荧光素-层状双金属氢氧化物复合体的发光性能及对Fe~(3+)的荧光识别
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摘要
采用离子交换法合成了FLN/OS-LDH复合体(FLN:荧光素,OS:1-辛烷磺酸钠,LDH:镁铝型层状双金属氢氧化物),并研究了其光致发光和对Fe~(3+)的识别性能.固态时,FLN不发光,而FLN/OS-LDH复合体呈黄绿色荧光(发射波长为565 nm),是荧光素(FLN)的特征发射光.在甲酰胺(FM)中可将该复合体方便剥离为胶状悬浮液,其发射波长发生蓝移,为绿光发射(531 nm).研究了复合体剥离液对金属离子的荧光识别特性,发现其对Fe~(3+)的选择性识别能力很强,远优于其它离子(Mg~(2+),Ni~(2+),Co~(2+),Cu~(2+),Zn~(2+),Pb~(2+),Cd~(2+)和Hg~(2+)).该复合体与Fe~(3+)结合发生荧光猝灭现象,可将其用作检测Fe~(3+)的荧光传感器. Fe~(3+)检测限为1. 27×10~(-7)mol/L,猝灭常数(K_(sv))为3. 44×10~2L/mol.
FLN/OS-LDH composite( FLN is fluorescein,OS is 1-octane sulfonic acid sodium,and LDH is MgAl layered double hydroxide) was synthesized via ion-exchange method and the photoluminescence and detection for Fe( Ⅲ) was tested. In solid state,the FLN/OS-LDH composite displayed yellowish green emission( 565 nm) arising from organic FLN. In formamide( FM), the FLN/OS-LDH can be feasily delaminated into colloidal suspention,and showed blue-shifted green emission( ca. 531 nm). The recognition ability of the FLN/OS-LDH for metal cations was researched. The delaminated FLN/OS-LDH colloid in formamide exhibited high selectivity for Fe~(3+)over other ions( Mg~(2+),Ni~(2+),Co~(2+),Cu~(2+),Zn~(2+),Mn~(2+),Pb~(2+),Cd~(2+),and Hg~(2+)) with obvious fluorescence quenching,which can work as a kind of effective fluorescence sensor for detection of Fe~(3+). The detection limit of Fe~(3+)is determined to be 1. 27 × 10~(-7) mol/L and the quenching constant( K_(sv)) is 3. 44×10~2 L/mol.
FLN/OS-LDH composite( FLN is fluorescein,OS is 1-octane sulfonic acid sodium,and LDH is MgAl layered double hydroxide) was synthesized via ion-exchange method and the photoluminescence and detection for Fe( Ⅲ) was tested. In solid state,the FLN/OS-LDH composite displayed yellowish green emission( 565 nm) arising from organic FLN. In formamide( FM), the FLN/OS-LDH can be feasily delaminated into colloidal suspention,and showed blue-shifted green emission( ca. 531 nm). The recognition ability of the FLN/OS-LDH for metal cations was researched. The delaminated FLN/OS-LDH colloid in formamide exhibited high selectivity for Fe~(3+)over other ions( Mg~(2+),Ni~(2+),Co~(2+),Cu~(2+),Zn~(2+),Mn~(2+),Pb~(2+),Cd~(2+),and Hg~(2+)) with obvious fluorescence quenching,which can work as a kind of effective fluorescence sensor for detection of Fe~(3+). The detection limit of Fe~(3+)is determined to be 1. 27 × 10~(-7) mol/L and the quenching constant( K_(sv)) is 3. 44×10~2 L/mol.
引文
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[2]Klemkaite K.,Prosycevas I.,Taraskevicius R.,Khinsky A.,Kareiva A.,Cent.Eur.J.Chem.,2011,9(2),275-282
[3]Klemkaite K.,Khinsky A.,Kareiva A.,Mater.Lett.,2011,65(2),388-391
[4]Wu J.,Ren Z.Y.,Du S.C.,Kong L.J.,Liu B.W.,Xi W.,Zhu J.Q.,Fu H.G.,Nano Res.,2016,9(3),713-725
[5]Miyata S.,Clay Clay Min.,1983,31(4),305-311
[6]Newman S.P.,Jones W.,New J.Chem.,1998,22(2),105-115
[7]Jaubertie C.,Holgado M.J.,San Roman M.S.,Rives V.,Chem.Mat.,2006,18(13),3114-3121
[8]Klemkaite-Ramanauske K.,Zilinskas A.,Taraskevicius R.,Khinsky A.,Kareiva A.,Polyhedron,2014,68,340-345
[9]Kuwahara Y.,Tamagawa S.,Fujitani T.,Yamashita H.,Bull.Chem.Soc.Jpn.,2016,89(4),472-480
[10]Salak A.N.,Tedim J.,Kuznetsova A.I.,Ribeiro J.L.,Vieira L.G.,Zheludkevich M.L.,Ferreira M.G.S.,Chem.Phys.,2012,397,102-108
[11]Carneiro J.,Caetano A.F.,Kuznetsova A.,Maia F.,Salak A.N.,Tedim J.,Scharnagl N.,Zheludkevich M.L.,Ferreira M.G.S.,RSCAdv.,2015,5(50),39916-39929
[12]Li H.J.,Su X.Y.,Bai C.H.,Xu Y.Q.,Pei Z.C.,Sun S.G.,Sens.Actuator B Chem.,2016,225,109-114
[13]Lu P.,Liang S.,Qiu L.,Gao Y.S.,Wang Q.,J.Membr.Sci.,2016,504,196-205
[14]Serdechnova M.,Salak A.N.,Barbosa F.S.,Vieira D.E.L.,Tedim J.,Zheludkevich M.L.,Ferreira M.G.S.,J.Solid State Chem.,2016,233,158-165
[15]Jiang Y.,Song Y.,Li Y.,Tian W.,Pan Z.,Yang P.,Li Y.,Gu Q.,Hu L.,ACS Appl.Mater.Interfaces,2017,9(43),37645-37654
[16]Hu Z.Q.,Chen G.M.,Adv.Mater.,2014,26(34),5950-5956
[17]Liu J.,Chen G.M.,Yang J.P.,Polymer,2008,49(18),3923-3927
[18]Binnemans K.,Chem.Rev.,2009,109(9),4283-4374
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[39]Asadpour-Zeynali K.,Amini R.,Sens.Actuator B Chem.,2017,246,961-968
[40]Ma S.L.,Fan C.H.,Du L.,Huang G.L.,Yang X.J.,Tang W.P.,Makita Y.,Ooi K.,Chem.Mat.,2009,21(15),3602-3610
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[50]Martwiset S.,Nijpanich S.,Banturngsaksiri A.,Sriring,M.,Pandhumas T.,Youngme S.,J.Appl.Polym.Sci.,2013,130(5),3205-3211
[51]Jeong H.,Lee B.I.,Byeon S.H.,ACS Appl.Mater.Interfaces,2016,8(17),10946-10953
[52]Chen L.,Wul C.L.,Du P.,Feng X.W.,Wu P.,Cai C.M.,Talanta,2017,164,100-109