环氧沥青改性剂研究进展
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摘要
针对环氧沥青在使用过程中存在的柔韧性低、低温抗性不足、相容性差等问题,介绍了热塑性弹性体、纤维、固体颗粒等几类环氧沥青改性剂的最新研究进展,并探讨了各自的优缺点,从改性效果和改性机理等角度进行了分析总结,指出了未来改性剂应围绕着改性工艺和复合改性来进行深入研究,为环氧沥青改性剂的研究提供了方向。
In view of the problems of low flexibility,low temperature resistance and poor compatibility during the use of epoxy asphalt,the latest research progress of several types of epoxy asphalt modifiers such as thermoplastic elastomers,fibers and solid particles is presented. Discussed their respective advantages and disadvantages. From the perspectives of modification effect and modification mechanism,it is pointed out that the future research of modifiers should be carried out in-depth research around the modification process and composite modification,which provide a direction for the research of epoxy asphalt modifiers.
In view of the problems of low flexibility,low temperature resistance and poor compatibility during the use of epoxy asphalt,the latest research progress of several types of epoxy asphalt modifiers such as thermoplastic elastomers,fibers and solid particles is presented. Discussed their respective advantages and disadvantages. From the perspectives of modification effect and modification mechanism,it is pointed out that the future research of modifiers should be carried out in-depth research around the modification process and composite modification,which provide a direction for the research of epoxy asphalt modifiers.
引文
[1]蒋玲.环氧沥青混合料应用研究现状与发展趋势[J].化工新型材料,2010,38(9):34-36.
[2] Lu Q,Bors J. Alternate uses of epoxy asphalt on bridge decks and roadways[J]. Construction&Building Materials,2015(78):18-25.
[3] Qian Z,Chen L,Jiang C,et al. Performance evaluation of a lightweight epoxy asphalt mixture for bascule bridge pavements[J]. Construction&Building Materials,2011,25(7):3117-3122.
[4]黄卫,钱振东,程刚.环氧沥青混凝土在大跨径钢桥面铺装中的应用[J].东南大学学报:自然科学版,2002,32(5):783-787.
[5]晏永,郭大进,封基良,等.钢桥铺装用环氧沥青的研究现状及展望[J].公路交通科技,2016,33(9):69-77.
[6]佘庆彦,田洪池,韩吉彬,等.热塑性弹性体的研究与产业化进展[J].中国材料进展,2012,31(2):24-32.
[7]丛培良,李思勰.环氧沥青混合料低温抗裂性能研究进展[J].石油沥青,2015,29(5):1-5.
[8]曹东伟,张艳君,张海燕,等.一种聚脲改性环氧沥青及混合料:CN,104987737A[P]. 2015-06-07.
[9]卜鑫德,程烽雷.聚氨酯-环氧复合改性沥青及其路用性能研究[J].公路,2016(8):171-174.
[10]陈华鑫,张争奇,胡长顺.纤维沥青混合料的低温抗裂性能[J].华南理工大学学报:自然科学版,2004,32(4):82-86.
[11]王水.聚酯纤维掺量对环氧沥青桥面铺装混合料技术性能的影响[J].公路工程,2015,40(4):95-99.
[12]汪林,陈仕周,黄冰释.掺纤维环氧沥青混合料性能试验研究[J].中外公路,2010(5):189-191.
[13] Xue Y,Qian Z. Development and performance evaluation of epoxy asphalt concrete modified with mineral fiber[J].Construction&Building Materials,2016,102:378-383.
[14]钱振东,刘长波,唐宗鑫,等.短切玄武岩纤维对环氧沥青及其混合料性能的影响[J].公路交通科技,2015,32(6):1-5.
[15] Qin J,Woloctt M,Zhang J. Use of polycarboxylic acid derived from partially depolymerized lignin as a curing agent for epoxy application[J]. Acs Sustainable Chemistry&Engineering,2013,2(2):188-193.
[16] Xin J,Pei Z,Wolcott M P,et al. Partial depolymerization of enzymolysis lignin via mild hydrogenolysis over Raney Nickel[J]. Bioresource Technology,2014,155(4):422-426.
[17] Xin J,Li M,Li R,et al. Green epoxy resin system based on lignin and tung oil and its application in epoxy asphalt[J]. Acs Sustainable Chemistry&Engineering,2016,4(5):2754-2761.
[18]韩树峰.环氧沥青混凝土钢桥面铺装层增柔改性技术研究[J].公路,2013(7):27-32.
[19]孙一帆.环氧沥青/纳米粘土复合物的性能研究[D].南京:南京大学,2016.
[20] Wang B,Qi N,Gong W,et al. Study on the microstructure and mechanical properties for epoxy resin/montmorillonite nanocomposites by positron[J]. Radiation Physics&Chemistry,2007,76(2):146-149.
[21]晏英,肖新颜,刘武,等.有机蒙脱土/环氧树脂复合改性沥青的性能[J].高分子材料科学与工程,2015,31(4):52-56.
[22]曹东伟,张艳君,张海燕,等.一种双环戊二烯改性环氧沥青混合料及制法和应用:CN,105130278A[P].2015-06-07.
[23] Corcione C E,Frigione M. A novel procedure able to predict the rheological behavior of trifunctional epoxy resin/hyperbranched aliphatic polyester mixtures[J]. Polymer Testing,2009,28(8):830-835.
[24]叶欢.基于增韧特性的环氧沥青制备及性能研究[D].西安:长安大学,2015.
[2] Lu Q,Bors J. Alternate uses of epoxy asphalt on bridge decks and roadways[J]. Construction&Building Materials,2015(78):18-25.
[3] Qian Z,Chen L,Jiang C,et al. Performance evaluation of a lightweight epoxy asphalt mixture for bascule bridge pavements[J]. Construction&Building Materials,2011,25(7):3117-3122.
[4]黄卫,钱振东,程刚.环氧沥青混凝土在大跨径钢桥面铺装中的应用[J].东南大学学报:自然科学版,2002,32(5):783-787.
[5]晏永,郭大进,封基良,等.钢桥铺装用环氧沥青的研究现状及展望[J].公路交通科技,2016,33(9):69-77.
[6]佘庆彦,田洪池,韩吉彬,等.热塑性弹性体的研究与产业化进展[J].中国材料进展,2012,31(2):24-32.
[7]丛培良,李思勰.环氧沥青混合料低温抗裂性能研究进展[J].石油沥青,2015,29(5):1-5.
[8]曹东伟,张艳君,张海燕,等.一种聚脲改性环氧沥青及混合料:CN,104987737A[P]. 2015-06-07.
[9]卜鑫德,程烽雷.聚氨酯-环氧复合改性沥青及其路用性能研究[J].公路,2016(8):171-174.
[10]陈华鑫,张争奇,胡长顺.纤维沥青混合料的低温抗裂性能[J].华南理工大学学报:自然科学版,2004,32(4):82-86.
[11]王水.聚酯纤维掺量对环氧沥青桥面铺装混合料技术性能的影响[J].公路工程,2015,40(4):95-99.
[12]汪林,陈仕周,黄冰释.掺纤维环氧沥青混合料性能试验研究[J].中外公路,2010(5):189-191.
[13] Xue Y,Qian Z. Development and performance evaluation of epoxy asphalt concrete modified with mineral fiber[J].Construction&Building Materials,2016,102:378-383.
[14]钱振东,刘长波,唐宗鑫,等.短切玄武岩纤维对环氧沥青及其混合料性能的影响[J].公路交通科技,2015,32(6):1-5.
[15] Qin J,Woloctt M,Zhang J. Use of polycarboxylic acid derived from partially depolymerized lignin as a curing agent for epoxy application[J]. Acs Sustainable Chemistry&Engineering,2013,2(2):188-193.
[16] Xin J,Pei Z,Wolcott M P,et al. Partial depolymerization of enzymolysis lignin via mild hydrogenolysis over Raney Nickel[J]. Bioresource Technology,2014,155(4):422-426.
[17] Xin J,Li M,Li R,et al. Green epoxy resin system based on lignin and tung oil and its application in epoxy asphalt[J]. Acs Sustainable Chemistry&Engineering,2016,4(5):2754-2761.
[18]韩树峰.环氧沥青混凝土钢桥面铺装层增柔改性技术研究[J].公路,2013(7):27-32.
[19]孙一帆.环氧沥青/纳米粘土复合物的性能研究[D].南京:南京大学,2016.
[20] Wang B,Qi N,Gong W,et al. Study on the microstructure and mechanical properties for epoxy resin/montmorillonite nanocomposites by positron[J]. Radiation Physics&Chemistry,2007,76(2):146-149.
[21]晏英,肖新颜,刘武,等.有机蒙脱土/环氧树脂复合改性沥青的性能[J].高分子材料科学与工程,2015,31(4):52-56.
[22]曹东伟,张艳君,张海燕,等.一种双环戊二烯改性环氧沥青混合料及制法和应用:CN,105130278A[P].2015-06-07.
[23] Corcione C E,Frigione M. A novel procedure able to predict the rheological behavior of trifunctional epoxy resin/hyperbranched aliphatic polyester mixtures[J]. Polymer Testing,2009,28(8):830-835.
[24]叶欢.基于增韧特性的环氧沥青制备及性能研究[D].西安:长安大学,2015.