinoxylans contributes to flexibility of acetylated arabinoxylan films[J]. Journal Applied PolymerScience,2012, 125(3): 2348-2355. DOI: 10.1002/app.36458
[21] PENG X W, REN J L, ZHONG L X, et al. Nanocomposite films based on xylan-rich hemicelluloses and cellulose nanofibers with enhanced mechanical properties[J]. Biomacromolecules, 2011, 12(9): 3321-3329. DOI: 10.1021/bm2008795
[22] FARHAT W, VENDITTI R, QUICK A, et al. Hemicellulose extraction and characterization for applications in paper coatings and adhesives[J]. Industrial Crops & Products, 2017, 107: 370-377. DOI: 10.1016/j.indcrop.2017.05.055
[23] KISONEN V, XU C, BOLLSTR?M R, et al. O-Acetyl galactoglucomannan esters for barrier coatings[J]. Cellulose, 2014, 21(6): 4497-4509. DOI: 10.1007/s10570-014-0428-7
[24] 赵梦晓,付时雨.乙酰化半纤维素对涂成膜的粘结性能的影响[J].造纸科学与技术, 2018, 37(2): 58-64.
[25] 李倩钰.氧化醋酸酯淀粉胶黏剂的制备及在白卡纸涂布中的应用[J].造纸科学与技术, 2018, 37(1): 38-42.DOI: 10.19696/j.issn1671-4571.2018.01.009