A Study of Hydrogen Accumulation in Multiwall Carbon Nanotubes by Electrochemical Techniques

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• 作者：L. E. Tsygankova ; V. I. Vigdorovich…
• 刊名：Protection of Metals and Physical Chemistry of Surfaces
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：52
• 期：2
• 页码：211-217
• 全文大小：677 KB
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• 作者单位：L. E. Tsygankova (1)
  V. I. Vigdorovich (2)
  A. A. Zvereva (1)
  V. I. Kichigin (3)
  
  1. Derzhavin Tambov State University, ul. Internatsional’naya 33, Tambov, 392000, Russia
  2. All-Russian Scientific-Research Institute of Technics and Oil Products Usage in Agriculture, per. Novo-Rubezhnyi 28, Tambov, 392022, Russia
  3. Perm State University, Bukireva ul. 15, Perm, 614990, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Tribology, Corrosion and Coatings
  Materials Science
  Metallic Materials
  Inorganic Chemistry
  Industrial Chemistry and Chemical Engineering
  Characterization and Evaluation Materials
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：2070-206X

文摘

Accumulation of electrolytic hydrogen in alkaline medium (5 M KOH) by multiwall carbon nanotubes (MWCNTs) 20–60 nm in inner diameter and 2 μm in length obtained by catalytic pyrolysis of propane/butane mixture has been studied by means of the electrochemical diffusion technique, cyclic voltammetry, and impedance spectroscopy. MWCNTs were applied on a steel membrane and were encapsulated by a 10-nm electrolytic nickel layer. Cyclic voltammograms were recorded in the range of potentials from −1.2 to +0.2 V and contained a current peak in the cathode region corresponding to hydrogen absorption by nanotubes at −0.9 V and current peak in the anode region corresponding to oxidation of absorbed hydrogen at −0.6 V. Hydrogen storage capacity of MWCNTs varies from 4.6 to 6.5% depending on the amount of nanotubes according to electrochemical diffusion data. The electrochemical impedance data correlate with the results of the above methods.