石墨烯在水处理中的应用
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摘要
石墨烯是一种具有独特的二维纳米结构、较大的比表面积和超高的导电率的新型炭材料,其在水处理方面的应用获得广泛的关注,研究取得较大进展。本文系统介绍了石墨烯材料的结构特点、制备方法及其在水处理方面的应用,主要包括在电容脱盐、吸附及过滤分离方向中的研究结果,总结了石墨烯作为水处理材料目前存在的问题,并对以后的研究发展和趋势作出了展望。
Graphene is an advanced carbon material with two-dimentional nanostructure, high specific surface area and high electrical conductivity. Benefiting from its structure, graphene has been attracted a lot of attention and regarded as an exciting material which can be used in the fields of water treatment. In this paper, the structural characteristics and preparation methods of graphene are introduced systematically, and its performance in water treatment, such as capacitive deionization, adsorption and filtration separation, are reviewed. At the end, the existing problems and the future development of graphene as the water treatment material are also put forward.
Graphene is an advanced carbon material with two-dimentional nanostructure, high specific surface area and high electrical conductivity. Benefiting from its structure, graphene has been attracted a lot of attention and regarded as an exciting material which can be used in the fields of water treatment. In this paper, the structural characteristics and preparation methods of graphene are introduced systematically, and its performance in water treatment, such as capacitive deionization, adsorption and filtration separation, are reviewed. At the end, the existing problems and the future development of graphene as the water treatment material are also put forward.
引文
[1]岳焕娟,孙红娟,彭同江.三维石墨烯材料的制备及在水处理中的应用研究进展[J].材料导报A:综述篇,2018,32(8):2601-2617.
[2]肖蓝,王祎龙,于水利.石墨烯及其复合材料在水处理中的应用[J].化学进展,2013,25(2/3):419-430.
[3]邓会,孙展鹏,张迎九.石墨烯材料在水处理中的应用:传质机制与吸附特性[J].科学通报,2015,60(33):3196-3209.
[4]Liu P,Yan T,Shi L.Graphene-based materials for capacitive deionization[J].Journal of Materials Chemistry A,2017,5(27):13907-13943.
[5]胡忠良,李雪锋,席柳江,等.石墨烯材料在水处理方面的研究进展[J].功能材料,2016,47(s1):1-6.
[6]于飞,孙怡然,王成显.多维度石墨烯材料在水处理中应用研究进展[J].中国材料进展,2018,37(2):109-126.
[7]邹禹涵.石墨烯材料在水处理中的应用进展研究[J].化工管理,2015(1):83-85.
[8]商辉,汪天也,张文慧,等.微波法制备石墨烯的研究进展[J].真空电子技术,2018(3):75-82.
[9]王金玉,黄志宇,吴洋.石墨烯及其复合材料在水处理方面的应用[J].应用化工,2017,46(11):2257-2261.
[10]孟海停.石墨烯及其衍生物在水处理中的研究进展[J].科技创新,2017(15):78.
[11]王学川,魏菲,李季.多孔体形石墨烯的构筑及其在水处理中的应用研究进展[J].陕西科技大学学报,2018,36(5):14-22.
[12]杨鸿鹰,张文存,高小媛.氧化石墨烯薄膜的制备及其在水处理应用中的研究进展[J].应用化工,2016,45(4):760-777.
[13]顾晓瑜.石墨烯复合材料的制备及其电容去离子化应用研究[D].广州:华南理工大学,2016.
[14]El-Deen A G,Choi J H,Kim C S,et al.TiO2nanorodintercalated reduced graphene oxide as high performance electrode material for membrane capacitive deionization[J].Desalination,2015,361:53-64.
[15]Li H,Lu T,Pan L.Electrosorption behavior of graphene in NaCl solutions[J].Journal of Materials Chemistry,2009,19(37):6773.
[16]Li Z,Song B,Wu Z,et al.3D porous graphene with ultrahigh surface area for microscale capacitive deionization[J].Nano Energy,2015(11):711-718.
[17]Xu X,Sun Z,Chua D H,et al.Novel nitrogen doped graphene sponge with ultrahigh capacitive deionization performance[J].Scientific Reports,2015,5:11225.
[18]熊传银.MnO2/石墨烯复合薄膜制备及作为超级电容器电极的研究[D].南京:南京邮电大学,2013.
[19]蔡棵.石墨烯及其复合材料在水处理中的应用[J].建材与装饰,2017(5):166-167.
[20]韩小伟,王英.水滑石及类水滑石材料的合成及应用新进展[J].江苏化工,2003,31(2):26-31.
[21]Yang J,Zou L,Song H.Preparing MnO2/PSS/CNTs composite electrodes by layer-by-layer deposition of MnO2in the membrane capacitive deionisation[J].Desalination,2012,286:108-114.
[22]吕莎莎,危晶,江峰,等.羧基化石墨烯对4种离子型染料的吸附脱色[J].应用化学,2013,30(10):1215-1221.
[23]顾斌,丁凡,陈淏燊.石墨烯及其复合材料作为吸附剂在水处理中的应用研究[J].化工新型材料,2017,45(9):17-19.
[24]Leng Y,Guo W,Su S,et al.Removal of antimony(III)from aqueous solution by graphene as an adsorbent[J].Chemical Engineering Journal,2012,211:406-411.
[25]Huang Z H,Zheng X,Lv W,et al.Adsorption of lead(IIions from aqueous solution on low-temperature exfoliated graphene nanosheets[J].Langmuir,2011,27(12):7558-7562.
[26]孙怡然,杨明轩,于飞.石墨烯气凝胶吸附剂的制备及其在水处理中的应用[J].化学进展,2015,27(8):1133-1146.
[27]Y Liu,X Cai,B Luo,et al.MnO2decorated on carbon sphere intercalated graphene film for high-performance supercapacitor electrodes[J].Carbon,2016,107:426-432.
[28]刘阳,顾平,张光辉.氧化石墨烯分离膜的制备及其水处理领域的应用进展[J].化工进展,2017,36:4151-4159.
[29]高晓琪,梁帅,曹俊.石墨烯在水处理膜改性中的研究与应用[J].环境科学与技术,2017,40(10):82-88
[2]肖蓝,王祎龙,于水利.石墨烯及其复合材料在水处理中的应用[J].化学进展,2013,25(2/3):419-430.
[3]邓会,孙展鹏,张迎九.石墨烯材料在水处理中的应用:传质机制与吸附特性[J].科学通报,2015,60(33):3196-3209.
[4]Liu P,Yan T,Shi L.Graphene-based materials for capacitive deionization[J].Journal of Materials Chemistry A,2017,5(27):13907-13943.
[5]胡忠良,李雪锋,席柳江,等.石墨烯材料在水处理方面的研究进展[J].功能材料,2016,47(s1):1-6.
[6]于飞,孙怡然,王成显.多维度石墨烯材料在水处理中应用研究进展[J].中国材料进展,2018,37(2):109-126.
[7]邹禹涵.石墨烯材料在水处理中的应用进展研究[J].化工管理,2015(1):83-85.
[8]商辉,汪天也,张文慧,等.微波法制备石墨烯的研究进展[J].真空电子技术,2018(3):75-82.
[9]王金玉,黄志宇,吴洋.石墨烯及其复合材料在水处理方面的应用[J].应用化工,2017,46(11):2257-2261.
[10]孟海停.石墨烯及其衍生物在水处理中的研究进展[J].科技创新,2017(15):78.
[11]王学川,魏菲,李季.多孔体形石墨烯的构筑及其在水处理中的应用研究进展[J].陕西科技大学学报,2018,36(5):14-22.
[12]杨鸿鹰,张文存,高小媛.氧化石墨烯薄膜的制备及其在水处理应用中的研究进展[J].应用化工,2016,45(4):760-777.
[13]顾晓瑜.石墨烯复合材料的制备及其电容去离子化应用研究[D].广州:华南理工大学,2016.
[14]El-Deen A G,Choi J H,Kim C S,et al.TiO2nanorodintercalated reduced graphene oxide as high performance electrode material for membrane capacitive deionization[J].Desalination,2015,361:53-64.
[15]Li H,Lu T,Pan L.Electrosorption behavior of graphene in NaCl solutions[J].Journal of Materials Chemistry,2009,19(37):6773.
[16]Li Z,Song B,Wu Z,et al.3D porous graphene with ultrahigh surface area for microscale capacitive deionization[J].Nano Energy,2015(11):711-718.
[17]Xu X,Sun Z,Chua D H,et al.Novel nitrogen doped graphene sponge with ultrahigh capacitive deionization performance[J].Scientific Reports,2015,5:11225.
[18]熊传银.MnO2/石墨烯复合薄膜制备及作为超级电容器电极的研究[D].南京:南京邮电大学,2013.
[19]蔡棵.石墨烯及其复合材料在水处理中的应用[J].建材与装饰,2017(5):166-167.
[20]韩小伟,王英.水滑石及类水滑石材料的合成及应用新进展[J].江苏化工,2003,31(2):26-31.
[21]Yang J,Zou L,Song H.Preparing MnO2/PSS/CNTs composite electrodes by layer-by-layer deposition of MnO2in the membrane capacitive deionisation[J].Desalination,2012,286:108-114.
[22]吕莎莎,危晶,江峰,等.羧基化石墨烯对4种离子型染料的吸附脱色[J].应用化学,2013,30(10):1215-1221.
[23]顾斌,丁凡,陈淏燊.石墨烯及其复合材料作为吸附剂在水处理中的应用研究[J].化工新型材料,2017,45(9):17-19.
[24]Leng Y,Guo W,Su S,et al.Removal of antimony(III)from aqueous solution by graphene as an adsorbent[J].Chemical Engineering Journal,2012,211:406-411.
[25]Huang Z H,Zheng X,Lv W,et al.Adsorption of lead(IIions from aqueous solution on low-temperature exfoliated graphene nanosheets[J].Langmuir,2011,27(12):7558-7562.
[26]孙怡然,杨明轩,于飞.石墨烯气凝胶吸附剂的制备及其在水处理中的应用[J].化学进展,2015,27(8):1133-1146.
[27]Y Liu,X Cai,B Luo,et al.MnO2decorated on carbon sphere intercalated graphene film for high-performance supercapacitor electrodes[J].Carbon,2016,107:426-432.
[28]刘阳,顾平,张光辉.氧化石墨烯分离膜的制备及其水处理领域的应用进展[J].化工进展,2017,36:4151-4159.
[29]高晓琪,梁帅,曹俊.石墨烯在水处理膜改性中的研究与应用[J].环境科学与技术,2017,40(10):82-88