Synthesis of New Salt-Resistant Sulfonate Gemini Surfactants with Hydroxyl Groups

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• 作者：Ming Zhou (1) (2)
  Liangliang Xia (2)
  Yinglan He (3)
  Ling Zhang (2)
  Xin Qiao (2)
  Xiang Zhong (2)
  
  1. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation ; Southwest Petroleum University ; Chengdu ; 610500 ; Sichuan ; China
  2. School of Materials Science and Engineering ; Southwest Petroleum University ; Chengdu ; 610500 ; China
  3. Library ; Southwest Petroleum University ; Chengdu ; China
  
• 关键词：Synthesis ; Diglycidyl ether ; Sulfonate gemini surfactant ; Hydroxyl group ; Salt resistance
• 刊名：Journal of Surfactants and Detergents
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：18
• 期：2
• 页码：303-308
• 全文大小：268 KB
• 参考文献：1. Yang JP, Xie JY, Chen GM, Chen XC (2009) Surface, interfacial and aggregation properties of sulfonic acid-containing gemini surfactants with different spacer lengths. Langmuir 11:6100鈥?105 CrossRef
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  5. Zhou M, Zhong X, Zhao JZ, Wang X (2013) Synthesis and surface active properties of 1,1,1,1-tetra-(2-oxypropyl sulfonate-3-alkylether-propoxy) neopentanes. J Surfact Deterg 16:285鈥?90 CrossRef
  6. Zhu YP, Masuyama A, Okahara M (1990) Preparation and properties of double or triple chain surfactants with two sulfonate groups derived from / N-acyldiethanolamines. J Am Oil Chem Soc 67:459鈥?63 CrossRef
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  11. Kang HC, Lee BM, Yoon J, Yoon M (2000) Improvement of the phase-transfer catalysis method for synthesis of glycidyl ether. J Am Oil Chem Soc 78:423鈥?29 CrossRef
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Surfaces and Interfaces and Thin Films
  Polymer Sciences
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Analytical Chemistry
  Physical Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1558-9293

文摘

Though the gemini surfactants have unique properties, their high cost limits their scope of application. The new salt-resistant sulfonate gemini surfactants disodium 5,12-bis(alkyloxymethyl)-4,7,10,13-tetraoxa-2,15-dihydroxyhexadecane 1,16-disulfonates bearing two alkyl chains, two hydroxyl and two sulfonate groups were prepared from fatty alcohol, epichlorohydrin, glycol, sodium hydroxide, sodium bisulfite and sodium sulfite. Their synthesis exhibited the advantages of low raw material cost, mild reaction conditions and easy operation. The structures of prepared compounds were confirmed by FTIR and 1H NMR. These gemini surfactants show excellent surface-active properties, good salt resistance and excellent foaming ability.