TiO_2基薄膜的光生阴极保护研究进展
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摘要
综述了Ti O_2薄膜的光生阴极保护基本原理、制备技术及其改性和复合的研究现状。探讨了Ti O_2基薄膜制备技术的优缺点,分析了Ti O_2基薄膜微观结构、离子掺杂、贵金属表面沉积及复合材料对光生阴极保护的影响及其作用机理。最后,对Ti O_2基薄膜光生阴极保护的未来前景进行了展望。
In this work,the mechanism of photo-cathodic protection of Ti O2-based films was introduced,and the research progress of preparation technology and modification were reviewed. The characteristics of the preparation technology of Ti O2-based films were discussed,and the influencing mechanisms of microstructure,ion doping,precious-metal deposition and composite materials on the photo-cathodic protection of Ti O2-based films were further analyzed. As last,the future development on the photo-cathodic protection of Ti O2-based films was forecasted.
In this work,the mechanism of photo-cathodic protection of Ti O2-based films was introduced,and the research progress of preparation technology and modification were reviewed. The characteristics of the preparation technology of Ti O2-based films were discussed,and the influencing mechanisms of microstructure,ion doping,precious-metal deposition and composite materials on the photo-cathodic protection of Ti O2-based films were further analyzed. As last,the future development on the photo-cathodic protection of Ti O2-based films was forecasted.
引文
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[2]于立新.石油化工设备腐蚀的防护与检测[J].石油技术,2016(6):1-6.
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[13]SUN L C,HOU P.Spectroscopic ellipsometry study on e-beam deposited titanium dioxide films[J].Thin Solid Films,2004,455(1):525-529.
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[18]LI J,LIN C J,LAI Y K,et al.Photogenerated cathodic protection of flower-like,nanostructured,N-doped Ti O2film on stainless steel[J].Surface and Coatings Technology,2010,205:557-564.
[19]ZHANG W W,GUO H L,SUN H Q,et al.Hydrothermal synthesis and photoelectrochemical performance enhancement of Ti O2/graphene composite in photo-generated cathodic protection[J].Applied Surface Science,2016,382:128-134.
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[21]李洪义,冉津,王金淑,等.液相沉积法制备Ti O2薄膜及其对304不锈钢的光生阴极防护[J].北京工业大学学报,2009,35(9):102-106.
[22]LI H,WANG X T,ZHANG L,et al.Preparation and photocathodic protection performance of Cd Se/reduced graphene oxide/Ti O2composite[J].Corrosion Science,2015,94:342-349.
[23]ZHANG J,DU R G,ZHU Y F,et al.Highly efficient Cd Se/Cd S co-sensitized Ti O2nanotube films for photocathodic protection of stainless steel[J].Electrochimica Acta,2012,83:59-64.
[24]LI H,WANG X T,LIU Y,et al.Ag and Sn O2co-sensitized Ti O2photoanodes for protection of 304SS under visible light[J].Corrosion Science,2014,82:145-153.
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[28]HUANG J G,GUO X T,WANG B,et al.Synthesis and photocatalytic activity of Mo-doped Ti O2nanoparticles[J].Journal of Spectroscopy,2015,3:1-8.
[29]YANG Y,LIAO J J,LI Y F,et al.Electrochemically selfdoped hierarchical Ti O2nanotube arrays for enhanced visible-light photoelctrochemical performance:an experimental and computational study[J].RSC Advances,2016(6):46 871-46 878.
[30]常磊.Ti O2纳米管阵列的多元改性及其光电化学性质研究[D].郑州:河南工业大学,2016.
[31]ARMAN S Y,OMIDVAR H,TABAIAN S H,et al.Evaluation of nanostructured S-doped Ti O2thin films and their photoelectrochemical application as photoanode for corrosion protection of 304 stainless steel[J].Surface and Coatings Technology,2014,382:128-134.
[32]ZHU L,CUI X L,SHEN J,et al.Visible light photoelectrochemical response of carbon-doped Ti O2thin films prepared by DC reactive magnetron sputtering[J].Acta PhysicoChimica Sinica,2007,23(11):1 662-1 666.
[33]GUO X Q,CAO L X,SU G,et al.Graphene incorporated nanocrystalline Ti O2films for the photocathodic protection of304 stainless steel[J].Applied Surface Science,2013,20(9):13-16.
[34]ZHU L,XIE J S,CUI X L,et al.Photoelectrochemical and optical properties of N-doped Ti O2thin films prepared by oxidation of sputtered Ti Nxfilms[J].Vacuum,2010,84(6):797-802.
[35]WANG H F,WANG Z Q,HONG H X,et al.Preparation of cerium-doped Ti O2film on 304 stainless steel and its bactericidal effect in the presence of sulfate-reducing bacteria(SRB)[J].Materials Chemistry and Physics,2010,124(1):791-794.
[36]张伟华.Ag负载对N掺杂Ti O2薄膜的光电及光催化性能的影响[D].太原:太原理工大学,2016.
[37]YANG Z L,LU J,YE W C,et al.Preparation of Pt/Ti O2hollow nanofibers with highly visible light photocatalytic activity[J].Applied Surface Science,2017,392:472-480.
[38]TATSUMA T,SAITOH S,OHKO Y,et al.Ti O2-WO3Photoelectrochemical anticorrosion system with an energy storage ability[J].Chemistry of Materials,2001,13:2 838-2 842.
[39]SUBASRI R,SHINOHARA T.Investigations on Sn O2-Ti O2composite photoelectrodes for corrosion protection[J].Electrochemistry Communications,2003(5):897-902.
[40]ZHOU M J,ZENG Z O,ZHONG L.Photogenerated cathode protection properties of nano-sized Ti O2/WO3coating[J].Corrosion Science,2009,51:1 386-1 391.
[41]ZHOU M J,ZENG Z O,ZHONG L.Energy storage ability and anti-corrosion protection properties of Ti O2-Sn O2system[J].Materials and Corrosion,2010,61(4):324-327.
[42]SHEN G X,CHEN Y C,LIN C J.Preparation of nano Ti O2-V2O5composite coating and its functions in corrosion protection of metals[J].Acta Physico-Chimica Sinica,2005,21(5):485-489.
[43]SUN M M,CHEN Z Y.Enhanced photoelectrochemical cathodic protection performance of the In2O3/Ti O2composite[J].Journal of the Electrochemical Society,2015,16(3):C96-C104.
[44]张亮,王秀通,李红,等.Cd Se-Ti O2复合材料对304不锈钢的光生阴极保护性能[J].腐蚀与防护,2015,36(3):258-262.
[45]ZHANG L,WANG X T,LIU F G,et al.Photogenerated cathodic protection of 304SS by Zn Se/Ti O2NTs under visible light[J].Materials Letters,2015,143:116-119.
[46]LI H,WANG X T,WEI Q Y,et al.Enhanced photocathodic protection performance of Ag/graphene/Ti O2composite for304SS under visible light[J].Nanotechnology,2017,28(22):225 701-225 711.
[47]LI H,WANG X T,ZHANG L,et al.Cd Te and graphene cosensitized Ti O2nanotube array photoanodes for protection of304SS under visible light[J].Nanotechnology,2015,26(15):155 704-155 714.
[48]ZHANG J,HU J,ZHU Y F,et al.Fabrication of Cd Te/Zn S core/shell quantum dots sensitized Ti O2nanotube films for photocathodic protection of stainless steel[J].Corrosion Science,2015,99:118-124.
[49]刘男.Ti O2/Al2O3复合薄膜光催化特性研究[D].西安:西安电子科技大学,2007.
[50]TANG X K,FENG Q M,LIU K,et al.Synthesis and characterization of a novel nanofibrous Ti O2/Si O2composite with enhanced photocatalytic activity[J].Materials Letters,2016,183:175-178.
[51]REN J F,QIAN B,LI J Z,et al.Highly efficient polypyrrole sensitized Ti O2nanotube films for photocathodic protection of Q235 carbon steel[J].Corrosion Science,2016,111:596-601.
[52]CUI S W,YIN X Y,YU Q L,et al.Polypyrrole nanowire/Ti O2nanotube nanocomposites as photoanodes for photocathodic protection of Ti substrate and 304 stainless steel under visible light[J].Corrosion Science,2015,98:471-477.
[53]LIU L,HU J M,LENG W H,et al.Novel bis-silane/Ti O2bifunctional hybrid films for metal corrosion protection both under ultraviolet irradiation and in the dark[J].Scripta Materialia,2007,57:549-552.
[2]于立新.石油化工设备腐蚀的防护与检测[J].石油技术,2016(6):1-6.
[3]李婷,张耀武,吕岩,等.船体材料腐蚀与防护措施的研究进展[J].广州化工,2015,43(6):33-35.
[4]周芳,岩雨,谢春乾,等.腐蚀与摩擦交互作用对人工关节钴合金材料损失机理的影响:第六届全国腐蚀大会论文集[C].银川:全国摩擦大会,2011.
[5]柯伟.中国工业与自然环境腐蚀调查[J].全面腐蚀控制,2003,17(1):1-10.
[6]KUMAR P S S,SIVAKUMAR R,ANANDAN S,et al.Photocatalytic degradation of acid red 88 using Au-Ti O2nanoparticles in aqueous solution[J].Water Research,2008,42(19):4 878-4 884.
[7]JIANG Y H,SUN Y M,LIU H,et al,Solar photocatalytic degradation of C.I.basic blue 41 in an aqueous suspension of Ti O2-Zn O[J].Dyes and Pigments,2008,78(1):77-83.
[8]VENKATACHALAM N,PALANICHAMY M,MURUGESAN V.Sol-gel preparation and characterization of nanosize Ti O2:Its photocatalytic performance[J].Materials Chemistry and Physics,2007,104:454-459.
[9]YUAN J,FUJISAWA R,TSUJIKAMA S.Photopotentials of copper coated with Ti O2by sol-gel method[J].Zairyo-toKankyo,1994,43:433-436.
[10]曹楚南.腐蚀电化学原理[M].北京:化学工业出版社,2008:24-26.
[11]张盼盼.磁控溅射制备Ti O2薄膜研究[D].沈阳:沈阳大学,2015.
[12]YANG T S,SHIU C B,WONG M S,et al.Structure and hydrophilicity of titanium oxide films prepared by electron beam evaporation[J].Surface Science,2004,548:75-82.
[13]SUN L C,HOU P.Spectroscopic ellipsometry study on e-beam deposited titanium dioxide films[J].Thin Solid Films,2004,455(1):525-529.
[14]SAHNESARAYI M K,SARPOOLAKY H,RASTEGARI S,et al.Effect of heat treatment temperature on the performance of nano-Ti O2coating in protecting 316L stainless steel against corrosion under UV illumination and dark conditions[J].Surface and Coatings Technology,2014,258:861-870.
[15]ZHU Y F,ZHANG J,ZHANG Y Y,et al.Anticorrosion properties of modified nano-Ti O2films prepared by sol-gel method[J].Acta Physico-Chimica Sinica,2012,28(2):393-398.
[16]LI J,YUN H,LIN C J.Reparation and investigations on the Ti O2nanotube arrays for cathodic protection of 316L stainless steel[J].Electrochemistry,2007,13(4):367-371.
[17]LI M C,LUO S Z,WU P F,et al.Photocathodic protection effect of Ti O2films for carbon steel in 3%Na Cl solutions[J].Electrochimica Acta,2005,50:3 401-3 406.
[18]LI J,LIN C J,LAI Y K,et al.Photogenerated cathodic protection of flower-like,nanostructured,N-doped Ti O2film on stainless steel[J].Surface and Coatings Technology,2010,205:557-564.
[19]ZHANG W W,GUO H L,SUN H Q,et al.Hydrothermal synthesis and photoelectrochemical performance enhancement of Ti O2/graphene composite in photo-generated cathodic protection[J].Applied Surface Science,2016,382:128-134.
[20]LEI C X,LIU Y,ZHOU H,et al.Photogenerated cathodic protection of stainless steel by liquid-phase-deposited sodium polyacrylate/Ti O2hybrid films[J].Corrosion Science,2013,68:214-222.
[21]李洪义,冉津,王金淑,等.液相沉积法制备Ti O2薄膜及其对304不锈钢的光生阴极防护[J].北京工业大学学报,2009,35(9):102-106.
[22]LI H,WANG X T,ZHANG L,et al.Preparation and photocathodic protection performance of Cd Se/reduced graphene oxide/Ti O2composite[J].Corrosion Science,2015,94:342-349.
[23]ZHANG J,DU R G,ZHU Y F,et al.Highly efficient Cd Se/Cd S co-sensitized Ti O2nanotube films for photocathodic protection of stainless steel[J].Electrochimica Acta,2012,83:59-64.
[24]LI H,WANG X T,LIU Y,et al.Ag and Sn O2co-sensitized Ti O2photoanodes for protection of 304SS under visible light[J].Corrosion Science,2014,82:145-153.
[25]漆海清,朱燕峰,张娟,等.Ti O2纳米管阵列膜的制备及对304不锈钢的光生阴极保护效应[J].功能材料,2012,43(9):1 147-1 150.
[26]ZHU Y F,DU R G,LI J,et al.Photogenerated cathodic protection properties of a Ti O2nanowire film prepared by a hydrothermal method[J].Acta Physico-Chimica Sinica,2010,26(9):2 349-2 353.
[27]CAI C X,ZHOU H,WANG C,et al.Self-assembly of ordered mesoporous Ti O2thin films as photoanodes for cathodic protection of stainless steel[J].Electrochimica Acta,2013,87:245-249.
[28]HUANG J G,GUO X T,WANG B,et al.Synthesis and photocatalytic activity of Mo-doped Ti O2nanoparticles[J].Journal of Spectroscopy,2015,3:1-8.
[29]YANG Y,LIAO J J,LI Y F,et al.Electrochemically selfdoped hierarchical Ti O2nanotube arrays for enhanced visible-light photoelctrochemical performance:an experimental and computational study[J].RSC Advances,2016(6):46 871-46 878.
[30]常磊.Ti O2纳米管阵列的多元改性及其光电化学性质研究[D].郑州:河南工业大学,2016.
[31]ARMAN S Y,OMIDVAR H,TABAIAN S H,et al.Evaluation of nanostructured S-doped Ti O2thin films and their photoelectrochemical application as photoanode for corrosion protection of 304 stainless steel[J].Surface and Coatings Technology,2014,382:128-134.
[32]ZHU L,CUI X L,SHEN J,et al.Visible light photoelectrochemical response of carbon-doped Ti O2thin films prepared by DC reactive magnetron sputtering[J].Acta PhysicoChimica Sinica,2007,23(11):1 662-1 666.
[33]GUO X Q,CAO L X,SU G,et al.Graphene incorporated nanocrystalline Ti O2films for the photocathodic protection of304 stainless steel[J].Applied Surface Science,2013,20(9):13-16.
[34]ZHU L,XIE J S,CUI X L,et al.Photoelectrochemical and optical properties of N-doped Ti O2thin films prepared by oxidation of sputtered Ti Nxfilms[J].Vacuum,2010,84(6):797-802.
[35]WANG H F,WANG Z Q,HONG H X,et al.Preparation of cerium-doped Ti O2film on 304 stainless steel and its bactericidal effect in the presence of sulfate-reducing bacteria(SRB)[J].Materials Chemistry and Physics,2010,124(1):791-794.
[36]张伟华.Ag负载对N掺杂Ti O2薄膜的光电及光催化性能的影响[D].太原:太原理工大学,2016.
[37]YANG Z L,LU J,YE W C,et al.Preparation of Pt/Ti O2hollow nanofibers with highly visible light photocatalytic activity[J].Applied Surface Science,2017,392:472-480.
[38]TATSUMA T,SAITOH S,OHKO Y,et al.Ti O2-WO3Photoelectrochemical anticorrosion system with an energy storage ability[J].Chemistry of Materials,2001,13:2 838-2 842.
[39]SUBASRI R,SHINOHARA T.Investigations on Sn O2-Ti O2composite photoelectrodes for corrosion protection[J].Electrochemistry Communications,2003(5):897-902.
[40]ZHOU M J,ZENG Z O,ZHONG L.Photogenerated cathode protection properties of nano-sized Ti O2/WO3coating[J].Corrosion Science,2009,51:1 386-1 391.
[41]ZHOU M J,ZENG Z O,ZHONG L.Energy storage ability and anti-corrosion protection properties of Ti O2-Sn O2system[J].Materials and Corrosion,2010,61(4):324-327.
[42]SHEN G X,CHEN Y C,LIN C J.Preparation of nano Ti O2-V2O5composite coating and its functions in corrosion protection of metals[J].Acta Physico-Chimica Sinica,2005,21(5):485-489.
[43]SUN M M,CHEN Z Y.Enhanced photoelectrochemical cathodic protection performance of the In2O3/Ti O2composite[J].Journal of the Electrochemical Society,2015,16(3):C96-C104.
[44]张亮,王秀通,李红,等.Cd Se-Ti O2复合材料对304不锈钢的光生阴极保护性能[J].腐蚀与防护,2015,36(3):258-262.
[45]ZHANG L,WANG X T,LIU F G,et al.Photogenerated cathodic protection of 304SS by Zn Se/Ti O2NTs under visible light[J].Materials Letters,2015,143:116-119.
[46]LI H,WANG X T,WEI Q Y,et al.Enhanced photocathodic protection performance of Ag/graphene/Ti O2composite for304SS under visible light[J].Nanotechnology,2017,28(22):225 701-225 711.
[47]LI H,WANG X T,ZHANG L,et al.Cd Te and graphene cosensitized Ti O2nanotube array photoanodes for protection of304SS under visible light[J].Nanotechnology,2015,26(15):155 704-155 714.
[48]ZHANG J,HU J,ZHU Y F,et al.Fabrication of Cd Te/Zn S core/shell quantum dots sensitized Ti O2nanotube films for photocathodic protection of stainless steel[J].Corrosion Science,2015,99:118-124.
[49]刘男.Ti O2/Al2O3复合薄膜光催化特性研究[D].西安:西安电子科技大学,2007.
[50]TANG X K,FENG Q M,LIU K,et al.Synthesis and characterization of a novel nanofibrous Ti O2/Si O2composite with enhanced photocatalytic activity[J].Materials Letters,2016,183:175-178.
[51]REN J F,QIAN B,LI J Z,et al.Highly efficient polypyrrole sensitized Ti O2nanotube films for photocathodic protection of Q235 carbon steel[J].Corrosion Science,2016,111:596-601.
[52]CUI S W,YIN X Y,YU Q L,et al.Polypyrrole nanowire/Ti O2nanotube nanocomposites as photoanodes for photocathodic protection of Ti substrate and 304 stainless steel under visible light[J].Corrosion Science,2015,98:471-477.
[53]LIU L,HU J M,LENG W H,et al.Novel bis-silane/Ti O2bifunctional hybrid films for metal corrosion protection both under ultraviolet irradiation and in the dark[J].Scripta Materialia,2007,57:549-552.