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铜冶炼过程汞的流向和分布
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  • 英文篇名:Flow Direction and Distribution of Mercury in Copper Smelting Process
  • 作者:胡若鹏 ; 黄小凤 ; 安俊菁 ; 赵杨 ; 刘秀状 ; 赵丹 ; 尚志标
  • 英文作者:HU Ruo-peng;HUANG Xiao-feng;AN Jun-jing;ZHAO Yang;LIU Xiu-zhuang;ZHAO Dan;SHANG Zhi-biao;Environmental Management of Solid Waste in Yunnan;Faculty of Environmental Science and Engineering,Kunming University of Science and Technology;Guangdong Polytechnic College;
  • 关键词:铜冶炼 ; ; 元素走向 ; 平衡分析
  • 英文关键词:copper smelting process;;mercury;;distribution of element;;equilibrium analysis
  • 中文刊名:METE
  • 英文刊名:Nonferrous Metals(Extractive Metallurgy)
  • 机构:云南省固体废物管理中心;昆明理工大学环境科学与工程学院;广东理工学院;
  • 出版日期:2018-12-12
  • 出版单位:有色金属(冶炼部分)
  • 年:2018
  • 基金:云南省环境保护厅2017年省级环保专项资金项目(KKF0201722012)
  • 语种:中文;
  • 页:METE201812002
  • 页数:4
  • CN:12
  • ISSN:11-1841/TF
  • 分类号:8-11
摘要
利用物料衡算法对云南省某铜冶炼企业铜冶炼过程中汞的流向进行系统分析。结果表明,铜冶炼系统中的汞主要来自铜精矿;经过制酸工艺,汞绝大部分进入到酸泥、污酸中,一部分进入到硫酸产品中,很少一部分随烟气排放;烟气中的汞能够达到规定的排放限值;经过污水处理系统,污酸中的汞进入到砷钙渣、中和渣和石膏渣中,回用水指标合格。
        Mercury flow in copper smelting process of a copper smelting enterprise in Yunnan Province was systematically analyzed by material balance algorithm.The results show that mercury mainly comes from copper concentrate in copper smelting system.Most of mercury enteres into acid mud and waste acid,some enteres into sulfuric acid,and few is charged with smoke during acid making.Mercury in flue gas meets the emission limits.After treated by sewage disposal system,mercury in waste acid enteres into arseniccalcium slag,neutralization slag and gypsum slag.The return water index was qualified.
引文
[1]吴清茹.中国有色金属冶炼行业汞排放特征及减排潜力研究[D].北京:清华大学,2015.
    [2]徐磊,阮胜寿.矿铜冶炼过程中汞的走向及回收工艺探讨[J].铜业工程,2017(1):71-74.
    [3]SHEU G R,MASON R P.An examination of methods for the measurements of reactive gaseous mercury in the atmosphere[J].Environmental Science&Technology,2001,35(6):1209-1216.
    [4]LANDIS M S,KEELER G J,AL-WALI K I,et al.Divalent inorganic reactive gaseous mercury emissions from a mercury cell chlor-alkali plant and its impact on near-field atmospheric dry deposition[J].Atmospheric Environment,2004,38(4):613-622.
    [5]LINDBERG S E,HANSON P J,MEYERS T P,et al.Air/surface exchange of mercury vapor over forests-The need for a reassessment of continental biogenic emissions[J].Atmos Environ,1998,32(5):895-908.
    [6]PYLE D M,MATHER T A.The importance of volcanic emissions for the global atmospheric mercury cycle[J].Atmos Environ,2003,37(36):5115-5124.
    [7]PACYNA E G,PACYNA J M.Global emission of mercury from anthropogenic sources in 1995[J].Water Air Soil Pollut,2002,137(1/2/3/4):149-165.
    [8]STREETS D G,HAO J M,WU Y,et al.Anthropogenic mercury emissions in China[J].Atmos Environ,2005,39(40):7789-7806.
    [9]PACYNA E G,PACYNA J M,SUNDSETH K,et al.Global emission of mercury to the atmosphere from anthropogenic sources in 2005and projections to 2020[J]. Atmospheric Environment,2010,44(20):2487-2499.
    [10]STREETS D G,HAO J,WU Y,et al.Anthropogenic mercury emissions in China[J]. Atmospheric Environment,2005,39(40):7789-7806.
    [11]WU Y,WANG S,STREETS D G,et al.Trends in anthropogenic mercury emissions in China from 1995to2003[J].Environmental Science&Technology,2006,40(17):5312-5318.
    [12]PIRRONE N,CINNIRELLA S,FENG X,et al.Global mercuryemissionstotheatmospherefrom anthropogenic and natural sources[J].Atmospheric Chemistry&Physics Discussions,2010,10(13):5951-5964.
    [13]吴晓云,郑有飞,林克思.我国大气环境中汞污染现状[J].中国环境科学,2015,35(9):2623-2635.
    [14]STREETS D G,HAO J,WU Y,et al.Anthropogenic mercury emissions in China[J]. Atmospheric Environment,2005,39(40):7789-7806.
    [15]PACYNA E G,PACYNA J M,SUNDSETH K,et al.Global emission of mercury to the atmosphere from anthropogenic sources in 2005and projections to 2020[J]. Atmospheric Environment,2010,44(20):2487-2499.
    [16]王书肖,刘敏,蒋靖坤,等.中国非燃煤大气汞排放量估算[J].环境科学,2006,27(12):2401-2406.
    [17]朱祖泽,贺家齐.现代铜冶金学[M].北京:科学出版社,2003:3-4.
    [18]赵军锋.散装重有色金属浮选精矿取样、制样方法评析[J].世界有色金属,2009(7):67-69.

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