用户名: 密码: 验证码:
磁场效应强化湿法冶金的现状及前景
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Current status and prospect of hydrometallurgy enhancement by magnetic field
  • 作者:姚夏妍 ; 汪友元 ; 鲁兴武 ; 程亮 ; 李彦龙 ; 焦晓斌
  • 英文作者:YAO Xia-yan;WANG You-yuan;LU Xing-wu;CHENG Liang;LI Yan-long;JIAO Xiao-bin;
  • 关键词:磁化效应 ; 湿法冶金 ; 协同作用 ; 反应动力学 ; 活化
  • 英文关键词:magnetization effect;;hydrometallurgy;;synergism;;reaction kinetics;;activate
  • 中文刊名:YSYL
  • 英文刊名:China Nonferrous Metallurgy
  • 机构:西北矿冶研究院甘肃省有色金属冶炼新工艺及伴生稀散金属高效综合利用重点实验室;白银有色集团股份有限公司;
  • 出版日期:2019-02-28
  • 出版单位:中国有色冶金
  • 年:2019
  • 期:v.48
  • 基金:甘肃省青年科技基金计划资助(1606RJYA305)
  • 语种:中文;
  • 页:YSYL201901004
  • 页数:6
  • CN:01
  • ISSN:11-5066/TF
  • 分类号:15-20
摘要
新型磁性材料的开发和磁场相关理论的研究发展为磁处理的高效应用奠定了坚实的理论基础,拓宽了磁处理的利用空间,尤其是磁场在动力学方面的相关研究极大地推动了其在湿法冶金中的应用。磁场能够控制化学反应、改变分子结构、提高渗透性等作用,具有投资小、操作方便、无污染等优势,加之离子本身磁性的差异和运动的带电离子在磁场中受到洛伦兹力和磁场梯度力的特性,因此,磁场可以突破限制湿法冶金的浸出、净化和水溶液电解过程的瓶颈。本文就磁处理强化湿法冶金领城的扩散、萃取、离子分离、电化学以及蒸发浓缩等方面的研究现状及前景进行了综述与分析,并展望了磁处理在湿法冶金中的应用前景。
        Development of new magnetic materials, research and development of magnetic field related theory have laid solid theoretical basis and great space for the efficient application of magnetic treatment. In particular, the research on the dynamics of magnetic field has greatly promoted its application in hydrometallurgy. Magnetic field can control chemical reaction, change molecular structure and improve permeability. It has advantages of small investment, convenient operation and no pollution. Meanwhile, there are magnetic differences of ions and the movement of charged ions is affected by Lorentz force and magnetic field gradient force in magnetic field. Therefore, the magnetic field can bring many conveniences to the three operation processes of hydrometallurgical leaching, purification and aqueous solution electrolysis. This paper summarizes and analyzes the research status quo and prospect of diffusion,extraction, ion separation, electrochemistry, evaporation and concentration in the field of hydrometallurgy enhancement by magnetic field effect. The prospect of magnetic field in hydrometallurgy is also described.
引文
[1]韩鹏,李英,王海.磁场对酒石酸与铁化学反应的影响[J].北京:首都师范大学学报,2017, 38(3):23-26.
    [2]姚夏妍.磁场作用于循环冷却水系统防垢阻垢机理的研究[D].兰州:兰州理工大学,2017.
    [3]叶宽伟.电催化氧化法处理电镀废水中有机污染物的研究[D].杭州:浙江大学,2011.
    [4]王建国,梁延东,尹钊,等.电磁抑垢效果及其机理研究进展[J].吉林:东北电力大学学报,2016, 36(6):1-4.
    [5]陈珍,吕战鹏,肖茜,等.磁场对铁在含亚硝酸根的氯化钠溶液中不同电位下极化电流的影响[J].腐蚀与防护,2017, 38(1):6-9.
    [6]HINDS G, RHEN F M F, COEY J M D. Magnetic field effects on the rest potential of ferromagnetic electrode[J]. IEEE transactions on Magnetics,2016, 38(5):1-5.
    [7]SUEPTITZ R, TSCHULIK K, UHLEMANN M, et al. Impact of magnetic field gradients on the free corrosion of iron[J]. Electrochemistry Acta, 2010, 55(18):5200-5204.
    [8]JIANG L L, YAO X Y, YU H T, et al. Effect of permanent magnetic field on scale inhibition property of circulating water[J].Water Science&Technology,2017, 76(8):21-25.
    [9]JIANG L L, YAO X Y, YU H T, et al. Effects of permanent magnetic filed on water association of circulating water[J]. Desalina-tion&Water Treatment, 2017, 79:152-155.
    [10]MICHAEI E G, RAY O'Brien, MICHAEI Kinsella,et al. Effect of external magnetic fields on electron transfer and ion pairing dynamics at ferrocenyl alkane thiol SAM solution interfaces[J]. Electrochemistry Communications,2010,12(11):1527-1530.
    [11]LIU Y B,SUN Q J,LIU J P,et al. Effect of axial external magnetic field on cold metal transfer welds of aluminum alloy and stainless steel[J]. Materials Letters, 2015, 152:29-33.
    [12]姜丽丽,姚夏妍,侯新刚,等.循环水磁防垢除垢作用机理及影响因素分析[J].中国冶金,2017, 27(4):67-70.
    [13]侯新刚,姚夏妍,姜丽丽,等.磁处理水阻垢性能的研究现状及进展[J].中国冶金,2017, 27(5):1-4.
    [14]陈散兴,樊栋,张三平.磁场对电化学腐蚀行为的影响[J].材料保护,2015, 48(9):31-34.
    [15]WANG X P, ZHAO J,HU Y, et al. Effects of the lorentz force and the gradient magnetic force on the anodic dissolution of nickel in HNO_3+NaCl solution[J]. Electrochemistry Acta,2014,117:113-116.
    [16]梁丽萍.磁场强化零价铁去除水中Se(Ⅳ)和Se(Ⅵ)的效能和机制[D].哈尔滨:哈尔滨工业大学,2014.
    [17]刘丹妮,延克军.磁场处理对PFS溶液粘度和表面张力的影响研究[J].硅酸盐通报,2017, 36(5):1806-1810.
    [18]赵艳,彭犇,郭敏,等.红土镍矿微波水热法浸提镍钴[J].北京:北京科技大学学报,2012, 34(6):632-635.
    [19]孙乐栋,李杰,光明,等.炼铜烟灰硫酸浸出及铜浸出动力学研究[J].矿冶工程,2016,36(1):97-100.
    [20]伍凌,陈嘉彬,钟胜奎,等.机械活化-盐酸常压浸出钛铁矿的影响[J].中国有色金属学报,2015,25(1):211-215.
    [21]苑文仪,孟雯,王晓岩,等.机械活化强化废弃荧光粉中稀土金属的回收[J].上海第二工业大学学报,2015, 32(1):1-4.
    [22]牛梓璇,胡源,张艳,等.磁效应对水处理的影响研究[J].广州化工,2016, 44(16):21-25.
    [23]秦亚平.微波和磁场强化细菌浸出黄铜矿研究[J].科技创新导报,2011(5):20-24.
    [24]程海翔,张辉,徐天有,等.铜矿尾矿资源化利用研究进展[J].化工进展,2015, 34(31):192-195.
    [25]卢丽丽.电磁场强化细菌浸出铜尾矿重金属技术研究[D].重庆:重庆大学,2012.
    [26]宛鹤,何廷树,谢建宏,等.磁化处理技术在矿物加工中的应用[J].黄金,2011,32(1):53-55.
    [27]申大志,庄荣传,谢洪珍.强化氰化浸金技术进展[J].矿产综合利用,2014(2):15-18.
    [28]张德文,邱廷省,巫銮东,等.原生金矿石选矿技术现状及发展[J].黄金,2013, 34(9):57-60.
    [29]夏添.电磁场影响循环冷却水中CaC03结晶行为及动力学研究[D].呼和浩特:内蒙古工业大学,2015.
    [30]刘兴.磁絮凝反应器开发与应用研究[D].镇江:江苏大学,2010.
    [31]夏青,王健.提高含铜难浸金矿金浸出率的细菌预处理研究[J].金属矿山,2010(5):77-80.
    [32]夏青,邱廷省.采用磁场强化浸出提高某含铜难浸金矿浸出率的试验研究[J].矿产综合利用,2010(5):15-19.
    [33]龙琼,路坊海,周登凤,等.磁场下硫酸浸出赤泥回收钛的研究[J].广东化工,2016,43(17):32-36.
    [34]朱丽芳.含铜镍浸出渣中铁、铜、镍的分离回收研究[D].西安:西安建筑科技大学,2013.
    [35]李婉然.磁化电动法处理污泥中重金属的研究[D].大连:大连海事大学,2017.
    [36]卢丽丽,廖婵娟,邓娜,等.磁场对细菌浸出尾矿中铜、锌的影响[J].当代化工,2015,44(11):2524-2527.
    [37]JIANG X,QIAO J L,IRENE M C LO,et al. Enhanced paramagnetic Cu_2+ions removal by coupling a weak magnetic field with zero valent iron[J]. Journal of Hazardous Materials,2015,283:880-884.
    [38]张裕平.关于磁场增强效应的固相萃取新技术发展的几点思考[J].新乡:河南科技学院学报,2016, 44(06):33-36.
    [39]朱小华.电磁场下的热力学及其应用研究[D].广州:华南理工大学,2010.
    [40]周芸,张珍,张盛贵,等.正交试验优化磁场法提取枸杞黄酮工艺[J].食品科学,2012, 33(18):98-101.
    [41]赵金艳,王金生,郑骥.有色金属冶炼废渣有价金属湿法回收技术及现状[J].矿产综合利用,2012(4):7-10.
    [42]SUWA M,WATARAI H. Magnetoanalysis of micro/nanoparticles:a review[J]. Analytica Chimica Acta, 2011, 690(2):137-140.
    [43]WANG H, WU Z K,CHEN B B, et al. Chip-based array magnetic solid phase microextraction on-line coupled with inductively coupled plasma mass spectrometry for the determination of trace heavy metals in cells[J]. Analyst, 2015,140(16):5619-5622.
    [44]WANG H, CHEN B,ZHU S, et al. Chip-based magnetic solid-phase microextraction online coupled with micro HPLC-ICPMS for the determination of mercury species in cells[J]. Analytical Chemiatry,2016, 8(1):796-799.
    [45]任秀峰,官月平,王强,等.磁性流体固定床萃取分离低浓度金离子[J].化工学报,2012, 63(5):1443-1447.
    [46]IBRAHIW W A Wan, NODEN H R,ABOUL-ENEIN H Y,et al.Magnetic solid-phase extraction based on modified ferum oxides for enrichment, preconcentration, and isolation of pesticides and selected pollutants[J]. Critical Reviews in Analytical Chemistry,2015,45(3):270-274.
    [47]MOLNER-MARTINEZ Y, PRIMA-GARCIA H, RIBER A A,et al. Magnetic in-tube solid phase microextraction[J]. Analytical Chemistry,2012,84(16):7233-7236.
    [48]MOLINRER-MARTINE Y,VITTA Y,PRIMA-GARCIA H, et al.Silica supported Fe_3O_4 magnetic nanoparticles for magneticsolidphase extraction andmagnetic in-tube solid-phase microextraction:application to organophosphorous compounds[J]. Analytical and Bioanalytical Chemistry,2014,406(8):2211-2215.
    [49]GONZALEZ-FUENZALIDA R A, MOLINER-MARTINEZ Y,PRIMA-GARCIA H, et al. Evaluation of superparamagnetic silica nanoparticles for extraction of triazines in magnetic in-tube solid phase microextraction coupled to capillary liquid chromatography[J]. Nanomaterials, 2014,4(2):242-246.
    [50]MANBOHI A, AHMADI S H. In-tube magnetic solid phase microextraction of some fluoroquinolones based on the use of sodium dodecyl sulfate coated Fe304 nanoparticles packed tube[J]. Analytica Chimica Acta, 2015, 885:114-117.
    [51]任琦.磁性复合微球的制备及其在蛋白吸附中的应用[D].无锡:江南大学,2011.
    [52]尹军,张居奎,姜世坤,等.磁化对饮用水物理化学特性的影响[J].环境与健康杂志,2010, 27(4):357-360.
    [53]梁龙伟.湿法炼锌新三段净化工艺研究[D].昆明:昆明理工大学,2012.
    [54]白炳轶,郭艳玲,金永丽,等.白云鄂博矿磁场作用下的强化还原研究[J].上海金属,2016, 38(6):59-64.
    [55]WANGX, ZHAO J,HU Y,et al. Effects of the lorentz force and the gradient magnetic force on the anodic dissolution of nickel in HNO_3+NaCl solution[J]. Electrochemistry Acta, 2014,117:113-117.
    [56]PRAKASH Chandra Mondal, CLAUDIO Fontanesi, DAVID H.Waldeck, et al. Field and chirality effects on electrochemical charge transfer rates:spin dependent electrochemistry.[J]. ACS nano,2015,9(3):3377-3384.
    [57]CAO Longchao, YANG Yang, JIANG Ping,et al. Optimization of processing parameters of AISI 316L laser welding influenced by external magnetic field combining RBFNN and GA[J]. Results in Physics,2017, 29(3):1329-1338.
    [58]Mohan S, Saravanan G. A Bund. Role of magnetic forces in pulse electrochemical deposition of Ni-nano A1203 composites[J]. Electrochemistry Acta, 2012, 64:94-97.
    [59]EJAZ A, LU Z, CHEN J J,et al. The effects of hydrogen on anodic dissolution and passivation of iron in alkaline solutions[J].Corrosion Science, 2015, 101:165-169.
    [60]王小平.磁场作用下镍的阳极溶解过程[D].徐州:江苏师范大学,2014.
    [61]SUEPTITZ R, TSCHULIK K, UHLEMANN M, et al. Magnetic field effects on the active dissolution of iron[J]. Electrochemistry Acta, 2011,56(17):5866-5870.
    [62]MUHLENHOFFS, MUTSCHKE G, KOSCHICHOW D, et al.Lorentz-force-driven convection during copper magnetoelectrolysis in the presence of a supporting buoyancy force[J]. Electrochemistry Acta, 2012, 69:209-214.
    [63]HU J, DONG C,LI X, et al. Effects of applied magnetic field on corrosion of beryllium copper in NaCl solution[J]. Journal of Materials Science&Technology, 2010, 26(4):355-359.
    [64]SUEPTITZ R, TSCHULIK K,UHLEMANN M. Effect of high gradient magnetic fields on the anodic behavior and localized corrosion of iron in sulphuric acid solutions[J]. Corrosion Science,2011,53:3222-3230.
    [65]SUEPTITZ R, TSCHULIK K, UHLEMANN M, et al. Magnetic field effects on the active dissolution of iron[J]. Electrochemistry Acta, 2011,56(17):5866-5870.
    [66]ANDERSON E C, WESTON M C, FRITSCH I. Investigations of redox magnetohydrodynamic fluid flow at microelectrode arrays using microbeads[J]. Analytical Chemistry, 2010, 82(7):2643-3648.
    [67]SUEPTITZ R, TSCHULIK K, UHLEMANN M, et al. Impact of magnetic field gradients on the free corrosion of iron[J]. Electrochemistry Acta, 2010(55(18):5200-5204.
    [68]贾卫平,贾振元,苗斌,等.垂直磁场作用下电沉积数值分析与实验[J].大连:大连理工大学学报,2013, 53(5):671-675.
    [69]王金东,赵岩,朱砚葛,等.磁场强度对磁场-电沉积Ni-TiN镀层的影响[J].兵器材料科学与工程,2016, 39(3):83-86.
    [70]贾卫平,杨帆,吴蒙华.磁场下电沉积镍晶微铸件表面形貌与织构研究[J].机械设计与制造,2013(1):254-258.
    [71]敖正红,薛玉君,姜韶峰,等.电沉积方式对Ni-ZrO_2纳米复合镀层耐腐蚀性能的影响[J].表面技术,2015, 44(1):72-75.
    [72]刘娜娜,吴蒙华,李智,等.磁场作用下电沉积镀层技术的研究进展[J].稀有金属材料与工程,2013, 42(3):649-654.
    [73]吕战鹏,陈俊劼,肖茜,等.磁场对铜在几种酸性溶液中阳极溶解的影响[J].腐蚀与防护,2014, 35(12):1187-1190.
    [74]李希娇.基于数字全息术研究磁场作用下金属的阳极溶解过程[D].徐州:江苏师范大学,2017.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700