微胶囊相变材料及其在成品油储罐蒸发损耗防控方面的应用展望
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摘要
随着石油工业的日益发展,成品油储运量的增加和储罐区规模的扩大,储罐成品油蒸发损耗问题日益突出,而降低成品油的蒸发损耗对我国能源储备具有重大的影响意义;因此,相变储能材料以其储能控温特性成为目前储能领域的研究热点。介绍了相变材料及石蜡的性能,综述了微胶囊相变材料的制备方法——原位聚合法和界面聚合法,总结了微胶囊相变材料在涂料应用领域的研究进展,并对微胶囊相变材料在成品油储罐蒸发损耗防控方向的发展前景进行了展望。
With the increasing development of the petroleum industry and the increasing of petroleum and the expansion tank zone,the evaporation loss caused by storage and transportation have been becoming increasingly prominent.So,reducing the evaporation loss of oil had a significant Influences and significances on China's energy reserves.The thermal property and heat storage performance of phase change material have becomed the research hotspots in the field of energy reserves.Phase change materials and the characterization of paraffin were introduced,the two preparation methods for microcapsule phase change materials were presented,that is,in situ polymerization and interfacial polymerization.The researching development of application in coating of microcapsule phase change materials were reviewed,the development prospects of fuel oil evaporation loss control using microcapsule phase change materials were also analyzed.
With the increasing development of the petroleum industry and the increasing of petroleum and the expansion tank zone,the evaporation loss caused by storage and transportation have been becoming increasingly prominent.So,reducing the evaporation loss of oil had a significant Influences and significances on China's energy reserves.The thermal property and heat storage performance of phase change material have becomed the research hotspots in the field of energy reserves.Phase change materials and the characterization of paraffin were introduced,the two preparation methods for microcapsule phase change materials were presented,that is,in situ polymerization and interfacial polymerization.The researching development of application in coating of microcapsule phase change materials were reviewed,the development prospects of fuel oil evaporation loss control using microcapsule phase change materials were also analyzed.
引文
[1]杨宏伟,胡役芹,杨士亮.轻质燃料油蒸发抑制表面覆盖技术研究[J].石油商技,2008,26(4):54-55.
[2]师欢,王毅,冯辉霞,等.微胶囊相变材料研究进展[J].应用化工,2013,42(1):122-127.
[3]李钰,刑建伟,陆少峰.微胶囊相变材料研究进展[J].粘接,2014,35(12):87-91.
[4]鄢瑛,张会平,刘剑.微胶囊相变材料的制备与特性研究[J].材料导报,2009,23(4):49-51.
[5]刘臣臻.相变微胶囊储能过程传热与流动特性研究[D].江苏:中国矿业大学,2017.
[6]张兴祥,王馨,吴文建,等.相变材料胶囊制备与应用[M].北京:化学工业出版社,2009.
[7]Sharma S D,Sagara K.Latent heat storage materials and systems:a review[J].International Journal of Green Energy,2005,2(1):1-56.
[8]龚长勇.聚合物包覆正十八烷的微胶囊化相变材料的制备与性能研究[D].北京:北京化工大学,2009.
[9]郑涛杰,陈志莉,刘洪涛,等.低温相变储能材料及其应用[J].当代化工,2017,46(12):2572-2577.
[10]付江辉.有机蓄热相变材料的热化学研究[D].北京:北京化工大学,2004.
[11]Sharma S D,Kitano H,Sagara K.Phase change materials for low temperature solar thermal applications[J].Res.rep.fac.eng.mie Univ,2004,29:31-64.
[12]Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Renewable&Sustainable Energy Reviews,2009,13(2):318-345.
[13]付新,周雷,李华宇,等.脲醛树脂石蜡微胶囊的制备及其在保温隔热涂料中的应用[J].电镀与涂饰,2013,32(4):59-63.
[14]张金辉.石蜡及其复合相变材料的热物性研究[D].青岛:青岛科技大学,2014.
[15]张仁元.相变材料与相变储能技术[M].北京:科学出版社,2009.
[16]Brown R C,Rasberry J D,Overmann S P.Microencapsulated phase-change materials as heat transfer media in gas-fluidized beds[J].Powder Technology,1998,98(3):217-222.
[17]韩鹏举.基于控温包装的相变胶囊及其复合材料的制备与性能研究[D].江苏:江南大学,2017.
[18]彭飞飞,刘子凡,梁熙.相变材料微胶囊制备技术及其在建筑节能中的应用研究进展[J].材料导报:纳米与新材料专辑,2016(1):436-439.
[19]Gtucho M H.Microcapsules and Microencapsulation Techniques[M].New York:Noyes Date Corp Press,1976.
[20]崔锦峰,崔卓,周应萍,等.微胶囊相变材料研究进展[J].中国涂料,2013,28(9):15-18.
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[22]梁治齐.微胶囊技术及其应用[M].北京:北京轻工业出版社,1999.
[23]Jamekhorshid A,Sadrameli S M,Farid M.A review of microencapsulation methods of phase change materials(PCMs)as a thermal energy storage(TES)medium[J].Renewable&Sustainable Energy Reviews,2014,31(2):531-542.
[24]吴晓,温玉全,杨莉燕,等.微胶囊相变材料的制备及应用[J].化学世界,2007,48(10):625-628.
[25]许时婴.微胶囊技术:原理与应用[M].北京:化学工业出版社,2006.
[26]Zhang H,Wang X.Fabrication and performances of microencapsulated phase change materials based on n-octadecane core and resorcinol-modified melamine-formaldehyde shell[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2009,332(2):129-138.
[27]Jian M,Hua Y,Xi Z.In situ polymerization of uniform poly(urea-formaldehyde)microcapsules containing paraffins under the high-speed agitation without emulsifier[J].Polymer Bulletin,2012,69(6):649-660.
[28]Giro-Paloma J,Alkan C,Chimenos J,et al.Comparison of microencapsulated phase change materials prepared at laboratory containing the same core and different shell material[J].Applied Sciences,2017,7(7):723-731.
[29]Fan Y F,Zhang X X,Wang X C,et al.Super-cooling prevention of microencapsulated phase change material[J].Thermochimica Acta,2004,413:1-6.
[30]申天伟,陆少锋,辛成,等.微胶囊相变材料的研究进展[J].纺织导报,2017(1):69-73.
[31]Zhou Y S,Wang Y,Ji J L.Study on double-shell thermal insulated microcapsules synthesized by interfacial polymerization[J].Textile Auxiliaries,2013,30(2):17-19.
[32]Zhang H,Wang X.Synthesis and properties of microencapsulated n-octadecane with polyurea shells containing different soft segments for heat energy storage and thermal regulation[J].Solar Energy Materials&Solar Cells,2009,93(8):1366-1376.
[33]Lan X Z,Tan Z C,Zou G L,et al.Microencapsulation of n-eicosane as energy storage material[J].Chinese Journal of Chemistry,2004,22(5):411-414.
[34]Wei J,Liu X,Yu H F.Preparation and properties of thermal energy storage and temperature conditioning paraffin microencapsulated phase change material[J].React Funct Polym,2010,23(1):73-76.
[35]Lu S,Shen T,Xing J,et al.Preparation,characterization,and thermal stability of double-composition shell microencapsulated phase change material by interfacial polymerization[J].Colloid&Polymer Science,2017,295(10):2061-2067.
[36]宋健,陈磊,李效军,等.微胶囊化技术及应用[M].北京:化学工业出版社,2004.
[37]张仁元.相变材料与相变储能技术[M].北京:科学出版社,2009.
[38]Han X,Li Y,Yuan L,et al.Experimental study on effect of microencapsulated phase change coating on indoor temperature response and energy consumption[J].Advances in Mechanical Engineering,2017(6):9.
[39]杨保平,席满意,崔锦峰,等.相变微胶囊的制备及其在涂料中的应用研究[J].当代化工,2014,43(1):32-35.
[40]孙文艳,吕绪良,郑玉辉.微胶囊相变材料制备及其在红外隐身涂料中的应用[J].解放军理工大学学报,2009,10(2):156-159.
[41]杨宏伟.轻质燃料油蒸发损耗控制软浮顶油罐技术研究[D].江苏:中国矿业大学,2014.
[42]刘术兵.油品的蒸发损耗及降耗措施[J].中国石油和化工标准与质量,2011,31(5):209-209.
[43]冯希全.油品的蒸发损耗及降耗措施[J].山东科学,2001,14(2):62-65.
[44]贾玮,崔之健.探讨原油储罐蒸发损耗的危害、影响因素及控制措施[J].中国化工贸易,2013,10(10):334-334.
[45]费逸伟,马晓宇,佟丽萍,等.氟化相变微球控制燃料油蒸发损耗试验[J].油气储运,2010,29(4):497-500.
[2]师欢,王毅,冯辉霞,等.微胶囊相变材料研究进展[J].应用化工,2013,42(1):122-127.
[3]李钰,刑建伟,陆少峰.微胶囊相变材料研究进展[J].粘接,2014,35(12):87-91.
[4]鄢瑛,张会平,刘剑.微胶囊相变材料的制备与特性研究[J].材料导报,2009,23(4):49-51.
[5]刘臣臻.相变微胶囊储能过程传热与流动特性研究[D].江苏:中国矿业大学,2017.
[6]张兴祥,王馨,吴文建,等.相变材料胶囊制备与应用[M].北京:化学工业出版社,2009.
[7]Sharma S D,Sagara K.Latent heat storage materials and systems:a review[J].International Journal of Green Energy,2005,2(1):1-56.
[8]龚长勇.聚合物包覆正十八烷的微胶囊化相变材料的制备与性能研究[D].北京:北京化工大学,2009.
[9]郑涛杰,陈志莉,刘洪涛,等.低温相变储能材料及其应用[J].当代化工,2017,46(12):2572-2577.
[10]付江辉.有机蓄热相变材料的热化学研究[D].北京:北京化工大学,2004.
[11]Sharma S D,Kitano H,Sagara K.Phase change materials for low temperature solar thermal applications[J].Res.rep.fac.eng.mie Univ,2004,29:31-64.
[12]Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Renewable&Sustainable Energy Reviews,2009,13(2):318-345.
[13]付新,周雷,李华宇,等.脲醛树脂石蜡微胶囊的制备及其在保温隔热涂料中的应用[J].电镀与涂饰,2013,32(4):59-63.
[14]张金辉.石蜡及其复合相变材料的热物性研究[D].青岛:青岛科技大学,2014.
[15]张仁元.相变材料与相变储能技术[M].北京:科学出版社,2009.
[16]Brown R C,Rasberry J D,Overmann S P.Microencapsulated phase-change materials as heat transfer media in gas-fluidized beds[J].Powder Technology,1998,98(3):217-222.
[17]韩鹏举.基于控温包装的相变胶囊及其复合材料的制备与性能研究[D].江苏:江南大学,2017.
[18]彭飞飞,刘子凡,梁熙.相变材料微胶囊制备技术及其在建筑节能中的应用研究进展[J].材料导报:纳米与新材料专辑,2016(1):436-439.
[19]Gtucho M H.Microcapsules and Microencapsulation Techniques[M].New York:Noyes Date Corp Press,1976.
[20]崔锦峰,崔卓,周应萍,等.微胶囊相变材料研究进展[J].中国涂料,2013,28(9):15-18.
[21]Ghosh S K.Functional coatings:By polymer microencapsulation[J].2006,61(3):163-165.
[22]梁治齐.微胶囊技术及其应用[M].北京:北京轻工业出版社,1999.
[23]Jamekhorshid A,Sadrameli S M,Farid M.A review of microencapsulation methods of phase change materials(PCMs)as a thermal energy storage(TES)medium[J].Renewable&Sustainable Energy Reviews,2014,31(2):531-542.
[24]吴晓,温玉全,杨莉燕,等.微胶囊相变材料的制备及应用[J].化学世界,2007,48(10):625-628.
[25]许时婴.微胶囊技术:原理与应用[M].北京:化学工业出版社,2006.
[26]Zhang H,Wang X.Fabrication and performances of microencapsulated phase change materials based on n-octadecane core and resorcinol-modified melamine-formaldehyde shell[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2009,332(2):129-138.
[27]Jian M,Hua Y,Xi Z.In situ polymerization of uniform poly(urea-formaldehyde)microcapsules containing paraffins under the high-speed agitation without emulsifier[J].Polymer Bulletin,2012,69(6):649-660.
[28]Giro-Paloma J,Alkan C,Chimenos J,et al.Comparison of microencapsulated phase change materials prepared at laboratory containing the same core and different shell material[J].Applied Sciences,2017,7(7):723-731.
[29]Fan Y F,Zhang X X,Wang X C,et al.Super-cooling prevention of microencapsulated phase change material[J].Thermochimica Acta,2004,413:1-6.
[30]申天伟,陆少锋,辛成,等.微胶囊相变材料的研究进展[J].纺织导报,2017(1):69-73.
[31]Zhou Y S,Wang Y,Ji J L.Study on double-shell thermal insulated microcapsules synthesized by interfacial polymerization[J].Textile Auxiliaries,2013,30(2):17-19.
[32]Zhang H,Wang X.Synthesis and properties of microencapsulated n-octadecane with polyurea shells containing different soft segments for heat energy storage and thermal regulation[J].Solar Energy Materials&Solar Cells,2009,93(8):1366-1376.
[33]Lan X Z,Tan Z C,Zou G L,et al.Microencapsulation of n-eicosane as energy storage material[J].Chinese Journal of Chemistry,2004,22(5):411-414.
[34]Wei J,Liu X,Yu H F.Preparation and properties of thermal energy storage and temperature conditioning paraffin microencapsulated phase change material[J].React Funct Polym,2010,23(1):73-76.
[35]Lu S,Shen T,Xing J,et al.Preparation,characterization,and thermal stability of double-composition shell microencapsulated phase change material by interfacial polymerization[J].Colloid&Polymer Science,2017,295(10):2061-2067.
[36]宋健,陈磊,李效军,等.微胶囊化技术及应用[M].北京:化学工业出版社,2004.
[37]张仁元.相变材料与相变储能技术[M].北京:科学出版社,2009.
[38]Han X,Li Y,Yuan L,et al.Experimental study on effect of microencapsulated phase change coating on indoor temperature response and energy consumption[J].Advances in Mechanical Engineering,2017(6):9.
[39]杨保平,席满意,崔锦峰,等.相变微胶囊的制备及其在涂料中的应用研究[J].当代化工,2014,43(1):32-35.
[40]孙文艳,吕绪良,郑玉辉.微胶囊相变材料制备及其在红外隐身涂料中的应用[J].解放军理工大学学报,2009,10(2):156-159.
[41]杨宏伟.轻质燃料油蒸发损耗控制软浮顶油罐技术研究[D].江苏:中国矿业大学,2014.
[42]刘术兵.油品的蒸发损耗及降耗措施[J].中国石油和化工标准与质量,2011,31(5):209-209.
[43]冯希全.油品的蒸发损耗及降耗措施[J].山东科学,2001,14(2):62-65.
[44]贾玮,崔之健.探讨原油储罐蒸发损耗的危害、影响因素及控制措施[J].中国化工贸易,2013,10(10):334-334.
[45]费逸伟,马晓宇,佟丽萍,等.氟化相变微球控制燃料油蒸发损耗试验[J].油气储运,2010,29(4):497-500.
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