植物原料中半纤维素预水解反应动力学及其机理研究进展
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摘要
植物原料中半纤维素预水解受预水解时间、预水解温度等的影响,生产中应严格控制这些条件,以提高半纤维素预水解的质量。本文综述了近几年来植物原料半纤维素预水解反应动力学及其机理的研究状况,其中重点介绍了几种植物原料半纤维素预水解反应动力学模型及其机理。
The pre-hydrolysis of hemicellulose in plant materials is affected by hydrolysis time,hydrolysis temperature,etc. These conditions should be strictly controlled during production to improve the hydrolysis quality. In this paper,the research progress on the kinetics and mechanism of hemicellulose pre-hydrolysis of plant raw materials in recent years were reveiwed,several kinetic models and mechanism of some plant materials hemicellulose pre-hydrolysis were emphatically introduced.
The pre-hydrolysis of hemicellulose in plant materials is affected by hydrolysis time,hydrolysis temperature,etc. These conditions should be strictly controlled during production to improve the hydrolysis quality. In this paper,the research progress on the kinetics and mechanism of hemicellulose pre-hydrolysis of plant raw materials in recent years were reveiwed,several kinetic models and mechanism of some plant materials hemicellulose pre-hydrolysis were emphatically introduced.
引文
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[9] Aguilar R,Ramrez J A,Garrote G,et al. Kinetic study of the acidhydrolysis of sugar cane bagasse[J]. Journal of Food Engineering,2002,55(4):309.
[10] Garrote G,Dominguez H,Parajo J C. Kinetic modelling of corncobautohydrolysis[J]. Process Bio-Chemistry,2001,36(6):571.
[11] Garrote G,Dominguez H,Parajo J C. Autohydrolysis of corncob:study of non-isothermal operation for xylooligosaccharide production[J]. Journal of Food Engineering,2002,52(3):211.
[12] YUE Chang-hai,BO De-chen,LI Ping-li. Kinetics of acetic acidhydrolysis of xylan in corncob[J]. Chemical Engineering,2011,39(9):16.岳昌海,薄德臣,李凭力.醋酸水解玉米芯中木聚糖的动力学[J].化学工程,2011,39(9):16.
[13] ZHONG Xin,JIANG Chong-wen,ZHOU Ke-yuan. Research onhemicellulose hydrolysis kinetics catalyzed by SO24-/Ti-MCM-41solid acid[J]. Cellulose Science and Technology, 2014, 22(1):36.钟馨,蒋崇文,周克渊. SO24-/Ti-MCM-41固体酸催化半纤维素水解动力学研究[J].纤维素科学与技术,2014,22(1):36.
[14] Kumar L,Chandra R,Chung P A,et al. Can the same steam pre-treatment conditions be used for most softwoods to achieve good,en-zymatic hydrolysis and sugar yields?[J]. Bioresource Technology,2010,101(20):7827.
[15] MA Jing. Local chemical dissolution mechanism of poplar hemicellu-lose pretreated by hot water[J]. Beijing:Beijing Forestry Universi-ty,2015.马静.热水预处理杨木半纤维素的局部化学溶解机理[D].北京:北京林业大学,2015.
[16] Conner A L,Lorenz L F. Kinetic modeling of hardwood prehydrolys-is. Part III. Water and dilute acetic acid prehydorlysis of southernred oak[J]. Wood Fiber,1986,18(2):248.
[17] Borrega M,Nieminen K,Sixta H. Degradation kinetics of the maincarbohydrates in birch wood during hot water extraction in a batch re-actor at elevated temperatures[J]. Bioresource Technology,2011,102(22):10724.
[18] Tizazu B Z,Moholkar V S. Kinetic and thermodynamic analysis ofdilute acid hydrolysis of sugarcane bagasse[J]. Bioresource Technol-ogy,2018,250:197.
[19] DENG Yuan-de. Study on hydrolysis kinetics of wheat straw hemi-cellulose in formic acid-hydrochloric acid mixed solution[J]. FoodTechnology,2010,35(8):157.邓远德.麦草半纤维素在甲酸-盐酸混合溶液中水解动力学研究[J].食品科技,2010,35(8):157.
[20] Overend R P,Chornet E. Fractionation of lignocellulosics by steam-aqueous pretreatments[J]. Philosophical Transactions for the RoyalSociety of London. Series A,1987,321(1561):523.
[21] Brasch D J,Free K W. Prehydrolysis-kraft pulping of Pinus radiatagrown in New Zealand[J]. Tappi Journal,1965,48(4):245.
[22] DUAN Chao,FENG Wenying,ZHANG Yanling,et al. Effect ofpre-hydrolysis of hot water on hemi-cellulose extraction of poplar andsubsequent kraft pulping[J]. Transactions of China Pulp and Pa-per,2013,28(2):1.段超,冯文英,张艳玲,等.热水预水解对杨木半纤维素提取及后续硫酸盐法制浆的影响[J].中国造纸学报,2013,28(2):1.
[23] XU Feng,YANG Guihua,JI Xingxiang,et al. Effect of P Factor onDissolution of Poplar Hemicellulose during the Hydrothermal Pre-treatment Process[J]. China Pulp&Paper,2018,37(8):1.徐丰,杨桂花,吉兴香,等.热水预处理过程中P因子对杨木半纤维素溶出效果的影响[J].中国造纸,2018,37(8):1.
[24] LI Hong-bin,FANG Gui-gan,SHI Ying-qiao,et al. Study on theExtraction efficiency of hemicellulose by pre-hydrolysis conditions ofeucalyptus[J]. Paper Science&Technology,2016,35(1):28.李红斌,房桂干,施英乔,等.桉木预水解条件对半纤维素提取效果的研究[J].造纸科学与技术,2016,35(1):28.
[25] Shi Hai Qiang,Guo Kai Yuan,Sun Yan Ning,et al. Extraction of-hemicellulose from Acacia Wood via autohydrolysis and ethanol pre-cipitation[J]. Paper and Biomaterials,2016,1(1):1.
[26] WANG An,BI Jiajie,LI Haiming. Research on Variations of Cellu-lose and Hemicellulose in Acid Catalytic Pre-hydrolysis of Corn Stalk[J]. China Pulp&Paper,2016,35(4):6.王安,毕佳捷,李海明.玉米秸秆酸催化预水解过程中纤维素和半纤维素变化规律研究[J].中国造纸,2016,35(4):6.
[27] Liu C,Wyman C E. The effect of flow rate of compressed hot wateron xylan,lignin,and total mass removal from corn stover[J]. In-dustrial&Engineering Chemistry Research,2003,42(21):5409.
[28] YU Qiang,ZHUANG Xin-shu,YUAN Zhen-hong,et al. Hydrolysisof sweet sorghum bagasse hemi-cellulose in high temperature liquidwater and mechanism[J]. Journal of Chemical Industry,2012,63(2):599.余强,庄新姝,袁振宏,等.高温液态水中甜高粱渣半纤维素水解及其机理[J].化工学报,2012,63(2):599.
[29] XIA Qing,TIAN Yan,YAO Lan,et al. Extraction and properties ofhemicellulose from corn stalk before and after ethanol pretreatment[J]. Transactions of China Pulp and Paper,2015,30(2):12.夏青,田彦,姚兰,等.乙醇预处理前后玉米秸秆半纤维素的提取及性质研究[J].中国造纸学报,2015,30(2):12.
[30] Fu LianHua,Liu Shan,Li ShuMing,et al. Characterization ofhemicelluloses extracted from Populus Tomentosa Carr. by the hy-drothermal method with ethanol[J]. Paper and Biomaterials,2017,2(3):1.
[2] JIN Qiang,ZHANG Hong-man,XU Rui,et al. Hydrolysis kinetics ofhemicellulose dilute acid cycle spray filtration[J]. Journal of Chemi-cal Industry,2011,62(1):103.金强,张红漫,徐锐,等.半纤维素稀酸循环喷淋冲滤水解动力学[J].化工学报,2011,62(1):103.
[3] TIAN Long,MA Xiao-jian. Degradation kinetics of wheat straw hemi-cellulose propionic acid pretreatment[J]. Journal of Agricultural Ma-chinery,2012,43(10):105.田龙,马晓建.小麦秸秆半纤维素丙酸法预处理降解动力学[J].农业机械学报,2012,43(10):105.
[4] TAN Lihong,MA Lefan,LIU Dingjun,et al. Research of dissolutionkinetics of water prehydrolyzed hemicellulose of bamboo[J]. Transac-tions of China Pulp and Paper,2012,27(3):33.谭丽红,马乐凡,刘定军,等.楠竹水预水解半纤维素溶出动力学的研究[J].中国造纸学报,2012,27(3):33.
[5] BIN Dong-ming. Study on the technology and mechanism of pre-ex-traction of hemicellulose before sugar cane bagasse pulping[D].Nanning:Guangxi University,2009.宾东明.甘蔗渣制浆前预抽提半纤维素的工艺及机理研究[D].南宁:广西大学,2009.
[6] Saeman J F. Kinetics of wood saccharification-hydrolysis of celluloseand decomposition of sugars in dilute acid at high temperature[J].Industrial&Engineering Chemistry,1945,37(1):43.
[7] SUN Yong,ZHANG Jin-ping,YANG Gang,et al. Kinetic studies ofhydrochloric acid hydrolysis of xylan in corn straw[J]. Chemical En-gineering,2007(10):49.孙勇,张金平,杨刚,等.盐酸水解玉米秸秆木聚糖的动力学研究[J].化学工程,2007(10):49.
[8] Garrote G,Dominguez H,Parajo J C. Hydrothermal processing of lig-nocellulosic materials[J]. European Journal of Wood and Wood Prod-ucts,1999,57(3):191.
[9] Aguilar R,Ramrez J A,Garrote G,et al. Kinetic study of the acidhydrolysis of sugar cane bagasse[J]. Journal of Food Engineering,2002,55(4):309.
[10] Garrote G,Dominguez H,Parajo J C. Kinetic modelling of corncobautohydrolysis[J]. Process Bio-Chemistry,2001,36(6):571.
[11] Garrote G,Dominguez H,Parajo J C. Autohydrolysis of corncob:study of non-isothermal operation for xylooligosaccharide production[J]. Journal of Food Engineering,2002,52(3):211.
[12] YUE Chang-hai,BO De-chen,LI Ping-li. Kinetics of acetic acidhydrolysis of xylan in corncob[J]. Chemical Engineering,2011,39(9):16.岳昌海,薄德臣,李凭力.醋酸水解玉米芯中木聚糖的动力学[J].化学工程,2011,39(9):16.
[13] ZHONG Xin,JIANG Chong-wen,ZHOU Ke-yuan. Research onhemicellulose hydrolysis kinetics catalyzed by SO24-/Ti-MCM-41solid acid[J]. Cellulose Science and Technology, 2014, 22(1):36.钟馨,蒋崇文,周克渊. SO24-/Ti-MCM-41固体酸催化半纤维素水解动力学研究[J].纤维素科学与技术,2014,22(1):36.
[14] Kumar L,Chandra R,Chung P A,et al. Can the same steam pre-treatment conditions be used for most softwoods to achieve good,en-zymatic hydrolysis and sugar yields?[J]. Bioresource Technology,2010,101(20):7827.
[15] MA Jing. Local chemical dissolution mechanism of poplar hemicellu-lose pretreated by hot water[J]. Beijing:Beijing Forestry Universi-ty,2015.马静.热水预处理杨木半纤维素的局部化学溶解机理[D].北京:北京林业大学,2015.
[16] Conner A L,Lorenz L F. Kinetic modeling of hardwood prehydrolys-is. Part III. Water and dilute acetic acid prehydorlysis of southernred oak[J]. Wood Fiber,1986,18(2):248.
[17] Borrega M,Nieminen K,Sixta H. Degradation kinetics of the maincarbohydrates in birch wood during hot water extraction in a batch re-actor at elevated temperatures[J]. Bioresource Technology,2011,102(22):10724.
[18] Tizazu B Z,Moholkar V S. Kinetic and thermodynamic analysis ofdilute acid hydrolysis of sugarcane bagasse[J]. Bioresource Technol-ogy,2018,250:197.
[19] DENG Yuan-de. Study on hydrolysis kinetics of wheat straw hemi-cellulose in formic acid-hydrochloric acid mixed solution[J]. FoodTechnology,2010,35(8):157.邓远德.麦草半纤维素在甲酸-盐酸混合溶液中水解动力学研究[J].食品科技,2010,35(8):157.
[20] Overend R P,Chornet E. Fractionation of lignocellulosics by steam-aqueous pretreatments[J]. Philosophical Transactions for the RoyalSociety of London. Series A,1987,321(1561):523.
[21] Brasch D J,Free K W. Prehydrolysis-kraft pulping of Pinus radiatagrown in New Zealand[J]. Tappi Journal,1965,48(4):245.
[22] DUAN Chao,FENG Wenying,ZHANG Yanling,et al. Effect ofpre-hydrolysis of hot water on hemi-cellulose extraction of poplar andsubsequent kraft pulping[J]. Transactions of China Pulp and Pa-per,2013,28(2):1.段超,冯文英,张艳玲,等.热水预水解对杨木半纤维素提取及后续硫酸盐法制浆的影响[J].中国造纸学报,2013,28(2):1.
[23] XU Feng,YANG Guihua,JI Xingxiang,et al. Effect of P Factor onDissolution of Poplar Hemicellulose during the Hydrothermal Pre-treatment Process[J]. China Pulp&Paper,2018,37(8):1.徐丰,杨桂花,吉兴香,等.热水预处理过程中P因子对杨木半纤维素溶出效果的影响[J].中国造纸,2018,37(8):1.
[24] LI Hong-bin,FANG Gui-gan,SHI Ying-qiao,et al. Study on theExtraction efficiency of hemicellulose by pre-hydrolysis conditions ofeucalyptus[J]. Paper Science&Technology,2016,35(1):28.李红斌,房桂干,施英乔,等.桉木预水解条件对半纤维素提取效果的研究[J].造纸科学与技术,2016,35(1):28.
[25] Shi Hai Qiang,Guo Kai Yuan,Sun Yan Ning,et al. Extraction of-hemicellulose from Acacia Wood via autohydrolysis and ethanol pre-cipitation[J]. Paper and Biomaterials,2016,1(1):1.
[26] WANG An,BI Jiajie,LI Haiming. Research on Variations of Cellu-lose and Hemicellulose in Acid Catalytic Pre-hydrolysis of Corn Stalk[J]. China Pulp&Paper,2016,35(4):6.王安,毕佳捷,李海明.玉米秸秆酸催化预水解过程中纤维素和半纤维素变化规律研究[J].中国造纸,2016,35(4):6.
[27] Liu C,Wyman C E. The effect of flow rate of compressed hot wateron xylan,lignin,and total mass removal from corn stover[J]. In-dustrial&Engineering Chemistry Research,2003,42(21):5409.
[28] YU Qiang,ZHUANG Xin-shu,YUAN Zhen-hong,et al. Hydrolysisof sweet sorghum bagasse hemi-cellulose in high temperature liquidwater and mechanism[J]. Journal of Chemical Industry,2012,63(2):599.余强,庄新姝,袁振宏,等.高温液态水中甜高粱渣半纤维素水解及其机理[J].化工学报,2012,63(2):599.
[29] XIA Qing,TIAN Yan,YAO Lan,et al. Extraction and properties ofhemicellulose from corn stalk before and after ethanol pretreatment[J]. Transactions of China Pulp and Paper,2015,30(2):12.夏青,田彦,姚兰,等.乙醇预处理前后玉米秸秆半纤维素的提取及性质研究[J].中国造纸学报,2015,30(2):12.
[30] Fu LianHua,Liu Shan,Li ShuMing,et al. Characterization ofhemicelluloses extracted from Populus Tomentosa Carr. by the hy-drothermal method with ethanol[J]. Paper and Biomaterials,2017,2(3):1.