Colloid and nanosized catalysts in organic synthesis: XII. Hydrogenation of carbonitriles catalyzed by nickel nanoparticles

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• 作者：V. M. Mokhov ; Yu. V. Popov ; K. V. Shcherbakova
• 关键词：catalysis ; nanoparticles ; nickel ; hydrogenation ; nitrile ; amine ; hydrogenolysis ; decyanation
• 刊名：Russian Journal of General Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：86
• 期：2
• 页码：273-280
• 全文大小：259 KB
• 参考文献：1.Popov, Yu.V., Mokhov, V.M., and Nebykov, D.N., Russ. J. Gen. Chem., 2016, vol. 86, no. 1, p. 43.CrossRef
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• 作者单位：V. M. Mokhov (1)
  Yu. V. Popov (1)
  K. V. Shcherbakova (1)
  
  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in isopropanol proceeds under atmospheric pressure of hydrogen within 6–15 h to yield mainly secondary amines. Hydrogenation of α-aminonitriles results in reductive decyanation. β-Aminonitriles undergo hydrogenolysis at the nitrogen–carbon bond.