X荧光分析法测量不同人群头发中的重金属含量
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摘要
本工作按性格类型、年龄段、抽烟与否、染发与否、长期食用外卖与否对采样人群进行分组,用X荧光分析法测量了人发中重金属元素(Zn、Cu、Fe)的含量,分析了重金属元素在不同人群头发中的含量差异.结果表明:精确型性格人群头发内Zn元素含量显著高于外向型性格人群;头发内Zn元素含量随着人类年龄的增加大致呈现出先增加后减少的趋势,在20～30岁年龄段达到峰值;吸烟者和染发者头发内Zn元素含量偏低,Cu、Fe元素含量偏高.
This study aims to examine the differences of heavy metal content among different human's hair. The hair samples are measured by Energy Dispersive X-ray Fluorescence analysis(ED-XRF), which are divided into 15 groups according to volunteers' personality type, age and lifestyles. The results reveal: Accuracy personality people show significant higher content of Zinc in the hair than people from extroversion personality group; With the age increasing, the content of Zinc increases until forming a peak at 20-30 age group, and then the content of Zinc is falling down; It is found that the people smoking cigarette and having hair dyeing have higher Copper and Iron and lower Zinc on average but not significant.
This study aims to examine the differences of heavy metal content among different human's hair. The hair samples are measured by Energy Dispersive X-ray Fluorescence analysis(ED-XRF), which are divided into 15 groups according to volunteers' personality type, age and lifestyles. The results reveal: Accuracy personality people show significant higher content of Zinc in the hair than people from extroversion personality group; With the age increasing, the content of Zinc increases until forming a peak at 20-30 age group, and then the content of Zinc is falling down; It is found that the people smoking cigarette and having hair dyeing have higher Copper and Iron and lower Zinc on average but not significant.
引文
[1] Onuwa P O,Namonu L A,Eneji I S,et al.Analysis of heavy metals in human scalp hair using energy dispersive X-ray fluorescence technique [J].Journal of Analytical Science:Methods and Instrumentation,2012,2(4):187.
[2] Ryabukhin Y S.Nuclear-based methods for the analysis of trace element pollutants in human hair [J].Journal of Radio Analytical Chemistry,1980,60(1):7.
[3] 许涛,罗立强.铅锌矿区居民头发中Pb、Fe、Cu、Zn元素的SRXRF微区分布分析与来源分析 [J].核技术,2011,34(6):427.
[4] Skalny A V,Simashkova N V,Klyushnik T P.Assessment of serum trace elements and electrolytes in children with childhood and atypical autism [J].Journal of Trace Elements in Medicine & Biology,2016 (43):9.
[5] Bencko V.Use of human hair as a biomarker in the assessment of exposure to pollutants in occupational and environmental settings [J].Toxicology,1995,101(1-2):29.
[6] Srogi K.Hair Analysis as Method for Determination of Level of Drugs and Pharmaceutical in Human Body:Review of Chromatographic Procedures [J].Analytical Letters,2006,39(2):231.
[7] Srogi K.Testing for Drugs in Hair-a Review of Chromatographic Procedures [J].Microchimica Acta,2006,154(3-4):191.
[8] 杨炳忻,徐克尊,张芳,等.人发微量元素相关关系和判别疾病的初步研究 [J].核技术,1990,(9):540.
[9] 倪善芹,李瑞萍,王安建.赣东北德兴矿区周边女性居民头发中重金属分布特征 [J].中国环境监测,2012,28(2):84.
[10] 徐友宁,张江华,柯海玲,等.某金矿污染区人群头发重金属累积及其变化 [J].地质通报,2014,(7):1089.
[11] 尹庆顺,高玉芳.龋病患儿头发中微量元素含量分析 [J].山东医学高等专科学校校报,2006,26(6):435.
[12] Afridi H I,Brabazon D,Kazi T G,et al.Evaluation of essential trace and toxic elements in scalp hair samples of smokers and alcohol user hypertensive patients [J].Biological Trace Element Research,2011,143(3):1349.
[13] Serdar M A,Akin B S,Razi C,et al.The correlation between smoking status of family members and concentrations of toxic trace elements in the hair of children [J].Biological Trace Element Research,2012,148(1):11.
[14] 魏振林,芮玉奎,申琳.染发对头发中重金属含量的影响 [J].光谱学与光谱分析,2008,28(9):2187.
[15] 吉昂.X射线荧光光谱分析 [M].北京:科学出版社,2003.
[16] Glenn F K.辐射探测与测量 [M].李旭,译.北京:原子能出版社,1988.
[17] 黄近丹,郑荣华,张文芳,等.头发样的X射线荧光光谱的测定 [J].福建分析测试.1995,(3):330.
[18] Khudzari J M.Heavy metals Mn,Fe,Cu and Zn in human hair samples using energy dispersive X-ray fluorescence analysis [J].International Journal of the Physical Sciences,2011,6(8):2090.
[19] 李强,张学华.粉末压片-X射线荧光光谱法测定深海富铁粘土中主次量组分 [J].冶金分析,2018 (4):57.
[20] 王鑫,康明铭.X荧光分析法测定地表灰尘和空调灰中重金属含量 [J].物理学报,2018 (1):46.
[21] 钱翌,李少权.山东某大学116例学生头发中重金属含量调查 [J].职业与健康,2017,33(3):324.
[22] 汪月华,张平.乐安河流域儿童头发中微量元素中的调查与分析 [J].南昌航空工业学院学报,1997,(2):79.
[23] Liang G,Pan L,Liu X.Assessment of Typical Heavy Metals in Human Hair of Different Age Groups and Foodstuffs in Beijing,China.[J].International Journal of Environmental Research and Public Health,2017,14(8):914.
[24] 刘军,李晓雯.微量元素锌与人体健康 [J].中国热带医学,2003,3(1):64.
[2] Ryabukhin Y S.Nuclear-based methods for the analysis of trace element pollutants in human hair [J].Journal of Radio Analytical Chemistry,1980,60(1):7.
[3] 许涛,罗立强.铅锌矿区居民头发中Pb、Fe、Cu、Zn元素的SRXRF微区分布分析与来源分析 [J].核技术,2011,34(6):427.
[4] Skalny A V,Simashkova N V,Klyushnik T P.Assessment of serum trace elements and electrolytes in children with childhood and atypical autism [J].Journal of Trace Elements in Medicine & Biology,2016 (43):9.
[5] Bencko V.Use of human hair as a biomarker in the assessment of exposure to pollutants in occupational and environmental settings [J].Toxicology,1995,101(1-2):29.
[6] Srogi K.Hair Analysis as Method for Determination of Level of Drugs and Pharmaceutical in Human Body:Review of Chromatographic Procedures [J].Analytical Letters,2006,39(2):231.
[7] Srogi K.Testing for Drugs in Hair-a Review of Chromatographic Procedures [J].Microchimica Acta,2006,154(3-4):191.
[8] 杨炳忻,徐克尊,张芳,等.人发微量元素相关关系和判别疾病的初步研究 [J].核技术,1990,(9):540.
[9] 倪善芹,李瑞萍,王安建.赣东北德兴矿区周边女性居民头发中重金属分布特征 [J].中国环境监测,2012,28(2):84.
[10] 徐友宁,张江华,柯海玲,等.某金矿污染区人群头发重金属累积及其变化 [J].地质通报,2014,(7):1089.
[11] 尹庆顺,高玉芳.龋病患儿头发中微量元素含量分析 [J].山东医学高等专科学校校报,2006,26(6):435.
[12] Afridi H I,Brabazon D,Kazi T G,et al.Evaluation of essential trace and toxic elements in scalp hair samples of smokers and alcohol user hypertensive patients [J].Biological Trace Element Research,2011,143(3):1349.
[13] Serdar M A,Akin B S,Razi C,et al.The correlation between smoking status of family members and concentrations of toxic trace elements in the hair of children [J].Biological Trace Element Research,2012,148(1):11.
[14] 魏振林,芮玉奎,申琳.染发对头发中重金属含量的影响 [J].光谱学与光谱分析,2008,28(9):2187.
[15] 吉昂.X射线荧光光谱分析 [M].北京:科学出版社,2003.
[16] Glenn F K.辐射探测与测量 [M].李旭,译.北京:原子能出版社,1988.
[17] 黄近丹,郑荣华,张文芳,等.头发样的X射线荧光光谱的测定 [J].福建分析测试.1995,(3):330.
[18] Khudzari J M.Heavy metals Mn,Fe,Cu and Zn in human hair samples using energy dispersive X-ray fluorescence analysis [J].International Journal of the Physical Sciences,2011,6(8):2090.
[19] 李强,张学华.粉末压片-X射线荧光光谱法测定深海富铁粘土中主次量组分 [J].冶金分析,2018 (4):57.
[20] 王鑫,康明铭.X荧光分析法测定地表灰尘和空调灰中重金属含量 [J].物理学报,2018 (1):46.
[21] 钱翌,李少权.山东某大学116例学生头发中重金属含量调查 [J].职业与健康,2017,33(3):324.
[22] 汪月华,张平.乐安河流域儿童头发中微量元素中的调查与分析 [J].南昌航空工业学院学报,1997,(2):79.
[23] Liang G,Pan L,Liu X.Assessment of Typical Heavy Metals in Human Hair of Different Age Groups and Foodstuffs in Beijing,China.[J].International Journal of Environmental Research and Public Health,2017,14(8):914.
[24] 刘军,李晓雯.微量元素锌与人体健康 [J].中国热带医学,2003,3(1):64.
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