卷烟纸参数对细支卷烟主流烟气常规化学成分和香味成分释放量的影响
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摘要
为研究卷烟纸参数对细支卷烟主流烟气化学成分释放量的影响,通过单因素实验考察了卷烟纸透气度、定量,及麻浆和碳酸钙质量分数对细支卷烟主流烟气常规成分和香味成分释放量的影响。结果表明:(1)当透气度从50 CU增加至70 CU时,水分、CO和各种香味成分的释放量,香味成分的释放总量及其单位焦油释放量均降低。(2)当定量从27 g/m~2增加至37 g/m~2时,抽吸口数减少,TPM和水分的释放量均降低,CO的释放量增加;各种香味成分释放量及香味成分释放总量均降低,香味成分的单位焦油释放量降低。(3)当麻浆质量分数从0增加到40%时,TPM、水分、焦油及CO释放量均降低;各种香味成分的释放量及香味成分释放总量均小幅降低,香味成分的单位焦油释放量无明显变化。(4)当碳酸钙质量分数从27%增加到33%时,TPM、水分及焦油释放量降低,CO释放量小幅降低,各种香味成分的释放量及香味成分释放总量均小幅降低,香味成分的单位焦油释放量增加。
In order to investigate the effects of cigarette paper parameters on the releases of chemical components in mainstream smoke of slim cigarettes,the influences of paper air permeability,grammage,hemp pulp ratio and calcium carbonate content of cigarette paper were investigated by single-factor experiments.The results showed that:1) When cigarette paper air permeability increased from 50 to 70 CU,the releases of water,CO,single aroma component and total aroma components were decreased,and the delivery of total aroma components on per unit tar basis was reduced as well.2)When cigarette paper grammage increased from27 to 37 g/m~2,the puffing number decreased and the releases of TPM and water also decreased,while the release of CO increased.The releases of single aroma component and total aroma components were lowered,and the release of aroma components on per unit tar basis was also decreased.3) When hemp pulp ratio increased from 0 to 40%,the releases of TPM,water,tar and CO were reduced.The deliveries of single aroma component and total aroma components were decreased slightly,while the releases of aroma components on per unit tar basis did not change obviously.4)When calcium carbonate content increased from 27% to 33%,the releases of TPM,water,and tar were decreased;the releases of CO,single aroma component and total aroma components were decreased slightly,and the deliveries of aroma components on per unit tar basis were increased.
In order to investigate the effects of cigarette paper parameters on the releases of chemical components in mainstream smoke of slim cigarettes,the influences of paper air permeability,grammage,hemp pulp ratio and calcium carbonate content of cigarette paper were investigated by single-factor experiments.The results showed that:1) When cigarette paper air permeability increased from 50 to 70 CU,the releases of water,CO,single aroma component and total aroma components were decreased,and the delivery of total aroma components on per unit tar basis was reduced as well.2)When cigarette paper grammage increased from27 to 37 g/m~2,the puffing number decreased and the releases of TPM and water also decreased,while the release of CO increased.The releases of single aroma component and total aroma components were lowered,and the release of aroma components on per unit tar basis was also decreased.3) When hemp pulp ratio increased from 0 to 40%,the releases of TPM,water,tar and CO were reduced.The deliveries of single aroma component and total aroma components were decreased slightly,while the releases of aroma components on per unit tar basis did not change obviously.4)When calcium carbonate content increased from 27% to 33%,the releases of TPM,water,and tar were decreased;the releases of CO,single aroma component and total aroma components were decreased slightly,and the deliveries of aroma components on per unit tar basis were increased.
引文
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[2]郑琴,程占刚,李会荣,等.卷烟纸对卷烟主流烟气中7种有害成分释放量的影响[J].烟草科技,2010(12):49-51.ZHENG Qin,CHENG Zhangang,LI Huirong,et al.Effects of cigarette paper on deliveries of 7 harmful components in mainstream cigarette smoke[J].Tobacco Science&Technology,2010(12):49-51.
[3]赵乐,彭斌,于川芳,等.辅助材料设计参数对卷烟7种烟气有害成分释放量的影响[J].烟草科技,2012(10):46-50.ZHAO Le,PENG Bin,YU Chuanfang,et al.Effects of material parameters on deliveries of 7 harmful components in cigarette smoke[J].Tobacco Science&Technology,2012(10):46-50.
[4]彭斌,孙学辉,尚平平,等.辅助材料设计参数对烤烟型卷烟烟气焦油、烟碱和CO释放量的影响[J].烟草科技,2012(2):61-65.PENG Bin,SUN Xuehui,SHANG Pingping,et al.Effects of material’s parameters on deliveries of tar,nicotine,and CO in mainstream smoke of Virginia type cigarettes[J].Tobacco Science&Technology,2012(2):61-65.
[5]谢卫,黄朝章,苏明亮,等.辅助材料设计参数对卷烟7种烟气有害成分释放量及其危害性指数的影响[J].烟草科技,2013(1):31-38.XIE Wei,HUANG Chaozhang,SU Mingliang,et al.Relationships between design parameters of material and deliveries of 7 harmful components and hazard index of mainstream cigarette smoke[J].Tobacco Science&Technology,2013(1):31-38.
[6]李炎强,宗永立,屈展,等.通风稀释、加长滤嘴对卷烟主流烟气粒相挥发性、半挥发性中性成分释放量的影响[J].中国烟草学报,2008,14(6):19-23.LI Yanqiang,ZONG Yongli,QU Zhan,et al.Effects of ventilation dilution and longer filter on volatile and semi-volatile neutral components of mainstream cigarette smoke particulate[J].Acta Tabacaria Sinica,2008,14(6):19-23.
[7]蔡君兰,韩冰,张晓兵,等.滤嘴通风度对卷烟主流烟气中一些香味成分释放量的影响[J].烟草科技,2011(9):54-60.CAI Junlan,HAN Bing,ZHANG Xiaobing,et al.Effects of filter ventilation rate on deliveries of some aromatic components in mainstream cigarette smoke[J].Tobacco Science&Technology,2011(9):54-60.
[8]翟玉俊,田虎,朱先约,等.接装纸和成形纸透气度对主流烟气中碱性香味成分的影[J].烟草科技,2012(2):56-60.ZHAI Yujun,TIAN Hu,ZHU Xianyue,et al.Effects of permeability of tipping paper and plug wrapper on basic aroma components in mainstream cigarette smoke[J].Tobacco Science&Technology,2012(2):56-60.
[9]Mutti S,Hammond D,Borland R,et al.Beyond light and mild:cigarette brand descriptors and perceptions of risk in the International Tobacco Control(ITC)Four Country Survey[J].Addiction,2011,106(6):1166-1175.
[10]Schneider M,Schlüter A.A semi-empirical model for simulating the effect of design components on smoke deliveries[R/OL].Southampton:British American Tobacco.(1987)[2018-04-17].http://industrydocuments.library.ucsf.edu/tobacco/docs/#id=msfl0138.
[11]Irwin W D E.The effects of circumference on mainstream delivers and composition:progress report 2[R/OL].Southampton:British American Tobacco.(1989-02-22)[2018-04-17].http://industrydocuments.library.ucsf.edu/tobacco/docs/lnvv0205.
[12]Siu M,Mladjenovic N,Soo E.The analysis of mainstream smoke emissions of Canadian‘super slim’cigarettes[J].Tobacco Control,2013,22(6):e10.[2017-11-01].http://dx.doi.org/10.1136/tobaccocontrol-2012-050450.
[13]陈泽亮,罗玮,刘又年,等.碳酸钙粒径与含量对卷烟纸微孔结构及主流烟气CO释放量的影响[J].烟草科技,2015,48(5):41-46.CHEN Zeliang,LUO Wei,LIU Younian,et al.Effects of particle size and content of calcium carbonate on micropore structure of cigarette paper and CO delivery in mainstream cigarette smoke[J].Tobacco Science&Technology,2015,48(5):41-46.
[14]陈笃建,张颖璞,黄朝章,等.卷烟纸麻浆含量对卷烟感官质量的影响[J].中国造纸,2017,36(4):46-50.CHEN Dujian,ZHANG Yingpu,HUANG Chaozhang,et al.Effect of the proportion of hemp pulp in cigarette paper on cigarette sensory quality[J].China Pulp&Paper,2017,36(4):46-50.
[15]廖晓祥,赵云川,邹泉,等.梗丝形态对细支卷烟品质稳定性的影响[J].烟草科技,2016,49(10):74-80.LIAO Xiaoxiang,ZHAO Yunchuan,ZOU Quan,et al.Influences of cut stem morphology on quality consistency of super-slim cigarette[J].Tobacco Science&Technology,2016,49(10):74-80.
[16]甘学文,胡启秀,蒋锦锋,等.HCI模式对超细卷烟常规烟气成分测试结果的影响[J].烟草科技,2014(7):40-44.GAN Xuewen,HU Qixiu,JIANG Jinfeng,et al.Influences of HCI regime on determination results of routine smoke components of super slim cigarettes[J].Tobacco Science&Technology,2014(7):40-44.
[17]边照阳,王颖,李中皓,等.细支卷烟主流烟气有害成分释放量的分析[J].中国烟草学报,2016,22(5):33-40.BIAN Zhaoyang,WANG Ying,LI Zhonghao,et al.Analysis of mainstream smoke toxicant emissions of slim cigarettes[J].Acta Tabacaria Sinica,2016,22(5):33-40.
[18]田忠,陈闯,许宗保,等.制丝关键工序对细支卷烟燃烧温度及主流烟气成分的影响[J].中国烟草学报,2015,21(6):19-26.TIAN Zhong,CHEN Chuang,XU Zongbao,et al.Effects of key process steps on burning temperature and chemical components in mainstream smoke of slim cigarettes[J].Acta Tabacaria Sinica,2015,21(6):19-26.
[19]葛畅,赵明月,胡有持,等.细支与常规卷烟主流烟气常规指标及中性致香成分对比分析[J].烟草科技,2017,50(4):43-50.GE Chang,ZHAO Mingyue,HU Youchi,et al.Analysis of routine indexes and neutral aroma components in mainstream smoke of slim and normal cigarettes[J].Tobacco Science&Technology,2017,50(4):43-50.
[20]GB/T 16450—2004常规分析用吸烟机定义和标准条件[S].GB/T 16450—2004 Routine analytical cigarettesmoking machine—Definitions and standard conditions[S].
[21]GB/T 19609—2004卷烟用常规分析用吸烟机测定总粒相物和焦油[S].GB/T 19609—2004 Cigarette—Determination of total and nicotine-free dry particulate matter using a routine analytical machine[S].
[22]GB/T 23203.1—2008卷烟总粒相物中水分的测定第1部分:气相色谱法[S].GB/T 23203.1—2008 Cigarettes—Determination of water in smoke condensates—Part 1:Gas-chromatographic method[S].
[23]GB/T 23355—2009卷烟总粒相物中烟碱的测定气相色谱法[S].GB/T 23355—2009 Cigarettes—Determination of nicotine in smoke condensates—Gas-chromatographic method[S].
[24]GB/T 23356—2009卷烟烟气气相中一氧化碳的测定非散射红外线法[S].GB/T 23356—2009 Cigarette—Determination of carbon monoxide in the vapour phase of cigarette smoke—NDIR method[S].
[25]李春,向能军,沈宏林,等.卷烟纸对卷烟烟气有害物质的影响[J].光谱实验室,2009(6):1464-1468.LI Chun,XIANG Nengjun,SHEN Honglin,et al.Influence of cigarette paper to harmful components of cigarette smoke[J].Chinese Journal of Spectroscopy Laboratory,2009(6):1464-1468.
[26]黄朝章,李桂珍,连芬燕,等.卷烟纸特性对卷烟主流烟气7种有害成分释放量的影响[J].烟草科技,2011(4):38-45.HUANG Chaozhang,LI Guizhen,LIAN Fenyan,et al.Effects of cigarette paper properties on deliveries of 7harmful components in mainstream cigarette smoke[J].Tobacco Science&Technology,2011(4):38-45.
[27]谢卫,黄朝章,苏明亮,等.辅助材料设计参数对卷烟7种烟气有害成分释放量及其危害性指数的影响[J].烟草科技,2013(1):31-38.XIE Wei,HUANG Chaozhang,SU Mingliang,et al.Relationships between design parameters of material and deliveries of 7 harmful components and hazard index of mainstream cigarette smoke[J].Tobacco Science&Technology,2013(1):31-38.
[2]郑琴,程占刚,李会荣,等.卷烟纸对卷烟主流烟气中7种有害成分释放量的影响[J].烟草科技,2010(12):49-51.ZHENG Qin,CHENG Zhangang,LI Huirong,et al.Effects of cigarette paper on deliveries of 7 harmful components in mainstream cigarette smoke[J].Tobacco Science&Technology,2010(12):49-51.
[3]赵乐,彭斌,于川芳,等.辅助材料设计参数对卷烟7种烟气有害成分释放量的影响[J].烟草科技,2012(10):46-50.ZHAO Le,PENG Bin,YU Chuanfang,et al.Effects of material parameters on deliveries of 7 harmful components in cigarette smoke[J].Tobacco Science&Technology,2012(10):46-50.
[4]彭斌,孙学辉,尚平平,等.辅助材料设计参数对烤烟型卷烟烟气焦油、烟碱和CO释放量的影响[J].烟草科技,2012(2):61-65.PENG Bin,SUN Xuehui,SHANG Pingping,et al.Effects of material’s parameters on deliveries of tar,nicotine,and CO in mainstream smoke of Virginia type cigarettes[J].Tobacco Science&Technology,2012(2):61-65.
[5]谢卫,黄朝章,苏明亮,等.辅助材料设计参数对卷烟7种烟气有害成分释放量及其危害性指数的影响[J].烟草科技,2013(1):31-38.XIE Wei,HUANG Chaozhang,SU Mingliang,et al.Relationships between design parameters of material and deliveries of 7 harmful components and hazard index of mainstream cigarette smoke[J].Tobacco Science&Technology,2013(1):31-38.
[6]李炎强,宗永立,屈展,等.通风稀释、加长滤嘴对卷烟主流烟气粒相挥发性、半挥发性中性成分释放量的影响[J].中国烟草学报,2008,14(6):19-23.LI Yanqiang,ZONG Yongli,QU Zhan,et al.Effects of ventilation dilution and longer filter on volatile and semi-volatile neutral components of mainstream cigarette smoke particulate[J].Acta Tabacaria Sinica,2008,14(6):19-23.
[7]蔡君兰,韩冰,张晓兵,等.滤嘴通风度对卷烟主流烟气中一些香味成分释放量的影响[J].烟草科技,2011(9):54-60.CAI Junlan,HAN Bing,ZHANG Xiaobing,et al.Effects of filter ventilation rate on deliveries of some aromatic components in mainstream cigarette smoke[J].Tobacco Science&Technology,2011(9):54-60.
[8]翟玉俊,田虎,朱先约,等.接装纸和成形纸透气度对主流烟气中碱性香味成分的影[J].烟草科技,2012(2):56-60.ZHAI Yujun,TIAN Hu,ZHU Xianyue,et al.Effects of permeability of tipping paper and plug wrapper on basic aroma components in mainstream cigarette smoke[J].Tobacco Science&Technology,2012(2):56-60.
[9]Mutti S,Hammond D,Borland R,et al.Beyond light and mild:cigarette brand descriptors and perceptions of risk in the International Tobacco Control(ITC)Four Country Survey[J].Addiction,2011,106(6):1166-1175.
[10]Schneider M,Schlüter A.A semi-empirical model for simulating the effect of design components on smoke deliveries[R/OL].Southampton:British American Tobacco.(1987)[2018-04-17].http://industrydocuments.library.ucsf.edu/tobacco/docs/#id=msfl0138.
[11]Irwin W D E.The effects of circumference on mainstream delivers and composition:progress report 2[R/OL].Southampton:British American Tobacco.(1989-02-22)[2018-04-17].http://industrydocuments.library.ucsf.edu/tobacco/docs/lnvv0205.
[12]Siu M,Mladjenovic N,Soo E.The analysis of mainstream smoke emissions of Canadian‘super slim’cigarettes[J].Tobacco Control,2013,22(6):e10.[2017-11-01].http://dx.doi.org/10.1136/tobaccocontrol-2012-050450.
[13]陈泽亮,罗玮,刘又年,等.碳酸钙粒径与含量对卷烟纸微孔结构及主流烟气CO释放量的影响[J].烟草科技,2015,48(5):41-46.CHEN Zeliang,LUO Wei,LIU Younian,et al.Effects of particle size and content of calcium carbonate on micropore structure of cigarette paper and CO delivery in mainstream cigarette smoke[J].Tobacco Science&Technology,2015,48(5):41-46.
[14]陈笃建,张颖璞,黄朝章,等.卷烟纸麻浆含量对卷烟感官质量的影响[J].中国造纸,2017,36(4):46-50.CHEN Dujian,ZHANG Yingpu,HUANG Chaozhang,et al.Effect of the proportion of hemp pulp in cigarette paper on cigarette sensory quality[J].China Pulp&Paper,2017,36(4):46-50.
[15]廖晓祥,赵云川,邹泉,等.梗丝形态对细支卷烟品质稳定性的影响[J].烟草科技,2016,49(10):74-80.LIAO Xiaoxiang,ZHAO Yunchuan,ZOU Quan,et al.Influences of cut stem morphology on quality consistency of super-slim cigarette[J].Tobacco Science&Technology,2016,49(10):74-80.
[16]甘学文,胡启秀,蒋锦锋,等.HCI模式对超细卷烟常规烟气成分测试结果的影响[J].烟草科技,2014(7):40-44.GAN Xuewen,HU Qixiu,JIANG Jinfeng,et al.Influences of HCI regime on determination results of routine smoke components of super slim cigarettes[J].Tobacco Science&Technology,2014(7):40-44.
[17]边照阳,王颖,李中皓,等.细支卷烟主流烟气有害成分释放量的分析[J].中国烟草学报,2016,22(5):33-40.BIAN Zhaoyang,WANG Ying,LI Zhonghao,et al.Analysis of mainstream smoke toxicant emissions of slim cigarettes[J].Acta Tabacaria Sinica,2016,22(5):33-40.
[18]田忠,陈闯,许宗保,等.制丝关键工序对细支卷烟燃烧温度及主流烟气成分的影响[J].中国烟草学报,2015,21(6):19-26.TIAN Zhong,CHEN Chuang,XU Zongbao,et al.Effects of key process steps on burning temperature and chemical components in mainstream smoke of slim cigarettes[J].Acta Tabacaria Sinica,2015,21(6):19-26.
[19]葛畅,赵明月,胡有持,等.细支与常规卷烟主流烟气常规指标及中性致香成分对比分析[J].烟草科技,2017,50(4):43-50.GE Chang,ZHAO Mingyue,HU Youchi,et al.Analysis of routine indexes and neutral aroma components in mainstream smoke of slim and normal cigarettes[J].Tobacco Science&Technology,2017,50(4):43-50.
[20]GB/T 16450—2004常规分析用吸烟机定义和标准条件[S].GB/T 16450—2004 Routine analytical cigarettesmoking machine—Definitions and standard conditions[S].
[21]GB/T 19609—2004卷烟用常规分析用吸烟机测定总粒相物和焦油[S].GB/T 19609—2004 Cigarette—Determination of total and nicotine-free dry particulate matter using a routine analytical machine[S].
[22]GB/T 23203.1—2008卷烟总粒相物中水分的测定第1部分:气相色谱法[S].GB/T 23203.1—2008 Cigarettes—Determination of water in smoke condensates—Part 1:Gas-chromatographic method[S].
[23]GB/T 23355—2009卷烟总粒相物中烟碱的测定气相色谱法[S].GB/T 23355—2009 Cigarettes—Determination of nicotine in smoke condensates—Gas-chromatographic method[S].
[24]GB/T 23356—2009卷烟烟气气相中一氧化碳的测定非散射红外线法[S].GB/T 23356—2009 Cigarette—Determination of carbon monoxide in the vapour phase of cigarette smoke—NDIR method[S].
[25]李春,向能军,沈宏林,等.卷烟纸对卷烟烟气有害物质的影响[J].光谱实验室,2009(6):1464-1468.LI Chun,XIANG Nengjun,SHEN Honglin,et al.Influence of cigarette paper to harmful components of cigarette smoke[J].Chinese Journal of Spectroscopy Laboratory,2009(6):1464-1468.
[26]黄朝章,李桂珍,连芬燕,等.卷烟纸特性对卷烟主流烟气7种有害成分释放量的影响[J].烟草科技,2011(4):38-45.HUANG Chaozhang,LI Guizhen,LIAN Fenyan,et al.Effects of cigarette paper properties on deliveries of 7harmful components in mainstream cigarette smoke[J].Tobacco Science&Technology,2011(4):38-45.
[27]谢卫,黄朝章,苏明亮,等.辅助材料设计参数对卷烟7种烟气有害成分释放量及其危害性指数的影响[J].烟草科技,2013(1):31-38.XIE Wei,HUANG Chaozhang,SU Mingliang,et al.Relationships between design parameters of material and deliveries of 7 harmful components and hazard index of mainstream cigarette smoke[J].Tobacco Science&Technology,2013(1):31-38.