Facultative ligands: structural studies of some mono- and binuclear complexes

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• 作者：Jong Won Shin ; Young Hoon Lee ; Mi Seon Won&#8230
• 关键词：Facultative ligands ; Functionalised Schiff ; bases ; Mono ; 聽and bi ; nuclear complexes ; Crystal structures
• 刊名：Journal of Inclusion Phenomena and Macrocyclic Chemistry
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：82
• 期：1-2
• 页码：235-245
• 全文大小：837 KB
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• 作者单位：Jong Won Shin (1)
  Young Hoon Lee (2)
  Mi Seon Won (3)
  Mihyun Kim (3)
  Cindy Mora (3)
  Pierre Thu茅ry (4)
  Jack Harrowfield (5)
  Yang Kim (3)
  
  1. Beamline Department, Pohang Accelerator Laboratory/POSTECH, 80 Jigokro-127-beongil, Nam-gu, Pohang, Gyeongbuk, 790-784, South Korea
  2. Department of Chemistry & EHSRC, University of Ulsan, 29 Mugeo-dong, Nam-gu, Ulsan, 680-749, South Korea
  3. Department of Chemistry & Advanced Materials, Kosin University, 194, Wachi-Ro, Yeongdo-gu, Busan, 606-701, South Korea
  4. CEA, IRAMIS, NIMBE, UMR 3299 CEA/CNRS, B芒t. 125, 91191, Gif-sur-Yvette, France
  5. ISIS, Universit茅 de Strasbourg, 8, all茅e Gaspard Monge, 67083, Strasbourg, France
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Organic Chemistry
  Food Science
  Crystallography
  
• 出版者：Springer Netherlands
• ISSN：1573-1111

文摘

Single crystal, X-ray structure determinations on several transition metal ion complexes of multidentate ligands involving hydroxyl-O, imine-N and heterocycle-N donor atoms have shown that both mononuclear and binuclear species can be formed, depending on the ligand, although the form obtained may depend simply upon the reaction stoichiometry. The structures have been analysed in terms of factors which may influence the complex ion nuclearity.