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Advanced purification and comprehensive utilization of yellow phosphorous off gas
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  • 作者:Ping Ning (1)
    Xiangyu Wang (1)

    1. Faculty of Environmental Science and Engineering
    ; Kunming University of Science and Technology ; Kunming ; 650500 ; China
  • 关键词:yellow phosphorous off gas ; purification ; comprehensive utilization
  • 刊名:Frontiers of Environmental Science & Engineering
  • 出版年:2015
  • 出版时间:April 2015
  • 年:2015
  • 卷:9
  • 期:2
  • 页码:181-189
  • 全文大小:202 KB
  • 参考文献:1. Wang X Q, Ning P, Chen W. Studies on purification of yellow phosphorus off-gas by combined washing, catalytic oxidation, and desulphurization at a pilot scale. Separation and Purification Technology, 2011, 80(3): 519鈥?25 CrossRef
    2. Yang L P, Yi H H, Tang X L, Ning P, Yu Q F, Ye Z Q. Effect of rare earth addition on Cu-Fe/AC adsorbents for phosphine adsorption from yellow phosphorous tail gas. Journal of Rare Earths, 2010, 28: 322鈥?25 CrossRef
    3. Ning P, Yi H H, Yu Q F, Tang X L, Yang L P, Ye Z Q. Effect of zinc and cerium addition on property of copper-based adsorbents for phosphine adsorption. Journal of Rare Earths, 2010, 28(4): 581鈥?86 CrossRef
    4. Fan Y P, Hu S Y, Chen D J, Li Y R, Shen J Z. The evolution of phosphorus metabolism model in China. Journal of Cleaner Production, 2009, 17(9): 811鈥?20 CrossRef
    5. Xiong H, Yang X L, Li X G. Removal of sulfur and phosphorus from tail gas of in yellow phosphorus production by sodium hypochlorite oxidation process, Environmental Protection of Chemical. Industry., 2002, 22(3): 161鈥?64
    6. Ning P, Bart H J, Wang X Q, Ma L P, Chen L. Removal of P4, PH3 and H2S from yellow phosphoric tail gas by catalytic oxidation process. Engineering and Science, 2005, 7(6): 27鈥?5
    7. Ning P, Wang X Y, Bart H J, Tian S L, Zhang Y, Wang X Q. Removal of phosphorus and sulfur from yellow phosphorous off gas by metal-modified activated carbon. Journal of Cleaner Production, 2011, 19(13): 1547鈥?552 CrossRef
    8. Quinn R, Dahl T A, Toseland B A. An evaluation of synthesis gas contaminants as methanol synthesis catalyst poisons. Applied Catalysis A, General, 2004, 272(1鈥?): 61鈥?8 CrossRef
    9. Sun H, Hankins N P, Azzopardi B J, Hilal N, Almeida C A P. A pilot-plant study of the adsorptive micellar flocculation process: optimum design and operation. Separation and Purification Technology, 2008, 62(2): 273鈥?80 CrossRef
    10. Chen S J. Comprehensive utilization of tail gas from phosphorus furnace. Phosphate and Compound Fertilizer, 2008, 23(1): 45鈥?8 (in Chinese)
    11. Ma L P, Ning P, Zhang Y Y, Wang X Q. Experimental and modeling of fixed-bed reactor for yellow phosphorous tail gas purification over impregnated activated carbon. Chemical Engineering Journal, 2008, 137(3): 471鈥?79 CrossRef
    12. Wang X Q, Ning P, Shi Y, Jiang M. Adsorption of low concentration phosphine in yellow phosphorus off-gas by impregnated activated carbon. Journal of Hazardous Materials, 2009, 171(1鈥?): 588鈥?93 CrossRef
    13. Danh N T, Teresa J B. Activated carbons with metal containing bentonite binders as adsorbents of hydrogen sulfide. Carbon, 2005, 43(2): 359鈥?67 CrossRef
    14. Gonchamva L V, Clowes S K, Fogg R R, Ermakov A V, Hinch B J. Phosphine adsorption and the production of phosphide phases on Cu (001). Surface Science, 2002, 515(2鈥?): 553鈥?66 CrossRef
    15. Xiao Y H, Wang S D, Wu D Y, Yuan Q. Experimental and simulation study of hydrogen sulfide adsorption on impregnated activated carbon under anaerobic conditions. Journal of Hazardous Materials, 2008, 153(3): 1193鈥?200 CrossRef
    16. Wang X Q, Ning P, Jiang M, Li Z Y, Yang Y H. Adsorption of low concentration H2S on impregnated activated carbon. Journal of Wuhan University of Technology, 2008, 30: 37鈥?0
    17. Ning P, Wang X Q, Wu M C, Chen L, Chen Y H, Pan K C, Wu Y. Purifying yellow phosphorous tail gas by caustic washing-catalytic oxidation. Chemical Engineering, 2004, 34(5): 61鈥?5
    18. Yi H H, Yu Q F, Tang X L, Ning P, Yang L P, Ye Z Q, Song J H. Phosphine adsorption removal from yellow phosphorus tail gas over CuO-ZnO-La2O3/activated carbon. Industrial & Engineering Chemistry Research, 2011, 50(7): 3960鈥?965 CrossRef
    19. Andrey B, Teresa J B. H2S adsorption/oxidation on unmodified activated carbons: importance of prehumidification. Carbon, 2001, 39(15): 2303鈥?311 CrossRef
    20. Bandosz T J. On the adsorption/oxidation of hydrogen sulfide on activated carbons at ambient temperatures. Journal of Colloid and Interface Science, 2002, 246(1): 1鈥?0 CrossRef
    21. Li W C, Bai H, Hsu J N, Li S N, Chen C. Metal loaded zeolite adsorbents for phosphine removal. Industrial & Engineering Chemistry Research, 2008, 47(5): 1501鈥?505 CrossRef
    22. Teresa J B. Effect of pore structure and surface chemistry of virgin activated carbons on removal of hydrogen sulfide. Carbon, 1999, 37(3): 483鈥?91 CrossRef
    23. Huang C C, Chen C H, Chu S M. Effect of moisture on H2S adsorption by copper impregnated activated carbon. Journal of Hazardous Materials, 2006, 136(3): 866鈥?73 CrossRef
    24. Itaya Y, Kawahara K, Lee C W, Kobayashi J, Kobayashi N, Hatano S, Mori S. Dry gas cleaning process by adsorption of H2S into activated cokes in gasification of carbon resources. Fuel, 2009, 88(9): 1665鈥?672 CrossRef
    25. Sakanishi K, Wu Z, Matsumura A, Saito I, Hanaoka T, Minowa T, Tada M, Iwasaki T. Simultaneous removal of H2S and COS using activated carbons and their supported catalysts. Catalysis Today, 2005, 104(1): 94鈥?00 CrossRef
    26. Wang L, Cao B, Wang S D, Quan Y. H2S catalytic oxidation on impregnated activated carbon: Experiment and modeling. Chemical Engineering Journal, 2006, 118(3): 133鈥?39 CrossRef
    27. Quintanilla A, Casas J A, Rodriguez J J. Catalytic wet air oxidation of phenol with modified activated carbons and Fe/activated carbon catalysts. Applied Catalysis B: Environmental, 2007, 76(1鈥?): 135鈥?45 CrossRef
    28. Xiao Y H, Wang S D, Wu D Y, Yuan Q. Catalytic oxidation of hydrogen sulfide over unmodified and impregnated activated carbon. Separation and Purification Technology, 2008, 59(3): 326鈥?32 CrossRef
  • 刊物主题:Environment, general;
  • 出版者:Springer Berlin Heidelberg
  • ISSN:2095-221X
文摘
Yellow phosphorous is an important raw material in the chemical industry. However, during the production of yellow phosphorous, high concentrations of carbon monoxide and other impurities are released. Without appropriate purification and removal, this off gas has potential to cause severe pollution problems once released. Purified yellow phosphorous off gas can be beneficially reused as a raw material in chemical production for synthesis of high value-added chemical reagents. In this paper, the significance of purification and reutilization of yellow phosphorous off gas are explored. The principles, processes, and main characteristics of the technologies for purification and reuse of yellow phosphorus off gas (including technical measurements of impurity reduction, relevant engineering cases, and public acceptance of the technologies) are summarized. In view of the existing problems and scientific development requirements, this paper proposes several recommendations for green production based on the concept of recycle economics. We conclude that advanced purification and comprehensive reutilization can be an effective solution for heavy pollution resulting from yellow phosphorous off gassing.

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