摘要
以Na_2SiO_3·9H_2O、FeCl_3为原料,应用共聚工艺制备PFSC (聚硅酸铁混凝剂),研究该混凝剂制备的Fe、Si物质的量的比、反应时间、反应温度对其混凝性能的影响。在相同投加量下对含藻水体的混凝处理结果表明,PFSC混凝剂对含藻水的叶绿素a、浊度的去除效果优于市售的PFC (聚合氯化铁)。
PFSC(polyferric silicate chloride) was prepared by copolymerization process with Na_2SiO_3·9 H_2O and FeCl_3 as raw materials. The effects of the molar ratio of Fe∶Si, reaction time and reaction temperature on the coagulation performance were studied.The results of coagulation treatment of algae-laden water at the same dosage showed that the removal effect of PFSC on chlorophyll a and turbidity of algae-laden water was better than that of PFC(polyferric chloride) sold in the market.
引文
[1]REDDY V,YARAPATHI S,REDDY M,et al.Polymer supported ferric chloride:regiospecific nucleophilic ring opening of epoxides[J].Reactive&functional polymers,2005(64):157-161.
[2]FU Y,YU S L.Characterization and coagulation performance of solidpoly-silicic ferric(PSF)coagulant[J].Journal of non-crystalline solids,2007(353):2206-2213.
[3]李靓,于衍真,谭娟,等.暖贴制备聚硅酸铁镁锌混凝剂及其对腐殖酸废水的处理[J].给水排水,2017,43(6):75-80.
[4]付英,于水利,杨园晶.聚硅酸制备的数学建模及聚铁混凝剂性能[J].哈尔滨工业大学学报,2010,42(2):212-217.
[5]卢涌泉,邓振华.实用红外光谱分析[M].北京:电子工业出版社,1989.